| Common Name: | HYDROCHLORIC ACID, 20 DEG BE, TECHNICAL |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 6/1/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39D861 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2008 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 5/27/2014
REVISION DATE: 6/1/2017
REVISION NUMBER: G2
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: H1040
PRODUCT NAME: HYDROCHLORIC ACID, 20 DEG BE, TECHNICAL
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
MURIATIC ACID;
CHLOROHYDRIC ACID;
SPIRITS OF SALT
ACIDE CHLORHYDRIQUE (FRENCH)
CAS #: 7647--01-0
RTECS #: MW4025000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
IN THE PRODUCTION OF CHLORIDE; REFINING ORE IN THE PRODUCTION OF TIN AND
TANTALUM; FOR THE NEUTRALIZATION OF BASIC SYSTEMS; AS A LABORATORY REAGENT;
AS A CATALYST AND SOLVENT IN ORGANIC SYNTHESIS; FOR OIL AND GAS-WELL
TREATMENT; IN REMOVING SCALE FROM BOILERS AND HEAT EXCHANGE EQUIPMENT;
PHARMACEUTIC AID (ACIDIFIER); IN THE MANUFACTURE OF PHOSPHORIC ACID AND IN
THE PRODUCTION OF AMMONIUM CHLORIDE; METAL TREATING AGENT (STEEL PICKLING);
IN FOOD PROCESSING AS A STARTCH MODIFIER; IN THE MANUFACTURER OF SODIUM
GLUTAMATE; IN THE MANUFACTURER OF GELATIN; IN THE CONVERSION OF
CORNSTARTCH TO SYRUP; IN THE BREWING INDUSTRY; IN SUGAR REFINING; IN THE
MANUFACTURE OF FERTILIZERS, DYES AND DYESTUFFS, ARTIFICAL SILKS, PIGMENTS
FOR PAINTS; IN ELECTROPLATING, LEATHER TANNING, THE PHOTOGRAPHIC INDUSTRY,
IN SOAP REFINING, IN THE TEXTILE INDUSTRY, IN THE RUBBER INDUSTRY; IN
PETROLEUM ACTIVATION; METAL CLEANING OPERATIONS; RECOVERY OF ZINC FROM
GALVANIZED IRON SCRAP.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000.
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 4
ACUTE TOXICITY - INHALATION (GASES): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY A
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
HARMFUL IF INHALED
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
MAY CAUSE RESPIRATORY IRRITATION
CORROSION
EXCLAMATION MARK
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. IMMEDIATELY CALL
A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
RINSE MOUTH
DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
WATER 7732-18-5 68-70
HYDROGEN CHLORIDE 7647-01-0 30-32
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. FIRST
AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING
WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED
CLOTHES AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A
PHYSICIAN IMMEDIATELY.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS
OR CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED
OR INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A
POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. DO NOT GIVE SODIUM
BICARBONATE (BAKING SODA). NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IF VICTIM IS CONSCIOUS, GIVE WATER OR MILK. IMMEDIATE MEDICAL
ATTENTION IS REQUIRED. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SEVERE SKIN IRRITATION. SEVERE EYE IRRITATION. SEVERE SKIN AND EYE
IRRITATION OR BURNS. IRRITATING TO RESPIRATORY SYSTEM. BURNING SENSATION
OF THE RESPIRATORY TRACT. COUGHING. HOARSENESS OF THE VOICE. CHOKING
SENSATION. DYSPNEA (SHORTNESS OF BREATH AND DIFFICULTY BREATHING).
SHALLOW RESPIRATION. CAN BURN MOUTH, THROAT, AND STOMACH. MAY CAUSE
SALIVATION. THIRST. MAY CAUSE DIFFICULTY SWALLOWING. MAY CAUSE ABDOMINAL
PAIN, NAUSEA, VOMITING, DIARRHEA. WEAK, RAPID PULSE OR RAPID HEART RATE
(TACHYCARDIA). SHOCK.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH
THE FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS:
CONTACT WITH METALS MAY EVOLVE FLAMMABLE HYDROGEN GAS. CALCIUM CARBIDE
REACTS WITH HYDROGEN CHLORIDE GAS WITH INCANDESCENCE. URANIUM PHOSPHIDE
REACTS WITH HYDROCHLORIC ACID TO RELEASE SPONTANEOUSLY FLAMMABLE
PHOSPHINE. RUBIDIUM ACETYLENE CARBIDE BURNS WITH SLIGHTLY WARM HYDROCHLORIC
ACID. LITHIUM SILICIDE IN CONTACT WITH HYDROGEN CHLORIDE BECOMES
INCANDESCENT. WHEN DILUTE HYDROCHLORIC ACID IS USED, GAS THAT IS
SPONTANEOUSLY FLAMMABLE IN AIR IS EVOLVED. MAGNESIUM BORIDE TREATED WITH
CONCENTRATED HYDROCHLORIC ACID PRODUCES SPONTANEOUSLY FLAMMABLE GAS. CESIUM
ACETYLENE CARBIDE BURNS IN HYDROGEN CHLORIDE GAS. CESIUM CARBIDE IGNITES IN
CONTACT WITH HYDROCHLORIC ACID UNLESS ACID IS DILUTE. HYDROGEN CHLORIDE IN
CONTACT WITH THE FOLLOWING CAN CAUSE AN EXPLOSION, IGNITION ON CONTACT, OR
OTHER VIOLENT/VIGOROUS REACTION:
ACETIC ANHYDRIDE AgClO + CCl4 ALCOHOLS + HYDROGEN CYANIDE, ALUMINUM
ALUMINUM-TITANIUM ALLOYS (WITH HCl VAPOR), 2-AMINO ETHANOL, AMMONIUM
HYDROXIDE, CALCIUM CARBIDE Ca3P2 CHLORINE + DINITROANILINES (EVOLVES GAS),
CHLOROSULFONIC ACID CESIUM CARBIDE CESIUM ACETYLENE CARBIDE,
1,1-DIFLUOROETHYLENE ETHYLENE DIAMINE ETHYLENE IMINE, FLUORINE, HClO4
HEXALITHIUM DISILICIDE H2SO4 METAL ACETYLIDES OR CARBIDES, MAGNESIUM
BORIDE, MERCURIC SULFATE, OLEUM, POTASSIUM PERMANGANATE, BETA-PROPIOLACTONE
PROPYLENE OXIDE RUBIDIUM CARBIDE, RUBIDIUM, ACETYLENE CARBIDE SODIUM
(WITH AQUEOUS HCl), SODIUM HYDROXIDE SODIUM TETRASELENIUM, SULFONIC ACID,
TETRASELENIUM TETRANITRIDE, U3P4, VINYL ACETATE. SILVER PERCHLORATE WITH
CARBON TETRACHLORIDE IN THE PRESENCE OF HYDROCHLORIC ACID PRODUCES
TRICHLOROMETHYL PERCHLORATE WHICH DETONATES AT 40 DEG. C.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. USE PERSONAL PROTECTIVE EQUIPMENT.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. SHOULD NOT BE
RELEASED INTO THE ENVIRONMENT. DO NOT LET PRODUCT ENTER DRAINS. DO NOT
FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT: STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
METHODS FOR CLEANING UP:
NEUTRALIZE WITH SODIUM CARBONATE OR SODIUM BICARBONATE. DILUTE WITH WATER.
ABSORB SPILL WITH INERT MATERIAL (E.G. VERMICULITE, DRY SAND OR EARTH),
THEN PLACE IN A SUITABLE CHEMICAL WASTE CONTAINER. CLEAN CONTAMINATED
SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS OR SPRAY MIST. HANDLE IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. MAY CORRODE METALLIC SURFACES.
DO NOT STORE IN UNCOATED METALLIC CONTAINERS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
METALS
ALKALIS
ORGANIC MATERIALS
WATER
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS CAS-NO. OSHA NIOSH ACGIH AIHA WHEEL
WATER 7732-18-5 NONE NONE NONE NONE
HYDROGEN 7647-01-0 5 PPM 5 PPM 2 PPM NONE
CHLORIDE CEILING CEILING CEILING
7 MG/M3 7 MG/M3
CEILING CEILING
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
WATER 7732-18-5 NONE NONE NONE NONE
HYDROGEN 7647-01-0 2 PPM 2 PPM 2 PPM 5 PPM CEILING
CHLORIDE CEILING CEILING CEILING
7.5 MG/M3
3 MG/M3 CEILING
CEILING
AUSTRALIA AND MEXICO:
COMPONENTS CAS-NO. AUSTRALIA MEXICO
WATER 7732-18-5 NONE NONE
HYDROGEN CHLORIDE 7647-01-0 NONE 5 PPM CEILING
7 MG/M3 CEILING
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND
MIST BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: FACE-SHIELD
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT PROTECTIVE SUIT
GLOVES
BOOTS
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: COLORLESS. LIGHT YELLOW.
ODOR: PUNGENT. IRRITATING.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: HCl
MOLECULAR/FORMULA WEIGHT: NO INFORMATION AVAILABLE
FLAMMABILITY: NO INFORMATION AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F):
-62.25 DEG. C (-80 DEG. F) (20.69% HCl IN WATER)
-46.2 C (31.24% HCl IN WATER)
-25.4 C (39.17% HCl IN WATER)
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F):
108.58 C @ 760 MM Hg (FOR 20.22% HCl IN WATER)
83 C @ 760 MM Hg (FOR 31% HCl IN WATER)
50.5 C (FOR 37% HCl IN WATER)
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY:
1.1 - 1.19 (WATER = 1)
1.10 (20% AND 22% HCl SOLUTIONS)
1.12 (24% HCl SOLUTION)
1.15 (29.57% HCl SOLUTION)
1.16 (32% HCl SOLUTION)
1.186 - 1.19 (37% AND 38% HCl SOLUTIONS)
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: 1.267
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): 0.25 TO 10 PPM
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
SOLUBLE IN ETHER
SOLUBLE IN WATER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
FOR HYDROGEN CHLORIDE OR CONCENTRATED HYDROCHLORIC ACID:
REACTS WITH MOST METALS TO PRODUCE FLAMMABLE HYDROGEN GAS.
SODIUM REACTS VERY VIOLENTLY WITH GASEOUS HYDROGEN CHLORIDE.
CALCIUM PHOSPHIDE AND HYDROCHLORIC ACID UNDERGO A VERY ENERGETIC REACTION.
HYDROGEN CHLORIDE REACTS WITH OXIDIZERS RELEASING CHLORINE GAS.
HYDROGEN CHLORIDE GAS IS EMITTED WHEN HYDROCHLORIC ACID COMES IN CONTACT
WITH SULFURIC ACID.
ADSORPTION OF HYDCHLORIC ACID ONTO SILICON DIOXIDE RESULTS IN EXOTHERMIC
REACTION.
HYDROGEN CHLORIDE CAUSES ALDEHYDES AND EPOXIDES TO VIOLENTLY POLYMERIZE.
REACTS VIOLENTLY WITH BASES, OXIDIZERS FORMING TOXIC CHLORINE GAS.
REACTS, OFTEN VIOLENTLY OR VIGOROUSLY OR EXOTHERMICALLY, WITH ACETIC
ANHYDRIDE, ACTIVE METALS, ALIPHATIC AMINES, ALKANOLAMINES, ALKYLENE
OXIDES, AROMATIC AMINES, AMIDES, 2-AMINOETHANOL, AMMONIA, AMMONIUM
HYDROXIDE, CALCIUM PHOSPHIDE, CHLOROSULFONIC ACID, ETHYLENE DIAMINE,
ETHYLENEIMINE, EPICHLOROHYDRIN, ISOCYANATES, METAL ACETYLIDES, OLEUM,
ORGANIC ANHYDRIDES, PERCHLORIC ACID, 3-PROPIOLACTONE, URANIUM PHOSPHIDE,
SULFURIC ACID, VINYL ACETATE, VINYLIDENE FLUORIDE, ALCOHOLS + HYDROGEN
CYANIDE, ALUMINUM PHOSPHIDE, ALUMINUM-TITANIUM ALLOYS, 2-AMINO ETHANOL,
AMMONIUM HYDROXIDE, AMMONIUM, 1,4-BENZOQUINONE DIIMINE, CESIUM
TELLUROACYLATED, CHLORINE + DINITROANILINES, CHLOROACETALDEHYDE OXIME,
CYANOGEN CHLORIDE, 1,1-DIFLUOROEETHYLENE, DINITROANILINES, ETHYLENE,
ETHYL 2-FORMYLPROPIONATE OXIME, HEXALITHIUM DISILICIDE, HYDROGEN PEROXIDE,
METHYL VINYL ETHER, NITRIC ACID + GLYCEROL, POTASSIUM, POTASSIUM
PERMANGANATE, BETA-PROPIOLACTONE, PROPYLENE OXIDE, RUBIDIUM ACETYLIDE,
SILVER CHLORITE, SODIUM 2-ALLYLOXY-6-NITROPHENYLPYRUVATE OXIME, SODIUM
HYDROXIDE, SODIUM TERANITRIDE,
2,4,6-TRI(2-ACETYLHYDRAZINO)-1,3,5-TRINITROBENZENE, SULFONIC ACID, CESIUM
CYANOTRIDECAHYDRODECARBORATE(2-), POTASSIUM FERRICYANIDE, VINYLIDENE
FLUORIDE, POTASSIUM FERROCYANIDE, AMMONIUM HEXACYANOFERRATE (II).
REACTION WITH OXIDIZERS SUCH AS PERMANGANATES, CHLORATES, CHLORITES, AND
HYPOCHLORITES MAY PRODUCE CHLORINE OR BROMINE GAS.
REACTS VIGOROUSLY WITH ALKALIES AND WITH MANY ORGANIC MATERIALS.
CESIUM ACETYLENE CARBIDE BURNS IN HYDROGEN CHLORIDE GAS.
LITHIUM SILICIDE IN CONTACT WITH HYDROGEN CHLORIDE BECOMES INCANDESCENT.
MAGNESIUM BORIDE IN CONTACT WITH CONCENTRATED HYDROCHLORIC ACID PRODUCES
SPONTANEOUSLY FLAMMABLE GAS.
RUBIDIUM ACETYLENE CARBIDE BURNS WITH SLIGHTLY WARM HYDROCHLORIC ACID.
RUBIDIUM CARBIDE IGNITES IN CONTACT WITH HYDROCHLORIC ACID UNLESS ACID
IS DILUTE.
URANIUM PHOSPHIDE REACTS WITH HYDROCHLORIC ACID TO RELEASE SPONTANEOUSLY
FLAMMABLE PHOSPHINE.
CALCIUM CARBIDE REACTS WITH HYDROGEN CHLORIDE GAS WITH INCANDESCENCE.
ABSORPTION OF GASEOUS HYDROGEN CHLORIDE ON MERCURIC SULFATE BECOMES
VIOLENT @ 125 DEG C.
REACTION OF SILVER PERCHLORATE WITH CARBON TETRACHLORIDE IN PRESENCE OF
SMALL AMOUNT OF HYDROCHLORIC ACID PRODUCES TRICHLOROMETHYL PERCHLORATE,
WHICH DETONATES @ 40 DEG C.
CESIUM CARBIDE IGNITES IN CONTACT WITH HYDROCHLORIC ACID UNLESS ACID IS
DILUTE.
HYDROCHLORIC ACID IN THE PRESENCE OF ALCOHOL AND GLYCOLS RESULTS IN
DEHYDRATION REACTIONS.
HYDROGEN CHLORIDE GAS CAN REACT WITH FORMALDEHYDE TO FORM
BIS(CHLOROMETHYL)ETHER, A HUMAN CARCINOGEN.
EXOTHERMIC REACTION WITH WATER
ATTACKS SOME PLASTICS, RUBBER, AND COATINGS.
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: STABLE AT NORMAL CONDITIONS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
METALS
ALKALIS
ORGANIC MATERIALS
WATER
HAZARDOUS DECOMPOSITION PRODUCTS:
HYDROGEN CHLORIDE GAS. HYDROGEN. HYDROGEN, BY REACTION WITH METALS.
OTHER INFORMATION:
CORROSIVITY:
SEVERE CORROSIVE EFFECT ON 304 STAINLESS STEEL
SEVERE CORROSIVE EFFECT ON 316 STAINLESS STEEL
SEVERE CORROSIVE EFFECT ON COPPER AND COPPER ALLOYS
SEVERE CORROSIVE EFFECT ON BRONZE
SEVERE CORROSIVE EFFECT ON BRASS
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. INHALATION. INGESTION.
ACUTE TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
ATEMIX (INHALATION-GAS): 4115-7810 PPM; (4-HR)
COMPONENT INFORMATION:
WATER:
CAS-NO.: 7732-18-5
LD50/ORAL/RAT: >90 ML/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
HYDROGEN CHLORIDE:
CAS-NO.: 7647-01-0
LD50/ORAL/RAT:
238 - 277 MG/KG ORAL LD50 RAT
700 MG/KG ORAL LD50 RAT (TEST SUBSTANCE: 31.5% HYDROCHLORIC ACID SOLUTION)
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
>5010 MG/KG (TEST SUBSTANCE: 31.5% HYDROCHLORIC ACID SOLUTION - FROM
EUROPEAN CHEMICALS BUREAU IUCLID DATASET)
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
3124 PPM INHALATION LC50 RAT 1 H
1562 PPM 4 H
1.68 MG/L INHALATION LC50 RAT 1H
LC50/INHALATION/MOUSE: 1108 PPM 1 H
OTHER LD50 OR LC50 INFORMATION:
900 MG/KG ORAL LD50 RABBIT (NO INFORMATION ON TEST SUBSTANCE)
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX ORAL: 700 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: >5010 MG/KG
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT: CAUSES SKIN BURNS.
EYE CONTACT: CAUSES EYE BURNS.
INHALATION:
HARMFUL BY INHALATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND
UPPER RESPIRATORY TRACT.
INGESTION:
HARMFUL IF SWALLOWED. CAUSES IRRITATION AND BURNING, ULCERATION, OR
PERFORATION OF THE GASTROINTESTINAL TRACT AND RESULTANT PERITONITIS,
GASTRIC HEMORRHAGE AND INFECTION. CAN ALSO CAUSE NAUSEA, VOMITTING (WITH
"COFFEE GROUND" EMESIS), DIARRHEA, THIRST, DIFFICULTY SWALLOWING,
SALIVATION, CHILLS, FEVER, UNEASINESS, SHOCK, STRICTURES AND STENOSIS
(ESOPHOGEAL, GASTRIC, PYLORIC). MAY AFFECT BEHAVIOR (EXCITEMENT), THE
CARDIOVASCULAR SYSTEM (WEAK RAPID PULSE, TACHYCARDIA), RESPIRATION
(SHALLOW RESPIRATION), AND URINARY SYSTEM (KIDNEYS- RENAL FAILURE,
NEPHRITIS). ACUTE INGESTION CAN ALSO CAUSE EROSION OF TOOTH ENAMEL.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED OR REPEATED INHALATION AND/OR INGESTION MAY AFFECT LIVER, AND
CAUSE BLEEDING OF NOSE AND GUMS, NASAL AND ORAL MUCOSAL ULCERATION,
CONJUNCTIVITIS. IT MAY ALSO AFFECT RESPIRATORY TRACT (CHANGES IN PULMONARY
FUNCTION, CHRONIC BRONCHITIS, OVERT RESPIRATORY TRACT ABNORMALITIES),
TEETH (YELLOWING OF TEETH AND EROSION OF TOOTH ENAMEL), KIDNEYS, AND
BEHAVIOR/CENTRAL NERVOUS SYSTEM (MUSCLE CONTRACTION OR SPASTICITY).
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. PROLONGED OR
REPEATED EYE CONTACT WITH VAPOR/MIST CAN CAUSE CONJUNCTIVITIS.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
ANIMAL EXPERIMENTS SHOWED MUTAGENIC EFFECTS
CYTOGENETIC ANALYSIS - CHROMOSOME ABERRATION TEST (CHINESE HAMSTER OVARY):
GENOTOXIC EFFECTS WERE OBSERVED
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENTS CAS-NO. IARC ACGIH - NTP
CARCINOGENS
WATER 7732-18-5 NOT LISTED NOT LISTED NOT LISTED
HYDROGEN 7647-01-0 GROUP 3 - NOT A4 NOT NOT LISTED
CHLORIDE CLASSIFIABLE - CLASSIFIABLE
MONOGRAPH 54 AS A HUMAN
[1992] CARCINOGEN
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
WATER NOT LISTED NOT LISTED NOT LISTED
HYDROGEN CHLORIDE NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS:
NO INFORMATION ON DEVELOPMENTAL TOXICITY EFFECTS ON HUMANS WAS FOUND AN
INCREASE IN POSTNATAL MORTALITY WAS SEEN IN EXPERIMENTS WHERE RATS WERE
EXPOSED TO HYDROGEN CHLORIDE FOR 1 HOUR
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: SKIN. EYES. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
HYDROGEN CHLORIDE - 7647-01-0:
FRESHWATER FISH SPECIES DATA:
282 MG/L LC50 GAMBUSIA AFFINIS 96 H
862 MG/L LC50 LEUCISCUS IDUS
WATER FLEA DATA: <56 MG/L LC50 DAPHNIA MAGNA 72H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS CAS-NO. RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
WATER 7732-18-5 NONE NONE NONE NONE
HYDROGEN CHLORIDE 7647-01-0 NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1789
PROPER SHIPPING NAME: HYDROCHLORIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: II
EMERGENCY RESPONSE GUIDE NUMBER: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
SYMBOL(S):
[DOT]:
(R5) - IDENTIFIES A MATERIAL THAT IS A HAZARDOUS SUBSTANCE THAT HAS A
REPORTABLE QUANTITY (RQ) OF 5000 POUNDS (2270 KILOGRAMS).
DESCRIPTION: UN1789, HYDROCHLORIC ACID (SOLUTION),8,,PG II
TDG (CANADA):
UN-NO: UN1789
PROPER SHIPPING NAME: HYDROCHLORIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: HYDROCHLORIC ACID,8,UN1789,PG II,SOLUTION
ADR:
UN-NO: UN1789
PROPER SHIPPING NAME: HYDROCHLORIC ACID (SOLUTION)
HAZARD CLASS: 8
PACKING GROUP: II
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: UN1789 HYDROCHLORIC ACID,8,II,SOLUTION
IMO / IMDG:
UN-NO: UN1789
PROPER SHIPPING NAME: HYDROCHLORIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
RID:
UN-NO: UN1789
PROPER SHIPPING NAME: HYDROCHLORIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: 8
PACKING GROUP: II
DESCRIPTION: UN1789 HYDROCHLORIC ACID,8,II,RID,SOLUTION
ICAO:
UN-NO: UN1789
PROPER SHIPPING NAME: HYDROCHLORIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: HYDROCHLORIC ACID,8,UN1789,PG II,SOLUTION
IATA:
UN-NO: UN1789
PROPER SHIPPING NAME: HYDROCHLORIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
ERG CODE: 8L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1789, HYDROCHLORIC ACID,8,PG II,SOLUTION
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
WATER 7732-18-5 PRESENT PRESENT PRESENT
KE-35400
HYDROGEN CHLORIDE 7647-01-0 PRESENT PRESENT PRESENT
KE-20189
COMPONENTS JAPAN ENCS CHINA AUSTRALIA (AICS) EINECS-NO.
WATER NOT PRESENT PRESENT PRESENT PRESENT
231-791-2
HYDROGEN CHLORIDE PRESENT PRESENT PRESENT PRESENT
(1)-215 231-595-7
U.S. REGULATIONS:
HYDROGEN CHLORIDE:
MASSACHUSETTS RTK: PRESENT
MASSACHUSETTS EHS: EXTRAORDINARILY HAZARDOUS
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 1012
NEW JERSEY (EHS) LIST:
1012 500 LB TPQ
2909 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
NEW JERSEY TCPA - EHS:
15000LBTQ
5000LBTQ
5600LBTQ
2000LBTQ
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
MICHIGAN PSM HHC: = 5000 LB TQ
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
5000 LB RQ
100 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
5000LBFINAL RQAS LISTED IN 40 CFR 117.3 TABLE 117.3 AND 40 CFR 302.4
TABLE 302.4
2270KGFINAL RQAS LISTED IN 40 CFR 117.3 TABLE 117.3 AND 40 CFR 302.4
TABLE 302.4
5000LBRQAS LISTED IN LOUISIANA ADMINISTRATIVE CODE, TITLE 33, PART 1,
SUBPART 2, CHAPTER 39, SUBCHAPTER E. APPLIES TO UNAUTHORIZED EMISSIONS
BASED ON TOTAL MASS EMITTED INTO OR ONTO ALL MEDIA WITHIN ANY CONSECUTIVE
24-HOUR PERIOD
1000LBRQAS LISTED IN LOUISIANA ADMINISTRATIVE CODE, TITLE 33, PART 1,
SUBPART 2, CHAPTER 39, SUBCHAPTER E. APPLIES TO UNAUTHORIZED EMISSIONS
BASED ON TOTAL MASS EMITTED INTO THE ATMOSPHERE
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 182.1057
FDA - 21 CFR - TOTAL FOOD ADDITIVES:
133.129, 155.191, 155.194, 160.105, 160.185, 172.560, 172.892, 182.1057
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CAS-NO.
WATER 7732-18-5
HYDROGEN CHLORIDE 7647-01-0
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED
HYDROGEN CHLORIDE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CAS-NO. CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
WATER 7732-18-5 NONE NONE NONE
HYDROGEN 7647-01-0 5000 LB FINAL RQ 500 LB TPQ NONE
CHLORIDE 2270 KG FINAL RQ
5000 LB
EPCRA RQ
COMPONENTS SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
WATER NONE NONE
HYDROGEN CHLORIDE NONE 1.0% DE MINIMIS
CONCENTRATION
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION TSCA 8(D) - HEALTH
5(A)2 - CHEMICALS AND SAFETY REPORTING
WITH SIGNIFICANT NEW
USE RULES (SNURS)
WATER 7732-18-5 NOT APPLICABLE NOT APPLICABLE
HYDROGEN 7647-01-0 NOT APPLICABLE NOT APPLICABLE
CHLORIDE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
WATER NOT A DANGEROUS PRODUCT ACCORDING TO HPR
7732-18-5 (68-70) CLASSIFICATION CRITERIA
HYDROGEN CHLORIDE HYDROGEN CHLORIDE:
7647-01-0 (30-32) GASES UNDER PRESSURE - LIQUEFIED GAS:
H280:
CONTAINS GAS UNDER PRESSURE, MAY EXPLODE WHEN HEATED.
CORROSIVE TO METALS - CATEGORY 1:
H290:
MAY BE CORROSIVE TO METALS. (POTENTIALLY CORROSIVE
TO METALS; THE SUPPLIER SHOULD BE CONTACTED FOR MORE
INFORMATION)
ACUTE TOXICITY - INHALATION - CATEGORY 3:
H331: TOXIC IF INHALED.
HEALTH HAZARD NOT OTHERWISE CLASSIFIED - CATEGORY 1:
CAUSES SEVERE DAMAGE TO THE RESPIRATORY TRACT
SKIN CORROSION/IRRITATION - CATEGORY 1:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE.
HYDROCHLORIC ACID:
CORROSIVE TO METALS - CATEGORY 1:
H290:
MAY BE CORROSIVE TO METALS. (POTENTIALLY CORROSIVE
TO METALS; THE SUPPLIER SHOULD BE CONTACTED FOR MORE
INFORMATION)
ACUTE TOXICITY - ORAL - CATEGORY 4:
H302:
HARMFUL IF SWALLOWED. (3.6% IN AQUEOUS SOLUTION)
ACUTE TOXICITY - INHALATION - CATEGORY 2:
H330: FATAL IF INHALED.
HEALTH HAZARD NOT OTHERWISE CLASSIFIED - CATEGORY 1:
CAUSES SEVERE DAMAGE TO THE RESPIRATORY TRACT
SKIN CORROSION/IRRITATION - CATEGORY 1:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SKIN CORROSION/IRRITATION - CATEGORY 2:
H315:
CAUSES SKIN IRRITATION. (3.6% IN AQUEOUS SOLUTION)
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE.
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2:
H319:
CAUSES SERIOUS EYE IRRITATION. (3.6% IN AQUEOUS
SOLUTION)
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
WHMIS 1988 HAZARD CLASS:
D1A: VERY TOXIC MATERIALS
D1B: TOXIC MATERIALS
E: CORROSIVE MATERIAL
COMPONENTS WHMIS 1988
WATER UNCONTROLLED PRODUCT ACCORDING TO WHMIS
CLASSIFICATION CRITERIA
HYDROGEN CHLORIDE A,D1A,E
DIA, E
E 0.036% IN AQUEOUS SOLUTION, 0.36% IN AQUEOUS
SOLUTION, 3.6% IN AQUEOUS SOLUTION
DIB, E 28% IN AQUEOUS SOLUTION
D1A,E 31.45% IN AQUEOUS SOLUTION, 35.2% IN AQUEOUS
SOLUTION
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST -
HYDROGEN CHLORIDE 1%
INVENTORY:
COMPONENTS CAS-NO. CANADA (DSL) CANADA (NDSL)
WATER 7732-18-5 PRESENT NOT LISTED
HYDROGEN CHLORIDE 7647-01-0 PRESENT NOT LISTED
COMPONENTS CAS-NO. CEPA SCHEDULE I - TOXIC SUBSTANCES
WATER 7732-18-5 NOT LISTED
HYDROGEN CHLORIDE 7647-01-0 NOT LISTED
COMPONENTS CAS-NO. CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
WATER 7732-18-5 NOT LISTED
HYDROGEN CHLORIDE 7647-01-0 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 172/2008:
COMPONENTS CAS-NO. EU GHS - SV - CLP (172/2008)
WATER 7732-18-5
HYDROGEN CHLORIDE 7647-01-0 HYDROGEN CHLORIDE:
GASES UNDER PRESSURE:
H280:
CONTAINS GAS UNDER PRESSURE, MAY
EXPLODE WHEN HEATED.
ACUTE TOXICITY - INHALATION - ACUTE
TOX. 3:
H331:
TOXIC IF INHALED. (MINIMUM
CLASSIFICATION)
SKIN CORROSION/IRRITATION - SKIN CORR.
1A:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE.017-002-00-2
HYDROCHLORIC ACID:
SKIN CORROSION/IRRITATION - SKIN
CORR. 1B:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. (C >= 25 %)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - STOT SE 3:
H335:
MAY CAUSE RESPIRATORY IRRITATION.
(C >=10%)017-002-01-X
SKIN CORROSION/IRRITATION - SKIN
CORR. 1B:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. (C >=25%)
SKIN CORROSION/IRRITATION - SKIN
IRRIT. 2:
H315:
CAUSES SKIN IRRITATION. (10 % <=C <25%)
SERIOUS EYE DAMAGE/EYE IRRITATION - EYE
IRRIT. 2:
H319:
CAUSES SERIOUS EYE IRRITATION.
(10% <=C <25 %)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - STOT SE 3:
H335:
MAY CAUSE RESPIRATORY IRRITATION.
(C >=10%)017-002-01-X
EU - CLP (1272/2008):
R-PHRASE(S):
R34: CAUSES BURNS.
R37: IRRITATING TO RESPIRATORY SYSTEM.
S-PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
COMPONENTS CAS-NO. CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
WATER 7732-18-5 NO INFORMATION
HYDROGEN 7647-01-0 HYDROGEN HYDROGEN FOR HYDROGEN
CHLORIDE CHLORIDE CHLORIDE: CHLORIDE:
T; R23 0.02%<=C<0.2% S1/2 S9 S26
C; R35 XI;R36/37/38 S36/37/39 S45
0.2%<=C<0.5%
HYDROCHLORIC C;R34 HYDROCHLORIC
ACID: 0.5%<=C<1% ACID:
+ HYDROCHLORIC C;R20-34 S(1/2)-S26-S45
ACID... 1%<=C<5%
% C; C;R20-35
R34 - XI; R37 5%<=C
T;C;R23-35
CONCENTRATION
LIMIT(S):
C >=25% C;
R34-37
10% <= C <25%
XI; R36/37/38
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
C: CORROSIVE.
XI: IRRITANT.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 5/27/2014
REVISION DATE: 6/1/2017
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO
NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES
NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR
RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING
LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES
NO RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.