| Common Name: | TOUGH GUY CLOSED LOOP CONCENTRATED DISINFECTANT I |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 3/10/2015 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 38TH15 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
GRAINGER(R*)
FOR THE ONES WHO GET IT DONE
MANUFACTURED FOR:
W.W. GRAINGER, INC.
100 GRAINGER PKWY.
LAKE FOREST, IL 60045-5201
1-847-535-1000
WWW.GRAINGER.COM
| SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY CLOSED LOOP CONCENTRATED DISINFECTANT I
PRODUCT USE: CLEANER. DISINFECTANT. SANITIZER.
PRODUCT CODE: 38TH15
DATE OF ISSUE: 03/10/15
SUPERSEDES: NA
THIS PRODUCT IS A REGISTERED PESTICIDE. EPA ID NO. 6836-78-10637 PENDING
EMERGENCY TELEPHONE NUMBERS:
FOR MSDS INFORMATION:
TECHNICAL SERVICES: 1-847-535-5400
FOR MEDICAL EMERGENCY: (800) 983-4582 TOLL FREE
FOR TRANSPORTATION EMERGENCY:
CHEMTREC: (800) 424-9300 - ALL CALLS RECORDED
IN THE DISTRICT OF COLUMBIA: (202) 483-7616
PREPARED BY:
COMPLIANCE SERVICES
1420 SEABOARD INDUSTRIAL BLVD.
ATLANTA, GA 30318
| SECTION 2. HAZARDS IDENTIFICATION | |
*HAZARD DETERMINATION SYSTEM (HDS):
HEALTH 3
FLAMMABILITY 2
REACTIVITY 0
EMERGENCY OVERVIEW:
DANGER!
CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
HARMFUL IF SWALLOWED.
NOTE:
MSDS DATA PERTAINS TO THE PRODUCT AS DELIVERED IN THE ORIGINAL SHIPPING
CONTAINER(S). RISK OF ADVERSE EFFECTS ARE LESSENED BY FOLLOWING ALL
PRESCRIBED SAFETY PRECAUTIONS, INCLUDING THE USE OF PROPER PERSONAL
PROTECTIVE EQUIPMENT.
ROUTES OF ENTRY: DERMAL CONTACT. EYE CONTACT. INHALATION.
ACUTE EFFECTS:
EYES:
CAUSES EYE BURNS. DIRECT CONTACT WITH THE EYES CAN CAUSE IRREVERSIBLE
DAMAGE, INCLUDING BLINDNESS.
SKIN:
CAUSES SKIN BURNS. HARMFUL IF ABSORBED THROUGH THE SKIN. SKIN INFLAMMATION
IS CHARACTERIZED BY ITCHING, SCALING, REDDENING OR, OCCASIONALLY,
BLISTERING.
INHALATION:
AVOID DIRECT INHALATION OF SPRAY. OVER-EXPOSURE BY INHALATION MAY CAUSE
RESPIRATORY IRRITATION.
INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
CHRONIC EFFECTS:
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: KIDNEYS,
LIVER, CENTRAL NERVOUS SYSTEM (CNS), OPTIC NERVE.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
PRODUCT/INGREDIENT NAME: NOT AVAILABLE.
ADDITIONAL INFORMATION: SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
NAME OF HAZARDOUS INGREDIENTS CAS NUMBER % BY WEIGHT
QUATERNARY AMMONIUM CHLORIDES; BLEND OF 68424-85-1; 15 - 25
ALKYLDIMETHYLBENZYL AMMONIUM CHLORIDES, 68424-95-3;
ALKYL DIMETHYL AMMONIUM CHLORIDES, ETHANOL 64-17-5
ALCOHOLS, C9-11, ETHOXYLATED; LINEAR 68439-46-3 1 - 10
PRIMARY ALCOHOL ETHOXYLATE 1 - 5
TETRASODIUM ETHYLENEDIAMINE TETRAACETATE; 64-02-8 1 - 5
ETHYLENEDIAMINE TETRAACETIC ACID;
TETRASODIUM SALT
| SECTION 4. FIRST AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE
TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
FLUSH AFFECTED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND
SHOES. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS. WASH CLOTHING BEFORE REUSE.
INHALATION:
MOVE EXPOSED PERSON TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF
VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER
THE LUNGS. IF AFFECTED PERSON IS CONSCIOUS, GIVE PLENTY OF WATER TO DRINK.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION IMMEDIATELY.
| SECTION 5. FIRE FIGHTING MEASURES | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
3
2
0
FLASH POINT:
CLOSED CUP: 51.66 DEG. C (125 DEG. F)
FLAMMABLE LIMITS: NOT DETERMINED.
FLAMMABILITY: PRODUCT MAY FLASH, BUT WILL NOT SUSTAIN COMBUSTION.
FIRE HAZARD:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST, WITH THE RISK OF A SUBSEQUENT EXPLOSION. MAY EMIT TOXIC FUMES
UNDER FIRE CONDITIONS.
FIRE-FIGHTING PROCEDURES: USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
SPILL CLEAN UP:
ELIMINATE ALL IGNITION SOURCES. STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS
FROM SPILL AREA. DILUTE WITH WATER AND MOP UP IF WATER-SOLUBLE OR ABSORB
WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL
CONTAINER. USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT. DISPOSE OF
VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT
INGEST. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR
WHEN VENTILATION IS INADEQUATE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE
AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER. WASH THOROUGHLY AFTER
HANDLING. OBSERVE LABEL PRECAUTIONS.
STORAGE:
STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION
SOURCE.
STORE BETWEEN THE FOLLOWING TEMPERATURES:
40 DEG. F - 120 DEG. F (4.4 DEG. C - 49 DEG. C). KEEP AWAY FROM FOOD,
DRINK AND ANIMAL FEEDING STUFFS. KEEP OUT OF THE REACH OF CHILDREN.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRODUCT NAME EXPOSURE LIMITS
ETHANOL; ETHYL ALCOHOL; GRAIN ALCOHOL OSHA (UNITED STATES).
TWA: 1000 PPM
PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYES: CHEMICAL SPLASH GOGGLES OR FACE SHIELD.
BODY: WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
RECOMMENDED:
RUBBER GLOVES. NEOPRENE GLOVES. WEAR APRON OR COVERALL IF THERE IS A RISK
OF EXPOSURE TO SPLASHES.
RESPIRATORY:
USE WITH ADEQUATE VENTILATION. USE APPROPRIATE RESPIRATORY PROTECTION IF
THERE IS A RISK OF EXCEEDING ANY EXPOSURE LIMITS.
CHEMICAL GOGGLES
FACE SHIELD
GLOVES
APRON
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
PH: 12.5 - 13.5
BOILING POINT: NOT DETERMINED.
SPECIFIC GRAVITY: 1.01
SOLUBILITY:
SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
COLOR: GREEN. [DARK]
ODOR: ODORLESS.
VAPOR: PRESSURE NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: 1 (WATER = 1)
VOC (CONSUMER): 27.32 (G/L). 0.23 LBS/GAL (2.71%)
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY AND REACTIVITY: THE PRODUCT IS STABLE.
INCOMPATIBILITY:
SLIGHTLY REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING
MATERIALS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY EMIT TOXIC FUMES UNDER FIRE CONDITIONS. CARBON OXIDES (CO, CO2),
NITROGEN OXIDES (NO, NO2 ETC.)
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
ETHOXYLATED ALCOHOLS LD50 DERMAL RABBIT >2000 MG/KG
LD50 ORAL RAT 1400 MG/KG
QUATERNARY AMMONIUM LD50 DERMAL RABBIT 645 MG/KG
CHLORIDES LD50 DERMAL RABBIT 204 MG/KG
LD50 ORAL RAT 250 MG/KG
LD50 ORAL RAT 366 MG/KG
ETHANOL LD50 DERMAL RABBIT 2000 MG/KG
LD50 ORAL RAT 7060 MG/KG
LC50 INHALATION RAT 3000 PPM 4 HOURS
VAPOR
TETRASODIUM LD50 ORAL RAT 4100 MG/KG
ETHYLENEDIAMINE
TETRAACETATE
| SECTION 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
AQUATIC ECOTOXICITY: NOT AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE INFORMATION:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL CONTROL REGULATIONS. CONSULT YOUR LOCAL OR REGIONAL
AUTHORITIES FOR ADDITIONAL INFORMATION.
WASTE STREAM:
CODE: D001, D002
CLASSIFICATION: - [HAZARDOUS WASTE]
ORIGIN: - [RCRA WASTE.]
| SECTION 14. TRANSPORT INFORMATION | |
REGULATORY UN NUMBER PROPER SHIPPING NAME CLASSES PG* LABEL
INFORMATION
DOT NOT REGULATED. NOT A DOT CONTROLLED
CLASSIFICATION MATERIAL (UNITED
STATES).
IMDG CLASS NOT DETERMINED.
NOTE:
DOT CLASSIFICATION APPLIES TO MOST PACKAGE SIZES. FOR SPECIFIC CONTAINER
SIZE CLASSIFICATIONS OR FOR SIZE EXCEPTIONS, REFER TO THE BILL OF LADING
WITH YOUR SHIPMENT.
PG*: PACKING GROUP
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING:
NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 307: NO PRODUCTS WERE FOUND.
CLEAN WATER ACT (CWA) 311: NO PRODUCTS WERE FOUND.
CLEAN AIR ACT (CAA) 112 REGULATED TOXIC SUBSTANCES: NO PRODUCTS WERE FOUND.
ALL COMPONENTS OF THIS PRODUCT ARE LISTED OR EXEMPT FROM LISTING ON TSCA
INVENTORY.
STATE REGULATIONS:
CALIFORNIA PROP 65: NO PRODUCTS WERE FOUND.
| SECTION 16. OTHER INFORMATION | |
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS
ACCURATE. HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS
SUBSIDIARIES ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR
COMPLETENESS OF THE INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED
HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
*NOTE:
HAZARD DETERMINATION SYSTEM (HDS) RATINGS ARE BASED ON A 0-4 RATING SCALE,
WITH 0 REPRESENTING MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING
SIGNIFICANT HAZARDS OR RISKS ALTHOUGH THESE RATINGS ARE NOT REQUIRED ON
MSDSS UNDER 29 CFR 1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HDS
RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED PROGRAM TO RELAY THE
MEANINGS OF THIS SCALE.