| Common Name: | NITRIC ACID, 65 PERCENT, SOLUTION, REAGENT, NITRIC ACID, 65% |
| Manufacturer: | SPECTRUM CHEMICALS AND LABORATORY PRODUCTS |
| SDS Revision Date: | 4/7/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39D907 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(TM) CHEMICAL MFG CORP
S
ISO 9001-2008 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 4/7/2015
REVISION DATE: 4/7/2015
REVISION NUMBER: G1
PRODUCT IDENTIFIER:
PRODUCT CODE: N1089
PRODUCT NAME: NITRIC ACID, 65 PERCENT, SOLUTION, REAGENT
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NO INFORMATION AVAILABLE
CAS #: MIXTURE
RTECS #: NOT AVAILABLE
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICALS AND LABORATORY PRODUCTS, INC.
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION |  |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY A
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
OXIDIZING LIQUIDS: CATEGORY 3
LABEL ELEMENTS:
DANGER
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
MAY INTENSIFY FIRE; OXIDIZER
CORROSION
FLAME OVER CIRCLE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP/STORE AWAY FROM CLOTHING/.? /COMBUSTIBLE MATERIALS
TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES.?
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
SPECIFIC TREATMENT (SEE.? ON THIS LABEL)
USE WATER TO EXTINGUISH. DO NOT USE DRY CHEMICALS OR FOAMS. CO2 OR HALON
MAY PROVIDE LIMITED CONTROL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT % TRADE SECRET
NITRIC ACID 7697-37-2 65 *
7697-37-2
WATER 7732-18-5 35 *
7732-18-5
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
POISON INFORMATION CENTERS IN EACH STATE CAPITAL CITY CAN PROVIDE
ADDITIONAL ASSISTANCE FOR SCHEDULED POISONS (13 1126). ENSURE THAT MEDICAL
PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO
PROTECT THEMSELVES. FIRST AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED CLOTHES
AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
EYE CONTACT:
FLUSH EYE WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS OR
CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED OR
INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A
POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. IF VICTIM IS CONSCIOUS, GIVE WATER OR MILK.
FOLLOW WITH MILK OF MAGNESIA OR EGG WHITES BEATEN WITH WATER. IMMEDIATE
MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SEVERE SKIN AND EYE IRRITATION OR BURNS. DYSPNEA (SHORTNESS OF BREATH AND
DIFFICULTY BREATHING). ABDOMINAL PAIN. VOMITING.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER. CO2 MAY BE OF NO VALUE IN EXTINGUISHING FIRES INVOLVING OXIDIZERS
AND MAY ONLY PROVIDE LIMITED CONTROL.
UNSUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL. FOAM. HALONS.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS:
OXIDIZER. KEEP AWAY FROM COMBUSTIBLE MATERIALS (WOOD, PAPER, OIL, CLOTHING,
ETC.). THE PRODUCT IS NOT FLAMMABLE, BUT IT MAY CAUSE FIRE WHEN IN CONTACT
WITH OTHER MATERIAL. CONTACT WITH COMBUSTIBLE OR ORGANIC MATERIALS MAY
CAUSE FIRE. WILL ACCELERATE BURNING WHEN INVOLVED IN A FIRE. CONTAINER
EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED. FLAMMABLE IN
PRESENCE OF CELLULOSE OR OTHER COMBUSTIBLE MATERIALS.
PHOSPHINE, HYDROGEN SULFIDE, SELENIDE ALL IGNITE WHEN FUMING NITRIC ACID IS
DRIPPED INTO GAS.
PHOSPHINE IGNITES IN CONCENTRATED NITRIC ACID.
NICKEL TETRAPHOSPHIDE IGNITES WITH FUMING NITRIC ACID.
CONTACT WITH METALS MAY EVOLVE FLAMMABLE HYDROGEN GAS.
A JET OF AMMONIA WILL IGNITE NITRIC ACID VAPOR.
CELLULOSE MAY BE CONVERTED TO THE HIGHLY FLAMMABLE NITRATE ESTER ON CONTACT
WITH THE VAPOR OF NITRIC ACID AS WELL AS THE LIQUID ITSELF.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. USE PERSONAL PROTECTIVE EQUIPMENT.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. SHOULD NOT BE
RELEASED INTO THE ENVIRONMENT. DO NOT LET PRODUCT ENTER DRAINS. DO NOT
FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT: STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
METHODS FOR CLEANING UP:
NEUTRALIZE WITH SODIUM CARBONATE OR SODIUM BICARBONATE. DILUTE WITH WATER.
ABSORB OR COVER WITH DRY EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND
TRANSFER TO CONTAINERS. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS OR SPRAY MIST. HANDLE IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. MAY CORRODE METALLIC SURFACES.
DO NOT STORE IN UNCOATED METALLIC CONTAINERS. STORE IN A SEGRATED AND
APPROVED AREA. STORE AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
BASES. REDUCING AGENTS. COMBUSTIBLE MATERIALS. ORGANIC MATERIALS. METALS.
ACIDS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS OSHA NIOSH ACGIH AIHA WHEEL
NITRIC ACID - 2 PPM TWA 2 PPM TWA 4 PPM STEL NO INFORMATION
7697-37-2 5 MG/M3 TWA 5 MG/M3 TWA 2 PPM TWA AVAILABLE
4 PPM STEL
10 MG/M3 STEL
WATER - NONE NONE NONE NONE
7732-18-5
CANADA:
COMPONENTS ALBERTA BRITISH COLUMBIA ONTARIO QUEBEC
NITRIC ACID - 2 PPM TWA 2 PPM TWA 2 PPM TWA 2 PPM TWAEV
7697-37-2 5.2 MG/M3 TWA 4 PPM STEL 4 PPM STEL 5.2 MG/M3 TWAEV
4 PPM STEL 4 PPM STEV
10 MG/M3 STEL 10 MG/M3 STEV
WATER - NONE NONE NONE NONE
7732-18-5
AUSTRALIA AND MEXICO:
COMPONENTS AUSTRALIA MEXICO
NITRIC ACID 4 PPM STEL 2 PPM TWA
7697-37-2 10 MG/M3 STEL 5 MG/M3 TWA
2 PPM TWA 4 PPM STEL
5.2 MG/M3 TWA 10 MG/M3 STEL
WATER NONE NONE
7732-18-5
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST
BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: FACE-SHIELD.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT PROTECTIVE SUIT. GLOVES. BOOTS.
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
APPEARANCE: NO INFORMATION AVAILABLE
COLOR: COLORLESS. LIGHT YELLOW.
ODOR: ACRID. DISAGREEABLE. CHOKING.
TASTE: NO INFORMATION AVAILABLE
MOLECULAR/FORMULA WEIGHT: 63.01
FORMULA: NO INFORMATION AVAILABLE
FLASH POINT (DEG. C): NO DATA AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
PH: NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): -41 DEG. C/-42 DEG. F
BOILING POINT/RANGE (DEG. C/DEG. F): 121-122 DEG. C/249.8-251.6 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): 0.29-0.98
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY: FREELY SOLUBLE IN WATER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
OXIDIZER. REACTS VIOLENTLY WITH ALCOHOL, ORGANIC MATERIAL, TURPENE,
CHARCOAL.
VIOLENT REACTION WITH NITRIC ACID + ACETONE AND SULFURIC ACID. INCOMPATIBLE
WITH COMBUSTIBLE MATERIALS, METALLIC POWDERS, CARBIDES, ALDEHYDES,
CYANIDES, CHROMIC ACID, HYDROGEN SULFIDE, SULFIDES, METALS, ORGANIC
SOLVENTS, ACETIC ACID, ALKALIES, ALCOHOLS, CESIUM AND RUBIDIUM ACETYLIDES,
NITROBENZENE
FLAMMABLE IN PRESENCE OF CELLULOSE OR OTHER COMBUSTIBLE MATERIALS.
PHOSPHINE, HYDROGEN SULFIDE, SELENIDE ALL IGNITE WHEN FUMING NITRIC ACID IS
DRIPPED INTO GAS.
PHOSPHINE IGNITES IN CONCENTRATED NITRIC ACID.
NICKEL TETRAPHOSPHIDE IGNITES WITH FUMING NITRIC ACID.
CONTACT WITH METALS MAY EVOLVE FLAMMABLE HYDROGEN GAS.
A JET OF AMMONIA WILL IGNITE NITRIC ACID VAPOR.
CELLULOSE MAY BE CONVERTED TO THE HIGHLY FLAMMABLE NITRATE ESTER ON CONTACT
WITH THE VAPOR OF NITRIC ACID AS WELL AS THE LIQUID ITSELF
REACTS EXLPOSIVELY WITH METALLIC POWDERS, CARBIDES, CYANIDES, SULFIDES,
ALKALIES AND TURPENTINE.
CAN REACT EXPLOSIVELY WITH MANY REDUCING AGENTS.
ARSINE, PHOSPHINE, TETRABORANE ALL OXIDIZED EXPLOSIVELY IN PRESENCE OF
NITRIC ACID.
CESIUM AND RUBIDIUM ACETYLIDES EXPLODE IN CONTACT WITH NITRIC ACID.
EXPLOSIVE REACTION WITH NITRIC ACID + NITROBENZENE + WATER.
DETONATION WITH NITRIC ACID + 4-METHYLCYCLOHEXANE.
THE ADDITION OF WARM FUMING NITRIC ACID TO PHOSPHINE CAUSES EXPLOSION.
ADDITION OF WATER TO NITRATION MIXTURE DILUTED WITH AN EQUAL VOLUME OF
WATER CAN CAUSE A LOW ORDER EXPLOSION.
CYCLOPENTADIENE REACTS EXPLOSIVELY WITH FUMING NITRIC ACID.
MIXTURES OF FUMING NITRIC ACID AND ACETONITRILE ARE HIGH EXPLOSIVES
CHEMICAL STABILITY:
STABILITY: STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
BASES. REDUCING AGENTS. COMBUSTIBLE MATERIALS. ORGANIC MATERIALS. METALS.
ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS: NITROGEN OXIDES (NOX).
OTHER INFORMATION:
CORROSIVITY:
EXTREMELY CORROSIVE IN PRESENCE OF ALUMINUM, OF COPPER, OF BRASS.
NON-CORROSIVE IN PRESENCE OF GLASS, OF STAINLESS STEEL(304), OF STAINLESS
STEEL(316)
SPECIAL REMARKS ON CORROSIVITY:
IN PRESENCE OF TRACES OF OXIDES, IT ATTACKS ALL BASE METALS EXCEPT ALUMINUM
AND SPECIAL CHROMIUM STEELS.
IT WILL ATTACK SOME FORMS OF PLASTICS, RUBBER, AND COATINGS.
NITRIC ACID CORRODES ALMOST ALL METALS EXCEPT GOLD, AND WHITE GOLD, FORMING
NITRATES.
NO CORROSIVE EFFECT ON BRONZE.
NO CORROSIVITY DATA FOR ZINC, AND STEEL
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. INHALATION. INGESTION.
ACUTE TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
ATEMIX (INHALATION-GAS): 35714 MG/L
COMPONENT INFORMATION:
NITRIC ACID - 7697-37-2:
LD50/ORAL/RAT: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 67 PPM
INHALATION LC50 RAT 4 H:
130 MG/M3 4 H
7 MG/L 1 H
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: 430 MG/KG ORAL LDL RAT
WATER - 7732-18-5:
LD50/ORAL/RAT: >90 ML/KG ORAL LD50
RAT LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE -ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
SEVERE SKIN IRRITATION. CAUSES SKIN BURNS. MAY CAUSE DEEP PENETRATING
ULCERS OF THE SKIN WITH A CHARACTERISTIC YELLOW TO BROWNISH DISCOLORATION.
ABSORPTION THROUGH THE SKIN MAY CAUSE METHEMOGLOBINEMIA (THE FORMATION OF
METHEMOGLOBIN IN THE BLOOD WHICH CAUSES DEFICIENT OXYGENATION OF THE BLOOD
DUE TO DECREASED AVAILABLE HEMOGLOBIN).
EYE CONTACT:
SEVERE EYE IRRITATION. CAUSES EYE BURNS. MAY CAUSE IRREVERSIBLE EYE DAMAGE.
INHALATION:
CAUSES IRRITATION AND POSSIBLE BURNS OF THE RESPIRATORY TRACT WITH BURNING
PAIN IN THE NOSE AND THROAT, COUGHING, SNEEZING, WHEEZING, SHORTNESS OF
BREATH AND PULMONARY EDEMA..
INGESTION:
CAUSES SERIOUS GASTROINTESTINAL TRACT IRRITATION OR BURNS WITH NAUSEA,
VOMITING, SEVERE ABDOMINAL PAIN, AND POSSIBLE "COFFEE GROUNDS" APPEARANCE
OF THE VOMITUS. MAY CAUSE PERFORATION OF THE DIGESTIVE TRACT..
ASPIRATION HAZARD: NO INFORMATION AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
REPEATED INHALATION MAY PRODUCE CHANGES IN PULMONARY FUNCTION AND/OR
CHRONIC BRONCHITIS. IT MAY ALSO CAUSE WEIGHT LOSS, AND AFFECT
BEHAVIOR/CENTRAL NERVOUS SYSTEM (HEADACHE, DIZZINESS, DROWSINESS, MUSCLE
CONTACTION OR SPASTICITY, WEAKNESS, LOSS OF COORDINATON, MENTAL CONFUSION),
AND URINARY SYSTEM (KIDNEY FAILLURE, DECREASED URINARY OUTPUT AFTER SEVERAL
HOURS OF UNCORRECTED CIRCULATORY COLLAPSE).
REPEATED EXPOSURE MAY CAUSE DISCOLORATION AND/OR ERROSION OF TEETH (DENTAL
ENAMEL).
EYE IRRITATION AND RESPIRATORY TRACT SIGNS AND SYMPTOMS RESEMBLING THOSE OF
FREQUENT UPPER RESPIRATORY VIRAL INFECTIONS HAVE BEEN ASSOCIATED WITH
CHRONIC NITRIC ACID EXPOSURE.
SENSITIZATION: NO INFORMATION AVAILABLE
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC
COMPONENTS ACGIH - CARCINOGENS IARC NTP
NITRIC ACID NOT LISTED NOT LISTED NOT LISTED
WATER NOT LISTED NOT LISTED NOT LISTED
COMPONENTS OSHA HCS - AUSTRALIA - PROHIBITED AUSTRALIA - NOTIFIABLE
CARCINOGENS CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
NITRIC ACID NOT LISTED NOT LISTED NOT LISTED
WATER NOT LISTED NOT LISTED NOT LISTED
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS:
MAY CAUSE ADVERSE DEVELOPMENTAL EFFECTS BASED ON ANIMAL DATA
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE
TARGET ORGANS: SKIN. EYES. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: NO DATA AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE
MOBILITY: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS RCRA - F SERIES RCRA - K SERIES RCRA - P RCRA - U SERIES
WASTES WASTES SERIES WASTES
WASTES
NITRIC ACID NONE NONE NONE NONE
WATER NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN2031
PROPER SHIPPING NAME: NITRIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: 5.1
PACKING GROUP: II
ERG NO: 157
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: UN2031
PROPER SHIPPING NAME: NITRIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: 5.1
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: UN2031
PROPER SHIPPING NAME: NITRIC ACID (SOLUTION)
HAZARD CLASS: 8
PACKING GROUP: II
SUBSIDIARY RISK: 5.1
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
CEFIC TREMCARD NO: NO INFORMATION AVAILABLE
IMO / IMDG:
UN-NO: UN2031
PROPER SHIPPING NAME: NITRIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: 5.1
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IMDG PAGE: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
MFAG: NO INFORMATION AVAILABLE
MAXIMUM QUANTITY: NO INFORMATION AVAILABLE
RID:
UN-NO: UN2031
PROPER SHIPPING NAME: NITRIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: 8 + 5.1
PACKING GROUP: II
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ICAO:
UN-NO: UN2031
PROPER SHIPPING NAME: NITRIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: 5.1
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IATA:
UN-NO: UN2031
PROPER SHIPPING NAME: NITRIC ACID (SOLUTION)
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
ERG CODE: 8L
DESCRIPTION: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS U.S. TSCA KOREA KECL PHILIPPINES JAPAN ENCS
(PICCS)
NITRIC ACID PRESENT PRESENT KE- PRESENT PRESENT (1)-
25911 394
WATER PRESENT PRESENT KE- PRESENT NOT PRESENT
35400
COMPONENTS CHINA AUSTRALIA EINECS-NO.
(AICS)
NITRIC ACID PRESENT PRESENT PRESENT 231-714-2
WATER PRESENT PRESENT PRESENT 231-791-2
U.S. REGULATIONS:
NITRIC ACID:
MASSACHUSETTS RTK: PRESENT
MASSACHUSETTS EHS: EXTRAORDINARILY HAZARDOUS
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: PRESENT
NEW JERSEY (EHS) LIST: PRESENT
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
NEW JERSEY TCPA - EHS:
15000 LB TQ
450 LB TQ
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
MICHIGAN PSM HHC: =500 LB TQ 94.5% BY WEIGHT OR GREATER
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
1000 LB RQ
100 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
1000 LB FINAL RQAS LISTED IN 40 CFR 117.3 TABLE 117.3 AND 40 CFR 302.4
TABLE 302.4
454 KG FINAL RQAS LISTED IN 40 CFR 117.3 TABLE 117.3 AND 40 CFR 302.4 TABLE
302.4
1000 LB RQ AS LISTED IN LOUISIANA ADMINISTRATIVE CODE, TITLE 33, PART 1,
SUBPART 2, CHAPTER 39, SUBCHAPTER E. APPLIES TO UNAUTHORIZED EMISSIONS
BASED ON TOTAL MASS EMITTED INTO OR ONTO ALL MEDIA WITHIN ANY CONSECUTIVE
24-HOUR PERIOD
100 LB RQ AS LISTED IN LOUISIANA ADMINISTRATIVE CODE, TITLE 33, PART 1,
SUBPART 2, CHAPTER 39, SUBCHAPTER E. APPLIES TO UNAUTHORIZED EMISSIONS
BASED ON TOTAL MASS EMITTED INTO THE ATMOSPHERE
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY:
NITRIC ACID NOT LISTED NOT LISTED NOT LISTED NOT LISTED
WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY HAZARDOUS EXTREMELY HAZARDOUS
THEIR REPORTABLE SUBSTANCES AND TPQS SUBSTANCES AND RQS
QUANTITIES
NITRIC ACID 1000 LB FINAL RQ 1000 LB TPQ NONE
454 KG FINAL RQ
WATER NONE NONE NONE
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
NITRIC ACID NONE 1.0% DE MINIMIS
CONCENTRATION
WATER NONE NONE
U.S. TSCA:
COMPONENTS TSCA SECTION 5(A)2 - CHEMICALS TSCA 8(D) - HEALTH AND
WITH SIGNIFICANT NEW USE SAFETY REPORTING
RULES (SNURS)
NITRIC ACID NOT APPLICABLE NOT APPLICABLE
WATER NOT APPLICABLE NOT APPLICABLE
CANADA:
WHMIS HAZARD CLASS:
C: OXIDIZING MATERIALS
E: CORROSIVE MATERIAL
NITRIC ACID:
C E INCLUDING 61.3%, 67.18%, 70%
E 0.63%, 6.3%
WATER: UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST
NITRIC ACID 1%
INVENTORY:
COMPONENTS CANADA (DSL) CANADA (NDSL)
NITRIC ACID PRESENT NOT LISTED
WATER PRESENT NOT LISTED
COMPONENTS CEPA SCHEDULE I - CEPA - 2010 GREENHOUSE GASES SUBJECT
TOXIC SUBSTANCES TO MANDITORY REPORTING
NITRIC ACID NOT LISTED NOT LISTED
WATER NOT LISTED NOT LISTED
EU CLASSIFICATION:
R-PHRASE(S):
R35: CAUSES SEVERE BURNS.
R 8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
S -PHRASE(S):
S23: DO NOT BREATHE GAS/FUMES/VAPOR/SPRAY.
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S36: WEAR SUITABLE PROTECTIVE CLOTHING.
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
COMPONENTS CLASSIFICATION CONCENTRATION LIMITS SAFETY PHRASES
NITRIC ACID C;R35 20%<=C C;R35 S(1/2)-S23-S26-S36-S45
O;R8 5%<=C<20% C;R34
70%<=C O;R8
WATER NO INFORMATION
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
C: CORROSIVE.
O: OXIDISING.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 4/7/2015
REVISION DATE: 4/7/2015
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.
SPECTRUM(R*)
S
ISO 9002 CERTIFIED
GARDENA, CA
NEW BRUNSWICK, NJ
MATERIAL SAFETY DATA SHEET
NFPA:
4
0
0
OXY
HMIS:
HEALTH HAZARD 3
FIRE HAZARD 0
REACTIVITY 0
PERSONAL PROTECTIVE EQUIPMENT:
FACE SHIELD
FULL SUIT
VAPOR RESPIRATOR
GLOVES
BOOTS
SEE SECTION 15.
| SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
COMMON NAME/ TRADE NAME: NITRIC ACID, 65%
MANUFACTURER:
SPECTRUM LABORATORY PRODUCTS INC.
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
IN CASE OF EMERGENCY:
CHEMTREC (24HR): 800-424-9300
CALL: (310) 516-8000
COMMERCIAL NAME(S): NOT AVAILABLE.
SYNONYM: NITRIC ACID, 65%
CHEMICAL NAME: NOT APPLICABLE.
CHEMICAL FAMILY: (ACID.)
CHEMICAL FORMULA: NOT APPLICABLE.
CATALOG NUMBER(S): N1089
CAS#: MIXTURE.
RTECS: NOT APPLICABLE.
TSCA:
TSCA 8(B) INVENTORY: WATER; NITRIC ACID, FUMING
CI#: NOT APPLICABLE.
SUPPLIER:
SPECTRUM LABORATORY PRODUCTS INC.
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
| SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS | |
NAME CAS # EXPOSURE LIMITS % BY WEIGHT
TWA (MG/M3) STEL (MG/M3) CEIL (MG/M3)
1) WATER 7732-18-5 35
2) NITRIC 7697-37-2 2 4 65
ACID,
FUMING
TOXICOLOGICAL DATA ON INGREDIENTS:
NITRIC ACID, FUMING:
VAPOR (LC50):
ACUTE:
244 PPM 0.5 HOURS [RAT].
344 PPM 0.5 HOURS [RAT].
| SECTION 3. HAZARDS IDENTIFICATION | |
POTENTIAL ACUTE HEALTH EFFECTS:
VERY HAZARDOUS IN CASE OF SKIN CONTACT (CORROSIVE, IRRITANT, PERMEATOR), OF
EYE CONTACT (IRRITANT, CORROSIVE), OF INGESTION,. SLIGHTLY HAZARDOUS IN
CASE OF INHALATION (LUNG SENSITIZER). LIQUID OR SPRAY MIST MAY PRODUCE
TISSUE DAMAGE PARTICULARLY ON MUCOUS MEMBRANES OF EYES, MOUTH AND
RESPIRATORY TRACT. SKIN CONTACT MAY PRODUCE BURNS. INHALATION OF THE SPRAY
MIST MAY PRODUCE SEVERE IRRITATION OF RESPIRATORY TRACT, CHARACTERIZED BY
COUGHING, CHOKING, OR SHORTNESS OF BREATH. PROLONGED EXPOSURE MAY RESULT IN
SKI N BURNS AND ULCERATIONS. OVER-EXPOSURE BY INHALATION MAY CAUSE
RESPIRATORY IRRITATION. SEVERE OVER-EXPOSURE CAN RESULT IN DEATH.
INFLAMMATION OF THE EYE IS CHARACTERIZED BY REDNESS, WATERING, AND ITCHING.
SKIN INFLAMMATION IS CHARACTERIZED BY ITCHING, SCALING, REDDENING, OR,
OCCASIONALLY, BLISTERING.
POTENTIAL CHRONIC HEALTH EFFECTS:
CARCINOGENIC EFFECTS: NOT AVAILABLE.
MUTAGENIC EFFECTS: NOT AVAILABLE.
TERATOGENIC EFFECTS: NOT AVAILABLE.
DEVELOPMENTAL TOXICITY: NOT AVAILABLE.
THE SUBSTANCE MAY BE TOXIC TO LUNGS, MUCOUS MEMBRANES, UPPER RESPIRATORY
TRACT, SKIN, EYES, TEETH. REPEATED OR PROLONGED EXPOSURE TO THE SUBSTANCE
CAN PRODUCE TARGET ORGANS DAMAGE. REPEATED OR PROLONGED CONTACT WITH SPRAY
MIST MAY PRODUCE CHRONIC EYE IRRITATION AND SEVERE SKIN IRRITATION.
REPEATED OR PROLONGED EXPOSURE TO SPRAY MIST MAY PRODUCE RESPIRATORY TRACT
IRRITATION LEADING TO FREQUENT ATTACKS OF BRONCHIAL INFECTION.
| SECTION 4. FIRST AID MEASURES | |
EYE CONTACT:
CHECK FOR AND REMOVE ANY CONTACT LENSES. IN CASE OF CONTACT, IMMEDIATELY
FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. COLD WATER MAY BE
USED. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKI N WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. COVER THE
IRRITATED SKIN WITH AN EMOLLIENT. COLD WATER MAY BE USED. WASH CLOTHING
BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL ATTENTION
IMMEDIATELY.
SERIOUS SKIN CONTACT:
WASH WITH A DISINFECTANT SOAP AND COVER THE CONTAMINATED SKIN WITH AN
ANTI-BACTERIAL CREAM. SEEK IMMEDIATE MEDICAL ATTENTION.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION
IMMEDIATELY.
SERIOUS INHALATION:
EVACUATE THE VICTIM TO A SAFE AREA AS SOON AS POSSIBLE. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND. IF BREATHING IS
DIFFICULT, ADMINISTER OXYGEN. IF THE VICTIM IS NOT BREATHING, PERFORM
MOUTH-TO-MOUTH RESUSCITATION.
WARNING:
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED MATERIAL IS TOXIC, INFECTIOUS OR CORROSIVE.
SEEK IMMEDIATE MEDICAL ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND. GET MEDICAL
ATTENTION IMMEDIATELY.
SERIOUS INGESTION: NOT AVAILABLE.
| SECTION 5. FIRE AND EXPLOSION DATA | |
FLAMMABILITY OF THE PRODUCT: NON-FLAMMABLE.
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE.
FLASH POINTS: NOT APPLICABLE.
FLAMMABLE LIMITS: NOT APPLICABLE.
PRODUCTS OF COMBUSTION: NOT AVAILABLE.
FIRE HAZARDS IN PRESENCE OF VARIOUS SUBSTANCES: OF COMBUSTIBLE MATERIALS
EXPLOSION HAZARDS IN PRESENCE OF VARIOUS SUBSTANCES:
EXPLOSIVE IN PRESENCE OF REDUCING MATERIALS, OF ORGANIC MATERIALS, OF
METALS, OF ALKALIS.
NON-EXPLOSIVE IN PRESENCE OF OPEN FLAMES AND SPARKS, OF SHOCKS.
FIRE FIGHTING MEDIA AND INSTRUCTIONS: NOT APPLICABLE.
SPECIAL REMARKS ON FIRE HAZARDS:
FLAMMABLE IN PRESENCE OF CELLULOSE OR OTHER COMBUSTIBLE MATERIALS.
PHOSPHINE, HYDROGEN SULFIDE, SELENIDE ALL IGNITE WHEN FUMING NITRIC ACID
IS DRIPPED INTO GAS. (NITRIC ACID, FUMING)
SPECIAL REMARKS ON EXPLOSION HAZARDS:
REACTS EXLPOSIVELY WITH METALLIC POWDERS, CARBIDES, CYANIDES, SULFIDES,
ALKALIES AND TURPENTINE.
CAN REACT EXPLOSIVELY WITH MANY REDUCING AGENTS.
ARSINE, PHOSPHINE, TETRABORANE ALL OXIDIZED EXPLOSIVELY IN PRESENCE OF
NITRIC ACID.
CESIUM AND RUBIDIUM ACETYLIDES EXPLODE IN CONTACT WITH NITRIC ACID.
EXPLOSIVE REACTION WITH NITRIC ACID + NITROBENZENE + WATER.
DETONATION WITH NITRIC ACID + 4-METHYLCYCLOHEXANE.
(NITRIC ACID, FUMING)
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
DILUTE WITH WATER AND MOP UP, OR ABSORB WITH AN INERT DRY MATERIAL AND
PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER.
IF NECESSARY:
NEUTRALIZE THE RESIDUE WITH A DILUTE SOLUTION OF SODIUM CARBONATE.
LARGE SPILL:
CORROSIVE LIQUID. OXIDIZING MATERIAL. POISONOUS LIQUID.
STOP LEAK IF WITHOUT RISK. ABSORB WITH DRY EARTH, SAND OR OTHER
NON-COMBUSTIBLE MATERIAL. DO NOT GET WATER INSIDE CONTAINER. AVOID CONTACT
WITH A COMBUSTIBLE MATERIAL (WOOD, PAPER, OIL, CLOTHING...). KEEP SUBSTANCE
DAMP USING WATER SPRAY. DO NOT TOUCH SPILLED MATERIAL. USE WATER SPRAY
CURTAIN TO DIVERT VAPOR DRIFT. USE WATER SPRAY TO REDUCE VAPORS. PREVENT
ENTRY INTO SEWERS, BASEMENTS OR CONFINED AREAS; DIKE IF NEEDED. CALL FOR
ASSISTANCE ON DISPOSAL. NEUTRALIZE THE RESIDUE WITH A DILUTE SOLUTION OF
SODIUM CARBONATE. BE CAREFUL THAT THE PRODUCT IS NOT PRESENT AT A
CONCENTRATION LEVEL ABOVE TLV. CHECK TLV ON THE MSDS AND WITH LOCAL
AUTHORITIES.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS:
KEEP LOCKED UP.. KEEP CONTAINER DRY. KEEP AWAY FROM HEAT. KEEP AWAY FROM
SOURCES OF IGNITION. KEEP AWAY FROM COMBUSTIBLE MATERIAL.. DO NOT INGEST.
DO NOT BREATHE GAS/FUMES/ VAPOR/SPRAY. NEVER ADD WATER TO THIS PRODUCT. IN
CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT. IF
INGESTED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THE CONTAINER OR THE
LABEL. AVOID CONTACT WITH SKIN AND EYES. KEEP AWAY FROM INCOMPATIBLES SUCH
AS REDUCING AGENTS, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS, METALS,
ACIDS, ALKALIS, MOISTURE.
MAY CORRODE METALLIC SURFACES. STORE IN A METALLIC OR COATED FIBERBOARD
DRUM USING A STRONG POLYETHYLENE INNER PACKAGE.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED. KEEP CONTAINER IN A COOL, WELL-VENTILATED
AREA. SEPARATE FROM ACIDS, ALKALIES, REDUCING AGENTS AND COMBUSTIBLES. SEE
NFPA 43A, CODE FOR THE STORAGE OF LIQUID AND SOLID OXIDIZERS. DO NOT STORE
ABOVE 23 DEG. C (73.4 DEG. F).
| SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE
AIRBORNE CONCENTRATIONS OF VAPORS BELOW THEIR RESPECTIVE THRESHOLD LIMIT
VALUE. ENSURE THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE PROXIMAL TO THE
WORK-STATION LOCATION.
PERSONAL PROTECTION:
FACE SHIELD. FULL SUIT. VAPOR RESPIRATOR. BE SURE TO USE AN
APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT. GLOVES. BOOTS.
PERSONAL PROTECTION IN CASE OF A LARGE SPILL:
SPLASH GOGGLES. FULL SUIT. VAPOR RESPIRATOR. BOOTS. GLOVES. A SELF
CONTAINED BREATHING APPARATUS SHOULD BE USED TO AVOID INHALATION OF THE
PRODUCT. SUGGESTED PROTECTIVE CLOTHING MIGHT NOT BE SUFFICIENT; CONSULT A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
EXPOSURE LIMITS:
TWA: 2
STEL: 4 (PPM) FROM ACGIH (TLV) [UNITED STATES]
TWA: 2
STEL: 4 FROM OSHA (PEL) [UNITED STATES]
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE AND APPEARANCE: LIQUID.
ODOR: ACRID. DISAGREEABLE AND CHOKING. (STRONG.)
TASTE: NOT AVAILABLE.
MOLECULAR WEIGHT: NOT APPLICABLE.
COLOR: COLORLESS TO LIGHT YELLOW.
PH (1% SOLN/WATER): ACIDIC.
BOILING POINT: 121 DEG. C (249.8 DEG. F)
MELTING POINT: -41.6 DEG. C (-42.9 DEG. F)
CRITICAL TEMPERATURE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.408 (WATER = 1)
VAPOR PRESSURE: 6 KPA (@ 20 DEG. C)
VAPOR DENSITY: 2.5 (AIR = 1)
VOLATILITY: NOT AVAILABLE.
ODOR THRESHOLD: 0.29 PPM
WATER/OIL DIST. COEFF.: NOT AVAILABLE.
IONICITY (IN WATER): NOT AVAILABLE.
DISPERSION PROPERTIES: SEE SOLUBILITY IN WATER, DIETHYL ETHER.
SOLUBILITY:
EASILY SOLUBLE IN COLD WATER, HOT WATER.
SOLUBLE IN DIETHYL ETHER.
| SECTION 10. STABILITY AND REACTIVITY DATA | |
STABILITY: THE PRODUCT IS STABLE.
INSTABILITY TEMPERATURE: NOT AVAILABLE.
CONDITIONS OF INSTABILITY: INCOMPATIBLE MATERIALS
INCOMPATIBILITY WITH VARIOUS SUBSTANCES:
HIGHLY REACTIVE WITH ALKALIS.
REACTIVE WITH REDUCING AGENTS, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS,
METALS, ACIDS.
CORROSIVITY:
EXTREMELY CORROSIVE IN PRESENCE OF ALUMINUM, OF COPPER.
NON-CORROSIVE IN PRESENCE OF GLASS, OF STAINLESS STEEL(304), OF STAINLESS
STEEL(316), OF BRASS.
SPECIAL REMARKS ON REACTIVITY:
A STRONG OXIDIZER.
REACTS VIOLENTLY WITH ALCOHOL, ORGANIC MATERIAL, TURPENE, CHARCOAL.
VIOLENT REACTION WITH NITRIC ACID + ACETONE AND SULFURIC ACID.
NITRIC ACID WILL REACT WITH WATER OR STEAM TO PRODUCE HEAT AND TOXIC,
CORROSIVE AND FLAMMABLE VAPORS. (NITRIC ACID, FUMING)
SPECIAL REMARKS ON CORROSIVITY:
IN PRESENCE OF TRACES OF OXIDES, IT ATTACKS ALL BASE METALS EXCEPT ALUMINUM
AND SPECIAL CHROMIUM STEELS.
IT WILL ATTACK SOME FORMS OF PLASTICS, RUBBER, AND COATINGS.
NO CORROSIVE EFFECT ON BRONZE.
NO CORROSIVITY DATA FOR ZINC, AND STEEL
POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF ENTRY:
ABSORBED THROUGH SKIN. DERMAL CONTACT. EYE CONTACT. INHALATION. INGESTION.
TOXICITY TO ANIMALS:
LD50: NOT AVAILABLE.
LC50: NOT AVAILABLE.
CHRONIC EFFECTS ON HUMANS:
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
LUNGS, MUCOUS MEMBRANES, UPPER RESPIRATORY TRACT, SKIN, EYES, TEETH.
OTHER TOXIC EFFECTS ON HUMANS:
EXTREMELY HAZARDOUS IN CASE OF INHALATION (LUNG CORROSIVE).
VERY HAZARDOUS IN CASE OF SKIN CONTACT (CORROSIVE, IRRITANT, PERMEATOR),
OF EYE CONTACT (CORROSIVE), OF INGESTION,.
SPECIAL REMARKS ON TOXICITY TO ANIMALS:
LDL - LOWEST PUBLISHED LETHAL DOSE [HUMAN] - ROUTE:
ORAL; DOSE: 430 MG/KG (NITRIC ACID, FUMING)
SPECIAL REMARKS ON CHRONIC EFFECTS ON HUMANS:
MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS (EFFECTS ON NEWBORN AND
FETOTOXICITY) BASED ON ANIMAL DATA. (NITRIC ACID, FUMING)
SPECIAL REMARKS ON OTHER TOXIC EFFECTS ON HUMANS:
ACUTE POTENTIAL HEALTH EFFECTS:
SKIN:
SEVERELY IRRITATES SKIN. CAUSES SKIN BURNS AND MAY CAUSE DEEP AND
PENETRATING ULCERS OF THE SKIN WITH A CHARACTERISTIC YELLOW TO BROWNISH
DISCOLORATION. MAY BE FATAL IF ABSORBED THROUGH SKIN.
EYES:
SEVERELY IRRITATES EYES. CAUSES EYE BURNS. MAY CAUSE IRREVERSIBLE EYE
INJURY.
INGESTION:
MAY BE FATAL IF SWALLOWED. CAUSES SERIOUS GASTROINTESTINAL TRACT IRRITATION
OR BURNS WITH NAUSEA, VOMITING, SEVERE ABDOMINAL PAIN, AND POSSIBLE "COFFEE
GROUNDS" APPEARANCE OF THE VOMITUS. MAY CAUSE PERFORATION OF THE DIGESTIVE
TRACT.
INHALATION:
MAY BE FATAL IF INHALED. VAPOR IS EXTREMELY HAZARDOUS. VAPOR MAY CAUSE
NITROUS GAS POISONING. EFFECTS MAY BE DELAYED. MAY CAUSE IRRITATION OF THE
MUCOUS MEMBRANES AND RESPIRATORY TRACT WITH BURNING PAIN IN THE NOSE AND
THROAT, COUGHING, SNEEZING, WHEEZING, SHORTNESS OF BREATH AND PULMONARY
EDEMA. OTHER SYMPTOMS MAY INCLUDE NAUSEA, AND VOMITING.
CHRONIC POTENTIAL HEALTH EFFECTS:
REPEATED INHALATION MAY PRODUCE CHANGES IN PULMONARY FUNCTION AND/OR
CHRONIC BRONCHITIS. IT MAY ALSO AFFECT BEHAVIOR (HEADACHE, DIZZINESS,
DROWSINESS, MUSCLE CONTACTION OR SPASTICITY, WEAKNESS, LOSS OF COORDINATON,
MENTAL CONFUSION), AND URINARY SYSTEM (KIDNEY FAILLURE, DECREASED URINARY
OUTPUT AFTER SEVERAL HOURS OF UNCORRECTED CIRCULATORY COLLAPSE).
REPEATED EXPOSURE MAY CAUSE DISCOL ORATION AND/OR ERROS ON OF TEETH
(DENTAL ENAMEL).
EYE IRRITATION AND RESPIRATORY TRACT SIGNS AND SYMPTOMS RESEMBLING THOSE OF
FREQUENT UPPER RESPIRATORY VIRAL INFECTIONS HAVE BEEN ASSOCIATED WITH
CHRONIC NITRIC ACID EXPOSURE.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NOT AVAILABLE.
BOD5 AND COD: NOT AVAILABLE.
PRODUCTS OF BIODEGRADATION:
POSSIBLY HAZARDOUS SHORT TERM DEGRADATION PRODUCTS ARE NOT LIKELY. HOWEVER,
LONG TERM DEGRADATION PRODUCTS MAY ARISE.
TOXICITY OF THE PRODUCTS OF BIODEGRADATION:
THE PRODUCTS OF DEGRADATION ARE LESS TOXIC THAN THE PRODUCT ITSELF.
SPECIAL REMARKS ON THE PRODUCTS OF BIODEGRADATION: NOT AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL CONTROL REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION:
CLASS 8: CORROSIVE MATERIAL
CLASS 5.1: OXIDIZING MATERIAL.
IDENTIFICATION:
UN NA:
2031: NITRIC ACID
PG: II
SPECIAL PROVISIONS FOR TRANSPORT: NOT AVAILABLE.
DOT (PICTOGRAMS):
CORROSIVE, CLASS/DIVISION 8
OXIDIZER, CLASS/DIVISION 5.1
| SECTION 15. OTHER REGULATORY INFORMATION AND PICTOGRAMS | |
FEDERAL AND STATE REGULATIONS:
CALIFORNIA PROP. 65:
THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS FOR WHICH THE STATE OF
CALIFORNIA HAS FOUND TO CAUSE BIRTH DEFECTS WHICH WOULD REQUIRE A WARNING
UNDER THE STATUTE: NO PRODUCTS WERE FOUND.
CALIFORNIA PROP. 65:
THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS FOR WHICH THE STATE OF
CALIFORNIA HAS FOUND TO CAUSE CANCER WHICH WOULD REQUIRE A WARNING UNDER
THE STATUTE: NO PRODUCTS WERE FOUND.
CONNECTICUT HAZARDOUS MATERIAL SURVEY.: NITRIC ACID
ILLINOIS TOXIC SUBSTANCES DISCLOSURE TO EMPLOYEE ACT: NITRIC ACID
ILLINOIS CHEMICAL SAFETY ACT: NITRIC ACID
NEW YORK RELEASE REPORTING LIST: NITRIC ACID
RHODE ISLAND RTK HAZARDOUS SUBSTANCES: NITRIC ACID
PENNSYLVANIA RTK: NITRIC ACID
FLORIDA: NITRIC ACID
MINNESOTA: NITRIC ACID
MASSACHUSETTS RTK: NITRIC ACID
MASSACHUSETTS SPILL LIST: NITRIC ACID
NEW JERSEY: NITRIC ACID
NEW JERSEY SPILL LIST: NITRIC ACID
LOUISIANA RTK REPORTING LIST: NITRIC ACID
LOUISIANA SPILL REPORTING: NITRIC ACID
CALIFORNIA DIRECTOR'S LIST OF HAZARDOUS SUBSTANCES: NITRIC ACID
TSCA 8(B) INVENTORY: WATER; NITRIC ACID
SARA 302/304/311/312 EXTREMELY HAZARDOUS SUBSTANCES: NITRIC ACID
SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING: NITRIC ACID
CERCLA:
HAZARDOUS SUBSTANCES:
NITRIC ACID: 1000 LBS (453.6 KG)
CALIFORNIA PROPOSITION 65:
WARNINGS:
CALIFORNIA PROP. 65:
THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS FOR WHICH THE STATE OF
CALIFORNIA HAS FOUND TO CAUSE CANCER WHICH WOULD REQUIRE A WARNING UNDER
THE STATUTE: NO PRODUCTS WERE FOUND.
CALIFORNIA PROP. 65:
THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS FOR WHICH THE STATE OF
CALIFORNIA HAS FOUND TO CAUSE BIRTH DEFECTS WHICH WOULD REQUIRE A WARNING
UNDER THE STATUTE: NO PRODUCTS WERE FOUND.
OTHER REGULATIONS:
OSHA:
HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200).
FOR NITRIC ACID (CAS NO. 7697-37-2):
EINECS:
THIS PRODUCT IS ON THE EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL
SUBSTANCES (EINECS NO. 231-714-2).
CANADA: LISTED ON CANADIAN DOMESTIC SUBSTANCE LIST (DSL).
CHINA: LISTED ON NATIONAL INVENTORY.
JAPAN: LISTED ON NATIONAL INVENTORY (ENCS).
KOREA: LISTED ON NATIONAL INVENTORY (KECI).
PHILIPPINES: LISTED ON NATIONAL INVENTORY (PICCS).
AUSTRALIA: LISTED ON AICS.
FOR WATER (CAS NO. 7732-18-5):
EINECS:
THIS PRODUCT IS ON THE EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL
SUBSTANCES (EINECS NO. 231-791-2).
CANADA: LISTED ON CANADIAN DOMESTIC SUBSTANCE LIST (DSL).
AUSTRALIA: LISTED ON AICS.
OTHER CLASSIFICATIONS:
WHMIS (CANADA):
CLASS C: OXIDIZING MATERIAL.
CLASS E: CORROSIVE LIQUID.
DSCL (EEC):
R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R35: CAUSES SEVERE BURNS.
S23: DO NOT BREATHE GAS/FUMES/VAPOUR/SPRAY [***]
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S36: WEAR SUITABLE PROTECTIVE CLOTHING.
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
HMIS (U.S.A.):
HEALTH HAZARD 3
FIRE HAZARD 0
REACTIVITY 0
PERSONAL PROTECTION
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 4
FLAMMABILITY 0
REACTIVITY 0
SPECIFIC HAZARD OXY
WHMIS (CANADA) (PICTOGRAMS):
D1 - MATERIALS CAUSING IMMEDIATE AND SERIOUS TOXIC EFFECTS
E - CORROSIVE MATERIAL
DSCL (EUROPE) (PICTOGRAMS):
C: CORROSIVE
O: OXIDISING AGENT
TDG (CANADA) (PICTOGRAMS):
CLASS 8, CORROSIVES
CLASS 5.1, OXIDIZING SUBSTANCES
ADR (EUROPE) (PICTOGRAMS):
CLASS 8, CORROSIVES
CLASS 5.1, OXIDIZING SUBSTANCES
PROTECTIVE EQUIPMENT:
GLOVES
FULL SUIT.
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IN INADEQUATE.
FACE SHIELD.
| SECTION 16. OTHER INFORMATION | |
MSDS CODE: N3396
REFERENCES: NOT AVAILABLE.
OTHER SPECIAL CONSIDERATIONS: NOT AVAILABLE.
VALIDATED BY SONIA OWEN ON: 5/29/2009.
VERIFIED BY: SONIA OWEN.
PRINTED: 5/29/2009.
CALL: (310) 516-8000
NOTICE TO READER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS MATERIAL SAFETY DATA SHEET (MSDS) APPLIES ONLY TO THE MATERIAL AS
PACKAGED. IF THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES,
OR BECOMES CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS MSDS. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
MSDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM QUALITY
PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY
OF THE INFORMATION CONTAINED HEREIN.