| Common Name: | WATERTITE 10.1-OZ 12 PK POLYURETHAN SLR, 5091 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 7/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 36VM22 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
DATE PRINTED: 7/7/2015
| 1. IDENTIFICATION |  |
PRODUCT NAME: WATERTITE 10.1-OZ 12 PK POLYURETHAN SLR
PRODUCT IDENTIFIER: 5091
PRODUCT USE/CLASS: SEALANT/ POLYURETHANE
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
REVISION DATE: 7/7/2015
SUPERCEDES DATE: NEW SDS
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
SIGNAL WORD: NO SIGNAL WORD HAS BEEN ASSIGNED.
GHS ADDITIONAL INFORMATION:
H362:
CONTAINS ONE OR MORE CATEGORY 1 OR CATEGORY 2 REPRODUCTIVE TOXICANTS AT
GREATER THAN 0.1%. A SAFETY DATA SHEET SHALL BE AVAILABLE FOR THE MIXTURE
UPON REQUEST.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% RANGE
NONYLPHENOL BRANCHED POLYURETHANE PROPRIETARY 25-50
LIMESTONE 1317-65-3 10-25
CALCIUM SULFATE 7778-18-9 10-25
CASTOR OIL DERIVATIVE PROPRIETARY 2.5-10
POLYAMINE PROPRIETARY 1.0-2.5
HYDROTREATED LIGHT DISTILLATE 64742-47-8 1.0-2.5
MINERAL OIL 8042-47-5 1.0-2.5
TOLUENE 108-88-3 1.0-2.5
TITANIUM DIOXIDE 13463-67-7 1.0-2.5
DIISODECYL PHTHALATE 26761-40-0 0.1-1.0
METHYL ISOBUTYL KETONE 108-10-1 0.1-1.0
CRYSTALLINE SILICA / QUARTZ 14808-60-7 0.1-1.0
CHEMICAL NAME GHS SYMBOLS GHS STATEMENTS
NONYLPHENOL BRANCHED POLYURETHANE NO INFORMATION NO INFORMATION
LIMESTONE NO INFORMATION NO INFORMATION
CALCIUM SULFATE NO INFORMATION NO INFORMATION
CASTOR OIL DERIVATIVE NO INFORMATION NO INFORMATION
POLYAMINE NO INFORMATION NO INFORMATION
HYDROTREATED LIGHT DISTILLATE GHS06-GHS08 H304-331
MINERAL OIL NO INFORMATION NO INFORMATION
TOLUENE GHS02-GHS07- H225-302-304-315-
GHS08 332-336-361-373
TITANIUM DIOXIDE NO INFORMATION NO INFORMATION
DIISODECYL PHTHALATE GHS07 H332
METHYL ISOBUTYL KETONE GHS02-GHS06 H225-319-331-335
CRYSTALLINE SILICA / QUARTZ GHS07 H302
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES
OR KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, RINSE MOUTH WITH WATER. IF FEELING UNWELL, GET MEDICAL
ATTENTION. SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM.
FOR LARGER AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF
WATER TO DRINK AND GET MEDICAL ATTENTION. IF SWALLOWED, INDUCE VOMITING
IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
KEEP CONTAINERS TIGHTLY CLOSED. FLASH POINT IS TESTED TO BE GREATER THAN
200 DEGREES F. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM.
IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IF SPILLED, CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
NONYLPHENOL BRANCHED POLYURETHANE PROPRIETARY 40.0
LIMESTONE 1317-65-3 15.0
CALCIUM SULFATE 7778-18-9 15.0
CASTOR OIL DERIVATIVE PROPRIETARY 10.0
POLYAMINE PROPRIETARY 5.0
HYDROTREATED LIGHT DISTILLATE 64742-47-8 5.0
MINERAL OIL 8042-47-5 5.0
TOLUENE 108-88-3 5.0
TITANIUM DIOXIDE 13463-67-7 5.0
DIISODECYL PHTHALATE 26761-40-0 1.0
METHYL ISOBUTYL KETONE 108-10-1 1.0
CRYSTALLINE SILICA / QUARTZ 14808-60-7 0.1
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
NONYLPHENOL BRANCHED N.E. N.E. N.E. N.E.
POLYURETHANE
LIMESTONE N.E. N.E. 15 MG/M3 N.E.
CALCIUM SULFATE 10 MG/M3 N.E. 15 MG/M3 N.E.
CASTOR OIL DERIVATIVE N.E. N.E. N.E. N.E.
POLYAMINE N.E. N.E. N.E. N.E.
HYDROTREATED LIGHT N.E. N.E. N.E. N.E.
DISTILLATE
MINERAL OIL N.E. N.E. N.E. N.E.
TOLUENE 20 PPM N.E. 200 PPM 300 PPM
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
DIISODECYL PHTHALATE N.E. N.E. N.E. N.E.
METHYL ISOBUTYL 20 PPM 75 PPM 100 PPM N.E.
KETONE
CRYSTALLINE 0.025 MG/M3 N.E. N.E. N.E.
SILICA / QUARTZ
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS
AND WINDOWS TO ACHIEVE CROSSVENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: GEL/PASTE
PHYSICAL STATE: PASTE
ODOR: MILD
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.278
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: NO INFORMATION
SOLUBILITY IN WATER: NEGLIGIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSTION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: 111 - 3,000
EXPLOSIVE LIMITS, VOL%: 0.6 - 7.0
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 94
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
CONTAINS SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND
FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY:
THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS. MAY FORM
PEROXIDES OF UNKOWN STABILITY.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
MAY BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. LOW HAZARD FOR USUAL
INDUSTRIAL HANDLING OR COMMERCIAL HANDLING BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST.
EFFECTS OF OVEREXPOSURE - INGESTION:
SUBSTANCE MAY BE HARMFUL IF SWALLOWED. MAY CAUSE OBSTRUCTION IN STOMACH,
AS IT HARDENS WITH MOISTURE. SYMPTOMS INCLUDE STOMACH PAIN, DISTRESS.
DRINKING GLYCERIN, GELATIN SOLUTIONS, OR LARGE VOLUMES OF WATER MAY
DELAY THE HARDENING OF CALCIUM SULFATE IN THE STOMACH. SURGICAL RELIEF OF
OBSTRUCTION, PARTICULARLY AT THE PYLORUS, MAY BE NECESSARY.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-
"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO
TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH
TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING
BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST
AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA.
(REF: IARC MONOGRAPH, VOL. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON
INDIVIDUAL COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
7778-18-9 CALCIUM SULFATE >3000 MG/KG N.I. N.I.
RAT
64742-47-8 HYDROTREATED LIGHT >5000 MG/KG >2000 MG/KG >5.2 MG/L
DISTILLATE RAT RABBIT RAT
8042-47-5 MINERAL OIL >5000 MG/KG N.I. N.I.
RAT
108-88-3 TOLUENE 636 MG/KG 8390 MG/KG 12.5 MG/L
RAT RABBIT RAT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG N.I. N.I.
RAT
26761-40-0 DIISODECYL 64000 MG/KG >3160 MG/KG >12.54 MG/L
PHTHALATE RAT RABBIT RAT
108-10-1 METHYL ISOBUTYL 2080 MG/KG >16000 MG/KG 8.2 MG/L
KETONE RAT RABBIT RAT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR TDG
(USDOT) (IMDG) (IATA) (CANADA)
UN NUMBER N.A. N.A. N.A. N.A.
PROPER SHIPPING NAME NOT NOT NOT NOT
REGULATED REGULATED REGULATED REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, REACTIVE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
TOLUENE 108-88-3
METHYL ISOBUTYL KETONE 108-10-1
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
VOLATILE ORGANIC COMPOUNDS, G/L: 57
MSDS REVISION DATE: 7/7/2015
REASON FOR REVISION:
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE
AS OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS
OF HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL,
WE ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION
MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR
RELIABILITY OF THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS
MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE
INFORMATION AND RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE
OFFERED FOR THE USERS' CONSIDERATION AND EXAMINATION. IT IS THE
RESPONSIBILITY OF THE USER TO DETERMINE THE FINAL SUITABILITY OF THIS
INFORMATION AND TO COMPLY WITH ALL APPLICABLE INTERNATIONAL, FEDERAL,
STATE, AND LOCAL LAWS AND REGULATIONS.