| Common Name: | BENZOIC ACID, CRYSTAL, REAGENT, ACS |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 5/15/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39G171 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 4/8/2013
REVISION DATE: 5/15/2018
REVISION NUMBER: G4
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: B1085
PRODUCT NAME: BENZOIC ACID, CRYSTAL, REAGENT, ACS
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
ACIDE BENZOIQUE (FRENCH)
ACIDO BENZOICO (SPANISH)
BENZENEFORMIC ACID
BENZENEMETHANOIC ACID
BENZOATE
BENZENECARBOXYLIC ACID
CARBOXYBENZENE
PHENYLCARBOXYLIC ACID
DRACYLIC ACID
PHENYLFORMIC ACID
CAS #: 65-85-0
RTECS #: DG0875000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: PRESERVATIVE. CHEMICAL INTERMEDIATE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: TOM TYNER (USA - WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (USA - EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
LABEL ELEMENTS:
WARNING:
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE RESPIRATORY IRRITATION
EXCLAMATION MARK
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
WEAR PROTECTIVE GLOVES
WEAR EYE/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED: CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL
RINSE MOUTH
PRECAUTIONARY STATEMENTS - STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT IN
ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS
AS APPLICABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO WEIGHT-%
BENZOIC ACID 65-85-0 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT: FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
IRRITATING TO EYES AND SKIN
IT MAY CAUSE DERMATITIS
IRRITATING TO RESPIRATORY SYSTEM
RESPIRATORY DEPRESSION
NAUSEA
VOMITING
MAY CAUSE DIARRHEA
CENTRAL NERVOUS SYSTEM EFFECTS
HEADACHE
TREMORS
DROWSINESS
FATIGUE
WEAKNESS
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL. CARBON DIOXIDE (CO2). WATER SPRAY MIST OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE.
SPECIFIC HAZARDS: MAY BE COMBUSTIBLE AT HIGH TEMPERATURES.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. USE PERSONAL
PROTECTIVE EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL
UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID DUST FORMATION.
REMOVE ALL SOURCES OF IGNITION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS. PREVENT FROM ENTERING INTO SOIL, DITCHES, SEWERS, WATERWAYS,
AND/OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. CLEAN
CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. AVOID DUST
FORMATION. KEEP AWAY FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. AVOID DUST FORMATION. DO NOT INGEST. DO NOT BREATHE DUST. KEEP
AWAY FROM HEAT AND SOURCES OF IGNITION. HANDLE IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE AWAY FROM INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
BASES
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENT CAS NO OSHA NIOSH ACGIH AIHA WEEL
BENZOIC ACID 65-85-0 NONE NONE NONE NONE
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
BENZOIC ACID 65-85-0 NONE NONE NONE NONE
AUSTRALIA AND MEXICO:
COMPONENT CAS NO AUSTRALIA MEXICO
BENZOIC ACID 65-85-0 NONE NONE
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. IF USER OPERATIONS GENERATE DUST, FUME OR
MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE
EXPOSURE LIMIT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES
SKIN AND BODY PROTECTION:
LONG SLEEVED CLOTHING
CHEMICAL RESISTANT APRON
GLOVES
RESPIRATORY PROTECTION:
EFFECTIVE DUST MASK. USE A DUST RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE
TO THE SUBSTANCE IS APPARENT (E.G. GENERATION OF HIGH CONCENTRATION OF
DUST (DUST CLOUDS), INADEQUATE VENTILATION, DEVELOPMENT OF RESPIRATORY
TRACT IRRITATION), AND ENGINEERING CONTROLS ARE NOT FEASIBLE. BE SURE TO
USE AN APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT WHEN USING, DO NOT EAT, DRINK OR
SMOKE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE. CRYSTALS. FLAKES.
COLOR: WHITE.
ODOR: NONE.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: C7-H6-O2
MOLECULAR/FORMULA WEIGHT (G/MOLE): 122.12
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE
FLASH POINT TESTED ACCORDING TO: NOT APPLICABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): 570 DEG. C/1058 DEG. F
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): 121-123 DEG. C/249.8-253.4 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F): 249-250 DEG. C/480.2-482 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3):
1.2659 @ 15 DEG. C
1.321 @ 20 DEG. C
SPECIFIC GRAVITY: NO INFORMATION AVAILABLE
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): 1.81-1.93
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
SOLUBILITY IN WATER: 0.9 PARTS IN WATER
SOLUBILITY IN ACETONE: 55.6 G/L
SOLUBILITY IN BENZENE: 12.2 G/L
SOLUBILITY IN CARBON TETRACHLORIDE: 4.1 G/L
SOLUBILITY IN CHLOROFORM: 2.5%
SOLUBILITY IN ETHANOL: 1 G/3 ML
SOLUBILITY IN ETHER: 40.8 G/L
SOLUBILITY IN HEXANE: 0.9 G/L
SOLUBILITY IN METHANOL: 71.5 G/L
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO INFORMATION AVAILABLE
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: HEAT. AVOID DUST FORMATION. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
BASES
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. INHALATION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
BENZOIC ACID:
CAS NO: 65-85-0
LD50/ORAL/RAT: 1700 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: 1940 MG/KG
LD50/DERMAL/RABBIT: >10000 MG/KG
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
>26 MG/M3 INHALATION LC50 1 H
>12.2 MG/L INHALATION LC50 4 H
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOXICITY: 1700 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX: 1940 MG/KG
LD50/DERMAL/RABBIT:
VALUE - ACUTE TOXICITY: >10000 MG/KG
LD50/DERMAL/RAT:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: >12.2 MG/L (RAT, 4 HR)
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT: CAUSES SKIN IRRITATION. MODERATELY IRRITATING TO THE SKIN.
EYE CONTACT: CAUSES EYE IRRITATION. MODERATELY IRRITATING TO THE EYES.
INHALATION: IRRITATING TO RESPIRATORY SYSTEM.
INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE DIGESTIVE (GASTOINTESTINAL) TRACT
IRRITATION. MAY CAUSE NAUSEA. MAY CAUSE VOMITING. MAY CAUSE DIARRHEA. MAY
CAUSE HEADACHE. MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (SOMNOLENCE).
MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (TREMORS, MUSCLE TWITICHING).
MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (FATIGUE, WEAKNESS). MAY AFFECT
RESPIRATION (RESPIRATORY DEPRESSION).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS, AND DRYNESS AND
CRACKING OF THE SKIN.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
MUTATIONS IN MICROORGANISMS
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
EXPERIMENTS WITH HUMAN LYMPHOCYTES HAVE SHOWN MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENTS CAS-NO. IARC ACGIH - NTP
CARCINOGENS
BENZOIC ACID 65-85-0 NOT LISTED NOT LISTED NOT LISTED
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
BENZOIC ACID NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
BENZOIC ACID - 65-85-0:
ALGAE/AQUATIC PLANTS: 5 MG/L EC50 ANABAENA INAEQUALIS 3 H
FISH: 180 MG/L LC50 GAMBUSIA AFFINIS 96 H
CRUSTACEA:
860 MG/L EC50 DAPHNIA MAGNA 48 H
300 MG/L EC50 DAPHNIA MAGNA 24 H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS CAS-NO. RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
BENZOIC ACID 65-85-0 NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
EMERGENCY RESPONSE GUIDE NUMBER: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
SYMBOL(S): NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN NUMBER: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
TRANSPORT HAZARD CLASS(ES): NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
IMDG:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
RID:
UN NUMBER: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
TRANSPORT HAZARD CLASS(ES): NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
ICAO (AIR):
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
IATA:
UN NUMBER: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
TRANSPORT HAZARD CLASS(ES): NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
PRECAUTIONARY STATEMENTS - RESPONSE: NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES (PICCS)
BENZOIC ACID 65-85-0 PRESENT(ACTIVE) PRESENT PRESENT
KE-02696
COMPONENTS JAPAN ENCS CHINA IECSC AUSTRALIA (AICS) EINECS-NO.
BENZOIC ACID PRESENT PRESENT PRESENT PRESENT
(3)-1397 200-618-2
U.S. REGULATIONS:
BENZOIC ACID:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: SN 0209
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
5000 LB RQ
100 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
5000LBFINAL RQ
2270KGFINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1021
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
150.141, 150.161, 166.110, 175.300, 177.1390, 184.1021
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENT CAS
BENZOIC ACID 65-85-0
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
BENZOIC ACID NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CAS-NO. CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
BENZOIC ACID 65-85-0 5000 LB FINAL RQ NONE NONE
2270 KG FINAL RQ
COMPONENTS SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
BENZOIC ACID NONE NONE
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION TSCA 8(D) - HEALTH
5(A)2 - CHEMICALS AND SAFETY REPORTING
WITH SIGNIFICANT NEW
USE RULES (SNURS)
BENZOIC ACID 65-85-0 NOT APPLICABLE NOT APPLICABLE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
BENZOIC ACID SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2:
65-85-0 (100) H319: CAUSES SERIOUS EYE IRRITATION.
COMBUSTIBLE DUST - CATEGORY 1:
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR (FACTORS
SUCH AS COMBUSTIBILITY AND EXPLOSIVENESS OF DUSTS
INCLUDING COMPOSITION AND SHAPE AND SIZE OF PARTICLES
COULD CAUSE SUBSTANCE TO BELONG TO 'COMBUSTIBLE DUST'
HAZARD CLASS)
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
DSL/NDSL:
COMPONENT CAS NO CANADA (DSL) CANADA (NDSL)
BENZOIC ACID 65-85-0 PRESENT NOT LISTED
COMPONENT CAS NO CEPA SCHEDULE I - TOXIC SUBSTANCES
BENZOIC ACID 65-85-0 NOT LISTED
COMPONENT CAS NO CEPA - 2010 GREENHOUSE GASES SUBJECT
TO MANDATORY REPORTING
BENZOIC ACID 65-85-0 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENT CAS NO EU GHS - SV - CLP (1272/2008)
BENZOIC ACID 65-85-0 SKIN CORROSION/IRRITATION - SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION - EYE DAM. 1:
H318: CAUSES SERIOUS EYE DAMAGE.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - STOT RE 1:
H372:
CAUSES DAMAGE TO LUNGS THROUGH PROLONGED OR
REPEATED EXPOSURE.607-705-00-8
EU - CLP (1272/2008):
R-PHRASE(S):
R38: IRRITATING TO SKIN
R41: RISK OF SERIOUS DAMAGE TO EYES
R48/23:
TOXIC:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH INHALATION
S-PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE
S39: WEAR EYE/FACE PROTECTION
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE)
S63:
IN CASE OF ACCIDENT BY INHALATION:
REMOVE CASUALTY TO FRESH AIR AND KEEP AT REST
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
BENZOIC ACID 65-85-0 T; R48/23 NO INFORMATION S:
XI; R38-41 (1/2)26 39 45 63
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XI: IRRITANT
T: TOXIC
| 16. OTHER INFORMATION | |
PREPARATION DATE: 4/8/2013
REVISION DATE: 5/15/2018
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO
NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES
NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
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CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR
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SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
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CONTAINED HEREIN.