| Common Name: | TOUGH GUY DISINFECTING ALL-PURPOSE SPRAY |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 4/30/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 36XX41 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
DATE PREPARED: 04/30/2015
SDS NO: W.W. GRAINGER INC._DISINFECTING ALL-PURPOSE SPRAY
TOUGH GUY DISINFECTING ALL-PURPOSE SPRAY
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY DISINFECTING ALL-PURPOSE SPRAY
GENERAL USE: READY TO USE DISINFECTANT CLEANER
PRODUCT DESCRIPTION: DISINFECTING GLASS & MULTI-SURFACE CLEANER
CHEMICAL FAMILY: ALCOHOL/QUATERNARY AMMONIUM CHLORIDE
MANUFACTURED FOR:
W.W. GRAINGER INC.
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
CUSTOMER SERVICE: 800-472-4643
EPA REG. NO.: 10324-85-10637
24 HR. EMERGENCY TELEPHONE NUMBERS:
CHEM-TEL (MEDICAL AND TRANSPORTATION): 800-255-3924
POISON CONTROL CENTER (MEDICAL): 800-222-1222
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATIONS:
HEALTH:
SKIN IRRITATION: CATEGORY 3
EYE IRRITATION: CATEGORY 2B
GHS LABEL:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H320: CAUSES EYE IRRITATION.
H316: CAUSES MILD SKIN IRRITATION.
H303: MAY BE HARMFUL IF SWALLOWED.
PRECAUTIONARY STATEMENT(S):
PREVENTION:
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P234: KEEP ONLY IN ORIGINAL PACKAGING.
RESPONSE:
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
P405: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER ACCORDING TO ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
EMERGENCY OVERVIEW:
PHYSICAL APPEARANCE: BLUE LIQUID
IMMEDIATE CONCERNS: MODERATE EYE IRRITANT.
POTENTIAL HEALTH EFFECTS:
EYES: CONTACT CAUSES EYE IRRITATION.
SKIN: MAY BE MILDLY IRRITATING WITH PROLONGED OR REPEATED CONTACT.
SKIN ABSORPTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: HARMFUL IF SWALLOWED.
REPRODUCTIVE TOXICITY:
TERATOGENIC EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
ROUTES OF ENTRY: EYE, SKIN, INGESTION.
WARNING CAUTION LABELS: IRRITANT
PHYSICAL HAZARDS: NONE EXPECTED.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME WT.% CAS
ALKYL DIMETHYLBENZYL AMMONIUM CHLORIDE(C12-C16) 0.034 68424-85-1
OCTYL DECYL DIMETHYL AMMONIUM CHLORIDE 0.026 32426-11-2
DIOCTYL DIMETHYL AMMONIUM CHLORIDE 0.013 5538-94-3
DIDECYL DIMETHYL AMMONIUM CHLORIDE 0.013 7173-51-5
ISOPROPANOL 0 - 2 67-63-0
MONOETHANOLAMINE 0 - 1 141-43-5
DYE <0.1 N/A
FRAGRANCE <1 N/A
WATER 90 7732-18-5
| 4. FIRST AID MEASURES | |
EYES:
IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES, WHILE HOLDING
EYELIDS OPEN. REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5
MINUTES, THEN CONTINUE RINSING EYE. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN:
REMOVE CONTAMINATED CLOTHING. IMMEDIATELY FLUSH WITH WATER FOLLOWED BY
WASHING WITH MILD SOAP. SEEK MEDICAL ATTENTION.
INGESTION:
GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS INSTRUCTED
TO DO SO BY POISON CENTER OR PHYSICIAN.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND MONITOR. SEEK MEDICAL ADVISE IF IRRITATION
PERSISTS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
EYES: BURNING SENSATION WITH TEARS, REDNESS.
SKIN: REDNESS AND ITCHING SENSATION.
INGESTION:
IRRITATION OF MOUTH, THROAT, ALONG WITH STOMACH UPSET, VOMITING.
INHALATION:
IRRITATION OF NOSE, THROAT AND LUNGS WITH COUGHING, SNEEZING, POSSIBLE
DIFFICULTY BREATHING.
ACUTE TOXICITY: IRRITATING TO EYES, MILD SKIN IRRITATION.
| 5. FIRE FIGHTING MEASURES | |
FLAMMABLE CLASS: NONE
EXTINGUISHING MEDIA: NOT REQUIRED.
EXPLOSION HAZARDS: NONE
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE:
CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES.
| 6. ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS.
LARGE SPILL:
AVOID WALKING IN MATERIAL. PREVENT PRODUCT FROM ENTERING INTO STREAM,
SOIL, STORM SEWER OR OTHER BODIES OF WATER.
ENVIRONMENTAL PRECAUTIONS:
WATER SPILL: AVOID DISCHARGES INTO OPEN WATERWAYS.
LAND SPILL: AVOID DISCHARGE TO SOIL.
AIR SPILL:
NA = NOT APPLICABLE
GENERAL PROCEDURES:
ISOLATE SPILL OR LEAK AREA IMMEDIATELY. KEEP UNAUTHORIZED PERSONNEL AWAY.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. PREVENT ENTRY INTO
WATERWAYS, SEWERS, OR CONFINED AREAS. ABSORB WITH DRY EARTH, SAND OR OTHER
NONCOMBUSTIBLE MATERIAL AND TRANSFER TO CONTAINERS.
RELEASE NOTES: PRODUCT IS TOXIC TO FISH AND AQUATIC INVERTEBRATES.
SPECIAL PROTECTIVE EQUIPMENT:
EYE PROTECTION, RUBBER GLOVES, RUBBER BOOTS TO PROTECT FEET.
| 7. HANDLING AND STORAGE | |
GENERAL PROCEDURES:
DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL.
HANDLING:
AVOID CONTACT WITH SKIN AND EYES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES.
STORAGE:
STORE ONLY IN ORIGINAL CONTAINER. DO NOT REUSE EMPTY CONTAINER. IF A LEAKY
CONTAINER MUST BE CONTAINED WITHIN ANOTHER, MARK THE OUTER CONTAINER TO
IDENTIFY THE CONTENTS. STORE PESTICIDES AWAY FROM FOOD, PET FOOD, FEED,
AND WATER SOURCES.KEEP THIS PRODUCT UNDER LOCKED STORAGE SUFFICIENT TO
MAKE IT INACCESSIBLE TO CHILDREN OR PERSONS UNFAMILIAR WITH ITS PROPER
USE.
STORAGE TEMPERATURE: STORE AT AMBIENT TEMPERATURES.
STORAGE PRESSURE: STORE AT AMBIENT ATMOSPHERIC PRESSURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
CHEMICAL NAME OSHA PEL ACGIH TLV SUPPLIER OEL
PPM MG/M3 PPM MG/M3 PPM MG/M3
ISOPROPANOL TWA 400 980 200 490 NL NL
STEL 400 960 NL NL
MONOETHANOLAMINE TWA 3 6 3 7.5 NL NL
STEL 6 15 NL NL
PERSONAL PROTECTIVE EQUIPMENT:
EYES AND FACE: SAFETY GLASSES WITH SIDE SHIELDS.
SKIN: RUBBER OR OTHER CHEMICAL RESISTANT GLOVES.
RESPIRATORY:
A RESPIRATOR IS NOT NEEDED UNDER NORMAL AND INTENDED CONDITIONS OF PRODUCT
USE.
WORK HYGIENIC PRACTICES:
WASH WITH SOAP AND WATER AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHILE
USING PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
ODOR: CLEAN & FRESH
ODOR THRESHOLD: NOT ESTABLISHED
COLOR: LIGHT BLUE
PH: 10.0 TO 11.5
PERCENT VOLATILE: >98
FLASH POINT AND METHOD: NONE
FLAMMABLE LIMITS: N/A
AUTOIGNITION TEMPERATURE:
NA = NOT APPLICABLE
VAPOR PRESSURE: 20 MM HG AT (68 DEG. F)
VAPOR DENSITY: APPROX. 1 AIR = 1
BOILING POINT:
212 DEG. F
100 DEG. C
FREEZING POINT:
32 DEG. F
0 DEG. C
THERMAL DECOMPOSITION: NOT AVAILABLE
SOLUBILITY IN WATER: COMPLETE
EVAPORATION RATE: (WATER =1) 1.0
DENSITY: 8.29 AT 20 DEG. C (68 DEG. F)
SPECIFIC GRAVITY: 0.998 GRAMS/ML. AT 20 DEG. C (68 DEG. F)
VISCOSITY: WATER THIN.
(VOC): 2.500 % BY WEIGHT
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: NOT ESTABLISHED
HAZARDOUS DECOMPOSITION PRODUCTS: NONE EXPECTED.
INCOMPATIBLE MATERIALS: STRONG OXIDIZERS
| 11. TOXICOLOGICAL INFORMATION | |
CHEMICAL NAME ORAL DERMAL INHALATION
LD50 LD50 LC50
(RAT) (RABBIT) (RAT)
ALKYL DIMETHYLBENZYL 450 MG/KG 3342 MG/KG
AMMONIUM CHLORIDE(C12-C16) (RAT) (RABBIT)
OCTYL DECYL DIMETHYL 200 TO 2000 NOT AVAILABLE
AMMONIUM CHLORIDE MG/KG (RAT)
DIOCTYL DIMETHYL 50 MG/KG NOT AVAILABLE
AMMONIUM CHLORIDE (MOUSE)
DIDECYL DIMETHYL 268 MG/KG 2730 MG/KG
AMMONIUM CHLORIDE (MOUSE) (RABBIT)
ISOPROPANOL 5045 MG/KG 12800 MG/KG 16000 PPM
(RAT) (RABBIT)
MONOETHANOLAMINE 1089 MG/KG 2504 MG/KG APPROX. 1.48
(RAT) (RABBIT) MG/L
DERMAL LD50: >2000 MG/KG MALE AND FEMALE RABBITS.
ORAL LD50: >5000 MG/KG MALE AND FEMALE RATS.
EYE EFFECTS: MILD TO MODERATE EYE IRRITANT.
SKIN EFFECTS: MAY IRRITATE SKIN WITH PROLONGED OR REPEATED CONTACT.
CARCINOGENICITY:
IARC: NO LISTED SUBSTANCE
CORROSIVITY:
NA = NOT APPLICABLE
GENETIC EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
REPRODUCTIVE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TARGET ORGANS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL DATA: NOT ESTABLISHED
ECOTOXICOLOGICAL INFORMATION:
THIS PRODUCT IS TOXIC TO FISH AND AQUATIC INVERTEBRATES.
AQUATIC TOXICITY (ACUTE): NOT ESTABLISHED
CHEMICAL FATE INFORMATION: THIS PRODUCT IS BIODEGRADABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
ATTEMPT TO USE PRODUCT COMPLETELY IN ACCORDANCE WITH INTENDED USE.
PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER DISPOSAL OF EXCESS
PESTICIDE, SPRAY MIXTURE OR RINSATE IS A VIOLATION OF FEDERAL LAW. IF
THESE WASTES CANNOT BE DISPOSED OF BY USE ACCORDING TO LABEL INSTRUCTIONS,
CONTACT YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL AGENCY, OR THE
HAZARDOUS WASTE REPRESENTATIVE AT YOUR LOCAL OFFICE, OR THE NEAREST EPA
REGIONAL OFFICE FOR GUIDANCE.
FOR LARGE SPILLS:
CONSULT WITH LOCAL AND STATE AUTHORITIES FOR LARGE VOLUME DISPOSAL.
EMPTY CONTAINER:
TRIPLE RINSE CONTAINER PROMPTLY AFTER EMPTYING. FILL CONTAINER 1/4 FULL
WITH WATER AND RECAP. SHAKE FOR 10 SECONDS. DRAIN AND REPEAT. OFFER FOR
RECYCLING IF AVAILABLE OR PUNCTURE AND DISPOSE IN A SANITARY LANDFILL, OR
BY OTHER PROCEDURES APPROVED BY STATE AND LOCAL AUTHORITIES.
| 14. TRANSPORT INFORMATION | |
DOT (DEPARTMENT OF TRANSPORTATION):
PROPER SHIPPING NAME: NOT REGULATED.
PLACARDS: NONE
LABEL: NONE
U.S. CUSTOMS HARMONIZATION NUMBER: 3808.94.0000
AIR (ICAO/IATA):
SHIPPING NAME: NOT REGULATED.
VESSEL (IMO/IMDG):
SHIPPING NAME: NOT REGULATED.
| 15. REGULATORY INFORMATION | |
UNITED STATES:
DOT LABEL SYMBOL AND HAZARD CLASSIFICATION:
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
311/312 HAZARD CATEGORIES: HEALTH - ACUTE
FIRE: NO
PRESSURE GENERATING: NO
REACTIVITY: NO
ACUTE: YES
CHRONIC: NO
313 REPORTABLE INGREDIENTS: NO LISTED SUBSTANCE
302/304 EMERGENCY PLANNING:
EMERGENCY PLAN: NO LISTED SUBSTANCE
TSCA (TOXIC SUBSTANCE CONTROL ACT):
TSCA REGULATORY:
ALL INGREDIENTS ARE LISTED ON THE TSCA CHEMICAL INVENTORY.
STATES WITH SPECIAL REQUIREMENTS:
CHEMICAL NAME REQUIREMENTS
ISOPROPANOL ISOPROPANOL MASSACHUSETTS RIGHT TO
KNOW SUBSTANCE NEW JERSEY RIGHT TO
KNOW SUBSTANCE PENNSYLVANIA RIGHT
TO KNOW SUBSTANCE
MONOETHANOLAMINE MASSACHUSETTS RIGHT TO KNOW SUBSTANCE
NEW JERSEY RIGHT TO KNOW SUBSTANCE
NEW YORK RIGHT TO KNOW SUBSTANCE
PENNSYLVANIA RIGHT TO KNOW SUBSTANCE
CALIFORNIA PROPOSITION 65: NO LISTED SUBSTANCE
CARCINOGEN: NO LISTED SUBSTANCE
FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): REGULATED
| 16. OTHER INFORMATION | |
PREPARED BY: REGULATORY AFFAIRS DEPARTMENT
DATE PREPARED: 04/30/2015
HMIS RATING:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA CODES:
1
0
0
MANUFACTURER DISCLAIMER:
THIS COMPANY CANNOT ANTICIPATE ALL CONDITIONS OF HANDLING AND USE OF THIS
PRODUCT. THEREFORE, THIS COMPANY ACCEPTS NO RESPONSIBILITY FOR RESULTS
OBTAINED BY THE APPLICATION OF THIS INFORMATION, OR THE SAFETY AND
SUITABILITY OF THE PRODUCT EITHER ALONE OR IN COMBINATION WITH OTHER
PRODUCTS. IT IS THE RESPONSIBILITY OF THE EMPLOYER AND/OR USER TO PROVIDE
A SAFE WORKPLACE, USING HEALTH AND SAFETY INFORMATION CONTAINED HEREIN AS
A GUIDE. THIS COMPANY WILL ACCEPT NO LIABILITY FOR DAMAGES OR LOSSES
INCURRED FROM THE IMPROPER HANDLING AND USE OF THIS PRODUCT.