| Common Name: | CUPRIC SULFATE, ANHYDROUS, POWDER, REAGENT |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 1/31/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39G282 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 4/13/2017
REVISION DATE: 1/31/2019
REVISION NUMBER: G2
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: C1418
PRODUCT NAME: CUPRIC SULFATE, ANHYDROUS, POWDER, REAGENT
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NO INFORMATION AVAILABLE
CAS #: 7758-98-7
RTECS # GL8800000
CI #: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
WOOD PRESERVATION. ANTIFUNGAL. MOLLUSCIDE. AGENT FOR LEATHER TANNING AND
HIDE PRESERVATION. CHEMICAL INTERMEDIATE. FROTH FLOATATION AGENT.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: TOM TYNER (USA - WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (USA - EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 3
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
TOXIC IF SWALLOWED
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
SKULLS AND CROSSBONES
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS:
VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
VERY TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
WEAR PROTECTIVE GLOVES
WEAR EYE/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
RINSE MOUTH
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO WEIGHT-%
CUPRIC SULFATE, ANHYDROUS 7758-98-7 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. FIRST
AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT: FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. WARNING! IT MAY BE HAZARDOUS TO THE
PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION WHEN THE INHALED
OR INGESTED MATERIAL IS TOXIC, INFECTIOUS OR CORROSIVE. DO NOT USE
MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED OR INHALED THE SUBSTANCE;
INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A
ONE-WAY VALVE OR OTHER PROPER RESPIRATORY MEDICAL DEVICE. GET MEDICAL
ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. TOXIC IF
SWALLOWED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES EYE IRRITATION
CAUSES SKIN IRRITATION
MAY CAUSE A GREENISH DISCOLORATION OF THE SKIN
MAY CAUSE DISCOLORATION OF THE CORNEA
MAY CAUSE ULCERATION OF THE CORNEA
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND
DIARRHEA
ORAL MUCOSA, VOMITUS, STOOLS, AND SALILVA MAY BE STAINED BLUE OR GREEN
FOLLOWING INGESTION
MAY CAUSE METALLIC TASTE
ABDOMINAL PAIN
MAY CAUSE METABOLIC ACIDOSIS
MAY CAUSE METHEMOGLOBINEMIA
MAY AFFECT THE LIVER
JAUNDICE
IT MAY AFFECT THE KIDNEYS
MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS
MAY AFFECT THE CARDIOVASCULAR SYSTEM
HYPOTENSION
PERFORATION OF THE NASAL SEPTUM IF INHALED IN EXCESSIVE QUANTITIES
IRRITATING TO RESPIRATORY SYSTEM
COUGHING AND WHEEZING
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH THE
FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS:
IF IT IS INVOLVED IN A FIRE THE FOLLOWING CAN BE RELEASED:
COPPER OXIDES. SULFUR OXIDES.
SPECIFIC HAZARDS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. USE PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT PRODUCT FROM
ENTERING DRAINS. PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR
CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. CLEAN
CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS/DUST. HANDLE IN ACCORDANCE
WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE AWAY FROM INCOMPATIBLE
MATERIALS. STORE IN A SEGREGATED AND APPROVED AREA.
INCOMPATIBLE MATERIALS:
HYDROXYLAMINE
STRONG REDUCING AGENTS
POWDERED METALS
ACETYLENE
MAGNESIUM
OXIDIZING AGENTS
AMINES
STRONG BASES
ISOCYANATES
NITROMETHANE
SODIUM HYPOBROMITE
AMMONIA
HYDRAZINE
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENT CAS NO OSHA NIOSH ACGIH AIHA WEEL
CUPRIC SULFATE, 7758-98-7 NONE 1 MG/M3 TWA 1 MG/M3 TWA NONE
ANHYDROUS (AS Cu) (AS Cu)
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
CUPRIC SULFATE, 7758-98-7 NONE NONE NONE NONE
ANHYDROUS
AUSTRALIA AND MEXICO:
COMPONENT CAS NO AUSTRALIA MEXICO
CUPRIC SULFATE, ANHYDROUS 7758-98-7 NONE NONE
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. IF USER OPERATIONS GENERATE DUST, FUME OR
MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE
EXPOSURE LIMIT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
LONG SLEEVED CLOTHING
GLOVES
RESPIRATORY PROTECTION:
EFFECTIVE DUST MASK. USE A DUST RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE
TO THE SUBSTANCE IS APPARENT (E.G. GENERATION OF HIGH CONCENTRATION OF DUST
(DUST CLOUDS), INADEQUATE VENTILATION, DEVELOPMENT OF RESPIRATORY TRACT
IRRITATION), AND ENGINEERING CONTROLS ARE NOT FEASIBLE. BE SURE TO USE AN
APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT WHEN USING, DO NOT EAT, DRINK OR
SMOKE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
APPEARANCE: POWDER.
COLOR: GRAY. GRAYISH WHITE.
ODOR: ODORLESS.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: CuSO4
MOLECULAR/FORMULA WEIGHT (G/MOLE): 159.60
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLASHPOINT (DEG. C / DEG. F): NO INFORMATION AVAILABLE
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C / DEG. F): 590 DEG. C/1094 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C / DEG. F): 650 DEG. C/1202 DEG. F
BOILING POINT/RANGE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 3.6
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
EASILY SOLUBLE IN HOT WATER
SOLUBLE IN COLD WATER
SOLUBLE IN METHANOL
INSOLUBLE IN ETHANOL
IT READILY FORMS ALKALINE COMPLEXES AT SUFFICIENTLY HIGH CONCENTRATIONS OF
AMINES OR ALKALI CYANIDES
SOLUBILITY IN WATER:
243 G/L @ 0 DEG. C;
75.4 G/100 ML @ 100 DEG. C.
SOLUBILITY IN METHANOL: 1.04 G/100 ML @ 18 DEG. C
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
ANHYDROUS COPPER SULFATE CAUSES HYDROXYLAMINE TO IGNITE AND THE HYDRATED
SALT IS VIGOROUSLY REDUCED COPPER SALTS AND NITROMETHANE SPONTANEOUSLY FORM
EXPLOSIVE MATERIALS COPPER SALTS PROMOTE THE DECOMPOSITION OF HYDRAZINE
DANGEROUS ACETYLIDES MAY BE FORMED FROM MANY COPPER SALTS. THE COPPER
ACETYLIDES FORMED IN AMMONICAL OR CAUSTIC SOLUTIONS WITH Cu(II) SALTS AND
ACETYLENE ARE MORE EXPLOSIVE THAN THOSE DERIVED FROM CUPROUS Cu(I) SALTS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
HYDROXYLAMINE
STRONG REDUCING AGENTS
POWDERED METALS
ACETYLENE
MAGNESIUM
OXIDIZING AGENTS
AMINES
STRONG BASES
ISOCYANATES
NITROMETHANE
SODIUM HYPOBROMITE
AMMONIA
HYDRAZINE
HAZARDOUS DECOMPOSITION PRODUCTS:
WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES. SULFUR OXIDES.
OTHER INFORMATION:
CORROSIVITY:
EXTREMELY CORROSIVE IN PRESENCE OF ALUMINUM
HIGHLY CORROSIVE IN PRESCENCE OF STEEL
SLIGHTLY CORROSIVE IN PRESENCE OF STAINLESS STEEL (304)
SLIGHTLY CORROSIVE IN PRESENCE OF STAINLESS STEEL (316)
SEVERE CORROSIVE EFFECT ON BRASS
SEVERE CORROSIVE EFFECT ON BRONZE
SPECIAL REMARKS ON CORROSIVITY:
CAN BE CORROSIVE TO FERROUS BASED METALS.
VERY CORROSIVE TO PLAIN STEEL
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. INHALATION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
CUPRIC SULFATE, ANHYDROUS:
CAS NO: 7758-98-7
LD50/ORAL/RAT: 300 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: 369 MG/KG
LD50/DERMAL/RABBIT: 1000 MG/KG DERMAL LD50 RABBIT
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: 857 MG/KG ORAL LDL MAN
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX: 300 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: 369 MG/KG
LD50/DERMAL/RABBIT:
VALUE - ACUTE TOX: 1000 MG/KG
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
CAUSES SKIN IRRITATION. MAY CAUSE SKIN BURNS, ITCHING ALLERGIC DERMATITIS,
ECZEMA, AND GREENISH DISCOLORATION OF THE SKIN AND HAIR.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. MAY CAUSE BURNS. MAY CAUSE CONJUNCTIVITIS.
MAY CAUSE CORNEAL OPACITY. MAY CAUSE CORNEAL DISCOLORATION, ULCERATION.
INHALATION:
CAUSES RESPIRATORY TRACT (NOSE, THROAT, LUNG) IRRITATION WITH COUGHING AND
WHEEZING. MAY CAUSE ULCERATION AND PERFORATION OF THE NASAL SEPTUM IF
INHALED IN EXCESSIVE QUANTITIES. BURNING COPPER SULFATE MAY RESULT IN
IRRITATING AND POISONOUS GASES WHICH MAY IRRITATE THE RESPIRATORY TRACT AND
LUNGS, AND MAY CAUSE METAL FUME FEVER WHICH IS CHARACTERIZED BY FLU-LIKE
SYMPTOMS SUCH AS FEVER, CHILLS, MUSCLE ACHES.
INGESTION:
TOXIC IF SWALLOWED. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION WITH
NAUSEA, VOMITING, HYPERMOTILITY, DIARRHEA, METALLIC TASTE, BURNING
SENSATION IN THE STOMACH OR EPIGASTRUM, ABDOMINAL PAIN, AND POSSIBLE
GASTROINTESTINAL TRACT BLEEDING. MAY AFFECT METABOLISM(METABOLIC ACIDOSIS,
ANOREXIA, WEIGHT LOSS), LIVER (LIVER DAMAGE, JAUNDICE), BLOOD (RARELY
METHEMOGLOBINEMIA, HEMALYTIC ANEMIA), URINARY SYSTEM (KIDNEY DAMAGE,
HEMATURIA, HEMOGLOBINURIA, ALBUMINURIA), BEHAVIOR/CENTRAL NERVOUS SYSTEM
(CNS DEPRESSION, HEADACHE, SEIZURES, SOMNOLENCE, TREMOR, PSYCHOSIS, MUSCLE
WEAKNESS, COMA), CARDIOVASCULAR SYSTEM (LOWERING OF BLOOD PRESSURE,
DYSRYTHMIA). ORAL MUCOSA, VOMITUS, STOOLS, AND SALIVA MAY BE STAINED BLUE
OR GREEN FOLLOWING INGESTION. ASPIRATION PNEUMONIA MAY DEVELOP FOLLOWING
EMESIS (VOMITING).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE THICKENING OF THE SKIN.
PROLONGED OR REPEATED INGESTION MAY AFFECT THE LIVER. PROLONGED OR REPEATED
INGESTION MAY CAUSE NAUSEA, VOMITING, DIARRHEA. PROLONGED OR REPEATED
INGESTION MAY AFFECT THE BLOOD (CHANGES IN RED BLOOD CELL COUNT).
PROLONGED OR REPEATED INGESTION MAY AFFECT THE BLOOD (CHANGES IN SERUM
COMPOSITION). PROLONGED OR REPEATED EXPOSURE MAY AFFECT THE HEART. CHRONIC
EXPOSURE MAY AFFECT THE LIVER AND KIDNEYS. PROLONGED OR REPEATED INGESTION
MAY AFFECT THE SPLEEN. PROLONGED OR REPEATED INGESTION MAY AFFECT THE
ADRENAL GLAND. PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN ALLERGY.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
MUTATIONS IN MICROORGANISMS
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENT CAS NO IARC ACGIH - NTP
CARCINOGENS
CUPRIC SULFATE, ANHYDROUS 7758-98-7 NOT LISTED NOT LISTED NOT LISTED
COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
CUPRIC SULFATE, ANHYDROUS NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT OF
LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
CUPRIC SULFATE, ANHYDROUS - 7758-98-7:
FISH:
LC50: =0.1 MG/L (96H, ONCORHYNCHUS MYKISS)
CRUSTACEA:
EC50: 0.0058 - 0.0073 MG/L (48H, DAPHNIA MAGNA)
PERSISTENCE AND DEGRADABILITY:
IF RELEASED TO SOIL, COPPER SULFATE MAY LEACH TO GROUNDWATER, BE PARTLY
OXIDIZED, OR BIND TO HUMIC MATERIALS, CLAY, OR HYDROUS OF IRON AND
MANGANESE. IN WATER, IT WILL BIND TO CARBONATES AS WELL AS HUMIC MATERIALS,
CLAY AND HYDROUS OXIDES OF IRON AND MANGANESE. COPPER IS ACCUMULATED BY
PLANTS AND ANIMALS, BUT IT DOES NOT APPEAR TO BIOMAGNIFY FROM PLANTS TO
ANIMALS. THIS LACK OF BIOMAGNIFICATION APPEARS COMMON WITH HEAVY METALS. IN
AIR, COPPER AEROSOLS (IN GENERAL) HAVE A RESIDENCE TIME OF 2 TO 10 DAYS IN
AN UNPOLLUTED ATMOSPHERE AND 0.1 TO >4 IN A POLLUTED, URBAN AREAS.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENT CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
CUPRIC SULFATE, 7758-98-7 NONE NONE NONE NONE
ANHYDROUS
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN3288
PROPER SHIPPING NAME: TOXIC SOLID, INORGANIC, N.O.S. (SODIUM CHROMATE)
HAZARD CLASS: 6.1
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: III
EMERGENCY RESPONSE GUIDE NUMBER: 151
MARINE POLLUTANT: MARINE POLLUTANT
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: IB8, IP3, T1, TP33
SYMBOL(S): NO INFORMATION AVAILABLE
DESCRIPTION:
UN3288, TOXIC SOLID, INORGANIC, N.O.S. (CUPRIC SULFATE, ANHYDROUS), 6.1,
III
TDG (CANADA):
UN-NO: UN3288
PROPER SHIPPING NAME: TOXIC SOLID, INORGANIC, N.O.S. (SODIUM CHROMATE)
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION:
UN3288, TOXIC SOLID, INORGANIC, N.O.S. (CUPRIC SULFATE, ANHYDROUS), 6.1,
III
ADR:
UN NUMBER: UN3288
PROPER SHIPPING NAME: TOXIC SOLID, INORGANIC, N.O.S. (SODIUM CHROMATE)
TRANSPORT HAZARD CLASS(ES): 6.1
PACKING GROUP: III
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: 274
DESCRIPTION:
UN3288, TOXIC SOLID, INORGANIC, N.O.S. (CUPRIC SULFATE, ANHYDROUS), 6.1,
III, ENVIRONMENTALLY HAZARDOUS
IMDG:
UN-NO: UN3288
PROPER SHIPPING NAME: TOXIC SOLID, INORGANIC, N.O.S. (SODIUM CHROMATE)
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: MARINE POLLUTANT
EMS: F-A
SPECIAL PROVISIONS: 223, 274
DESCRIPTION:
UN3288, TOXIC SOLID, INORGANIC, N.O.S. (CUPRIC SULFATE, ANHYDROUS), 6.1,
III, MARINE POLLUTANT
RID:
UN NUMBER: UN3288
PROPER SHIPPING NAME: TOXIC SOLID, INORGANIC, N.O.S. (SODIUM CHROMATE)
TRANSPORT HAZARD CLASS(ES): 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
SPECIAL PROVISIONS: 274
DESCRIPTION:
UN3288, TOXIC SOLID, INORGANIC, N.O.S. (CUPRIC SULFATE, ANHYDROUS), 6.1,
III, ENVIRONMENTALLY HAZARDOUS
ICAO (AIR):
UN-NO: UN3288
PROPER SHIPPING NAME: TOXIC SOLID, INORGANIC, N.O.S. (SODIUM CHROMATE)
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION:
UN3288, TOXIC SOLID, INORGANIC, N.O.S. (CUPRIC SULFATE, ANHYDROUS), 6.1,
III
SPECIAL PROVISIONS: A3, A5
IATA:
UN NUMBER: UN3288
PROPER SHIPPING NAME: TOXIC SOLID, INORGANIC, N.O.S. (SODIUM CHROMATE)
TRANSPORT HAZARD CLASS(ES): 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
PRECAUTIONARY STATEMENTS - RESPONSE: 6L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION:
UN3288, TOXIC SOLID, INORGANIC, N.O.S. (CUPRIC SULFATE, ANHYDROUS), 6.1,
III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENT CAS NO U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
CUPRIC SULFATE, 7758-98-7 PRESENTACTIVE PRESENT PRESENT
ANHYDROUS KE-08956
COMPONENT JAPAN ENCS CHINA AUSTRALIA EINECS-NO.
IECSC AICS
CUPRIC SULFATE, PRESENT PRESENT PRESENT PRESENT
ANHYDROUS (1)-300 231-847-6
U.S. REGULATIONS:
CUPRIC SULFATE, ANHYDROUS:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: SN 0549
NEW JERSEY (EHS) LIST: SN 2215 500 LB. TPQ (COPPER COMPOUNDS)
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: 10 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
10 LB FINAL RQ
4.54 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1261
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS: 184.1261
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENT CAS NO
CUPRIC SULFATE, ANHYDROUS 7758-98-7
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
CUPRIC SULFATE, NOT LISTED NOT LISTED NOT LISTED NOT LISTED
ANHYDROUS
CERCLA/SARA:
COMPONENTS CAS NO CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY EXTREMELY
THEIR REPORTABLE HAZARDOUS HAZARDOUS
QUANTITIES SUBSTANCES SUBSTANCES
AND TPQS AND RQS
CUPRIC SULFATE, 7758-98-7 10 LB FINAL RQ NONE NONE
ANHYDROUS 4.54 KG FINAL RQ
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
CUPRIC SULFATE, ANHYDROUS COPPER COMPOUNDS 1.0%
U.S. TSCA:
COMPONENT CAS NO TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH AND
CHEMICALS WITH SAFETY REPORTING
SIGNIFICANT NEW USE
RULES (SNURS)
CUPRIC SULFATE, 7758-98-7 NOT APPLICABLE NOT APPLICABLE
ANHYDROUS
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
THE WHMIS 2015 CLASSIFICATION OF THIS PRODUCT HAS NOT BEEN VALIDATED OR
REVIEWED YET.
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
DSL/NDSL:
COMPONENT CAS NO CANADA (DSL) CANADA (NDSL)
CUPRIC SULFATE, ANHYDROUS 7758-98-7 PRESENT NOT LISTED
COMPONENT CAS NO CEPA SCHEDULE I - TOXIC SUBSTANCES
CUPRIC SULFATE, ANHYDROUS 7758-98-7 NOT LISTED
COMPONENT CAS NO CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
CUPRIC SULFATE, ANHYDROUS 7758-98-7 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENT CAS NO EU GHS - SV - CLP (1272/2008)
CUPRIC SULFATE, ANHYDROUS 7758-98-7 ACUTE TOXICITY - ORAL -
ACUTE TOX. 4:
H302:
HARMFUL IF SWALLOWED. (MINIMUM
CLASSIFICATION)
SKIN CORROSION/IRRITATION -
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE
IRRITATION - EYE IRRIT. 2:
H319:
CAUSES SERIOUS EYE IRRITATION.
HAZARDOUS TO AQUATIC
ENVIRONMENT - ACUTE HAZARD -
AQUATIC ACUTE 1:
H400: VERY TOXIC TO AQUATIC LIFE.
HAZARDOUS TO AQUATIC
ENVIRONMENT - CHRONIC HAZARD -
AQUATIC CHRONIC 1:
H410:
VERY TOXIC TO AQUATIC LIFE WITH
LONG LASTING EFFECTS.
029-004-00-0
EU - CLP (1272/2008):
R-PHRASE(S):
R22: HARMFUL IF SWALLOWED
R50: VERY TOXIC TO AQUATIC ORGANISMS
R53: MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT
R36/38: IRRITATING TO EYES AND SKIN
S-PHRASE(S):
S2: KEEP OUT OF THE REACH OF CHILDREN.
S22: DO NOT BREATHE DUST
S60: THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE
S61:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY DATA
SHEETS.
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
CUPRIC SULFATE, 7758-98-7 XN; R22 NO INFORMATION S: (2)-22-60-61
ANHYDROUS XI; R36/38
N; R50-53
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XN: HARMFUL
XI: IRRITANT
N: DANGEROUS FOR THE ENVIRONMENT
| 16. OTHER INFORMATION | |
PREPARATION DATE: 4/13/2017
REVISION DATE: 1/31/2019
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.