| Common Name: | SODIUM HYDROXIDE, 50 PERCENT (W/W) SOLUTION, TECHNICAL |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 7/21/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 39E315 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001:2008
REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 7/21/2015
REVISION DATE: 7/21/2015
REVISION NUMBER: G1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: S-622
PRODUCT NAME: SODIUM HYDROXIDE, 50 PERCENT (W/W) SOLUTION, TECHNICAL
OTHER MEANS OF IDENTIFICATION
SYNONYMS: NO INFORMATION AVAILABLE
CAS #: MIXTURE
RTECS #: NOT AVAILABLE
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY B
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
CORROSIVE TO METALS: CATEGORY 1
LABEL ELEMENTS:
DANGER
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
MAY BE CORROSIVE TO METALS
CORROSION
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: MAY BE HARMFUL IN CONTACT WITH SKIN
PRECAUTIONARY STATEMENTS - PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
KEEP ONLY IN ORIGINAL CONTAINER
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
SPECIFIC TREATMENT (SEE .? ON THIS LABEL)
ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN CORROSIVE RESISTANT/ .? CONTAINER WITH A RESISTANT INNER LINER
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO. WEIGHT-% TRADE SECRET
SODIUM HYDROXIDE 1310-73-2 50 *
WATER 7732-18-5 50 *
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
POISON INFORMATION CENTERS IN EACH STATE CAPITAL CITY CAN PROVIDE
ADDITIONAL ASSISTANCE FOR SCHEDULED POISONS (13 1126). ENSURE THAT
MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND TAKE
PRECAUTIONS TO PROTECT THEMSELVES. FIRST AIDER NEEDS TO PROTECT
HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED CLOTHES
AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
EYE CONTACT:
FLUSH EYE WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS
OR CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED
OR INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A
POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IF VICTIM IS CONSCIOUS, GIVE WATER OR
MILK. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR
POISON CONTROL CENTER IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SEVERE SKIN AND EYE IRRITATION OR BURNS. CAUSES DIGESTIVE
(GASTROINTESTINAL) TRACT IRRITATION. MAY CAUSE GASTROINTESTINAL
(DIGESTIVE) TRACT BURNS. MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING,
DIARRHEA.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH THE
FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL
UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. USE PERSONAL
PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. SHOULD NOT BE
RELEASED INTO THE ENVIRONMENT. DO NOT LET PRODUCT ENTER DRAINS. DO
NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. PREVENT ENTRY
INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
NEUTRALIZE WITH A DILUTE SOLUTION OF ACETIC ACID. DILUTE WITH WATER.
ABSORB SPILL WITH INERT MATERIAL (E.G. VERMICULITE, DRY SAND OR EARTH),
THEN PLACE IN A SUITABLE CHEMICAL WASTE CONTAINER. CLEAN CONTAMINATED
SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPOURS/DUST. HANDLE IN ACCORDANCE
WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE
AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE IN A SEGRATED AND
APPROVED AREA. STORE AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. REDUCING AGENTS. ACIDS. BASES. ALDEHYDES. METALS.
POWDERED METALS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS
UNITED STATES:
CHEMICAL NAME OSHA NIOSH ACGIH AIHA WHEEL
SODIUM HYDROXIDE 2 MG/M3 TWA 2 MG/M3 CEILING 2 MG/M3 CEILING NONE
1310-73-2
WATER NONE NONE NONE NONE
7732-18-5
CANADA:
COMPONENTS ALBERTA BRITISH COLUMBIA ONTARIO QUEBEC
SODIUM HYDROXIDE 2 MG/M3 2 MG/M3 CEILING 2 MG/M3 2 MG/M3
1310-73 CEILING CEILING CEILING
WATER NONE NONE NONE NONE
7732-18-5
AUSTRALIA AND MEXICO:
COMPONENTS AUSTRALIA MEXICO
SODIUM HYDROXIDE NONE 2 MG/M3 CEILING
1310-73-2
WATER NONE NONE
7732-18-5
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS
AND MIST BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: FACE-SHIELD
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT PROTECTIVE SUIT. GLOVES. BOOTS.
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR
OR EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT,
DRINK OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING
THE PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
APPEARANCE: NO INFORMATION AVAILABLE
COLOR: CLEAR. COLORLESS.
ODOR: ODORLESS.
TASTE: NO INFORMATION AVAILABLE
MOLECULAR/FORMULA WEIGHT: NO INFORMATION AVAILABLE
FORMULA: NO INFORMATION AVAILABLE
FLAMMABILITY: NO INFORMATION AVAILABLE
FLASH POINT (DEG. C): NO DATA AVAILABLE
FLASHPOINT (DEG. C/ DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
PH: NO INFORMATION AVAILABLE
MELTING POINT/RANGE(DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE(DEG. C/DEG. F): 142 DEG. C/287.6 DEG. F
DECOMPOSITION TEMPERATURE(DEG. C/DEG. F): NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 1.53 @ 15.6 DEG. C
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY: NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
FOR SODIUM HYDROXIDE:
SODIUM HYDROXIDE + ZINC METAL DUST CAUSES IGNITION OF THE LATTER.
UNDER PROPER CONDITIONS OF TEMPERATURE, PRESSURE AND STATE OF DIVISION,
IT CAN IGNITE OR REACT VIOLENTLY WITH ACETALDEHYDE, ALLY ALCOHOL, ALLYL
CHLORIDE, BENZENE-1,4-DIOL, CHLORINE TRIFLUORIDE, 1,2 DICHLORETHYLENE,
NITROETHANE, NITROMETHANE, NITROPARAFFINS, NITROPROPANE, CINNAMALDEHYDE,
2,2-DICHLORO-3,3-DIMETHYLBUTANE.
PHOSPHOROUS BOILED WITH NAOH YIELDS MIXED PHOSPHINES WHICH MAY IGNITE
SPONTANEOUSLY IN AIR.
SODIUM HYDROXIDE AND CINNAMALDEHYDE + HEAT MAY CAUSE IGNITION.
REACTION WITH CERTAIN METALS RELEASES FLAMMABLE AND EXPLOSIVE HYDROGEN
GAS.
GENERATES CONSIDERABLE HEAT WHEN A SODIUM HYDROXIDE SOLUTION IS MIXED WITH
AN ACID
SODIUM HYDROXIDE SOLUTION AND OCTANOL + DIBORANE DURING A WORK-UP OF A
REACTION MIXTURE OF OXIME AND DIBORANE IN TETRAHYROFURAN IS VERY
EXOTHERMIC, A MILD EXPLOSION BEING NOTED ON ONE OCCASSION.
REACTIVE WITH WATER, ACIDS (MINERAL, NON-OXIDIZING, E.G. HYDROCHLORIC,
HYDROFLUORIC ACID, MURIATIC ACID, PHOSPHORIC), ACIDS (MINERAL, OXIDIZING
E.G. CHROMIC ACID, HYPOCHLOROUS ACID, NITRIC ACID, SULFURIC ACID), ACIDS
(ORGANIC E.G. ACETIC ACID, BENZOIC ACID, FORMIC ACID, METHANOIC ACID,
OXALIC ACID), ALDEHYDES (E.G. ACETALDEHYDE, ACROLEIN, CHLORAL HYDRATE,
FORMALDEHYDE), CARBAMATES (E.G. CARBANOLATE, CARBOFURAN), ESTERS (E.G.
BUTYL ACETATE, ETHYL ACETATE, PROPYL FORMATE), HALOGENATED ORGANICS
(DIBROMOETHANE, HEXACHLOROBENZENE, METHYL CHLORIDE, TRICHLOROETHYLENE),
ISOCYANATES (E.G. METHYL ISOCYANATE), KETONES (ACETONE, ACETOPHENONE, MEK,
MIBK), ACID CHLORIDES, STRONG BASES, STRONG OXIDIZING AGENTS, STRONG
REDUCING AGENTS, FLAMMABLE LIQUIDS, POWDERED METALS AND METALS
(I.E ALUMINUM, TIN, ZINC, HAFNIUM, RANEY NICKEL), METALS (ALKALI AND
ALKALINE E.G. CESIUM, POTASSIUM, SODIUM), METAL COMPOUNDS (TOXIC E.G.
BERYLIUM, LEAD ACETATE, NICKEL CARBONYL, TETRAETHYL LEAD), NITRIDES
(E.G. POTASSIUM NITRIDE, SODIUM NITRIDE), NITRILES (E.G. ACETONITRILE,
METHYL CYANIDE), NITRO COMPOUNDS (ORGANIC E.G. NITROBENZENE,
NITROMETHANE), ACETIC ANHYDRIDE, HYDROQUINONE, CHLOROHYDRIN,
CHLOROSULFONIC ACID, ETHYLENE CYANOHYDRIN, GLYOXAL, HYDROSULFURIC ACID,
OLEUM, PROPIOLACTONE, ACYLONITRILE, PHOROSOUS PENTOXIDE, CHLOROETHANOL,
CHLOROFORM-METHANOL, TETRAHYDROBORATE, CYANOGEN AZIDE, 1,2,4,5
TETRACHLOROBENZENE, CINNAMALDEHYDE.
REACTS WITH FORMALDEHYDE HYDROXIDE TO YIELD FORMIC ACID, AND HYDROGEN.
SODIUM HYDROXIDE REACTS TO FORM EXPLOSIVE PRODUCTS WITH AMMONIA + SILVER
NITRATE.
BENZENE EXTRACT OF ALLYL BENZENESULFONATE PREPARED FROM ALLYL ALCOHOL,
AND BENZENE SULFONYL CHLORIDE IN PRESENCE OF AQUESOUS SODIUM
HYDROXIDE, UNDER VACUUM DISTILLATION, RESIDUE DARKENED AND EXPLODED.
SODIUM HYDROXDE + IMPURE TETRAHYDROFURAN, WHICH CAN CONTAIN PEROXIDES, CAN
CAUSE SERIOUS EXPLOSIONS.
SODIUM HYDROXIDE REACTS WITH SODIUM SALT OF TRICHLOROPHENOL + METHYL
ALCOHOL + TRICHLOROBENZENE + HEAT TO CAUSE AN EXPLOSION.
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. REDUCING AGENTS. ACIDS. BASES. ALDEHYDES. METALS.
POWDERED METALS.
HAZARDOUS DECOMPOSITION PRODUCTS: NO INFORMATION AVAILABLE
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY:
VERY CAUSTIC TO ALUMINUM AND OTHER METALS IN THE PRESENCE OF MOISTURE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. INHALATION. INGESTION.
ACUTE TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.:
ATEMIX (DERMAL): 2700MG/KG
COMPONENT INFORMATION:
SODIUM HYDROXIDE - 1310-73-2:
LD50/ORAL/RAT: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: 1350 MG/KG DERMAL LD50RABBIT
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFOMATION AVAILABLE
OTHER LD50 OR LC50INFORMATION:
500 MG/KG ORAL LDL(LOWEST LETHAL DOSE) RABBIT
WATER - 7732-18-5:
LD50/ORAL/RAT: >90 ML/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFOMATION AVAILABLE
OTHER LD50 OR LC50INFORMATION: NO INFORMATION AVAILABLE
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE- ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: 1350 MG/KG
LD50/DERMAL/RAT:
VALUE -ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
SEVERE SKIN IRRITATION. CAUSES SKIN BURNS. MAY CAUSE DEEP PENETRATING
ULCERS OF THE SKIN. HARMFUL IN CONTACT WITH SKIN.
EYE CONTACT:
SEVERE EYE IRRITATION. CAUSES EYE BURNS. MAY CAUSE CORNEAL DAMAGE.
INHALATION:
CAUSES SEVERE IRRITATION OF THE RESPIRATORY TRACT AND MUCOUS MEMBRANES
WITH COUGHING, BURNS, BREATHING DIFFICULTY, AND POSSIBLE COMA. IRRITATION
MAY LEAD TO CHEMICAL PNEUMONITIS, PNEUMOCONIOSIS, FIBROSIS, AND PULMONARY
EDEMA. CAN CAUSE CHEMICAL BURNS TO THE RESPIRATORY TRACT AND MUCOUS
MEMBRANES IT IS A RESPIRATORY STIMULANT WHEN INHALED AT LOWER
CONCENTRATIONS. IT MAY ALSO AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM
(CONVULSIONS, SEIZURES, ATAXIA, TREMOR), CARDIOVASCULAR SYSTEM (INCREASE
IN BLOOD PRESSURE AND PULSE RATE).
INGESTION:
CAUSES SEVERE GASTROINTESTINAL TRACT IRRITATION AND BURNS. CAUSES
SEVERE PAIN, NAUSEA, VOMITING, DIARRHEA, AND SHOCK. MAY CAUSE SEVERE
AND PERMANENT DAMAGE TO THE DIGESTIVE TRACT. MAY CAUSE PERFORATION OF
THE DIGESTIVE TRACT. MAY CAUSE CORROSION AND PERMANENT DESTRUCTION OF
THE ESOPHAGUS.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY: NO INFORMATION AVAILABLE
SENSITIZATION: NO INFORMATION AVAILABLE
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC
COMPONENTS IARC ACGIH - CARCINOGENS NTP
SODIUM HYDROXIDE NOT LISTED NOT LISTED NOT LISTED
WATER NOT LISTED NOT LISTED NOT LISTED
COMPONENTS OSHA HCS - AUSTRALIA - PROHIBITED AUSTRALIA -
CARCINOGENS CARCINOGENIC SUBSTANCES NOTIFIABLE
CARCINOGENIC
SUBSTANCES
SODIUM HYDROXIDE NOT LISTED NOT LISTED NOT LISTED
WATER NOT LISTED NOT LISTED NOT LISTED
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE
TARGET ORGANS: SKIN. EYES. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
SODIUM HYDROXIDE - 1310-73-2:
FRESHWATER FISH SPECIES DATA:
45.4 MG/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE
MOBILITY: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS RCRA - F RCRA - K RCRA - P RCRA - U
SERIES WASTES SERIES WASTES SERIES WASTES SERIES WASTES
SODIUM NONE NONE NONE NONE
HYDROXIDE
WATER NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
ERG NO: 154
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
PACKING GROUP: II
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
CEFIC TREMCARD NO: NO INFORMATION AVAILABLE
IMO / IMDG:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IMDG PAGE: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
MFAG: NO INFORMATION AVAILABLE
MAXIMUM QUANTITY: NO INFORMATION AVAILABLE
RID:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: 8
PACKING GROUP: II
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ICAO:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IATA:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
ERG CODE: 8L
DESCRIPTION: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS U.S. TSCA KOREA KECL PHILIPPINES PICCS
SODIUM HYDROXIDE PRESENT PRESENT KE-31487 PRESENT
WATER PRESENT PRESENT KE-35400 PRESENT
COMPONENTS JAPAN ENCS CHINA AUSTRALIA (AICS) EINECS-NO.
SODIUM HYDROXIDE PRESENT (2)- PRESENT PRESENT PRESENT
1972 (1)-410 215-185-5
WATER NOT PRESENT PRESENT PRESENT PRESENT
231-791-2
U.S. REGULATIONS:
SODIUM HYDROXIDE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 1706
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
SODIUM HYDROXIDE:
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
1000 LB RQ
100 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
1000LBFINAL RQ
454KGFINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1763
FDA - DIRECT FOOD ADDITIVES: 21 CFR 173.310
FDA - 21 CFR - TOTAL FOOD ADDITIVES:
155.191 155.194 163.110 163.111 163.112 172.560 172.814 172.892 173.310
176.170 176.180 176.210 177.1600 177.2800 184.1763 73.85
CALIFORNIA PROP. 65:
SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE REPRODUCTIVE FEMALE
TOXICITY TOXICITY REPRODUCTIVE
TOXICITY
SODIUM NOT LISTED NOT LISTED NOT LISTED NOT LISTED
HYDROXIDE
WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CERCLA - HAZARDOUS SECTION 302 EXTREMELY SECTION 302
SUBSTANCES AND THEIR HAZARDOUS SUBSTANCES EXTREMELY
REPORTABLE QUANTITIES AND TPQS HAZARDOUS
SUBSTANCES
AND RQS
SODIUM 1000 LB FINAL RQ NONE NONE
HYDROXIDE 454 KG FINAL RQ
WATER NONE NONE NONE
COMPONENTS SECTION 313 - CHEMICAL CATEGORY SECTION 313 - REPORTING
DE MINIMIS
SODIUM HYDROXIDE NONE NONE
WATER NONE NONE
U.S. TSCA:
COMPONENTS TSCA SECTION 5(A)2 - TSCA 8(D) -HEALTH AND
CHEMICALS WITH SIGNIFICANT SAFETY REPORTING
NEW USE RULES (SNURS)
SODIUM HYDROXIDE NOT APPLICABLE NOT APPLICABLE
WATER NOT APPLICABLE NOT APPLICABLE
CANADA:
WHMIS HAZARD CLASS: E CORROSIVE MATERIAL
SODIUM HYDROXIDE:
E INCLUDING 0.04% IN AQUEOUS SOLUTION, 0.08%, 0.4% IN AQUEOUS SOLUTION,
2%, 2.5%, 4% IN AQUEOUS SOLUTION, 5%, 10%, 16%, 20%, 40%, 50% IN AQUEOUS
SOLUTION, 8.7N
WATER: UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST
SODIUM HYDROXIDE 1 %
INVENTORY:
COMPONENTS CANADA (DSL) CANADA (NDSL)
SODIUM HYDROXIDE PRESENT NOT LISTED
WATER PRESENT NOT LISTED
COMPONENTS CEPA SCHEDULE I - CEPA- 2010 GREENHOUSE GASES
TOXIC SUBSTANCES SUBJECT TO MANDITORY REPORTING
SODIUM HYDROXIDE NOT LISTED NOT LISTED
WATER NOT LISTED NOT LISTED
EU CLASSIFICATION:
R-PHRASE(S): R35 - CAUSES SEVERE BURNS.
S -PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
S37/39: WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION.
COMPONENTS CLASSIFICATION CONCENTRATION LIMITS SAFETY PHRASES
SODIUM HYDROXIDE C; R35 5%<=C: C; R: 35 S1/2 S26
2%<=C<5%: C; R: 34 S37/39 S45
0.5%<=C<2%: XI; R: 36/38
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
C - CORROSIVE.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 7/21/2015
REVISION DATE: 7/21/2015
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED.
IF THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR
BECOMES CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS.
THE PHYSICAL PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE
LITERATURE AND DO NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION
CONTAINED HEREIN DOES NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY, MERCHANTABILITY OR FITNESS OF THE GOODS FOR
A PARTICULAR PURPOSE. SPECTRUM CHEMICALS & LABORATORY PRODUCTS, INC.
ASSUMES NO RESPONSIBILITY FOR RESULTS OBTAINED OR FOR INCIDENTAL OR
CONSEQUENTIAL DAMAGES, INCLUDING LOST PROFITS, ARISING FROM THE USE
OF THESE DATA. NO WARRANTY AGAINST INFRINGEMENT OF ANY PATENT, COPYRIGHT
OR TRADEMARK IS MADE OR IMPLIED. IT SHALL BE THE USER'S RESPONSIBILITY
TO DEVELOP PROPER METHODS OF HANDLING AND PERSONAL PROTECTION BASED ON
THE ACTUAL CONDITIONS OF USE. WHILE THIS SDS IS BASED ON TECHNICAL DATA
JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO RESPONSIBILITY FOR THE
COMPLETENESS OR ACCURACY OF THE INFORMATION CONTAINED HEREIN.