| Common Name: | E-WELD NOZZLE |
| Manufacturer: | WALTER SURFACE TECHNOLOGIES |
| SDS Revision Date: | 9/30/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 39CH06, 52HR21 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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W
WALTER
SURFACE TECHNOLOGIES
CONFORMS TO HCS 2012 - UNITED STATES
SAFETY DATA SHEET
E-WELD NOZZLE
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: E-WELD NOZZLE
PRODUCT CODE: 53-F 212
SDS NO.: L-156E
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: LUBRICANT.
MANUFACTURER:
WALTER SURFACE TECHNOLOGIES INC.
5977 TRANS CANADA HIGHWAY
POINTE-CLAIRE, QC H9R 1C1
CANADA
INFO@WALTER.COM
WWW.WALTER.COM
GENERAL INFORMATION: 1-888-592-5837
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
INFOTRAC(R*): 1-800-535-5053.
INTERNATIONAL CALL COLLECT: 1-352-323-3500 24 HOURS/DAY, 7 DAYS/WEEK.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
SIMPLE ASPHYXIANTS
SERIOUS EYE DAMAGE/ EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC
EFFECTS): CATEGORY 3
AQUATIC HAZARD (ACUTE): CATEGORY 3
AQUATIC HAZARD (LONG-TERM): CATEGORY 3
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
NO CODE(S): MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P280: WEAR EYE OR FACE PROTECTION.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER
IGNITION SOURCES. NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P261: AVOID BREATHING VAPOR.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
RESPONSE:
P304 + P340 + P312:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL
A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
P405: STORE LOCKED UP.
P410: PROTECT FROM SUNLIGHT.
P412: DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F.
P403: STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
KEEP CONTAINER TIGHTLY CLOSED. USE ONLY WITH ADEQUATE VENTILATION. DO NOT
ENTER STORAGE AREAS AND CONFINED SPACES UNLESS ADEQUATELY VENTILATED.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT CODE: 53-F 212
INGREDIENT NAME % CAS NUMBER
ETHANOL >/=10 - </=25 64-17-5
ACETONE >/=10 - </=25 67-64-1
C.I. SOLVENT ORANGE 54 >/=1 - <2.5 85029-59-0
THIS MIXTURE CONTAINS BORON NITRIDE POWDER (CAS 10043-11-5) IN THE RANGE
BETWEEN 10-30%. THIS INGREDIENT IS NOT CLASSIFIED UNDER HAZCOM 2012.
THE EXACT PERCENTAGE (CONCENTRATION) IN THE COMPOSITION HAS BEEN WITHHELD
AS A TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CONTINUE TO RINSE FOR AT LEAST 20 MINUTES. GET MEDICAL
ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF
SYMPTOMS OCCUR.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND
THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK.
STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE DANGEROUS. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET MEDICAL
ATTENTION IF ADVERSE HEALTH EFFECTS PERSIST OR ARE SEVERE. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY
IF LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE, USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION
HAZARD. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE
CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT EXPLOSION. GAS MAY
ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE DISTANCE TO
A SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE OR EXPLOSION. BURSTING
AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT HIGH SPEED. THIS
MATERIAL IS HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE WATER
CONTAMINATED WITH THIS MATERIAL MUST BE CONTAINED AND PREVENTED FROM BEING
DISCHARGED TO ANY WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL IGNITION
SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. AVOID BREATHING
VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR
WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT
IF RELEASED IN LARGE QUANTITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER
USE. DO NOT INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID
BREATHING GAS. AVOID BREATHING VAPOR OR MIST. AVOID RELEASE TO THE
ENVIRONMENT. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. STORE AND USE AWAY FROM
HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE
EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL
HANDLING) EQUIPMENT. USE ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS
RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS
AND FACE BEFORE EATING, DRINKING AND SMOKING. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
OPTIMAL STORAGE:
8 DEG. C TO 21 DEG. C. STORAGE BELOW 8 DEG. C OR GREATER THAN 28 DEG. C
CAN ADVERSELY AFFECT PRODUCT PROPERTIES. STORE IN ACCORDANCE WITH LOCAL
REGULATIONS. PROTECT FROM SUNLIGHT. ELIMINATE ALL IGNITION SOURCES. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
ETHANOL ACGIH TLV (UNITED STATES,
3/2017).
STEL: 1000 PPM 15 MINUTES.
NIOSH REL (UNITED STATES,
10/2016).
TWA: 1000 PPM 10 HOURS.
TWA: 1900 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES,
6/2016).
TWA: 1000 PPM 8 HOURS.
TWA: 1900 MG/M3 8 HOURS.
ACETONE ACGIH TLV (UNITED STATES,
3/2017).
TWA: 250 PPM 8 HOURS.
STEL: 500 PPM 15 MINUTES.
NIOSH REL (UNITED STATES,
10/2016).
TWA: 250 PPM 10 HOURS.
TWA: 590 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES,
6/2016).
TWA: 1000 PPM 8 HOURS.
TWA: 2400 MG/M3 8 HOURS.
C.I. SOLVENT ORANGE 54 NONE.
APPROPRIATE ENGINEERING CONTROLS:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. AVOID
BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. WHEN WORKERS ARE FACING
CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST USE APPROPRIATE
CERTIFIED RESPIRATORS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN
A RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER
DEGREE OF PROTECTION: FACE SHIELD
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTI-STATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A NIOSH/MSHA APPROVED RESPIRATOR IF THERE IS A RISK OF EXPOSURE
AT LEVELS EXCEEDING THE EXPOSURE LIMITS. ADVICE SHOULD BE SOUGHT FROM
RESPIRATORY PROTECTION SPECIALISTS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: ORANGE.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT APPLICABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: -1 DEG. C (30.2 DEG. F) (PROPELLANT)
FLASH POINT CLOSED CUP: -60 DEG. C (-76 DEG. F) (PROPELLANT)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 365 DEG. C (689 DEG. F) (PROPELLANT)
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
FLOW TIME (ISO 2431): NOT AVAILABLE.
VOC CONTENT: 84% (W/W)
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 51.47 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT
OR ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL
NOT OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME).
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS, ACIDS AND ALKALIS.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
ETHANOL LC50 RAT 124700 4 HOURS
INHALATION MG/M3
VAPOR
LD50 ORAL RAT 7 G/KG
ACETONE LD50 ORAL RAT 5800
MG/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
ETHANOL EYES - MILD RABBIT 24 HOURS
IRRITANT 500 MG
EYES - RABBIT 0.066666667
MODERATE MINUTES
IRRITANT 100 MG
EYES - RABBIT 100
MODERATE (MICRO)L
IRRITANT
EYES - RABBIT 500 MG
SEVERE
IRRITANT
SKIN - MILD RABBIT 400 MG
IRRITANT
ACETONE EYES - MILD RABBIT 10
IRRITANT (MICRO)L
EYES - RABBIT 24 HOURS
MODERATE 20 MG
IRRITANT
EYES - RABBIT 20 MG
SEVERE
IRRITANT
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500 MG
SKIN - MILD RABBIT 395 MG
IRRITANT
SENSITIZATION: THERE IS NO DATA AVAILABLE.
MUTAGENICITY: THERE IS NO DATA AVAILABLE.
CARCINOGENICITY: THERE IS NO DATA AVAILABLE.
REPRODUCTIVE TOXICITY: THERE IS NO DATA AVAILABLE.
TERATOGENICITY: THERE IS NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY TARGET ORGANS
ACETONE CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
THERE IS NO DATA AVAILABLE.
ASPIRATION HAZARD: THERE IS NO DATA AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
DERMAL CONTACT. EYE CONTACT. INHALATION. INGESTION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM
SHORT AND LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: THERE IS NO DATA AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
ETHANOL ACUTE EC50 CRUSTACEANS - CYPRIS 48 HOURS
1074 MG/L FRESH SUBGLOBOSA
WATER
ACUTE LC50 5680 DAPHNIA - DAPHNIA 48 HOURS
MG/L FRESH WATER MAGNA - NEONATE
ACUTE LC50 FISH - ALBURNUS 96 HOURS
11000000 ALBURNUS
(MICRO)G/L MARINE
WATER
CHRONIC NOEC ALGAE - ULVA PERTUSA 96 HOURS
4.995 MG/L MARINE
WATER
CHRONIC NOEC 100 DAPHNIA - DAPHNIA 21 DAYS
UL/L FRESH WATER MAGNA - NEONATE
CHRONIC NOEC 0.375 FISH - GAMBUSIA 12 WEEKS
UL/L FRESH WATER HOLBROOKI - LARVAE
ACETONE ACUTE EC50 7200000 ALGAE - SELENASTRUM 96 HOURS
(MICRO)G/L FRESH SP.
WATER
ACUTE LC50 CRUSTACEANS - 48 HOURS
6000000 (MICRO)G/L GAMMARUS PULEX
FRESH WATER
ACUTE LC50 6900 DAPHNIA - DAPHNIA 48 HOURS
MG/L FRESH WATER MAGNA
ACUTE LC50 5600 FISH - POECILIA 96 HOURS
PPM FRESH WATER RETICULATA
CHRONIC NOEC 4.95 ALGAE - ULVA PERTUSA 96 HOURS
MG/L MARINE WATER
CHRONIC NOEC 0.016 CRUSTACEANS - 21 DAYS
ML/L FRESH WATER DAPHNIIDAE
CHRONIC NOEC 0.1 DAPHNIA - DAPHNIA 21 DAYS
ML/L FRESH WATER MAGNA - NEONATE
PERSISTENCE AND DEGRADABILITY: THERE IS NO DATA AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
ETHANOL -0.35 LOW
ACETONE -0.23 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD COMPLY WITH
THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL LEGISLATION
AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF SURPLUS AND
NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL CONTRACTOR. WASTE
SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS FULLY COMPLIANT
WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION. WASTE PACKAGING
SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE CONSIDERED WHEN
RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED
OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT
RESIDUES. DO NOT PUNCTURE OR INCINERATE CONTAINER.
UNITED STATES - RCRA TOXIC HAZARDOUS WASTE "U" LIST:
INGREDIENT CAS # STATUS REFERENCE NUMBER
ACETONE 67-64-1 LISTED U002
| SECTION 14. TRANSPORT INFORMATION | |
DOT IMDG IATA
CLASSIFICATION
UN NUMBER UN1950 UN1950 UN1950
UN PROPER AEROSOLS, FLAMMABLE AEROSOLS, AEROSOLS,
SHIPPING NAME (EACH NOT EXCEEDING FLAMMABLE (EACH FLAMMABLE
1 L CAPACITY) NOT EXCEEDING 1 (EACH NOT
L CAPACITY) EXCEEDING 1 L
CAPACITY)
TRANSPORT 2.1 2.1 2.1
HAZARD CLASS(ES) FLAMMABLE GAS, CLASS 2.1 - CLASS 2.1,
CLASS/DIVISION 2.1 FLAMMABLE GASES FLAMMABLE
GASES
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
AERG: 126
DOT-RQ DETAILS:
ACETONE: 5000 LBS / 2270 KG [758.12 GAL / 2869.8 L]
ADDITIONAL INFORMATION:
DOT CLASSIFICATION:
REPORTABLE QUANTITY 20833.3 LBS / 9458.3 KG. PACKAGE SIZES SHIPPED IN
QUANTITIES LESS THAN THE PRODUCT REPORTABLE QUANTITY ARE NOT SUBJECT
TO THE RQ (REPORTABLE QUANTITY) TRANSPORTATION REQUIREMENTS.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE. PROTECT FROM FREEZING. FREEZING WILL DAMAGE PRODUCT
AND RENDER IT UNUSABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN WATER ACT (CWA) 307: C.I. SOLVENT ORANGE 54
CLEAN AIR ACT (CAA) 112 REGULATED FLAMMABLE SUBSTANCES: BUTANE; PROPANE
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION:
FLAMMABLE AEROSOLS - CATEGORY 1
GASES UNDER PRESSURE - COMPRESSED GAS
SIMPLE ASPHYXIANTS
SERIOUS EYE DAMAGE/ EYE IRRITATION - CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC
EFFECTS) - CATEGORY 3
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME CLASSIFICATION
ETHANOL FLAMMABLE LIQUIDS - CATEGORY 2
SERIOUS EYE DAMAGE/ EYE
IRRITATION - CATEGORY 2A
ACETONE FLAMMABLE LIQUIDS - CATEGORY 2
SERIOUS EYE DAMAGE/ EYE
IRRITATION - CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY
(SINGLE EXPOSURE) (NARCOTIC
EFFECTS) - CATEGORY 3
SARA 313: THERE IS NO DATA AVAILABLE.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: BUTANE; PROPANE; ETHANOL; ACETONE
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: ACETONE
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
BUTANE; PROPANE; ETHANOL; ACETONE; C.I. SOLVENT ORANGE 54
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
BUTANE; PROPANE; ETHANOL; ACETONE; C.I. SOLVENT ORANGE 54
CALIFORNIA PROP. 65: NO PRODUCTS WERE FOUND.
INTERNATIONAL LISTS:
NATIONAL INVENTORY:
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
NEW ZEALAND: ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN: ALL COMPONENTS ARE LISTED OR EXEMPTED.
TURKEY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
| SECTION 16. OTHER INFORMATION | |
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE AEROSOLS - CATEGORY 1 ON BASIS OF TEST DATA
GASES UNDER PRESSURE - COMPRESSED GAS EXPERT JUDGMENT
SIMPLE ASPHYXIANTS CALCULATION METHOD
SERIOUS EYE DAMAGE/ EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(NARCOTIC EFFECTS) - CATEGORY 3
AQUATIC HAZARD (ACUTE) - CATEGORY 3 CALCULATION METHOD
AQUATIC HAZARD (LONG-TERM) - CATEGORY 3 CALCULATION METHOD
HISTORY:
DATE OF ISSUE MM/DD/YYYY: 09/30/2018
DATE OF PREVIOUS ISSUE: 01/15/2017
VERSION: 4
PREPARED BY: KMK REGULATORY SERVICES INC.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
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