| Common Name: | HERCULES PLUMBER'S CAULK -SILICONE WHITE AND CLEAR |
| Manufacturer: | HCC HOLDINGS |
| SDS Revision Date: | 5/12/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 39AP03 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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H
HERCULES(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: HERCULES PLUMBER'S CAULK -SILICONE WHITE AND CLEAR
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 7332E
SYNONYMS:
PART NUMBERS: 25666
RECOMMENDED USE:
CAULK AND SEALANT FOR USE AROUND TUBS, SINKS AND OTHER PLUMBING
APPLICATIONS.
RECOMMENDED RESTRICTIONS:
DO NOT US ON APPLICATIONS WHERE PRODUCT WILL BE SUBMERGED UNDER WATER.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
COMPANY NAME: HCC HOLDINGS, INC. AN OATEY AFFILIATE
ADDRESS:
4700 WEST 160TH STREET
CLEVELAND, OH 44135
TELEPHONE: 216-267-7100
E-MAIL: INFO@OATEY.COM
TRANSPORT EMERGENCY:
CHEMTREC: 1-800-424-9300 (OUTSIDE THE US 1-703-527-3887)
EMERGENCY FIRST AID: 1-877-740-5015
CONTACT PERSON: MSDS COORDINATOR
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
FLAMMABLE LIQUIDS, CATEGORY 4:
H227: COMBUSTIBLE LIQUID
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE, CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE.
REPRODUCTIVE TOXICITY, CATEGORY 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
GHS LABEL ELEMENT:
HAZARD PICTOGRAMS:
HEALTH HAZARD
CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H227: COMBUSTIBLE LIQUID
H315: CAUSES SKIN IRRITATION.
H318: CAUSES SERIOUS EYE DAMAGE.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P280: WEAR EYE PROTECTION/ FACE PROTECTION.
P280: WEAR PROTECTIVE GLOVES.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
RESPONSE:
P302 + P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P370 + P378:
IN CASE OF FIRE:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT FOR EXTINCTION.
STORAGE:
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
DISPOSAL:
P501: DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
SEE SECTION 11 FOR MORE DETAILED INFORMATION ON HEALTH EFFECTS AND
SYMPTOMS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS INGREDIENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION (%)
POLYSILOXANEDIOL 70131-67-8 >=50 - <=100%
OCTAMETHYLCYCLOTETRASILOXANE 556-67-2 >=2 - <5%
METHYLSILANETRIYL-TRIACETATE 4253-34-3 >=2 - <5%
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
| 4. FIRST AID MEASURES | |
IF INHALED:
MOVE TO FRESH AIR.
CONSULT A PHYSICIAN AFTER SIGNIFICANT EXPOSURE.
IN CASE OF SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING AND SHOES IMMEDIATELY.
WASH OFF WITH SOAP AND PLENTY OF WATER.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF EYE CONTACT:
SMALL AMOUNTS SPLASHED INTO EYES CAN CAUSE IRREVERSIBLE TISSUE DAMAGE AND
BLINDNESS.
IN THE CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER
AND SEEK MEDICAL ADVICE.
CONTINUE RINSING EYES DURING TRANSPORT TO HOSPITAL.
REMOVE CONTACT LENSES.
KEEP EYE WIDE OPEN WHILE RINSING.
IF SWALLOWED:
CLEAN MOUTH WITH WATER AND DRINK AFTERWARDS PLENTY OF WATER.
INDUCE VOMITING IMMEDIATELY AND CALL A PHYSICIAN.
DO NOT INDUCE VOMITING.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
IRRITANT EFFECTS
EXCESSIVE LACHRYMATION
ERYTHEMA
DERMATITIS
SEE SECTION 11 FOR MORE DETAILED INFORMATION ON HEALTH EFFECTS AND
SYMPTOMS.
PROTECTION OF FIRST-AIDERS:
MOVE OUT OF DANGEROUS AREA.
CONSULT A PHYSICIAN.
SHOW THIS MATERIAL SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: CARBON DIOXIDE (CO2)
UNSUITABLE EXTINGUISHING MEDIA: WATER
SPECIFIC EXTINGUISHING METHODS:
COLLECT CONTAMINATED FIRE EXTINGUISHING WATER SEPARATELY. THIS MUST NOT BE
DISCHARGED INTO DRAINS.
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF
IN ACCORDANCE WITH LOCAL REGULATIONS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
DENY ACCESS TO UNPROTECTED PERSONS.
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPORS OR SPRAY MIST.
AVOID EXCEEDING THE GIVEN OCCUPATIONAL EXPOSURE LIMITS (SEE SECTION 8).
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
FOR PERSONAL PROTECTION SEE SECTION 8.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOLLOW STANDARD HYGIENE MEASURES WHEN HANDLING CHEMICAL PRODUCTS.
CONDITIONS FOR SAFE STORAGE:
STORE IN ORIGINAL CONTAINER.
KEEP IN A WELL-VENTILATED PLACE.
OBSERVE LABEL PRECAUTIONS.
STORE IN ACCORDANCE WITH LOCAL REGULATIONS.
MATERIALS TO AVOID: NO DATA AVAILABLE
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTAINS NO SUBSTANCES WITH OCCUPATIONAL EXPOSURE LIMIT VALUES.
ENGINEERING MEASURES:
USE OF ADEQUATE VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS. IF THE USE OF THIS PRODUCT GENERATES DUST, FUMES,
GAS, VAPOR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION OR
OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE BELOW ANY RECOMMENDED OR
STATUTORY LIMITS.
THE ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST
CONCENTRATIONS BELOW ANY LOWER EXPLOSIVE LIMITS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED NIOSH APPROVED AIR-PURIFYING OR AIR-FED RESPIRATOR
COMPLYING WITH AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS
NECESSARY.
THE FILTER CLASS FOR THE RESPIRATOR MUST BE SUITABLE FOR THE MAXIMUM
EXPECTED CONTAMINANT CONCENTRATION (GAS/VAPOR/AEROSOL/PARTICULATES) THAT
MAY ARISE WHEN HANDLING THE PRODUCT. IF THIS CONCENTRATION IS EXCEEDED,
SELF-CONTAINED BREATHING APPARATUS MUST BE USED.
HAND PROTECTION:
REMARKS:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY.
EYE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY.
SKIN AND BODY PROTECTION:
CHOOSE BODY PROTECTION IN RELATION TO ITS TYPE, TO THE CONCENTRATION AND
AMOUNT OF DANGEROUS SUBSTANCES, AND TO THE SPECIFIC WORK-PLACE.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE PRODUCT.
REMOVE RESPIRATORY AND SKIN/EYE PROTECTION ONLY AFTER VAPORS HAVE BEEN
CLEARED FROM THE AREA.
REMOVE CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING
EATING AREAS.
WASH THOROUGHLY AFTER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: PASTE
COLOR: RED
ODOR: VINEGAR-LIKE
ODOR THRESHOLD: NO DATA AVAILABLE
FLASH POINT: 199 DEG. F (93 DEG. C)
IGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT (VOL%): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT (VOL%): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
PH:
NOTE: NOT APPLICABLE
MELTING POINT/RANGE / FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
DENSITY: CA. 1.06 G/CM3 AT 73 DEG. F (23 DEG. C)
WATER SOLUBILITY:
NOTE: INSOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: >20.5 MM2/S AT 104 DEG. F (40 DEG. C)
RELATIVE VAPOR DENSITY: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
BURNING RATE: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS (VOC) CONTENT: 20 G/L
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: THE PRODUCT IS CHEMICALLY STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: EXTREMES OF TEMPERATURE AND DIRECT SUNLIGHT.
INCOMPATIBLE MATERIALS: NO DATA AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT:
ACUTE ORAL TOXICITY: NO DATA AVAILABLE
ACUTE INHALATION TOXICITY: NO DATA AVAILABLE
ACUTE DERMAL TOXICITY: NO DATA AVAILABLE
INGREDIENTS:
OCTAMETHYLCYCLOTETRASILOXANE:
ACUTE INHALATION TOXICITY:
LC50 RAT: 36 MG/L
EXPOSURE TIME: 4 H
SKIN CORROSION/IRRITATION:
PRODUCT: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION:
PRODUCT: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION:
PRODUCT: NO DATA AVAILABLE
GERM CELL MUTAGENICITY:
PRODUCT:
MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
PRODUCT:
CARCINOGENICITY: NO DATA AVAILABLE
IARC: NOT APPLICABLE
NTP: NOT APPLICABLE
REPRODUCTIVE TOXICITY/FERTILITY:
PRODUCT:
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
REPRODUCTIVE TOXICITY/DEVELOPMENT/TERATOGENICITY:
PRODUCT:
TERATOGENICITY: NO DATA AVAILABLE
STOT-SINGLE EXPOSURE:
PRODUCT:
ASSESSMENT: NO DATA AVAILABLE
STOT-REPEATED EXPOSURE:
PRODUCT:
ASSESSMENT: NO DATA AVAILABLE
ASPIRATION TOXICITY:
PRODUCT: NO DATA AVAILABLE
| 12. ECOLOGICAL INFORMATION | |
OTHER INFORMATION:
DO NOT EMPTY INTO DRAINS; DISPOSE OF THIS MATERIAL AND ITS CONTAINER IN A
SAFE WAY.
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES:
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT: NOT DANGEROUS GOODS
IATA: NOT DANGEROUS GOODS
IMDG: NOT DANGEROUS GOODS
SPECIAL PRECAUTIONS FOR USER: NO DATA AVAILABLE
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
TSCA LIST:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT ARE EITHER LISTED ON THE TSCA
INVENTORY OR ARE IN COMPLIANCE WITH A TSCA INVENTORY EXEMPTION.
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW:
CERCLA REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A CERCLA RQ.
SARA304 REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
FIRE HAZARD
SARA 302:
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313:
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
CLEAN AIR ACT:
OZONE-DEPLETION POTENTIAL:
THIS PRODUCT NEITHER CONTAINS, NOR WAS MANUFACTURED WITH A CLASS I OR
CLASS II ODS AS DEFINED BY THE U.S. CLEAN AIR ACT SECTION 602 (40 CFR 82,
SUBPT. A, APP.A + B).
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS (HAP), AS
DEFINED BY THE U.S. CLEAN AIR ACT SECTION 12 (40 CFR 61).
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS LISTED UNDER THE U.S. CLEAN AIR
ACT SECTION 112(R) FOR ACCIDENTAL RELEASE PREVENTION (40 CFR 68.130,
SUBPART F).
CALIFORNIA PROP 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
| 16. OTHER INFORMATION | |
ISSUE DATE: 12-MAY-2015
REVISION DATE:
VERSION #: 01
HMIS RATING:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARDS 0
DISCLAIMER:
HCC HOLDINGS INC. AN OATEY AFFILIATE CANNOT ANTICIPATE ALL CONDITIONS
UNDER WHICH THIS INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER
MANUFACTURERS IN COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE
USER'S RESPONSIBILITY TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND
DISPOSAL OF THE PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE
OR EXPENSE DUE TO IMPROPER USE. THE INFORMATION IN THE SHEET WAS WRITTEN
BASED ON THE BEST KNOWLEDGE AND EXPERIENCE CURRENTLY AVAILABLE.
HERCULES HIGH TEMP RED
SDS: #7332E
SDS US