SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. SPECTRUM(R*) CHEMICAL MFG CORP S ISO 9001-2008 REGISTERED SAFETY DATA SHEET PREPARATION DATE: 2/18/2014 REVISION DATE: 2/18/2014 REVISION NUMBER: G1
PRODUCT IDENTIFIER: PRODUCT CODE: S-675 PRODUCT NAME: SULFURIC ACID, 50 PERCENT (V/V) SOLUTION, APHA OTHER MEANS OF IDENTIFICATION: SYNONYMS: NO INFORMATION AVAILABLE CAS #: MIXTURE RTECS #: WS5600000 (FOR SULFURIC ACID) CI #: NOT AVAILABLE RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE: RECOMMENDED USE: NO INFORMATION AVAILABLE. USES ADVISED AGAINST: NO INFORMATION AVAILABLE SUPPLIER: SPECTRUM CHEMICALS AND LABORATORY PRODUCTS, INC. 14422 SOUTH SAN PEDRO ST. GARDENA, CA 90248 (310) 516-8000 ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM EMERGENCY TELEPHONE NUMBER: CHEMTREC: 1-800-424-9300 CONTACT PERSON: MARTIN LABENZ (WEST COAST) CONTACT PERSON: REGINA WACHENHEIM (EAST COAST)
CLASSIFICATION: THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) ACUTE TOXICITY - INHALATION (GASES): CATEGORY 2 ACUTE TOXICITY - INHALATION (VAPORS): CATEGORY 2 SKIN CORROSION/IRRITATION: CATEGORY 1 SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1 LABEL ELEMENTS: DANGER: HAZARD STATEMENTS: FATAL IF INHALED CAUSES SEVERE SKIN BURNS AND EYE DAMAGE CORROSION SKULLS AND CROSSBONES HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE OTHER HAZARDS: MAY BE HARMFUL IF SWALLOWED PRECAUTIONARY STATEMENTS - PREVENTION: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA WEAR RESPIRATORY PROTECTION WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION PRECAUTIONARY STATEMENTS - RESPONSE: SPECIFIC TREATMENT IS URGENT (SEE .. ON THIS LABEL) IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN SPECIFIC TREATMENT (SEE .. ON THIS LABEL) IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER WASH CONTAMINATED CLOTHING BEFORE REUSE IF INHALED: REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING PRECAUTIONARY STATEMENTS - STORAGE: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED STORE LOCKED UP PRECAUTIONARY STATEMENTS - DISPOSAL: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
COMPONENTS CAS-NO. WEIGHT % TRADE SECRET SULFURIC ACID 7664-93-9 50 * 7664-93-9 WATER 7732-18-5 50 * 7732-18-5
FIRST AID MEASURES: GENERAL ADVICE: POISON INFORMATION CENTRES IN EACH STATE CAPITAL CITY CAN PROVIDE ADDITIONAL ASSISTANCE FOR SCHEDULED POISONS (13 1126). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. FIRST AIDER NEEDS TO PROTECT HIMSELF. SKIN CONTACT: WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED CLOTHES AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN IMMEDIATELY. EYE CONTACT: FLUSH EYE WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN IMMEDIATELY. INHALATION: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. WARNING! IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS OR CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED OR INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF VICTIM IS CONSCIOUS, GIVE WATER OR MILK. FOLLOW WITH MILK OF MAGNESIA OR EGG WHITES BEATEN WITH WATER. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: SYMPTOMS: SEVERE SKIN AND EYE IRRITATION OR BURNS INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY PROTECTION OF FIRST-AIDERS: FIRST-AID PROVIDERS: AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS BIO-HAZARDOUS WASTE
EXTINGUISHING MEDIA: SUITABLE EXTINGUISHING MEDIA: THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH THE FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE. UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE. SPECIFIC HAZARDS: CONTACT WITH METALS MAY EVOLVE FLAMMABLE HYDROGEN GAS METAL ACETYLIDES (MONOCESIUM AND MONORUBIDIUM), AND CARBIDES IGNITE WITH CONCENTRATED SULFURIC ACID. WHITE PHOSPHOROUS + BOILING SULFURIC ACID OR ITS VAPOR IGNITES ON CONTACT. MAY IGNITE OTHER COMBUSTIBLE MATERIALS. MAY CAUSE FIRE WHEN SULFURIC ACID IS MIXED WITH CYCLOPENTADIENE, CYCLOPENTANONE OXIME, NITROARYL AMINES, HEXALITHIUM DISILICIDE, PHORPHOROUS (III) OXIDE, AND OXIDIZING AGENTS SUCH AS CHLORATES, HALOGENS, PERMANGANATES. MIXTURES OF SULFURIC ACID AND ANY OF THE FOLLOWING CAN EXPLODE: P-NITROTOLUENE, PENTASILVER TRIHYDROXYDIAMINOPHOSPHATE, PERCHLORATES, ALCOHOLS WITH STRONG HYDROGEN PEROXIDE, AMMONIUM TETRAPEROXYCHROMATE, MERCURIC NITRITE, POTASSIUM CHLORATE, POTASSIUM PERMANGANATE WITH POTASSIUM CHLORIDE, CARBIDES, NITRO COMPOUNDS, NITRATES, CARBIDES, PHOSPHOROUS, IODIDES, PICRATRES, FULMINATS, DIENES, ALCOHOLS (WHEN HEATED) NITRAMIDE DECOMPOSES EXPLOSIVELY ON CONTACT WITH CONCENTRATED SULFURIC ACID. 1,3,5-TRINITROSOHEXAHYDRO-1,3,5-TRIAZINE + SULFURIC ACID CAUSES EXPLOSIVE DECOMPOSITION. SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS: SPECIFIC METHODS: NO INFORMATION AVAILABLE. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: PERSONAL PRECAUTIONS: KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. ENVIRONMENTAL PRECAUTIONS: PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. SHOULD NOT BE RELEASED INTO THE ENVIRONMENT. DO NOT LET PRODUCT ENTER DRAINS. DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: METHODS FOR CONTAINMENT: STOP LEAK IF YOU CAN DO IT WITHOUT RISK. METHODS FOR CLEANING UP: NEUTRALIZE WITH SODIUM CARBONATE OR SODIUM BICARBONATE. DILUTE WITH WATER. ABSORB SPILL WITH INERT MATERIAL (E.G. VERMICULITE, DRY SAND OR EARTH), THEN PLACE IN A SUITABLE CHEMICAL WASTE CONTAINER. CLEAN CONTAMINATED SURFACE THOROUGHLY.
PRECAUTIONS FOR SAFE HANDLING: TECHNICAL MEASURES/PRECAUTIONS: USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. KEEP AWAY FROM INCOMPATIBLE MATERIALS. SAFE HANDLING ADVICE: WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS OR SPRAY MIST. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: TECHNICAL MEASURES/STORAGE CONDITIONS: KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. MAY CORRODE METALLIC SURFACES. DO NOT STORE IN UNCOATED METALLIC CONTAINERS. STORE IN A SEGRATED AND APPROVED AREA. STORE AWAY FROM INCOMPATIBLE MATERIALS. INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. REDUCING AGENTS. ORGANIC MATERIALS. COMBUSTIBLE MATERIALS. BASES. AMINES. METALS. ACIDS.
CONTROL PARAMETERS: NATIONAL OCCUPATIONAL EXPOSURE LIMITS: UNITED STATES: COMPONENTS OSHA NIOSH ACGIH AIHA WHEEL SULFURIC ACID - 1 MG/M3 TWA 1 MG/M3 TWA 0.2 MG/M3 TWA NONE 7664-93-9 THORACIC FRACTION WATER - NONE NONE NONE NONE 7732-18-5 CANADA: COMPONENTS ALBERTA BRITISH COLUMBIA ONTARIO QUEBEC SULFURIC ACID - 1 MG/M3 TWA 0.2 MG/M3 TWA 0.2 MG/M3 TWA 1 MG/M3 7664-93-9 THORACIC TWAEV 3 MG/M3 STEL 3 MG/M3 STEV WATER - NONE NONE NONE NONE 7732-18-5 AUSTRALIA AND MEXICO: COMPONENTS AUSTRALIA MEXICO SULFURIC ACID 3 MG/M3 STEL 1 MG/M3 TWA 7664-93-9 1 MG/M3 TWA WATER NONE NONE 7732-18-5 APPROPRIATE ENGINEERING CONTROLS: ENGINEERING MEASURES TO REDUCE EXPOSURE: ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE. INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT: PERSONAL PROTECTIVE EQUIPMENT: EYE PROTECTION: FACE-SHIELD. SKIN AND BODY PROTECTION: CHEMICAL RESISTANT PROTECTIVE SUIT. GLOVES. BOOTS. RESPIRATORY PROTECTION: VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT. HYGIENE MEASURES: AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE PRODUCT.
PHYSICAL STATE: LIQUID. APPEARANCE: NO INFORMATION AVAILABLE COLOR: COLORLESS. ODOR: ODORLESS, BUT HAS A CHOKING ODOR WHEN HOT. TASTE: STRONG. ACID. MOLECULAR/FORMULA WEIGHT: NO INFORMATION AVAILABLE FLASH POINT (DEG. C): NO DATA AVAILABLE FLASHPOINT (DEG. C / DEG. F): NO INFORMATION AVAILABLE. FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE AUTOIGNITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE PH: NO INFORMATION AVAILABLE MELTING POINT/RANGE (DEG. C / DEG. F): NO INFORMATION AVAILABLE BOILING POINT/RANGE (DEG. C / DEG. F): NO INFORMATION AVAILABLE DECOMPOSITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE SPECIFIC GRAVITY: 1.3-1.4 DENSITY (G/CM3): NO INFORMATION AVAILABLE BULK DENSITY: NO INFORMATION AVAILABLE VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE EVAPORATION RATE: NO INFORMATION AVAILABLE VAPOR DENSITY: NO INFORMATION AVAILABLE VOC CONTENT (G/L): NO INFORMATION AVAILABLE ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE VISCOSITY: NO INFORMATION AVAILABLE MISCIBILITY: NO INFORMATION AVAILABLE SOLUBILITY: EASILY SOLUBLE IN COLD WATER
REACTIVITY: REACTS VIOLENTLY WITH WATER IT REACTS WITH ALCOHOLS AND AMINES INCOMPATIBLE (CAN REACT EXPLOSIVELY OR DANGEROUSLY) WITH THE FOLLOWING: ACETIC ACID, ACRYLIC ACID, AMMONIUM HYDROXIDE, CRESOL, CUMENE, DICHLOROETHYL ETHER, ETHYLENE CYANOHYDRIN, ETHYLENEIMINE, NITRIC ACID, 2-NITROPROPANE, PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOL MONOMETHYL ETHER, ETHYL ACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHER ACETATE, GLYOXAL, METHYL ETHYL KETONE, DEHYDRATING AGENTS, ORGANIC MATERIALS, MOISTURE (WATER), ACETIC ANHYDRIDE, ACETONE, CYANOHYDRIN, ACETONE+NITRIC ACID, ACETONE + POTASSIUM DICHROMATE, ACETONITRILE, ACROLEIN, ACRYLONITRILE, ACRYLONITRILE + WATER, ALCOHOLS + HYDROGEN PEROXIDE, ALLY COMPOUNDS SUCH AS ALLYL ALCOHOL, AND ALLYL CHLORIDE, 2-AMINOETHANOL, AMMONIUM HYDROXIDE, AMMONIUM TRIPERCHROMATE, ANILINE, BROMATE + METALS, BROMINE PENTAFLUORIDE, N-BUTYRALDEHYDE, CARBIDES, CESIUM ACETYLENE CARBIDE, CHLORATES, CYCLOPENTANONE OXIME, CHLORINATES, CHLORATES + METALS, CHLORINE TRIFLUORIDE, CHLOROSULFONIC ACID, 2-CYANO-4-NITROBENZENEDIAZONIUM HYDROGEN SULFATE, CUPROUS NITRIDE, P-CHLORONITROBENZENE, 1,5-DINITRONAPHTHLENE + SULFUR, DIISOBUTYLENE, P-DIMETHYLAMINOBENZALDEHYDE, 1,3-DIAZIDOBENZENE, DIMETHYLBENZYLCARBINOL + HYDROGEN PEROXIDE, EPICHLOROHYDRIN, ETHYL ALCOHOL + HYDROGEN PEROXIDE, ETHYLENE DIAMINE, ETHYLENE GLYCOL AND OTHER GLYCOLS, ETHYLENIMINE, FULMINATES, HYDROGEN PEROXIDE, HYDROCHLORIC ACID, HYDROFLUORIC ACID, IODINE HEPTAFLUORIDE, INDANE + NITRIC ACID, IRON, ISOPRENE, LITHIUM SILICIDE, MERCURIC NITRIDE, MESITYL OXIDE, MERCURY NITRIDE, METALS (POWDERED), NITROMETHANE, NITRIC ACID + GLYCERIDES, P-NITROTOLUENE, PENTASILVER TRIHYDROXYDIAMINOPHOSPHATE, PERCHLORATES, PERCHLORIC ACID, PERMANGANATES + BENZENE, 1-PHENYL-2-METHYLPROPYL ALCOHOL + HYDROGEN PEROXIDE, PHOSPHORUS, PHOSPHORUS ISOCYANATE, PICRATES, POTASSIUM TERT-BUTOXIDE, POTASSIUM CHLORATE, POTASSIUM PERMANGANATE AND OTHER PERMANGANATES, HALOGENS, AMINES, POTASSIUM PERMANGANATE + POTASSIUM CHLORIDE, POTASSIUM PERMANGANATE + WATER, PROPIOLACTONE (BETA)-, PYRIDINE, RUBIDIUM ACETEYLENE CARBIDE, SILVER PERMANGANATE, SODIUM, SODIUM CARBONATE, SODIUM HYDROXIDE, STEEL, STYRENE MONOMER, TOLUENE + NITRIC ACID, VINYL ACETATE, THALIUM (I) AZIDODITHIOCARBONATE, ZINC CHLORATE, ZINC IODIDE, AZIDES, CARBONATES, CYANIDES, SULFIDES, SULFITES, ALKALI HYDRIDES, CARBOXYLIC ACID ANHYDRIDES, NITRILES, OLEFINIC ORGANICS, AQUEOUS ACIDS, CYCLOPENTADIENE, CYANO-ALCOHOLS, METAL ACETYLIDES, EVOLVES FLAMMABLE HYDROGEN GAS ON CONTACT WITH METALS CONCENTRATED SULFURIC ACID OXIDIZES, DEHYDRATES, OR SULFONATES MOST ORGANIC COMPOUNDS CHEMICAL STABILITY: STABILITY: STABLE AT NORMAL CONDITIONS POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS. EXPOSURE TO WATER. INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. REDUCING AGENTS. ORGANIC MATERIALS. COMBUSTIBLE MATERIALS. BASES. AMINES. METALS. ACIDS. HAZARDOUS DECOMPOSITION PRODUCTS: SULPHUR OXIDES. OTHER INFORMATION: CORROSIVITY: NO INFORMATION AVAILABLE SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
INFORMATION ON LIKELY ROUTES OF EXPOSURE: PRINCIPAL ROUTES OF EXPOSURE: SKIN. INHALATION. INGESTION. ACUTE TOXICITY: THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS DOCUMENT: ATEMIX (ORAL): 4280 MG/KG ATEMIX (INHALATION-GAS): 694 (FOR 1 H); 347 (FOR 4 H) PPM COMPONENT INFORMATION: SULFURIC ACID - 7664-93-9: LD50/ORAL/RAT: 2140 MG/KG ORAL LD50 RAT LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE LD50/DERMAL/RAT: NO INFORMATION AVAILABLE LC50/INHALATION/RAT: 347 PPM 1 H 420 PPM 1 H 510 MG/M3 2 H LC50/INHALATION/MOUSE: 320 MG/M3 2 H OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE WATER - 7732-18-5: LD50/ORAL/RAT: >90 ML/KG ORAL LD50 RAT LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE LD50/DERMAL/RAT: NO INFORMATION AVAILABLE LC50/INHALATION/RAT: NO INFORMATION AVAILABLE LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE PRODUCT INFORMATION: LD50/ORAL/RAT: VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE LD50/ORAL/MOUSE: VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE LD50/DERMAL/RABBIT: VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE LD50/DERMAL/RAT: VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE LC50/INHALATION/RAT: VALUE-VAPOR: NO INFORMATION AVAILABLE VALUE-GAS: NO INFORMATION AVAILABLE VALUE-DUST/MIST: NO INFORMATION AVAILABLE LC50/INHALATION/MOUSE: VALUE-VAPOR: NO INFORMATION AVAILABLE VALUE-GAS: NO INFORMATION AVAILABLE VALUE-DUST/MIST: NO INFORMATION AVAILABLE SYMPTOMS: SKIN CONTACT: SEVERE SKIN IRRITATION. CAUSES SKIN BURNS. EYE CONTACT: SEVERE EYE IRRITATION. CAUSES EYE BURNS. INHALATION: FATAL IF INHALED. CAUSES SEVERE IRRITATION OF THE RESPIRATORY TRACT AND MUCOUS MEMBRANES WITH SORE THROAT, COUGHING, SNEEZING, SHORTNESS OF BREATH, AND DELAYED LUNG EDEMA. CAN CAUSE CHEMICAL BURNS (CORROSIVE ACTION) TO THE REPIRATORY TRACT AND MUCOUS MEMBRANES. INHALATION MAY BE FATAL AS A RESULT OF BRONCHOSPASM, INFLAMMATION, EDEMA OF THE LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS, AND PULMONARY EDEMA. MAY AFFECT CARDIOVASCULAR SYSTEM (HYPOTENSION, DEPRESSED CARDIAC OUTPUT, BRADYCARDIA). CIRCULATORY SHOCK/COLLAPSE WITH CLAMMY SKIN, WEAK AND RAPID PULSE, SHALLOW RESPIRATION, AND SCANTY URINE MAY FOLLOW. ISCHEMIC LIVER AND HEART LESIONS, KIDNEY FAILURE MAY OCCUR SEVERAL HOURS AFTER UNCHECKED CIRCULATORY COLLAPSE. CIRCULATORY SHOCK IS OFTEN THE IMMEDIATE CAUSE OF DEATH. MAY ALSO AFFECT TEETH(CHANGES IN TEETH AND SUPPORTING STRUCTURES - EROSION, DISCOLORATION). INGESTION: MAY BE HARMFUL IF SWALLOWED. CAUSES DIGESTIVE OR GASTROINTESTINAL TRACT BURNS. CORROSIVE TO THE MOUTH, THROAT, AND STOMACH. MAY CAUSE PERMANENT DAMAGE TO THE DIGESTIVE TRACT. MAY CAUSE PERFORATION OF THE DIGESTIVE TRACT. MAY CAUSE GASTRITIS. MAY CAUSE ABDOMINAL PAIN. INGESTION MAY CAUSE NAUSEA, VOMITING. VOMIT MAY RESEMBLE "COFFEE GROUNDS". MAY CAUSE METABOLIC ACIDOSIS. ASPIRATION HAZARD: NO INFORMATION AVAILABLE DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND LONG-TERM EXPOSURE: CHRONIC TOXICITY: INHALATION: PROLONGED OR REPEATED INHALATION MAY AFFECT BEHAVIOR (MUSCLE CONTRACTION OR SPASTICITY), URINARY SYSTEM (KIDNEY DAMAGE), AND RESPIRATORY SYSTEM/LUNGS(PULMONARY EDEMA, LUNG DAMAGE/CHANGES IN LUNG FUNCTION WITH CHRONIC BRONCHITIS AND EMPHYSEMA), TEETH (DENTAL DISCOLORATION, EROSION). SKIN: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. EYES: CONJUNCTIVITIS IS ALSO A COMMON FINDING WITH CHRONIC EXPOSURE. SENSITIZATION: NO INFORMATION AVAILABLE MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE CARCINOGENIC EFFECTS: MAY CAUSE CANCER. HOWEVER, EVIDENCE IS INCONCLUSIVE. CANCER STATUS: THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS CLASSIFIED "STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACID" AS A KNOWN HUMAN CARCINOGEN, (IARC GROUP 1). HOWEVER, THIS CLASSIFICATION APPLIES ONLY TO MISTS CONTAINING SULFURIC ACID GENERATED DURING AN INDUSTRIAL PROCESS AND NOT TO (ALMOST) PURE SULFURIC ACID OR SULFURIC ACID SOLUTIONS; THE ACGIH HAS CLASSIFIED "STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACID" AS A SUSPECTED HUMAN CARCINOGEN (ACGIH GROUP A2). HOWEVER, THIS CLASSIFICATION APPLIES ONLY TO MISTS CONTAINING SULFURIC ACID GENERATED DURING AN INDUSTRIAL PROCESS AND NOT TO (ALMOST) PURE SULFURIC ACID OR SULFURIC ACID SOLUTIONS. COMPONENT IARC ACGIH - NTP CARCINOGENS SULFURIC ACID A2 SUSPECTED GROUP 1 - NOT LISTED HUMAN CARCINOGEN MONOGRAPH 54 [1992] (CONTAINED IN STRONG OCCUPATIONAL EXPOSURE INORGANIC ACID MISTS) TO MISTS AND VAPOURS FROM SULFURIC ACID AND OTHER STRONG INORGANIC ACIDS WATER NOT LISTED NOT LISTED NOT LISTED COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA - CARCINOGENS NOTIFIABLE PROHIBITED CARCINOGENIC CARCINOGENIC SUBSTANCES SUBSTANCES SULFURIC ACID PRESENT NOT LISTED NOT LISTED WATER NOT LISTED NOT LISTED NOT LISTED REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE TERATOGENIC EFFECTS: DEVELOPMENTAL EFFECTS AND TERATOGENICITY: ACCORDING THE REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS REFERENCE - MURRY ET AL, "EMBRYROTOXICITY OF INHALED SULFURIC ACID AEROSOL IN MICE AND RABBITS", JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH, PART C, VOL. 13, PAGES 251-266, 1979), MUSCULOSKELETAL DEVELOPMENTAL ABNORMALITIES WERE FOUND IN RABBITS AT A DOSE OF 20 MG/M3 FOR 7 HRS. HOWEVER, REPROTOX AND SHEPARD'S CATALOG OF TERATOGENIC AGENTS, CITING THIS SAME STUDY, STATED THAT INHALATION OF SULFURIC ACID FUMES DID NOT INCREASE CONGENITAL ANOMALIES IN THE OFFSPRING OF TREATED PREGNANT MICE OR RABBITS. FURTHERMORE, THE HAZARD SUBSTANCE DATA BANK (HSDB) ALSO STATED THAT IN A DEVELOPMENTAL TOXICITY STUDY CONDUCTED UNDER A METHOD SIMILAR TO OECD TEST GUIDELINE 414 THAT NO SIGNIFICANT EFFECTS ON MEAN NUMBERS OF IMPLANTS/DAM, LIVE FETUSES/LITER OR RESORPTIONS/LITTER WERE OBSERVED IN MICE AND RABBITS EXPOSED BY INHALATION TO SULFURIC ACID AEROSOL AT 5 AND 20 MG/M3 DURING GESTATION AND THEREFORE COULD NOT BE CONSIDERED EMBRYOTOXIC, OR FETOXIC. SPECIFIC TARGET ORGAN TOXICITY: STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE TARGET ORGANS: SKIN. EYES. RESPIRATORY SYSTEM.
ECOTOXICITY: ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT. SULFURIC ACID - 7664-93-9: FRESHWATER FISH SPECIES DATA: 500 MG/L LC50 BRACHYDANIO RERIO 96 H STATIC 1 PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE MOBILITY: NO INFORMATION AVAILABLE
DISPOSAL METHODS: WASTE FROM RESIDUES/UNUSED PRODUCTS: WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATION. CONTAMINATED PACKAGING: EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE DISPOSAL COMPONENTS RCRA - F RCRA - K RCRA - P RCRA - U SERIES SERIES SERIES SERIES WASTES WASTES WASTES WASTES SULFURIC ACID NONE NONE NONE NONE WATER NONE NONE NONE NONE
DOT: UN-NO: UN1830 PROPER SHIPPING NAME: SULFURIC ACID HAZARD CLASS: 8 SUBSIDIARY RISK: NOT APPLICABLE PACKING GROUP: II MARINE POLLUTANT: NO DATA AVAILABLE ERG NO: 137 DOT RQ (LBS): NO INFORMATION AVAILABLE SYMBOL(S): R4 TDG (CANADA): UN-NO: UN1830 PROPER SHIPPING NAME: SULFURIC ACID HAZARD CLASS: 8 SUBSIDIARY RISK: NO INFORMATION AVAILABLE PACKING GROUP: II DESCRIPTION: NO INFORMATION AVAILABLE ADR: UN-NO: UN1830 PROPER SHIPPING NAME: SULPHURIC ACID HAZARD CLASS: 8 PACKING GROUP: II SUBSIDIARY RISK: NO INFORMATION AVAILABLE CLASSIFICATION CODE: NO INFORMATION AVAILABLE DESCRIPTION: NO INFORMATION AVAILABLE CEFIC TREMCARD NO: NO INFORMATION AVAILABLE IMO/IMDG: UN-NO: UN1830 PROPER SHIPPING NAME: SULPHURIC ACID HAZARD CLASS: 8 SUBSIDIARY RISK: NO INFORMATION AVAILABLE PACKING GROUP: II DESCRIPTION: NO INFORMATION AVAILABLE IMDG PAGE: NO INFORMATION AVAILABLE MARINE POLLUTANT: NO INFORMATION AVAILABLE EMS: F-A MFAG: NO INFORMATION AVAILABLE MAXIMUM QUANTITY: NO INFORMATION AVAILABLE RID: UN-NO: UN1830 PROPER SHIPPING NAME: SULPHURIC ACID HAZARD CLASS: 8 SUBSIDIARY RISK: 8 PACKING GROUP: II CLASSIFICATION CODE: NO INFORMATION AVAILABLE DESCRIPTION: NO INFORMATION AVAILABLE ICAO: UN-NO: UN1830 PROPER SHIPPING NAME: SULPHURIC ACID HAZARD CLASS: 8 SUBSIDIARY RISK: NO INFORMATION AVAILABLE PACKING GROUP: II DESCRIPTION: NO INFORMATION AVAILABLE IATA: UN-NO: UN1830 PROPER SHIPPING NAME: SULPHURIC ACID HAZARD CLASS: 8 SUBSIDIARY RISK: NO INFORMATION AVAILABLE PACKING GROUP: II ERG CODE: 8L DESCRIPTION: NO INFORMATION AVAILABLE
INTERNATIONAL INVENTORIES: COMPONENTS U.S. TSCA KOREA KECL PHILIPPINES (PICCS) SULFURIC ACID PRESENT PRESENT PRESENT KE-32570 WATER PRESENT PRESENT PRESENT KE-35400 COMPONENTS JAPAN ENCS CHINA AUSTRALIA EINECS-NO. (AICS) SULFURIC ACID PRESENT PRESENT PRESENT PRESENT (1)-724 (1)-430 231-639-5 WATER NOT PRESENT PRESENT PRESENT PRESENT 231-791-2 U.S. REGULATIONS: SULFURIC ACID: MASSACHUSETTS RTK: PRESENT NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: PRESENT NEW JERSEY (EHS) LIST: PRESENT NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: 1000 LB RQ 100 LB RQ LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS: 1000 LB FINAL RQ 454 KG FINAL RQ CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1095 CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986. CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. (SEE TABLE BELOW) CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY: THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER CALIFORNIA PROP. 65. (SEE TABLE BELOW) COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE TOXICITY REPRODUCTIVE REPRODUCTIVE TOXICITY TOXICITY SULFURIC ACID LISTED UNDER NOT LISTED NOT LISTED NOT LISTED STRONG INORGANIC MISTS CONTAINING SULFURIC ACID WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED CERCLA/SARA: COMPONENTS CERCLA - HAZARDOUS SECTION 302 SECTION 302 SUBSTANCES AND EXTREMELY EXTREMELY THEIR REPORTABLE HAZARDOUS HAZARDOUS QUANTITIES SUBSTANCES SUBSTANCES AND TPQS AND RQS SULFURIC ACID 1000 LB FINAL RQ 1000 LB TPQ NONE 454 KG FINAL RQ WATER NONE NONE NONE COMPONENTS SECTION 313 - SECTION 313 - REPORTING CHEMICAL CATEGORY DE MINIMIS SULFURIC ACID NONE 1.0% DE MINIMIS CONCENTRATION WATER NONE NONE U.S. TSCA: COMPONENTS TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH AND CHEMICALS WITH SAFETY REPORTING SIGNIFICANT NEW USE RULES (SNURS) SULFURIC ACID NOT APPLICABLE NOT APPLICABLE WATER NOT APPLICABLE NOT APPLICABLE CANADA: WHMIS HAZARD CLASS: D1A: VERY TOXIC MATERIALS E: CORROSIVE MATERIAL SULFURIC ACID: D1A: E INCLUDING & GT; 51%, <=51% WATER: UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA CANADA CONTROLLED PRODUCTS REGULATION: THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR. COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST SULFURIC ACID 1% INVENTORY: COMPONENTS CANADA (DSL) CANADA (NDSL) SULFURIC ACID PRESENT NOT LISTED WATER PRESENT NOT LISTED COMPONENTS CEPA SCHEDULE I - CEPA - 2010 GREENHOUSE GASES TOXIC SUBSTANCES SUBJECT TO MANDITORY REPORTING SULFURIC ACID NOT LISTED NOT LISTED WATER NOT LISTED NOT LISTED EU CLASSIFICATION: R-PHRASE(S): R35: CAUSES SEVERE BURNS. S-PHRASE(S): S26: IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. S30: NEVER ADD WATER TO THIS PRODUCT. S45: IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). S1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN. COMPONENTS CLASSIFICATION CONCENTRATION LIMITS SAFETY PHRASES SULFURIC ACID C; R35 15% <=C: C; S1/2 S26 S30 S45 R:35 5% <=C <15%: XI; R: 36/38 WATER NO INFORMATION THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE 67/548/EEC: INDICATION OF DANGER: C: CORROSIVE. C: CORROSIVE
NFPA: 3 0 0 HMIS: HEALTH HAZARD 3 FIRE HAZARD 0 REACTIVITY 0 PERSONAL PROTECTIVE EQUIPMENT: FACE SHIELD FULL SUIT ORGANIC RESPIRATOR GLOVES BOOTS SEE SECTION 8. PREPARATION DATE: 2/18/2014 REVISION DATE: 2/18/2014 PREPARED BY: SONIA OWEN DISCLAIMER: ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY, MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION CONTAINED HEREIN. |