| Common Name: | PTG-4449 |
| Manufacturer: | PRAXAIR |
| SDS Revision Date: | 2/19/2020 |
| SDS Format: | No Format Specified |
| Item Number(s): | 36T526 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PORTAGAS
BY PRAXAIR
PTG-4449
SAFETY DATA SHEET
PTG-4449
THIS SDS CONFORMS TO U.S. CODE OF FEDERAL REGULATIONS 29 CFR 1910.1200,
HAZARD COMMUNICATION. PREPARED FOR CANADA ACCORDING TO THE HAZARDOUS
PRODUCTS REGULATION (FEBRUARY 11, 2015).
DATE OF ISSUE: 02/06/2020
REVISION DATE: 02/19/2020
VERSION: 1.0
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: PTG-4449
FORMULA:
(0.0001 - 0.0999%) CARBON MONOXIDE, (0.0001 - 3.75%) METHANE, (19.5 -
23.5%) OXYGEN IN NITROGEN.
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: INDUSTRIAL USE; USE AS DIRECTED.
RECOMMENDED USE AND RESTRICTIONS ON USE: CALIBRATION / REFERENCE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
USA:
PRAXAIR DISTRIBUTION, INC. (PORTAGAS)
1202 E SAM HOUSTON PKWY S
PASADENA, TX 77503
T: +1 713-928-6477
F: +1 713-928-9961
PDIMSDS@PRAXAIR.COM
CANADA:
PRAXAIR CANADA INC.
1 CITY CENTRE DRIVE, SUITE 1200
MISSISSAUGA, ONTARIO, L5B 1M2
1-888-257-5149
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
ONSITE EMERGENCY: 1-800-645-4633
CHEMTREC, 24HR/DAY 7DAYS/WEEK - WITHIN USA:
1-800-424-9300, OUTSIDE USA: 001-703-527-3887 (COLLECT CALLS ACCEPTED,
CONTRACT 17729)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
PRESS. GAS (COMP.): H280
2.2. LABEL ELEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
GHS04: GAS CYLINDER
SIGNAL WORD (GHS US): WARNING
HAZARD STATEMENTS (GHS US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
CGA-HG24: SUPPORTS COMBUSTION.
PRECAUTIONARY STATEMENTS (GHS US):
P403: USE AND STORE ONLY OUTDOORS OR IN A WELL-VENTILATED PLACE.
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F).
CGA-PG12: DO NOT OPEN VALVE UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG21: OPEN VALVE SLOWLY.
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
CGA-PG11:
NEVER PUT CYLINDERS INTO UNVENTILATED AREAS OF PASSENGER VEHICLES.
CGA-PG27: READ AND FOLLOW THE SAFETY DATA SHEET (SDS) BEFORE USE.
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE.
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-CA CLASSIFICATION:
PRESS. GAS (COMP.): H280
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-CA LABELING:
HAZARD PICTOGRAMS:
GHS04: GAS CYLINDER
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED SUPPORTS COMBUSTION.
PRECAUTIONARY STATEMENTS:
USE AND STORE ONLY OUTDOORS OR IN A WELL-VENTILATED PLACE.
READ AND FOLLOW THE SAFETY DATA SHEET (SDS) BEFORE USE.
OPEN VALVE SLOWLY.
DO NOT OPEN VALVE UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE.
NEVER PUT CYLINDERS INTO UNVENTILATED AREAS OF PASSENGER VEHICLES.
USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F).
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. GET MEDICAL
ADVICE/ATTENTION.
AVOID BREATHING GAS, VAPORS
2.3. OTHER HAZARDS:
2.4. UNKNOWN ACUTE TOXICITY (GHS CA): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % COMMON NAME (SYNONYMS)
NITROGEN (CAS-NO.) 7727-37-9 72.65 - 100 NITROGEN GAS / NITROGEN /
NITROGEN, COMPRESSED
OXYGEN (CAS-NO.) 7782-44-7 19.5 - 23.5 OXYGEN (DISSOLVED) / OXYGEN
GAS / OXYGEN, COMPRESSED /
OXYGEN, DISSOLVED
METHANE (CAS-NO.) 74-82-8 0.0001 - 3.75 MARSH GAS / NATURAL GAS,
REFRIGERATED LIQUID /
METHANE, COMPRESSED
CARBON (CAS-NO.) 630-08-0 0.0001 - 0.1 CARBON MONOXIDE,
MONOXIDE COMPRESSED / COMPRESSED
CARBON MONOXIDE / CARBON
OXIDE (CO) / CARBON(II)
OXIDE / CARBON OXIDE
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES AFTER INHALATION:
REMOVE TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, TRAINED PERSONNEL SHOULD GIVE OXYGEN. CALL A PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. HOLD
THE EYELIDS OPEN AND AWAY FROM THE EYEBALLS TO ENSURE THAT ALL SURFACES ARE
FLUSHED THOROUGHLY. CONTACT AN OPHTHALMOLOGIST IMMEDIATELY.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO ADDITIONAL INFORMATION AVAILABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NONE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EVACUATE ALL PERSONNEL FROM THE DANGER AREA. USE SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND PROTECTIVE CLOTHING. IMMEDIATELY COOL CONTAINERS WITH
WATER FROM MAXIMUM DISTANCE. STOP FLOW OF GAS IF SAFE TO DO SO, WHILE
CONTINUING COOLING WATER SPRAY. REMOVE IGNITION SOURCES IF SAFE TO DO SO.
REMOVE CONTAINERS FROM AREA OF FIRE IF SAFE TO DO SO. ON-SITE FIRE BRIGADES
MUST COMPLY WITH OSHA 29 CFR 1910.156 AND APPLICABLE STANDARDS UNDER 29 CFR
1910 SUBPART L-FIRE PROTECTION.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL: NO ADDITIONAL INFORMATION AVAILABLE
6.1.2. FOR EMERGENCY RESPONDERS: NO ADDITIONAL INFORMATION AVAILABLE
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT WASTE FROM CONTAMINATING THE SURROUNDING ENVIRONMENT. PREVENT SOIL
AND WATER POLLUTION. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS. CONTACT SUPPLIER FOR ANY
SPECIAL REQUIREMENTS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
NO ADDITIONAL INFORMATION AVAILABLE
6.4. REFERENCE TO OTHER SECTIONS: SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WEAR LEATHER SAFETY GLOVES AND SAFETY SHOES WHEN HANDLING CYLINDERS.
PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL, SLIDE OR DROP.
WHILE MOVING CYLINDER, ALWAYS KEEP IN PLACE REMOVABLE VALVE COVER. NEVER
ATTEMPT TO LIFT A CYLINDER BY ITS CAP; THE CAP IS INTENDED SOLELY TO
PROTECT THE VALVE. WHEN MOVING CYLINDERS, EVEN FOR SHORT DISTANCES, USE A
CART (TROLLEY, HAND TRUCK, ETC.) DESIGNED TO TRANSPORT CYLINDERS. NEVER
INSERT AN OBJECT (E.G, WRENCH, SCREWDRIVER, PRY BAR) INTO CAP OPENINGS;
DOING SO MAY DAMAGE THE VALVE AND CAUSE A LEAK. USE AN ADJUSTABLE STRAP
WRENCH TO REMOVE OVER-TIGHT OR RUSTED CAPS. SLOWLY OPEN THE VALVE. IF THE
VALVE IS HARD TO OPEN, DISCONTINUE USE AND CONTACT YOUR SUPPLIER. CLOSE THE
CONTAINER VALVE AFTER EACH USE; KEEP CLOSED EVEN WHEN EMPTY. NEVER APPLY
FLAME OR LOCALIZED HEAT DIRECTLY TO ANY PART OF THE CONTAINER. HIGH
TEMPERATURES MAY DAMAGE THE CONTAINER AND COULD CAUSE THE PRESSURE RELIEF
DEVICE TO FAIL PREMATURELY, VENTING THE CONTAINER CONTENTS. FOR OTHER
PRECAUTIONS IN USING THIS PRODUCT, SEE SECTION 16.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN A COOL, WELL-VENTILATED PLACE. STORE AND USE WITH ADEQUATE
VENTILATION. STORE ONLY WHERE TEMPERATURE WILL NOT EXCEED 125 DEG. F (52
DEG. C). FIRMLY SECURE CONTAINERS UPRIGHT TO KEEP THEM FROM FALLING OR
BEING KNOCKED OVER. INSTALL VALVE PROTECTION CAP, IF PROVIDED, FIRMLY IN
PLACE BY HAND. STORE FULL AND EMPTY CONTAINERS SEPARATELY. USE A FIRST-IN,
FIRST-OUT INVENTORY SYSTEM TO PREVENT STORING FULL CONTAINERS FOR LONG
PERIODS.
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE:
WHEN HANDLING PRODUCT UNDER PRESSURE, USE PIPING AND EQUIPMENT ADEQUATELY
DESIGNED TO WITHSTAND THE PRESSURES TO BE ENCOUNTERED. NEVER WORK ON A
PRESSURIZED SYSTEM. USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING. GASES
CAN CAUSE RAPID SUFFOCATION BECAUSE OF OXYGEN DEFICIENCY; STORE AND USE
WITH ADEQUATE VENTILATION. IF A LEAK OCCURS, CLOSE THE CONTAINER VALVE AND
BLOW DOWN THE SYSTEM IN A SAFE AND ENVIRONMENTALLY CORRECT MANNER IN
COMPLIANCE WITH ALL INTERNATIONAL, FEDERAL/NATIONAL, STATE/PROVINCIAL, AND
LOCAL LAWS; THEN REPAIR THE LEAK. NEVER PLACE A CONTAINER WHERE IT MAY
BECOME PART OF AN ELECTRICAL CIRCUIT.
7.3. SPECIFIC END USE(S): NONE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PTG-4449:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
CARBON MONOXIDE (630-08-0):
ACGIH:
ACGIH TLV-TWA (PPM): 25 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 55 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
METHANE (74-82-8):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
OXYGEN (7782-44-7):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
NITROGEN (7727-37-9):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
CARBON MONOXIDE (630-08-0):
ACGIH:
ACGIH TLV-TWA (PPM): 25 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 55 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
IDLH:
US IDLH (PPM): 1200 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 40 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 35 PPM
NIOSH:
NIOSH REL (CEILING) (MG/M3): 229 MG/M3
NIOSH:
NIOSH REL (CEILING) (PPM): 200 PPM
ALBERTA:
OEL TWA (MG/M3): 29 MG/M3
ALBERTA:
OEL TWA (PPM): 25 PPM
BRITISH COLUMBIA:
OEL STEL (PPM): 100 PPM
BRITISH COLUMBIA:
OEL TWA (PPM): 25 PPM
MANITOBA:
OEL TWA (PPM): 25 PPM
NEW BRUNSWICK:
OEL TWA (MG/M3): 29 MG/M3
NEW BRUNSWICK:
OEL TWA (PPM): 25 PPM
NEWFOUNDLAND & LABRADOR:
OEL TWA (PPM): 25 PPM
NOVA SCOTIA:
OEL TWA (PPM): 25 PPM
NUNAVUT:
OEL STEL (MG/M3): 460 MG/M3
NUNAVUT:
OEL STEL (PPM): 190 PPM
NUNAVUT:
OEL TWA (MG/M3): 57 MG/M3
NUNAVUT:
OEL TWA (PPM): 25 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 190 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 25 PPM
ONTARIO:
OEL TWA (PPM): 25 PPM
PRINCE EDWARD ISLAND:
OEL TWA (PPM): 25 PPM
QUEBEC:
VECD (MG/M3): 230 MG/M3
QUEBEC:
VECD (PPM): 200 PPM
QUEBEC:
VEMP (MG/M3): 40 MG/M3
QUEBEC:
VEMP (PPM): 35 PPM
SASKATCHEWAN:
OEL STEL (PPM): 190 PPM
SASKATCHEWAN:
OEL TWA (PPM): 25 PPM
YUKON:
OEL STEL (MG/M3): 440 MG/M3
YUKON:
OEL STEL (PPM): 400 PPM
YUKON:
OEL TWA (MG/M3): 55 MG/M3
YUKON:
OEL TWA (PPM): 50 PPM
METHANE (74-82-8):
BRITISH COLUMBIA:
OEL TWA (PPM): 1000 PPM
NUNAVUT:
OEL STEL (PPM): 1250 PPM
NUNAVUT:
OEL TWA (PPM): 1000 PPM
NORTHWEST TERRITORIES:
OEL STEL (PPM): 1250 PPM
NORTHWEST TERRITORIES:
OEL TWA (PPM): 1000 PPM
SASKATCHEWAN:
OEL STEL (PPM): 1250 PPM
SASKATCHEWAN:
OEL TWA (PPM): 1000 PPM
NITROGEN (7727-37-9):
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. ENSURE EXPOSURE IS
BELOW OCCUPATIONAL EXPOSURE LIMITS (WHERE AVAILABLE).
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
EYE PROTECTION:
WEAR SAFETY GLASSES WHEN HANDLING CYLINDERS; VAPOR-PROOF GOGGLES AND A FACE
SHIELD DURING CYLINDER CHANGEOUT OR WHENEVER CONTACT WITH PRODUCT IS
POSSIBLE. SELECT EYE PROTECTION IN ACCORDANCE WITH OSHA 29 CFR 1910.133.
SELECT IN ACCORDANCE WITH THE CURRENT CSA STANDARD Z94.3, "INDUSTRIAL EYE
AND FACE PROTECTION", AND ANY PROVINCIAL REGULATIONS, LOCAL BYLAWS OR
GUIDELINES.
SKIN AND BODY PROTECTION:
WEAR METATARSAL SHOES AND WORK GLOVES FOR CYLINDER HANDLING, AND PROTECTIVE
CLOTHING WHERE NEEDED. WEAR APPROPRIATE CHEMICAL GLOVES DURING CYLINDER
CHANGEOUT OR WHEREVER CONTACT WITH PRODUCT IS POSSIBLE. SELECT PER OSHA 29
CFR 1910.132, 1910.136, AND 1910.138. SAFETY SHOES: SELECT IN ACCORDANCE
WITH THE CURRENT CSA STANDARD Z195, "PROTECTIVE FOOT WEAR", AND ANY
PROVINCIAL REGULATIONS, LOCAL BYLAWS OR GUIDELINES.
RESPIRATORY PROTECTION:
WHEN WORKPLACE CONDITIONS WARRANT RESPIRATOR USE, FOLLOW A RESPIRATORY
PROTECTION PROGRAM THAT MEETS OSHA 29 CFR 1910.134, ANSI Z88.2, OR MSHA 30
CFR 72.710 (WHERE APPLICABLE). USE AN AIR-SUPPLIED OR AIR-PURIFYING
CARTRIDGE IF THE ACTION LEVEL IS EXCEEDED. ENSURE THAT THE RESPIRATOR HAS
THE APPROPRIATE PROTECTION FACTOR FOR THE EXPOSURE LEVEL. IF CARTRIDGE TYPE
RESPIRATORS ARE USED, THE CARTRIDGE MUST BE APPROPRIATE FOR THE CHEMICAL
EXPOSURE. FOR EMERGENCIES OR INSTANCES WITH UNKNOWN EXPOSURE LEVELS, USE A
SELF-CONTAINED BREATHING APPARATUS (SCBA).
RESPIRATORY PROTECTION:
USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WORKING IN
CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE
BELOW TLV. SELECT IN ACCORDANCE WITH PROVINCIAL REGULATIONS, LOCAL BYLAWS
OR GUIDELINES. SELECTION SHOULD BE BASED ON THE CURRENT CSA STANDARD Z94.4,
"SELECTION, CARE, AND USE OF RESPIRATORS." RESPIRATORS SHOULD ALSO BE
APPROVED BY NIOSH AND MSHA. FOR EMERGENCIES OR INSTANCES WITH UNKNOWN
EXPOSURE LEVELS, USE A SELF-CONTAINED BREATHING APPARATUS (SCBA).
THERMAL HAZARD PROTECTION:
WEAR COLD INSULATING GLOVES WHEN TRANSFILLING OR BREAKING TRANSFER
CONNECTIONS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
COLOR: COLORLESS
ODOR: NO DATA AVAILABLE
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE.
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1):
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE.
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE.
VAPOR PRESSURE: NOT APPLICABLE.
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SOLUBILITY:
WATER: NO DATA AVAILABLE
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NOT APPLICABLE.
VISCOSITY, DYNAMIC: NOT APPLICABLE.
9.2. OTHER INFORMATION:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NONE.
10.4. CONDITIONS TO AVOID: NONE.
10.5. INCOMPATIBLE MATERIALS: NONE.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NONE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
CARBON MONOXIDE (630-08-0):
LC50 INHALATION RAT (PPM): 3760 PPM/1H
ATE US (GASES): 1880 PPMV/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: NO KNOWN ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.2. PERSISTENCE AND DEGRADABILITY:
PTG-4449:
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
PERSISTENCE AND DEGRADABILITY:
THE SUBSTANCE IS BIODEGRADABLE. UNLIKELY TO PERSIST.
OXYGEN (7782-44-7):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.3. BIOACCUMULATIVE POTENTIAL:
PTG-4449:
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
CARBON MONOXIDE (630-08-0):
LOG KOW: NOT APPLICABLE.
METHANE (74-82-8):
LOG POW: 1.09
BIOACCUMULATIVE POTENTIAL:
NOT EXPECTED TO BIOACCUMULATE DUE TO THE LOW LOG KOW (LOG KOW <4). REFER
TO SECTION 9.
OXYGEN (7782-44-7):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.4. MOBILITY IN SOIL:
PTG-4449:
MOBILITY IN SOIL: NO DATA AVAILABLE.
CARBON MONOXIDE (630-08-0):
MOBILITY IN SOIL: NO DATA AVAILABLE.
METHANE (74-82-8):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND OR
WATER POLLUTION.
OXYGEN (7782-44-7):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER: NONE.
EFFECT ON THE GLOBAL WARMING:
CONTAINS GREENHOUSE GAS(ES) NOT COVERED BY 842/2006/EC.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
PRODUCT/PACKAGING DISPOSAL RECOMMENDATIONS:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED QUANTITIES. RETURN
CONTAINER TO SUPPLIER.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1956 COMPRESSED GAS, N.O.S., 2.2
UN-NO.(DOT): UN1956
PROPER SHIPPING NAME (DOT): COMPRESSED GAS, N.O.S.
CLASS (DOT): 2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
DOT PACKAGING NON BULK (49 CFR 173.XXX): 302;305
DOT PACKAGING BULK (49 CFR 173.XXX): 314;315
DOT SYMBOLS:
G - IDENTIFIES PROPER SHIPPING NAME (PSN) REQUIRING THE ADDITION OF
TECHNICAL NAME(S) IN PARENTHESES FOLLOWING THE PSN.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 306;307
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 172.101 HMT,
COLUMN 9A): 75 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 172.101 HMT, COLUMN
9B): 150 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
ADDITIONAL INFORMATION:
EMERGENCY RESPONSE GUIDE (ERG) NUMBER: 126
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY. BEFORE TRANSPORTING PRODUCT CONTAINERS: - ENSURE THERE IS
ADEQUATE VENTILATION. - ENSURE THAT CONTAINERS ARE FIRMLY SECURED. - ENSURE
CYLINDER VALVE IS CLOSED AND NOT LEAKING. - ENSURE VALVE OUTLET CAP NUT OR
PLUG (WHERE PROVIDED) IS CORRECTLY FITTED. - ENSURE VALVE PROTECTION DEVICE
(WHERE PROVIDED) IS CORRECTLY FITTED.
IN ACCORDANCE WITH TDG:
TRANSPORTATION OF DANGEROUS GOODS:
UN-NO. (TDG): UN1956
PROPER SHIPPING NAME (TRANSPORTATION OF DANGEROUS GOODS):
COMPRESSED GAS, N.O.S.
TDG PRIMARY HAZARD CLASSES:
2.2 - CLASS 2.2 - NON-FLAMMABLE, NON-TOXIC GAS.
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 0.125L
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER CARRYING RAILWAY VEHICLE
INDEX: 75 L
TRANSPORT BY SEA:
UN-NO. (IMDG): 1956
PROPER SHIPPING NAME (IMDG): COMPRESSED GAS, N.O.S.
CLASS (IMDG): 2 - GASES
LIMITED QUANTITIES (IMDG): 120ML
EMS-NO. (1): F-C
MFAG-NO: 620
EMS-NO. (2): S-V
AIR TRANSPORT:
UN-NO. (IATA): 1956
PROPER SHIPPING NAME (IATA): COMPRESSED GAS, N.O.S.
CLASS (IATA): 2
INSTRUCTION "CARGO" (ICAO): 200
INSTRUCTION "PASSENGER" (ICAO): 200
INSTRUCTION "PASSENGER" - LIMITED QUANTITIES (ICAO): FORBIDDEN
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
CARBON MONOXIDE (630-08-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
METHANE (74-82-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
OXYGEN (7782-44-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
NITROGEN (7727-37-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
CARBON MONOXIDE (630-08-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
METHANE (74-82-8): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
OXYGEN (7782-44-7): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS C - OXIDIZING MATERIAL
NITROGEN (7727-37-9): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION: CLASS A - COMPRESSED GAS
EU-REGULATIONS:
CARBON MONOXIDE (630-08-0):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
METHANE (74-82-8):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NITROGEN (7727-37-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
PRESS. GAS (COMP.) H280
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
CARBON MONOXIDE (630-08-0):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE JAPANESE ISHL (INDUSTRIAL SAFETY AND HEALTH LAW)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
LISTED ON INSQ (MEXICAN NATIONAL INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON THE TCSI (TAIWAN CHEMICAL SUBSTANCE INVENTORY)
METHANE (74-82-8):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON INSQ (MEXICAN NATIONAL INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON CICR (TURKISH INVENTORY AND CONTROL OF CHEMICALS)
OXYGEN (7782-44-7):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON INSQ (MEXICAN NATIONAL INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON THE TCSI (TAIWAN CHEMICAL SUBSTANCE INVENTORY)
NITROGEN (7727-37-9):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON INSQ (MEXICAN NATIONAL INVENTORY OF CHEMICAL SUBSTANCES)
15.3. US STATE REGULATIONS:
CARBON MONOXIDE (630-08-0):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL)
CARBON MONOXIDE (630-08-0):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
METHANE (74-82-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
OXYGEN (7782-44-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
NITROGEN (7727-37-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 02/19/2020
OTHER INFORMATION:
WHEN YOU MIX TWO OR MORE CHEMICALS, YOU CAN CREATE ADDITIONAL, UNEXPECTED
HAZARDS. OBTAIN AND EVALUATE THE SAFETY INFORMATION FOR EACH COMPONENT
BEFORE YOU PRODUCE THE MIXTURE. CONSULT AN INDUSTRIAL HYGIENIST OR OTHER
TRAINED PERSON WHEN YOU EVALUATE THE END PRODUCT. BEFORE USING ANY
PLASTICS, CONFIRM THEIR COMPATIBILITY WITH THIS PRODUCT.
PRAXAIR ASKS USERS OF THIS PRODUCT TO STUDY THIS SDS AND BECOME AWARE OF
THE PRODUCT HAZARDS AND SAFETY INFORMATION. TO PROMOTE SAFE USE OF THIS
PRODUCT, A USER SHOULD (1) NOTIFY EMPLOYEES, AGENTS, AND CONTRACTORS OF THE
INFORMATION IN THIS SDS AND OF ANY OTHER KNOWN PRODUCT HAZARDS AND SAFETY
INFORMATION, (2) FURNISH THIS INFORMATION TO EACH PURCHASER OF THE PRODUCT,
AND (3) ASK EACH PURCHASER TO NOTIFY ITS EMPLOYEES AND CUSTOMERS OF THE
PRODUCT HAZARDS AND SAFETY INFORMATION.
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN
PRAXAIR, INC. WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS CURRENT
AS OF THE DATE OF THIS SAFETY DATA SHEET. SINCE THE USE OF THIS INFORMATION
AND THE CONDITIONS OF USE ARE NOT WITHIN THE CONTROL OF PRAXAIR, INC, IT IS
THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE
PRODUCT.
PRAXAIR SDSS ARE FURNISHED ON SALE OR DELIVERY BY PRAXAIR OR THE
INDEPENDENT DISTRIBUTORS AND SUPPLIERS WHO PACKAGE AND SELL OUR PRODUCTS.
TO OBTAIN CURRENT SDSS FOR THESE PRODUCTS, CONTACT YOUR PRAXAIR SALES
REPRESENTATIVE, LOCAL DISTRIBUTOR, OR SUPPLIER, OR DOWNLOAD FROM
WWW.PRAXAIR.COM. IF YOU HAVE QUESTIONS REGARDING PRAXAIR SDSS, WOULD LIKE
THE DOCUMENT NUMBER AND DATE OF THE LATEST SDS, OR WOULD LIKE THE NAMES OF
THE PRAXAIR SUPPLIERS IN YOUR AREA, PHONE OR WRITE THE PRAXAIR CALL CENTER
(PHONE: 1-800-PRAXAIR/1- 800-772-9247; ADDRESS: PRAXAIR CALL CENTER,
PRAXAIR, INC, P.O. BOX 44, TONAWANDA, NY 14151-0044).
PRAXAIR AND THE FLOWING AIRSTREAM DESIGN ARE TRADEMARKS OR REGISTERED
TRADEMARKS OF PRAXAIR TECHNOLOGY, INC. IN THE UNITED STATES AND/OR OTHER
COUNTRIES.
SDS US_AND_CANADA
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT.
PRAXAIR AND THE FLOWING AIRSTREAM DESIGN ARE TRADEMARKS OR REGISTERED
TRADEMARKS OF PRAXAIR TECHNOLOGY, INC. IN THE UNITED STATES AND/OR OTHER
COUNTRIES.
EN (ENGLISH US)
SDS ID: PTG-4449