| Common Name: | AMMONIUM HYDROXIDE, 26 DEG BE, TECHNICAL |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 9/20/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39D968 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 11/03/2014
REVISION DATE: 9/20/2018
REVISION NUMBER: G5
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: A1200
PRODUCT NAME: AMMONIUM HYDROXIDE, 26 DEG BE, TECHNICAL
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
L'HYDROXYDE D'AMMONIUM(FRENCH)
AQUEOUS AMMONIA
AQUA AMMONIA
AMMONIUM HYDROXIDE WITH 27-31% AMMONIA AND 69-73% WATER
HIDROXIDO DE AMONIO (SPANISH)
CAS #: 1336-21-6
RTECS #: BQ9625000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
BLEACHING AGENT. IN THE MANUFACTURER OF TEXTILES. DETERGENT.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 4
ACUTE TOXICITY - INHALATION (GASES): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY B
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
HARMFUL IF INHALED
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
MAY CAUSE RESPIRATORY IRRITATION
CORROSION
EXCLAMATION MARK
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS:
VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
VERY TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER OR DOCTOR/PHYSICIAN. CALL A POISON CENTER OR
DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
RINSE MOUTH
DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
AMMONIUM HYDROXIDE 1336-21-6 100
[CONSISTS OF 27-31% AMMONIA
(CAS NO. 7664-41-7) IN 69-73% WATER]
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. FIRST
AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED CLOTHES
AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS
OR CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED
OR INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF
A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IF VICTIM IS CONSCIOUS, GIVE WATER OR
MILK. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SEVERE SKIN AND EYE IRRITATION OR BURNS
MAY CAUSE INFLAMMATION AND CAUSE DEEP, PENETRATING ULCERS OF THE SKIN,
STAINING OF THE SKIN, AND THICKENING OF THE SKIN
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION
MAY CAUSE GASTROINTESTINAL (DIGESTIVE) TRACT BURNS
SEVERE IRRITATION OF THE UPPER RESPIRATORY TRACT
MAY CAUSE CHEMICAL BURNS TO THE RESPIRATORY TRACT
MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS
MAY AFFECT THE CARDIOVASCULAR SYSTEM
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH THE
FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: AMMONIA. NITROGEN OXIDES.
SPECIFIC HAZARDS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. SHOULD NOT BE
RELEASED INTO THE ENVIRONMENT. DO NOT LET PRODUCT ENTER DRAINS. DO NOT
FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. ABSORB SPILL WITH INERT MATERIAL
(E.G. VERMICULITE, DRY SAND OR EARTH).
METHODS FOR CLEANING UP:
DILUTE WITH WATER. NEUTRALIZE THE RESIDUE WITH A DILUTE SOLUTION OF ACETIC
ACID. USE APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE
CHEMICAL WASTE DISPOSAL CONTAINER. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS OR SPRAY MIST. HANDLE IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
STORE AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. KEEP AT TEMPERATURES
BELOW 26 DEG. C. STORE IN A SEGREGATED AND APPROVED AREA. STORE AWAY FROM
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
ACIDS
METALS
POWDERED METALS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS CAS-NO. OSHA NIOSH ACGIH AIHA WEEL
AMMONIUM HYDROXIDE 1336-21-6 NONE NONE NONE NONE
[CONSISTS OF 27-31% AMMONIA
(CAS NO. 7664-41-7)
IN 69-73% WATER]
CANADA:
COMPONENTS CAS-NO. CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
AMMONIUM HYDROXIDE 1336-21-6 NONE NONE NONE NONE
[CONSISTS OF 27-31%
AMMONIA (CAS NO.
7664-41-7) IN
69-73% WATER]
AUSTRALIA AND MEXICO:
COMPONENTS CAS-NO. AUSTRALIA MEXICO
AMMONIUM HYDROXIDE 1336-21-6 NONE NONE
[CONSISTS OF 27-31% AMMONIA
(CAS NO. 7664-41-7) IN 69-73% WATER]
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND
MIST BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: FACE-SHIELD.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT PROTECTIVE SUIT
GLOVES
BOOTS
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: CLEAR. COLORLESS.
ODOR: STRONG. AMMONIA.
TASTE: ACRID.
FORMULA: NH4OH
MOLECULAR/FORMULA WEIGHT (G/MOLE): 35.05
FLAMMABILITY: NO INFORMATION AVAILABLE
FLASHPOINT (DEG. C/ DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): -69.2 DEG. C/-92.6 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F): 31-38 DEG. C/87.8-100.4 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 0.898
PH: 11.6 - THIS IS THE ACTUAL PH IN A 1 N SOLUTION
VAPOR PRESSURE @ 20 DEG. C (KPA): 287.9 @ 25 DEG. C
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): 5-50 (AS AMMONIA)
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY: EASILY SOLUBLE IN COLD WATER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
HALOGENS, SALTS OF SILVER AND ZINC, AIR AND HYDROCARBONS, CALCIUM,
1-CHLORO-2,4-DINITROBENZENE, CHLOROFORMAMIDINIUM NITRATE,
2-CHLORONITROBENZENE, CHLORINE AZIDE, MAGNESIUM PERCHLORATE, HALOGENS OR
INTERHALOGENS, IODINE, POTASSIUM, NITROGEN TRICHLORIDE, POTASSIUM CHLORATE,
NITRYL CHLORIDE, CHROMYL CHLORIDE, CHROMIUM TRIOXIDE, TRIOXYGEN DIFLUORIDE,
SELENIUM DIFLUORIDE DIOXIDE, NITRIC ACID, HYDROGEN PEROXIDE, NITROGEN
OXIDE, DINITROGEN TETRAOXIDE, OXYGEN, PLATINIUM, SILVER CHLORIDE,
THIOCARBONYL AZIDE THIOCYANATE, SULFINYL CHLORIDE, THIOTRITHIAZYL CHLORIDE,
TETRAMETHYLAMMONIUM AMIDE, TELLURIUM TETRACHLORIDE, TELLURIUM TETRABROMIDE,
SILVER (I) OXIDE, DICHLORINE OXIDE, SILVER NITRATE, ETHYLENE OXIDE,
ACETALDEHYDE, ACROLEIN, BORON, BORON TRIIODIDE, BROMINE, BROMINE
PENTAFLUORIDE, FLUORINE, CHLORIC ACID, CHLORINE MONOXIDE, CHLORINE
TRIFLUORIDE, CHLORITES, CHLOROSILANE, CHROMIC ANHYDRIDE, ETHYLENE
DICHLORIDE, HYDROGEN BROMIDE, HYPOCHLOROUS ACID, NITROGEN PEROXIDE,
FLUORINE, SOME HEAVY METALS (GOLD, SILVER, MERCURY), HEXACHLOROMELAMINE,
HYDRAZINE, ALKALI METALS, NITROGEN TRIFLUORIDE, OXYGEN DIFLUORIDE,
PHOSPHOROUS TRIOXIDE, POTASSIUM AND ARSINE, POTASSIUM AND PHOSPHINE,
POTASSIUM AND SODIUM NITRITE, POTASSIUM FERRICYANIDE, POTASSIUM
MERCURICYANIDE, SODIUM AND CARBON MONOXIDE, STIBINE, SULFUR, SULFUR
DICHLORIDE, TELLURIUM HYDROPENTACHLORIDE, TRICHLOROMELAMINE, ORGANIC
ACIDS, AMIDES, ORGANIC ANHYDRIDES, ISOCYANATES, VINYL ACETATE,
EPICHLORHYDRIN, ALDEHYDES, ACRYLIC ACID, CHLOROSULFONIC ACID, DIMETHYL
SULFATE, FLUORINE, GOLD + AQUA REGIA, HYDROCHLORIC ACID, HYDROFLUORIC ACID,
HYDROGEN PEROXIDE, IODINE, NITRIC ACID, OLELUM, PROPIOLACTONE, PROPYLENE
OXIDE, SILVER NITRATE, SILVER OXIDE + ETHYL ALCOHOL, NITROMETHANE, SILVER
PERMANGANATE, SULFURIC ACID, GOLD, MERCURY, AND HALIDE SALTS. FORMS
EXPLOSIVE COMPOUNDS WITH MANY HEAVY METALS (SILVER, LEAD, ZINC). FORMS
EXPLOSIVE COMPOUNDS WITH MANY HEAVY METALS SUCH AS SILVER, LEAD, ZINC AND
THEIR HALIDE SALTS.IT CAN FORM SHOCK SENSITIVE COMPOUNDS WITH HALOGENS,
MERCURY OXIDE, AND SILIVER OXIDE
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
ACIDS
METALS
POWDERED METALS
HAZARDOUS DECOMPOSITION PRODUCTS:
AMMONIA GAS MAY BE LIBERATED AT HIGH TEMPERATURES. NITROGEN OXIDES (NOX).
OTHER INFORMATION:
CORROSIVITY:
SEVERE CORROSIVE EFFECT ON BRASS
SEVERE CORROSIVE EFFECT ON BRONZE
SPECIAL REMARKS ON CORROSIVITY:
CORROSIVE TO GALVANIZED SURFACES.SEVERE CORROSIVE EFFECT ON BRASS AND
BRONZE.LIQUID AMMONIA OR AMMONIUM HYDROXIDE WILL ATTACK SOME FORMS OF
PLASTICS, RUBBER AND COATINGS SUCH AS ABS, ACETAL, HYTREL, BUNA (NITRILE),
NATURAL RUBBER, LDPE, NYLON, POLYCARBONATE, HYPALON, AND VITON.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. INHALATION. INGESTION. EYES.
ACUTE TOXICITY:
COMPONENT INFORMATION:
AMMONIUM HYDROXIDE [CONSISTS OF 27-31% AMMONIA (CAS NO. 7664-41-7)
IN 69-73% WATER]:
CAS-NO.: 1336-21-6
LD50/ORAL/RAT: 350 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION:
2000 PPM 4 HOURS LC50 INHALATION RAT (FOR AMMONIA)
4230 PPM 1 HOUR LC50 INHALATION MOUSE (FOR AMMONIA)
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX ORAL: 350 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: 6452-7407 PPM PPM (4-HR)
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
SEVERE SKIN IRRITATION. CAUSES SKIN BURNS. MAY CAUSE DEEP PENETRATING
ULCERS OF THE SKIN. CONTACT WITH SKIN MAY CAUSE STAINING, INFLAMMATION,
AND THICKENING OF THE SKIN.
EYE CONTACT:
SEVERE EYE IRRITATION. CAUSES EYE BURNS. MAY CAUSE IRREVERSIBLE EYE DAMAGE.
MAY CAUSE CORNEAL DAMAGE. MAY CAUSE CATARACTS.
INHALATION:
CAUSES SEVERE IRRITATION OF THE RESPIRATORY TRACT AND MUCOUS MEMBRANES
WITH COUGHING, BURNS, BREATHING DIFFICULTY, AND POSSIBLE COMA. IRRITATION
MAY LEAD TO CHEMICAL PNEUMONITIS, PNEUMOCONIOSIS, FIBROSIS, AND PULMONARY
EDEMA. CAN CAUSE CHEMICAL BURNS TO THE RESPIRATORY TRACT AND MUCOUS
MEMBRANESIT IS A RESPIRATORY STIMULANT WHEN INHALED AT LOWER
CONCENTRATIONS. IT MAY ALSO AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM
(CONVULSIONS, SEIZURES, ATAXIA, TREMOR), CARDIOVASCULAR SYSTEM (INCREASE
IN BLOOD PRESSURE AND PULSE RATE).
INGESTION:
HARMFUL IF SWALLOWED. CAUSES GASTROINTESTINAL TRACT CORROSION, BURNS,
SWELLING OF THE LIPS, MOUTH, AND LARYNX, THROAT CONSTRICTION, NAUSEA,
VOMITING, CONVULSIONS, SHOCK AND MAY CAUSE SEVERE AND PERMANENT DAMAGE TO
THE DIGESTIVE TRACT WITH PERFORAITON OF THE DIGESTIVE TRACT. IT MAY ALSO
AFFECT THE LIVER, AND URINARY SYSTEM (KIDNEYS), BEHAVIOR/CENTRAL NERVOUS
SYSTEM (CONVULSIONS, SEIZURES, ATAXIA, EXCITEMENT).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
INGESTION: MAY CAUSE EFFECTS SIMILAR TO THOSE OF ACUTE INGESTION.
INHALATION:
REPEATED EXPOSURE TO LOW CONCENTRATIONS MAY CAUSE BRONCHITIS WITH COUGH,
PHLEGM, AND/OR SHORTNESS OF BREATH. MAY ALSO CAUSE LIVER AND KIDNEY DAMAGE,
AND AFFECT THE BRAIN, AND BLOOD.
EYE:
MAY CAUSE CORNEAL DAMAGE AND THE DEVELOPMENT OF CATARACTS AND GLAUCOMA.
SKIN:
REPEATED SKIN CONTACT TO LOW CONCENTRATIONS MAY CAUSE DRYNESS, ITCHING,
AND REDNESS (DERMATITIS).
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
MUTATIONS IN MICROORGANISMS
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENTS CAS-NO. IARC ACGIH - NTP
CARCINOGENS
AMMONIUM HYDROXIDE 1336-21-6 NOT LISTED NOT LISTED NOT LISTED
[CONSISTS OF 27-31%
AMMONIA
(CAS NO. 7664-41-7)
IN 69-73% WATER]
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
AMMONIUM HYDROXIDE NOT LISTED NOT LISTED NOT LISTED
[CONSISTS OF 27-31%
AMMONIA
(CAS NO. 7664-41-7)
IN 69-73% WATER]
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: RESPIRATORY SYSTEM.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: SKIN. EYES. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
AMMONIUM HYDROXIDE [CONSISTS OF 27-31% AMMONIA (CAS NO. 7664-41-7)
IN 69-73% WATER] -:
FRESHWATER FISH SPECIES DATA: 8.2 MG/L LC50 PIMEPHALES PROMELAS 96 H 1
WATER FLEA DATA:
0.66 MG/L EC50 WATER FLEA 48 H
0.66 MG/L EC50 DAPHNIA PULEX 48 H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS CAS-NO. RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
AMMONIUM HYDROXIDE 1336-21-6 NONE NONE NONE NONE
[CONSISTS OF 27-31%
AMMONIA (CAS NO.
7664-41-7) IN
69-73% WATER]
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN2672
PROPER SHIPPING NAME: AMMONIA SOLUTION
HAZARD CLASS: 8
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: III
EMERGENCY RESPONSE GUIDE NUMBER: 154
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: 336, IB3, IP8, T7, TP2
SYMBOL(S):
[DOT]:
(R3) - IDENTIFIES A MATERIAL THAT IS A HAZARDOUS SUBSTANCE THAT HAS A
REPORTABLE QUANTITY (RQ) OF 100 POUNDS (45.4 KILOGRAMS).
DESCRIPTION: UN2672, AMMONIA SOLUTION, 8, III
TDG (CANADA):
UN-NO: UN2672
PROPER SHIPPING NAME: AMMONIA SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: UN2672, AMMONIA SOLUTION, 8, III
ADR:
UN-NO: UN2672
PROPER SHIPPING NAME: AMMONIA SOLUTION
HAZARD CLASS: 8
PACKING GROUP: III
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: 543
DESCRIPTION: UN2672, AMMONIA SOLUTION, 8, III, ENVIRONMENTALLY HAZARDOUS
IMO / IMDG:
UN-NO: UN2672
PROPER SHIPPING NAME: AMMONIA SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
DESCRIPTION:
UN2672, AMMONIA SOLUTION (AMMONIUM HYDROXIDE CONSISTING OF 27-31% AMMONIA
(CAS NO. 7664-41-7) IN 69-73% WATER (CAS NO. 7732-18-5)), 8, III, MARINE
POLLUTANT
RID:
UN-NO: UN2672
PROPER SHIPPING NAME: AMMONIA SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: 8
PACKING GROUP: III
SPECIAL PROVISIONS: 543
DESCRIPTION: UN2672, AMMONIA SOLUTION, 8, III, ENVIRONMENTALLY HAZARDOUS
ICAO:
UN-NO: UN2672
PROPER SHIPPING NAME: AMMONIA SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION: UN2672, AMMONIA SOLUTION, 8, III
SPECIAL PROVISIONS: A64
IATA:
UN-NO: UN2672
PROPER SHIPPING NAME: AMMONIA SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
ERG CODE: 8L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN2672, AMMONIA SOLUTION, 8, III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
AMMONIUM HYDROXIDE 1336-21-6 PRESENTACTIVE PRESENT PRESENT
[CONSISTS OF 27-31% KE-01688
AMMONIA (CAS NO.
7664-41-7) IN
69-73% WATER]
COMPONENTS JAPAN ENCS CHINA AUSTRALIA (AICS) EINECS-NO.
AMMONIUM HYDROXIDE PRESENT PRESENT PRESENT PRESENT
[CONSISTS OF 27-31% (1)-314 215-647-6
AMMONIA (CAS NO.
7664-41-7) IN
69-73% WATER]
U.S. REGULATIONS:
AMMONIUM HYDROXIDE [CONSISTS OF 27-31% AMMONIA (CAS NO. 7664-41-7) IN
69-73% WATER]:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0103
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
NEW JERSEY TCPA - EHS: 19000LBTQ
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
1000 LB RQ
100 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
1000LBFINAL RQ
454KGFINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1139
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
163.110, 163.111, 163.112, 177.1600, 184.1139, 73.85
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CAS-NO.
AMMONIUM HYDROXIDE 1336-21-6
[CONSISTS OF 27-31% AMMONIA (CAS NO. 7664-41-7)
IN 69-73% WATER]
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
AMMONIUM HYDROXIDE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
[CONSISTS OF 27-31%
AMMONIA (CAS NO.
7664-41-7) IN
69-73% WATER]
CERCLA/SARA:
COMPONENTS CAS-NO. CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
AMMONIUM 1336-21-6 1000 LB FINAL RQ NONE NONE
HYDROXIDE 454 KG FINAL RQ
[CONSISTS OF
27-31% AMMONIA
(CAS NO.
7664-41-7) IN
69-73% WATER]
COMPONENTS SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
AMMONIUM HYDROXIDE NONE NONE
[CONSISTS OF 27-31%
AMMONIA (CAS NO.
7664-41-7) IN
69-73% WATER]
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION TSCA 8(D) - HEALTH
5(A)2 - CHEMICALS AND SAFETY REPORTING
WITH SIGNIFICANT
NEW USE RULES
(SNURS)
AMMONIUM HYDROXIDE 1336-21-6 NOT APPLICABLE NOT APPLICABLE
[CONSISTS OF 27-31%
AMMONIA
(CAS NO. 7664-41-7)
IN 69-73% WATER]
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
AMMONIUM HYDROXIDE HEALTH HAZARD NOT OTHERWISE CLASSIFIED - CATEGORY 1:
[CONSISTS OF 27-31% CAUSES SEVERE DAMAGE TO THE RESPIRATORY TRACT
AMMONIA (CAS NO.
7664-41-7) IN SKIN CORROSION/IRRITATION - CATEGORY 1:
69-73% WATER] H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
(100)
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE.
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST -
AMMONIUM HYDROXIDE 1%
[CONSISTS OF 27-31% AMMONIA
(CAS NO. 7664-41-7) IN 69-73% WATER]
INVENTORY:
COMPONENTS CAS-NO. CANADA (DSL) CANADA (NDSL)
AMMONIUM HYDROXIDE 1336-21-6 PRESENT NOT LISTED
[CONSISTS OF 27-31% AMMONIA
(CAS NO. 7664-41-7) IN
69-73% WATER]
COMPONENTS CAS-NO. CEPA SCHEDULE I - TOXIC SUBSTANCES
AMMONIUM HYDROXIDE 1336-21-6 NOT LISTED
[CONSISTS OF 27-31%
AMMONIA (CAS NO.
7664-41-7) IN
69-73% WATER]
COMPONENTS CAS-NO. CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
AMMONIUM HYDROXIDE 1336-21-6 NOT LISTED
[CONSISTS OF 27-31% AMMONIA
(CAS NO. 7664-41-7) IN
69-73% WATER]
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENTS CAS-NO. EU GHS - SV - CLP (1272/2008)
AMMONIUM HYDROXIDE 1336-21-6 SKIN CORROSION/IRRITATION - SKIN
[CONSISTS OF 27-31% AMMONIA CORR. IN 1B:
(CAS NO. 7664-41-7) H314:
69-73% WATER] CAUSES SEVERE SKIN BURNS AND
EYE DAMAGE.
HAZARDOUS TO AQUATIC
ENVIRONMENT - ACUTE
HAZARD - AQUATIC ACUTE 1:
H400:
VERY TOXIC TO AQUATIC
LIFE.007-001-01-2
SPECIFIC TARGET ORGAN
TOXICITY - SINGLE
EXPOSURE - STOT SE 3:
H335:
MAY CAUSE RESPIRATORY
IRRITATION. (C >=5%)007-001-01-2
EU - CLP (1272/2008):
R-PHRASE(S):
R34: CAUSES BURNS.
R50: VERY TOXIC TO AQUATIC ORGANISMS.
S - PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
S61:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY
DATA SHEETS.
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
S36/37/39:
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION.
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
AMMONIUM 1336-21-6 C; R34 5%<=C<10% XI; S:
HYDROXIDE N; R50 R36/37/38 (1/2)-26-36/
[CONSISTS OF 10%<=C C; R34 37/39-45-61
27-31% AMMONIA
(CAS NO.
7664-41-7) IN
69-73% WATER]
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
C: CORROSIVE.
N: DANGEROUS FOR THE ENVIRONMENT.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 11/03/2014
REVISION DATE: 9/20/2018
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO
NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES
NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR
RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING
LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.