| Common Name: | 266733 CONSAV TUBE 6PK 21.2OZ FLEX JOINT SLNT KIT, CONSAV TUBE 6PK 21.2OZ FLEX J |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 8/15/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 38W371 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
RUST-OLEUM CORPORATION
REVISION DATE: 8/15/2016
RUST-OLEUM MULTI COMPONENT PRODUCT INFORMATION SHEET
266733 CONSAV TUBE 6PK 21.2OZ FLEX JOINT SLNT KIT IS A MULTI COMPONENT
PRODUCT COMPOSED OF THE FOLLOWING INDIVIDUAL CHEMICAL COMPONENTS:
266733A CONSAV TUBE 6PK 21.2OZ FLEX JOINT SLNT PART A
266733B CONSAV TUBE 6PK 21.2OZ FLEX JOINT SLNT PART B
SDSS FOR EACH COMPONENT FOLLOW THIS COVER SHEET.
TRANSPORTATION INFORMATION:
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. N.A. N.A. N.A.
PROPER SHIPPING NAME NOT NOT NOT NOT
REGULATED REGULATED REGULATED REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
FINISHED GOOD SCHEDULE B HARMONIZED TARIFF CODE: 3208.90.0000
DATE PRINTED: 8/15/2016
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
* TRUSTED QUALITY SINCE 1921 *
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: CONSAV TUBE 6PK 21.2OZ FLEX JOINT SLNT PART A
PRODUCT IDENTIFIER: 266733A
PRODUCT USE/CLASS: JOINT SEALANT/PART A
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
REVISION DATE: 8/15/2016
SUPERCEDES DATE: 8/17/2015
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
60% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
GHS HAZARD STATEMENTS:
CARCINOGENICITY, CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT, REPEATED EXPOSURE, CATEGORY 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
RESPIRATORY SENSITIZER, CATEGORY 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P260: DO NOT BREATHE DUST, FUMES, GASES, MISTS, VAPORS, OR SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P362: TAKE OFF CONTAMINATED CLOTHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
GHS SDS PRECAUTIONARY STATEMENTS:
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
ISOCYANIC-POLYPROPYLENE 53862-89-8 50-75 NOT AVAILABLE NOT AVAILABLE
GLYCOL PREPOLYMER
4,4'-DIPHENYLMETHANE 101-68-8 25-50 GHS07-GHS08 H315-317-319-
DIISOCYANATE (MDI) 332-334-335-
351-373
2,4'-DIPHENYLMETHANE 5873-54-1 10-25 GHS07-GHS08 H315-317-319-
DIISOCYANATE 332-334-335-
351-373
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM. FOR LARGER
AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF WATER TO
DRINK AND GET MEDICAL ATTENTION. IF SWALLOWED, RINSE MOUTH WITH WATER. IF
FEELING UNWELL, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED. KEEP CONTAINERS TIGHTLY CLOSED.
FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM. IF
WATER IS USED, FOG NOZZLES ARE PREFERRED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IF SPILLED, CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
ISOCYANIC-POLYPROPYLENE GLYCOL PREPOLYMER 53862-89-8 60.0
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) 101-68-8 30.0
2,4'-DIPHENYLMETHANE DIISOCYANATE 5873-54-1 15.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA PEL-
TLV-TWA TLV-STEL PEL-TWA CEILING
ISOCYANIC- N.E. N.E. N.E. N.E.
POLYPROPYLENE GLYCOL
PREPOLYMER
4,4'-DIPHENYLMETHANE 0.005 PPM N.E. N.E. 0.02 PPM
DIISOCYANATE (MDI)
2,4'-DIPHENYLMETHANE N.E. N.E. N.E. N.E.
DIISOCYANATE
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: MILD
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.158
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: NEGLIGIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: 260 - 376
EXPLOSIVE LIMITS, VOL%: N.A. - N.A.
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 94
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIS.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
MAY CAUSE SKIN SENSITIZATION, AN ALLERGIC REACTION, WHICH BECOMES EVIDENT
UPON RE-EXPOSURE TO THIS MATERIAL. LOW HAZARD FOR USUAL INDUSTRIAL HANDLING
OR COMMERCIAL HANDLING BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
MAY CAUSE ALLERGIC RESPIRATORY REACTION. HIGH GAS, VAPOR, MIST OR DUST
CONCENTRATIONS MAY BE HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY,
VAPORS, OR MIST.
EFFECTS OF OVEREXPOSURE - INGESTION: SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO
ISOCYANANTES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST. VAPOR AND SPRAY
MIST HARMFUL. OVEREXPOSURE MAY CAUSE LUNG DAMAGE. MAY CAUSE ALLERGIC SKIN
AND RESPIRATORY REACTION, EFFECTS MAY BE PERMANENT.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR
LC50
53862-89-8 ISOCYANIC-POLYPROPYLENE 9200 >9400 490
GLYCOL PREPOLYMER
101-68-8 4,4'-DIPHENYLMETHANE 31600 MG/KG RAT N.I. N.I.
DIISOCYANATE (MDI)
N.I.: NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG
(USDOT) (IMDG) (CANADA)
UN NUMBER: N.A. N.A. N.A. N.A.
PROPER SHIPPING NAME NOT REGULATED NOT REGULATED NOT REGULATED NOT
REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) 101-68-8
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 0
SDS REVISION DATE: 8/15/2016
REASON FOR REVISION:
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
02 - HAZARD IDENTIFICATION
03 - COMPOSITION/INFORMATION ON INGREDIENTS
09 - PHYSICAL & CHEMICAL PROPERTIES
11 - TOXICOLOGICAL INFORMATION
STATEMENT(S) CHANGED
LEGEND:
N.A.: NOT APPLICABLE
N.E.: NOT ESTABLISHED
N.D.: NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.
DATE PRINTED: 8/15/2016
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
* TRUSTED QUALITY SINCE 1921 *
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION | |
PRODUCT NAME: CONSAV TUBE 6PK 21.2OZ FLEX JOINT SLNT PART B
PRODUCT IDENTIFIER: 266733B
PRODUCT USE/CLASS: JOINT SEALANT/PART A
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
REVISION DATE: 8/15/2016
SUPERCEDES DATE: 8/17/2015
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT: EXCLAMATION MARK
SIGNAL WORD: WARNING
POSSIBLE HAZARDS:
9% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
GHS HAZARD STATEMENTS:
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
GHS LABEL PRECAUTIONARY STATEMENTS:
P261: AVOID BREATHING DUST, FUMES, GASES, MISTS, VAPORS, OR SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
GHS SDS PRECAUTIONARY STATEMENTS:
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
1,3-BENZENEDIAMINE, 102093-68-5 2.5-10 GHS07 H317
4-METHYL-2,6-
BIS(METHYLTHIO)-
ZEOLITE 1318-02-1 2.5-10 GHS06 H331
TITANIUM DIOXIDE 13463-67-7 2.5-10 NOT AVAILABLE NOT AVAILABLE
1,3-BENZENEDIAMINE, 104983-85-9 2.5-10 GHS07 H317
2-METHYL-4,6-
BIS(METHYLTHIO)-
CARBON BLACK 1333-86-4 0.1-1.0 NOT AVAILABLE NOT AVAILABLE
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM. FOR LARGER
AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF WATER TO
DRINK AND GET MEDICAL ATTENTION. IF SWALLOWED, RINSE MOUTH WITH WATER. IF
FEELING UNWELL, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED. KEEP CONTAINERS TIGHTLY CLOSED.
FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM. IF
WATER IS USED, FOG NOZZLES ARE PREFERRED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IF SPILLED, CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT %
LESS THAN
1,3-BENZENEDIAMINE, 4-METHYL-2,6-BIS(METHYLTHIO)- 102093-68-5 10.0
1,3-BENZENEDIAMINE, 2-METHYL-4,6-BIS(METHYLTHIO)- 104983-85-9 5.0
TITANIUM DIOXIDE 13463-67-7 5.0
ZEOLITE 1318-02-1 5.0
CARBON BLACK 1333-86-4 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA PEL-
TLV-TWA TLV-STEL PEL-TWA CEILING
1,3-BENZENEDIAMINE, N.E. N.E. N.E. N.E.
4-METHYL-2,6-
BIS(METHYLTHIO)-
1,3-BENZENEDIAMINE, N.E. N.E. N.E. N.E.
2-METHYL-4,6-
BIS(METHYLTHIO)-
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
ZEOLITE N.E. N.E. N.E. N.E.
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: GEL/PASTE
PHYSICAL STATE: LIQUID
ODOR: MILD
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.040
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: NONE
PARTITION COEFFICIENT, N-OCTANOL/DECOMPOSITION TEMP., DEG. C: N.D.
WATER: N.D.
BOILING RANGE, DEG. C: -18 - 3,000
EXPLOSIVE LIMITS, VOL%: N.A. - N.A.
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 94
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIS.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
LOW HAZARD FOR USUAL INDUSTRIAL HANDLING OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST.
EFFECTS OF OVEREXPOSURE - INGESTION: SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP
2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO
TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH
TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING
BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST
AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG
FIBROSIS, AND LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY
EXPOSED FOR LONG PERIODS OF TIME TO EXCESSIVE CONCENTRATIONS OF CARBON
BLACK AND SEVERAL INSOLUBLE FINE DUST PARTICLES. TUMORS HAVE NOT BEEN
OBSERVED IN OTHER ANIMAL SPECIES (I.E., MOUSE AND HAMSTER) UNDER SIMILAR
CIRCUMSTANCES AND STUDY CONDITIONS. EPIDEMIOLOGICAL STUDIES OF NORTH
AMERICAN WORKERS SHOW NO EVIDENCE OF CLINICALLY SIGNIFICANT ADVERSE HEALTH
EFFECTS DUE TO OCCUPATIONAL EXPOSURE TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
1318-02-1 ZEOLITE 5000 MG/KG RAT >2000 MG/KG 2.4 MG/L RAT
RABBIT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG RAT 2500 MG/KG N.I.
1333-86-4 CARBON BLACK >15400 MG/KG RAT N.I. N.I.
N.I.: NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG
(USDOT) (IMDG) (CANADA)
UN NUMBER: N.A. N.A. N.A. N.A.
PROPER SHIPPING NAME NOT REGULATED NOT REGULATED NOT REGULATED NOT
REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 0
SDS REVISION DATE: 8/15/2016
REASON FOR REVISION: SUBSTANCE HAZARD THRESHOLD % CHANGED
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
02 - HAZARD IDENTIFICATION
03 - COMPOSITION/INFORMATION ON INGREDIENTS
09 - PHYSICAL & CHEMICAL PROPERTIES
11 - TOXICOLOGICAL INFORMATION
15 - REGULATORY INFORMATION
SUBSTANCE HAZARDOUS FLAG CHANGED
STATEMENT(S) CHANGED
LEGEND:
N.A.: NOT APPLICABLE
N.E.: NOT ESTABLISHED
N.D.: NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.