| Common Name: | SAFE N' EASY HEAVY DUTY RESTORATION CLEANER |
| Manufacturer: | DUMOND CHEMICALS |
| SDS Revision Date: | 3/3/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 39C347, 39C348 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DUMOND(R*)
ARCHITECTURAL, INDUSTRIAL AND MARINE SOLUTIONS
SAFETY DATA SHEET
ISSUE DATE: 21-JUL-2006
REVISION DATE: 3-MAR-2015
VERSION: 1
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: SAFE N' EASY HEAVY DUTY RESTORATION CLEANER
OTHER MEANS OF IDENTIFICATION:
SDS #: DCI-024
UN/ID NO: UN3264
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: CLEANING AGENT.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
DUMOND CHEMICALS, INC.
83 GENERAL WARREN BLVD
SUITE 190
MALVERN, PA 19355
EMERGENCY TELEPHONE NUMBER:
COMPANY PHONE NUMBER: 1-609-655-7700
EMERGENCY TELEPHONE:
INFOTRAC:
1-352-323-3500 (INTERNATIONAL)
1-800-535-5053 (NORTH AMERICA)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
ACUTE TOXICITY - ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY C
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
EXCLAMATION MARK
CORROSION
APPEARANCE: CLEAR LIQUID
PHYSICAL STATE: LIQUID
ODOR:
NO ODOR WHEN THE PRODUCT IS APPLIED, AMMONIA IS RELEASED, WHICH HAS A
SLIGHTLY PUNGENT ODOR
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
RINSE MOUTH
DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO WEIGHT-%
AMMONIUM BIFLUORIDE 1341-49-7 20-30
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE: PROVIDE THIS SDS TO MEDICAL PERSONNEL FOR TREATMENT.
INHALATION:
REMOVE TO FRESH AIR. RESTORE BREATHING. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE ANY
CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. GET IMMEDIATE
MEDICAL ADVICE/ATTENTION.
INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE MILK, CHEWABLE
CALCIUM CARBONATE TABLETS, OR MILK OF MAGNESIA. IMMEDIATE MEDICAL ATTENTION
IS REQUIRED.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
MAY CAUSE SEVERE CHEMICAL BURNS WITH REDDENING AND PAIN. MAY CAUSE
RESPIRATORY IRRITATION. MAY CAUSE GASTROINTESTINAL IRRITATION, CNS
DEPRESSION, BLINDNESS, OR DEATH. MAY CAUSE FLUORIDE POISONING WITH
SYMPTOMS INCLUDING WEAKNESS, TREMORS, SHALLOW BREATHING, SPASMS OF THE
HANDS AND FEET, CONVULSIONS, AND COMA. MAY CAUSE MOTTLING OF TEETH, DAMAGE
TO BONE AND FLUOROSIS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS:
TREAT SYMPTOMATICALLY. SWALLOWING LARGE AMOUNTS MAY CAUSE HYPOCALCEMIA AND
HYPOMAGNESIA.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA: NOT DETERMINED.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTACT WITH ALKALIS AND METALS MAY EVOLVE FLAMMABLE HYDROGEN GAS. EMITS
TOXIC FUMES UNDER FIRE CONDITIONS.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR. COOL
CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
DIKE SPILL AND PREVENT SPILL FROM ENTERING SEWERS AND WATERWAYS. COLLECT
USING AN INERT ABSORBENT MATERIAL AND PLACE IN APPROPRIATE CONTAINERS FOR
DISPOSAL.
METHODS FOR CLEANING UP:
WASH SPILL AREA WITH PLENTY OF WATER. SPILLS AND RELEASES MAY HAVE TO BE
REPORTED TO FEDERAL AND/OR LOCAL AUTHORITIES. SEE SECTION 15.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. USE WITH ADEQUATE VENTILATION.
WASH FACE, HANDS, AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING. DO NOT
EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. DO NOT BREATHE DUST/FUME/
GAS/MIST/VAPORS/SPRAY. USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN A COOL, WELL VENTILATED AREA AWAY FROM ACIDS AND OTHER
INCOMPATIBLE SUBSTANCES. DO NOT STORE IN METAL CONTAINERS. STORE LOCKED UP.
INCOMPATIBLE MATERIALS:
ACIDS. ALKALI. SULFIDES. SULFUR OXIDES. AMMONIA. BASES. CAUSTIC.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
AMMONIUM BIFLUORIDE TWA: 2.5 MG/M3 F TWA: 2.5 MG/M3 F TWA: 2.5 MG/M3 F
1341-49-7
TWA:
2.5 MG/M3 DUST
(VACATED)
TWA: 2.5 MG/M3
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
IF THE RECOMMENDED EXPOSURE LIMIT IS EXCEEDED INCREASED MECHANICAL
VENTILATION SUCH AS LOCAL EXHAUST MAY BE REQUIRED. FOR OPERATIONS WHERE
CONTACT CAN OCCUR, A SAFETY SHOWER AND AN EYE WASH FACILITY SHOULD BE
AVAILABLE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: CHEMICAL SAFETY GOGGLES/FACESHIELD.
SKIN AND BODY PROTECTION:
WEAR PROTECTIVE GLOVES AND PROTECTIVE CLOTHING. NEOPRENE, NITRILE, 4H, OR
OTHER IMPERVIOUS GLOVES ARE RECOMMENDED TO PREVENT SKIN CONTACT.
RESPIRATORY PROTECTION:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. FOR SPRAY
APPLICATIONS OR LARGE JOBS, AN APPROVED FULL FACEPIECE PARTICULATE
RESPIRATOR WITH EYE PROTECTION.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR LIQUID
ODOR:
NO ODOR WHEN THE PRODUCT IS APPLIED, AMMONIA IS RELEASED, WHICH HAS A
SLIGHTLY PUNGENT ODOR
COLOR: CLEAR
ODOR THRESHOLD: NOT DETERMINED
PROPERTY VALUES REMARKS - METHOD
PH 4
MELTING POINT/FREEZING POINT NOT DETERMINED
BOILING POINT/BOILING RANGE NOT AVAILABLE
FLASH POINT NONE
EVAPORATION RATE SAME AS WATER
FLAMMABILITY (SOLID, GAS) NOT DETERMINED
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMITS NOT APPLICABLE
LOWER FLAMMABILITY LIMIT NOT APPLICABLE
VAPOR PRESSURE SAME AS WATER
VAPOR DENSITY NOT AVAILABLE
SPECIFIC GRAVITY APPROX. 1.05
WATER SOLUBILITY COMPLETELY SOLUBLE
SOLUBILITY IN OTHER SOLVENTS NOT DETERMINED
PARTITION COEFFICIENT NOT DETERMINED
AUTOIGNITION TEMPERATURE NONE
DECOMPOSITION TEMPERATURE NOT DETERMINED
KINEMATIC VISCOSITY NOT DETERMINED
DYNAMIC VISCOSITY NOT DETERMINED
EXPLOSIVE PROPERTIES NOT DETERMINED
OXIDIZING PROPERTIES NOT DETERMINED
OTHER INFORMATION:
VOC CONTENT (%) 0%
VOC CONTENT 0 LBS/GAL
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
CONTACT WITH METALS AND ALKALIS MAY RELEASE FLAMMABLE HYDROGEN GAS. REACTS
WITH ACIDS TO LIBERATE TOXIC AND CORROSIVE HYDROGEN FLUORIDE. REACTS WITH
BASES TO LIBERATE AMMONIA.
INCOMPATIBLE MATERIALS:
ACIDS. ALKALI. SULFIDES. SULFUR OXIDES. AMMONIA. BASES. CAUSTIC.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION MAY YIELD TOXIC HYDROGEN FLUORIDE, NITRIC OXIDES,
AND AMMONIA.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION: AVOID BREATHING VAPORS OR MISTS.
EYE CONTACT: CAUSES SEVERE EYE DAMAGE.
SKIN CONTACT: CAUSES SEVERE SKIN BURNS.
INGESTION: HARMFUL IF SWALLOWED.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
WATER >90 ML/KG (RAT)
7732-18-5
AMMONIUM BIFLUORIDE =130 MG/KG (RAT)
1341-49-7
INFORMATION ON PHYSICAL, CHEMICAL AND TOXICOLOGICAL EFFECTS:
SYMPTOMS:
MAY CAUSE BURNS TO MOUTH AND GASTROINTESTINAL CORROSION. MAY CAUSE FLUORIDE
POISONING WITH SYMPTOMS INCLUDING WEAKNESS, TREMORS, SHALLOW BREATHING,
SPASMS OF THE HANDS AND FEET, CONVULSIONS, AND COMA. MAY CAUSE SKIN AND EYE
IRRITATION. MAY CAUSE MOTTLING OF TEETH, DAMAGE TO BONE AND FLUOROSIS. MAY
CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. INHALATION OF HIGH VAPOR
CONCENTRATIONS MAY CAUSE SYMPTOMS LIKE HEADACHE, DIZZINESS, TIREDNESS,
NAUSEA AND VOMITING.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CARCINOGENICITY:
THE TABLE BELOW INDICATES WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT AS
A CARCINOGEN.
CHEMICAL NAME ACGIH IARC NTP OSHA
AMMONIUM BIFLUORIDE GROUP 3
1341-49-7
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 3 IARC COMPONENTS ARE "NOT CLASSIFIABLE AS HUMAN CARCINOGENS"
NUMERICAL MEASURES OF TOXICITY- PRODUCT: NOT DETERMINED
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.
ATEMIX (ORAL): 520 MG/KG
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL
PERSISTENCE AND DEGRADABILITY: NOT DETERMINED.
BIOACCUMULATION: NOT DETERMINED.
MOBILITY: NOT DETERMINED.
OTHER ADVERSE EFFECTS: NOT DETERMINED
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
| 14. TRANSPORT INFORMATION | |
NOTE:
PLEASE SEE CURRENT SHIPPING PAPER FOR MOST UP TO DATE SHIPPING INFORMATION,
INCLUDING EXEMPTIONS AND SPECIAL CIRCUMSTANCES
DOT:
UN/ID NO: UN3264
PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (AMMONIUM HYDROGENDIFLUORIDE)
HAZARD CLASS: 8
PACKING GROUP: III
IATA:
UN/ID NO: UN3264
PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (AMMONIUM HYDROGENDIFLUORIDE)
HAZARD CLASS: 8
PACKING GROUP: III
IMDG:
UN/ID NO: UN3264
PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (AMMONIUM HYDROGENDIFLUORIDE)
HAZARD CLASS: 8
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
CHEMICAL NAME CAS NO WEIGHT-% SARA 313 - THRESHOLD VALUES %
AMMONIUM BIFLUORIDE 1341-49-7 20-30 1.0
1341-49-7
SARA 311/312 HAZARD CATEGORIES:
CHEMICAL NAME CWA - CWA - TOXIC CWA - PRIORITY CWA -
REPORTABLE POLLUTANTS POLLUTANTS HAZARDOUS
QUANTITIES SUBSTANCES
AMMONIUM BIFLUORIDE 100 LB X
1341-49-7
CHEMICAL NAME HAZARDOUS CERCLA/SARA RQ REPORTABLE QUANTITY
SUBSTANCES RQS (RQ)
AMMONIUM BIFLUORIDE 100 LB RQ: 100 LB FINAL RQ
1341-49-7 RQ: 45.4 KG FINAL RQ
US STATE REGULATIONS:
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
AMMONIUM BIFLUORIDE X X X
1341-49-7
U.S. EPA LABEL INFORMATION:
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS NOT DETERMINED
FLAMMABILITY NOT DETERMINED
INSTABILITY NOT DETERMINED
SPECIAL HAZARDS NOT DETERMINED
HMIS:
HEALTH HAZARDS 3*
FLAMMABILITY 0
PHYSICAL HAZARDS 0
PERSONAL PROTECTION NOT DETERMINED
CHRONIC HAZARD STAR LEGEND:
* = CHRONIC HEALTH HAZARD
ISSUE DATE: 21-JUL-2006
REVISION DATE: 12-DEC-2012
REVISION NOTE: NEW FORMAT
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.