| Common Name: | FLAMEPROOF COATING 1300-2000 DEG. F (704-1093 DEG. C) FLAT BLACK |
| Manufacturer: | VHT PRODUCTS |
| SDS Revision Date: | 11/27/2022 |
| SDS Format: | No Format Specified |
| Item Number(s): | 38ER22, 801H48 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
SPB102
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME:
VHT(R*) FLAMEPROOF(TM) COATING 1300-2000 DEG. F (704-1093 DEG. C) FLAT
BLACK
PRODUCT CODE: SPB102
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: PAINT OR PAINT RELATED MATERIAL.
MANUFACTURER:
VHT PRODUCTS CO.
101 PROSPECT AVE.
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: (800) 247-3270
REGULATORY INFORMATION TELEPHONE NUMBER: (216) 566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 2
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY: CATEGORY 1A
TOXIC TO REPRODUCTION: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1
ASPIRATION HAZARD: CATEGORY 1
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY: 12.3% (ORAL), 12.3% (DERMAL), 12.3% (INHALATION)
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE CANCER.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. (LUNGS)
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES,
PROTECTIVE CLOTHING AND EYE OR FACE PROTECTION. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. USE
EXPLOSION-PROOF ELECTRICAL, VENTILATING OR LIGHTING EQUIPMENT. USE
NON-SPARKING TOOLS. TAKE ACTION TO PREVENT STATIC DISCHARGES. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. DO NOT BREATHE VAPOR. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE OR ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE OR ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE OR ATTENTION.
STORAGE:
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ADEQUATE VENTILATION
REQUIRED WHEN SANDING OR ABRADING THE DRIED FILM. IF ADEQUATE VENTILATION
CANNOT BE PROVIDED WEAR AN APPROVED PARTICULATE RESPIRATOR (NIOSH
APPROVED). FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE.
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. ABRADING OR SANDING OF THE DRY
FILM MAY RELEASE CRYSTALLINE SILICA WHICH HAS BEEN SHOWN TO CAUSE LUNG
DAMAGE AND CANCER UNDER LONG TERM EXPOSURE.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. DO NOT TRANSFER CONTENTS TO OTHER CONTAINERS FOR STORAGE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
| ACETONE >/=10 - </=25 67-64-1
MICA >/=10 - </=25 12001-26-2
XYLENE, MIXED ISOMERS >/=10 - </=19 1330-20-7
C.I. PIGMENT BLACK 26 >/=10 - </=25 68186-94-7
ETHYLBENZENE </=3 100-41-4
FUMED AMORPHOUS SILICA </=3 112945-52-5
CRYSTALLINE SILICA, RESPIRABLE POWDER <1 14808-60-7
LIGHT ALIPHATIC HYDROCARBON </=1 64742-47-8
TOLUENE </=0.3 108-88-3
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AND HENCE REQUIRE REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING
IT, OR WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. IF MATERIAL HAS BEEN
SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF
WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE
DANGEROUS. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE
DAMAGE. DO NOT INDUCE VOMITING. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT
LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING:
HIGHLY FLAMMABLE LIQUID AND VAPOR. RUNOFF TO SEWER MAY CREATE FIRE OR
EXPLOSION HAZARD. FROM THE CHEMICAL IN A FIRE OR IF HEATED, A PRESSURE
INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A
SUBSEQUENT EXPLOSION. THE VAPOR/GAS IS HEAVIER THAN AIR AND WILL SPREAD
ALONG THE GROUND. VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL
A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD
AREA. AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
EXPOSURE OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING
PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR
OR MIST. DO NOT SWALLOW. USE ONLY WITH ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. DO NOT ENTER STORAGE
AREAS AND CONFINED SPACES UNLESS ADEQUATELY VENTILATED. KEEP IN THE
ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. STORE AND USE AWAY FROM
HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF
ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE
ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC
DISCHARGES. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. STORE LOCKED UP. ELIMINATE ALL
IGNITION SOURCES. SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED
MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT
STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR INCOMPATIBLE MATERIALS
BEFORE HANDLING OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| ACETONE 67-64-1 ACGIH TLV (UNITED STATES, 1/2022).
TWA: 250 PPM 8 HOURS.
STEL: 500 PPM 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2020).
TWA: 250 PPM 10 HOURS.
TWA: 590 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 1000 PPM 8 HOURS.
TWA: 2400 MG/M3 8 HOURS.
MICA 12001-26-2 ACGIH TLV (UNITED STATES, 1/2022).
TWA: 0.1 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
NIOSH REL (UNITED STATES, 10/2020).
TWA: 3 MG/M3 10 HOURS.
FORM: RESPIRABLE FRACTION
OSHA PEL Z3 (UNITED STATES, 6/2016).
TWA: 20 MPPCF 8 HOURS.
XYLENE, MIXED 1330-20-7 ACGIH TLV (UNITED STATES, 1/2022). [XYLENE]
ISOMERS TWA: 20 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 5/2018).
[XYLENES]
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
C.I. PIGMENT 68186-94-7 NIOSH REL (UNITED STATES, 10/2020).
BLACK 26 [MANGANESE COMPOUNDS AND FUME]
TWA: 1 MG/M3, (AS Mn) 10 HOURS.
FORM: FUME
STEL: 3 MG/M3, (AS Mn) 15 MINUTES.
FORM: FUME
ACGIH TLV (UNITED STATES, 1/2022).
[MANGANESE AND INORGANIC COMPOUNDS]
TWA: 0.1 MG/M3, (AS Mn) 8 HOURS.
FORM: INHALABLE FRACTION
TWA: 0.02 MG/M3, (AS Mn) 8 HOURS.
FORM: RESPIRABLE FRACTION
OSHA PEL (UNITED STATES, 5/2018).
[MANGANESE COMPOUNDS]
CEIL: 5 MG/M3, (AS Mn)
ETHYLBENZENE 100-41-4 ACGIH TLV (UNITED STATES, 1/2022).
OTOTOXICANT.
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2020).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
FUMED AMORPHOUS 112945-52-5 NIOSH REL (UNITED STATES, 10/2020).
SILICA [SILICA, AMORPHOUS]
TWA: 6 MG/M3 10 HOURS.
CRYSTALLINE 14808-60-7 OSHA PEL Z3 (UNITED STATES, 6/2016).
SILICA, TWA: 250 MPPCF / (%SiO2+5) 8 HOURS.
RESPIRABLE FORM: RESPIRABLE
POWDER
TWA: 10 MG/M3 / (%SiO2+2) 8 HOURS.
FORM: RESPIRABLE
OSHA PEL (UNITED STATES, 5/2018).
[SILICA, CRYSTALLINE]
TWA: 50 (MICRO)G/M3 8 HOURS.
FORM: RESPIRABLE DUST
ACGIH TLV (UNITED STATES, 1/2022).
[SILICA, CRYSTALLINE]
TWA: 0.025 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
NIOSH REL (UNITED STATES, 10/2020).
[SILICA, CRYSTALLINE]
TWA: 0.05 MG/M3 10 HOURS.
FORM: RESPIRABLE DUST
LIGHT ALIPHATIC 64742-47-8 ACGIH TLV (UNITED STATES, 1/2022).
HYDROCARBON [KEROSENE] ABSORBED THROUGH SKIN.
TWA: 200 MG/M3, (AS TOTAL
HYDROCARBON VAPOR) 8 HOURS.
TOLUENE 108-88-3 OSHA PEL Z2 (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
CEIL: 300 PPM
AMP: 500 PPM 10 MINUTES.
NIOSH REL (UNITED STATES, 10/2020).
TWA: 100 PPM 10 HOURS.
TWA: 375 MG/M3 10 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 560 MG/M3 15 MINUTES.
ACGIH TLV (UNITED STATES, 1/2022).
OTOTOXICANT.
TWA: 20 PPM 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| ACETONE 67-64-1 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 1200 MG/M3 8 HOURS.
15 MIN OEL: 1800 MG/M3 15 MINUTES.
8 HRS OEL: 500 PPM 8 HOURS.
15 MIN OEL: 750 PPM 15 MINUTES.
CA BRITISH COLUMBIA PROVINCIAL (CANADA,
3/2022).
TWA: 250 PPM 8 HOURS.
STEL: 500 PPM 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 6/2019).
TWA: 250 PPM 8 HOURS.
STEL: 500 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 6/2021).
TWAEV: 500 PPM 8 HOURS.
TWAEV: 1190 MG/M3 8 HOURS.
STEV: 1000 PPM 15 MINUTES.
STEV: 2380 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013).
STEL: 750 PPM 15 MINUTES.
TWA: 500 PPM 8 HOURS.
XYLENE 1330-20-7 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
[DIMETHYLBENZENE]
8 HRS OEL: 100 PPM 8 HOURS.
15 MIN OEL: 651 MG/M3 15 MINUTES.
15 MIN OEL: 150 PPM 15 MINUTES.
8 HRS OEL: 434 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA,
3/2022). [XYLENE (O, M & P ISOMERS)]
TWA: 100 PPM 8 HOURS.
STEL: 150 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 6/2021).
[XYLENE]
TWAEV: 100 PPM 8 HOURS.
TWAEV: 434 MG/M3 8 HOURS.
STEV: 150 PPM 15 MINUTES.
STEV: 651 MG/M3 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 6/2019).
[XYLENE (O-, M-, P-ISOMERS)]
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013). [XYLENE]
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
ETHYLBENZENE 100-41-4 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 100 PPM 8 HOURS.
8 HRS OEL: 434 MG/M3 8 HOURS.
15 MIN OEL: 543 MG/M3 15 MINUTES.
15 MIN OEL: 125 PPM 15 MINUTES.
CA BRITISH COLUMBIA PROVINCIAL (CANADA,
3/2022).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 6/2019).
TWA: 20 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 6/2021).
TWAEV: 20 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013).
STEL: 125 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
QUARTZ 14808-60-7 CA BRITISH COLUMBIA PROVINCIAL (CANADA,
3/2022). [SILICA, CRYSTALLINE - ALPHA
QUARTZ AND CRISTOBALITE]
TWA: 0.025 MG/M3 8 HOURS.
FORM: RESPIRABLE
CA QUEBEC PROVINCIAL (CANADA, 6/2021).
[SILICA CRYSTALLINE - QUARTZ]
TWAEV: 0.1 MG/M3 8 HOURS.
FORM: RESPIRABLE DUST.
CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 0.025 MG/M3 8 HOURS.
FORM: RESPIRABLE PARTICULATE
CA ONTARIO PROVINCIAL (CANADA, 6/2019).
[SILICA, CRYSTALLINE (QUARTZ/TRIPOLI)]
TWA: 0.1 MG/M3 8 HOURS.
FORM: RESPIRABLE PARTICULATE MATTER.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013).
TWA: 0.05 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
KAOLIN 1332-58-7 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE
CA BRITISH COLUMBIA PROVINCIAL (CANADA,
3/2022).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE
CA QUEBEC PROVINCIAL (CANADA, 6/2021).
TWAEV: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE DUST.
CA ONTARIO PROVINCIAL (CANADA, 6/2019).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE PARTICULATE MATTER.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013).
STEL: 4 MG/M3 15 MINUTES.
FORM: RESPIRABLE FRACTION
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
PETROLEUM REFINING, 64742-47-8 CA BRITISH COLUMBIA PROVINCIAL (CANADA,
HYDROTREATED LIGHT DISTILLATE 3/2022). [KEROSENE/JET FUELS]
ABSORBED THROUGH SKIN.
TWA: 200 MG/M3, (AS TOTAL HYDROCARBON
VAPOUR) 8 HOURS.
CA ALBERTA PROVINCIAL (CANADA, 6/2018).
[KEROSENE/JET FUELS] ABSORBED THROUGH
SKIN.
8 HRS OEL: 200 MG/M3, (AS TOTAL
HYDROCARBON VAPOUR) 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 6/2019).
ABSORBED THROUGH SKIN.
TWA: 200 MG/M3, (AS TOTAL HYDROCARBON
VAPOUR) 8 HOURS.
TOLUENE 108-88-3 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
ABSORBED THROUGH SKIN.
8 HRS OEL: 50 PPM 8 HOURS.
8 HRS OEL: 188 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA,
3/2022).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 6/2019).
TWA: 20 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 6/2021).
ABSORBED THROUGH SKIN.
TWAEV: 50 PPM 8 HOURS.
TWAEV: 188 MG/M3 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013). ABSORBED THROUGH SKIN.
STEL: 60 PPM 15 MINUTES.
TWA: 50 PPM 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
CAS # EXPOSURE LIMITS
| ACETONE 67-64-1 NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 500 PPM 8 HOURS.
STEL: 750 PPM 15 MINUTES.
XYLENE, MIXED ISOMERS 1330-20-7 NOM-010-STPS-2014 (MEXICO, 4/2016).
[XYLENES (MIXED)]
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
ETHYLBENZENE 100-41-4 NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 20 PPM 8 HOURS.
TOLUENE 108-88-3 NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 20 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
THE CONDITIONS OF MEASUREMENT OF ALL PROPERTIES ARE AT STANDARD TEMPERATURE
AND PRESSURE UNLESS OTHERWISE INDICATED.
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: BLACK.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
BOILING POINT, INITIAL BOILING POINT, AND BOILING RANGE:
55 DEG. C (131 DEG. F)
FLASH POINT:
CLOSED CUP: 2 DEG. C (35.6 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 5.6 (BUTYL ACETATE = 1)
FLAMMABILITY: NOT AVAILABLE.
LOWER AND UPPER EXPLOSION LIMIT/FLAMMABILITY LIMIT:
LOWER: 1%
UPPER: 12.8%
VAPOR PRESSURE: 24 KPA (180 MMHg)
RELATIVE VAPOR DENSITY: 2 [AIR = 1]
RELATIVE DENSITY: 1.29
SOLUBILITY(IES): NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): <20.5 MM2/S (<20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
HEAT OF COMBUSTION: 9.699 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION. DO NOT ALLOW VAPOR TO ACCUMULATE IN LOW OR CONFINED
AREAS.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
| ACETONE LD50 ORAL RAT 5800 MG/KG
XYLENE, MIXED ISOMERS LC50 INHALATION RAT 6700 PPM 4 HOURS
GAS.
LD50 ORAL RAT 4300 MG/KG
ETHYLBENZENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
FUMED AMORPHOUS SILICA LD50 ORAL RAT 3160 MG/KG
TOLUENE LC50 INHALATION RAT 49 G/M3 4 HOURS
VAPOR
LD50 ORAL RAT 636 MG/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
| ACETONE EYES - MILD HUMAN 186300 PPM
IRRITANT
EYES - MILD RABBIT 10 UL
IRRITANT
EYES - RABBIT 24 HOURS
MODERATE 20 MG
IRRITANT
EYES - RABBIT 20 MG
SEVERE
IRRITANT
SKIN - MILD RABBIT 395 MG
IRRITANT
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500 MG
XYLENE, MIXED EYES - MILD RABBIT 87 MG
ISOMERS IRRITANT
EYES - RABBIT 24 HOURS
SEVERE 5 MG
IRRITANT
SKIN - MILD RAT 8 HOURS
IRRITANT 60 UL
SKIN - RABBIT 100%
MODERATE
IRRITANT
SKIN - RABBIT 24 HOURS
MODERATE 500 MG
IRRITANT
ETHYLBENZENE EYES - RABBIT 500 MG
SEVERE
IRRITANT
SKIN - MILD RABBIT 24 HOURS
IRRITANT 15 MG
TOLUENE EYES - MILD RABBIT 0.5 MINUTES
IRRITANT 100 MG
EYES - MILD RABBIT 870 UG
IRRITANT
EYES - RABBIT 24 HOURS
SEVERE 2 MG
IRRITANT
SKIN - MILD PIG 24 HOURS
IRRITANT 250 UL
SKIN - MILD RABBIT 435 MG
IRRITANT
SKIN - RABBIT 24 HOURS
MODERATE 20 MG
IRRITANT
SKIN - RABBIT 500 MG
MODERATE
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
| XYLENE, MIXED ISOMERS 3
ETHYLBENZENE 2B
FUMED AMORPHOUS SILICA 3
CRYSTALLINE SILICA, RESPIRABLE 1 KNOWN TO BE A HUMAN
POWDER CARCINOGEN.
TOLUENE 3
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
ACETONE CATEGORY 3 RESPIRATORY TRACT
IRRITATION
CATEGORY 3 NARCOTIC EFFECTS
XYLENE, MIXED ISOMERS CATEGORY 3 RESPIRATORY TRACT
IRRITATION
ETHYLBENZENE CATEGORY 3 RESPIRATORY TRACT
IRRITATION
CATEGORY 3 NARCOTIC EFFECTS
TOLUENE CATEGORY 3 RESPIRATORY TRACT
IRRITATION
CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
| ACETONE CATEGORY 2
MICA CATEGORY 1 INHALATION LUNGS
XYLENE, MIXED ISOMERS CATEGORY 2
ETHYLBENZENE CATEGORY 2
CRYSTALLINE SILICA, CATEGORY 1 INHALATION
RESPIRABLE POWDER
TOLUENE CATEGORY 2
ASPIRATION HAZARD:
NAME RESULT
XYLENE, MIXED ISOMERS ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
LIGHT ALIPHATIC HYDROCARBON ASPIRATION HAZARD - CATEGORY 1
TOLUENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY:
MAY CAUSE CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 25752.15 MG/KG
DERMAL 8000.31 MG/KG
INHALATION (GASES) 48729.16 PPM
INHALATION (VAPORS) 458.4 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
| ACETONE ACUTE EC50: ALGAE - SELENASTRUM SP. 96 HOURS
7200000 (MICRO)G/L
FRESH WATER
ACUTE LC50: CRUSTACEANS - ACARTIA 48 HOURS
4.42589 ML/L TONSA - COPEPODID
MARINE WATER
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
7460000 (MICRO)G/L CUCULLATA
FRESH WATER
ACUTE LC50: FISH - POECILIA 96 HOURS
5600 PPM RETICULATA
FRESH WATER
CHRONIC NOEC: ALGAE - ULVA PERTUSA 96 HOURS
4.95 MG/L
MARINE WATER
CHRONIC NOEC: CRUSTACEANS - DAPHNIIDAE 21 DAYS
0.016 ML/L
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
0.1 ML/L FRESH MAGNA - NEONATE
WATER
CHRONIC NOEC: FISH - GASTEROSTEUS 42 DAYS
5 (MICRO)G/L ACULEATUS - LARVAE
MARINE WATER
XYLENE, MIXED ACUTE LC50: CRUSTACEANS - 48 HOURS
ISOMERS 8500 (MICRO)G/L PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO)G/L PROMELAS
FRESH WATER
ETHYLBENZENE ACUTE EC50: ALGAE - SKELETONEMA 72 HOURS
4900 (MICRO)G/L COSTATUM
MARINE WATER
ACUTE EC50: ALGAE - SKELETONEMA 96 HOURS
7700 (MICRO)G/L COSTATUM
MARINE WATER
ACUTE EC50: CRUSTACEANS - ARTEMIA 48 HOURS
6.53 MG/L MARINE SP. - NAUPLII
WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2.93 MG/L FRESH MAGNA - NEONATE
WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO)G/L MYKISS
FRESH WATER
LIGHT ALIPHATIC ACUTE LC50: FISH - LEPOMIS 4 DAYS
HYDROCARBON 2200 (MICRO)G/L MACROCHIRUS
FRESH WATER
TOLUENE ACUTE EC50: ALGAE - SKELETONEMA 96 HOURS
>433 PPM MARINE COSTATUM
WATER
ACUTE EC50: CRUSTACEANS - GAMMARUS 48 HOURS
11600 (MICRO)G/L PSEUDOLIMNAEUS - ADULT
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
6000 (MICRO)G/L MAGNA - JUVENILE
FRESH WATER (FLEDGLING, HATCHLING,
WEANLING)
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
5500 (MICRO)G/L KISUTCH - FRY
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA MAGNA 21 DAYS
1 MG/L FRESH
WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
| ACETONE READILY
XYLENE, MIXED ISOMERS READILY
ETHYLBENZENE READILY
TOLUENE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
| XYLENE, MIXED ISOMERS 8.1 TO 25.9 LOW
TOLUENE 90 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT
RESIDUES MAY CREATE A HIGHLY FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE
CONTAINER. DO NOT CUT, WELD OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN
CLEANED THOROUGHLY INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1263 UN1263 UN1263
UN PROPER SHIPPING PAINT PAINT PAINT
NAME
TRANSPORT HAZARD 3 3 3
CLASS(ES) FLAMMABLE LIQUID, CLASS 3, CLASS 3,
CLASS/DIVISION FLAMMABLE FLAMMABLE
3.1, 3.2, 3.3 LIQUIDS LIQUIDS
PACKING GROUP II II II
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL PRODUCT
INFORMATION CLASSIFIED
AS PER THE
FOLLOWING
SECTIONS OF THE
TRANSPORTATION
OF DANGEROUS
GOODS
REGULATIONS:
2.18-2.19
(CLASS 3).
ERG NO.: 128 ERG NO.: 128 ERG NO.: 128
IATA IMDG
UN NUMBER UN1263 UN1263
| UN PROPER SHIPPING NAME PAINT PAINT. MARINE
POLLUTANT (ZINC
PHOSPHATE, ZINC
OXIDE)
TRANSPORT HAZARD 3 3
CLASS(ES) CLASS 3, FLAMMABLE CLASS 3 - FLAMMABLE
LIQUIDS LIQUIDS
ENVIRONMENT
PACKING GROUP II II
ENVIRONMENTAL HAZARDS NO NO
ADDITIONAL INFORMATION EMERGENCY SCHEDULES:
F-E, S-E
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON ALL
ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO IMO INSTRUMENTS: NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AIIC): NOT DETERMINED.
CHINA INVENTORY (IECSC): NOT DETERMINED.
JAPAN INVENTORY (CSCL): NOT DETERMINED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
KOREA INVENTORY (KECI): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
TAIWAN CHEMICAL SUBSTANCES INVENTORY (TCSI): NOT DETERMINED.
THAILAND INVENTORY: NOT DETERMINED.
TURKEY INVENTORY: NOT DETERMINED.
VIETNAM INVENTORY: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3*
FLAMMABILITY 3
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON SDSS
OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER MAY
CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE LIQUIDS - CATEGORY 2 ON BASIS OF TEST DATA
SKIN CORROSION/IRRITATION - CATEGORY 2 CALCULATION METHOD
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
CARCINOGENICITY - CATEGORY 1A CALCULATION METHOD
TOXIC TO REPRODUCTION - CATEGORY 2 CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(RESPIRATORY TRACT IRRITATION) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(NARCOTIC EFFECTS) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED CALCULATION METHOD
EXPOSURE) - CATEGORY 1
ASPIRATION HAZARD - CATEGORY 1 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 11/27/2022
DATE OF ISSUE/DATE OF REVISION: 11/27/2022
DATE OF PREVIOUS ISSUE: 6/22/2022
VERSION: 17
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
N/A: NOT AVAILABLE
SGG: SEGREGATION GROUP
UN UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA SHEET
(SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT AS
SPECIFICALLY INSTRUCTED BY THE MANUFACTURER, INCLUDING BUT NOT LIMITED TO
THE INCORPORATION OF PRODUCTS NOT SPECIFIED BY THE MANUFACTURER, OR THE USE
OR ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY THE MANUFACTURER.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.
SHW-85-NA-GHS-US