| Common Name: | COLLODION, USP |
| Manufacturer: | SPECTRUM CHEMICAL MFG. |
| SDS Revision Date: | 2/16/2021 |
| SDS Format: | GHS-US |
| Item Number(s): | 39G344, 39G345 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
SPECTRUM(R*)
ISO 9001:2015
S
REGISTERED
REVISION DATE: 16-FEBRUARY-2021
REVISION NUMBER: 2
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: COLLODION, USP
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE(S): CO120
UN/ID NO: UN2059
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE
RESTRICTIONS ON USE: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS
SPECTRUM CHEMICAL MFG. CORP.
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE:
CHEMTREC: 1-800-424-9300
| 2. HAZARD(S) IDENTIFICATION | |
CLASSIFICATION:
ACUTE TOXICITY - ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
REPRODUCTIVE TOXICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1
FLAMMABLE LIQUIDS: CATEGORY 1
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
LABEL ELEMENTS: DANGER
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
MAY DAMAGE FERTILITY OR THE UNBORN CHILD
MAY CAUSE RESPIRATORY IRRITATION
MAY CAUSE DROWSINESS OR DIZZINESS
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
EXTREMELY FLAMMABLE LIQUID AND VAPOR
EXCLAMATION MARK
HEALTH HAZARD
FLAME
APPEARANCE: CLEAR AND VISCOUS
PHYSICAL STATE: LIQUID
ODOR: ETHEREAL
PRECAUTIONARY STATEMENTS - PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF ELECTRICAL / VENTILATING / LIGHTING/ .? / EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
KEEP COOL
PRECAUTIONARY STATEMENTS - RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
SPECIFIC TREATMENT (SEE .? ON THIS LABEL)
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL
RINSE MOUTH
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM TO EXTINGUISH
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
UNKNOWN ACUTE TOXICITY:
0 % OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE ORAL TOXICITY
OTHER INFORMATION:
TENDS TO FORM EXPLOSIVE PEROXIDES WHEN EXPOSED TO AIR AND LIGHT, AND
ESPECIALLY WHEN EVAPORATED TO DRYNESS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE: NOT APPLICABLE.
MIXTURE:
CHEMICAL NAME CAS NO WEIGHT-% TRADE SECRET
ETHYL ETHER 60-29-7 68 - 72 *
ETHANOL 64-17-5 23 - 27 *
PYROXYLIN 9004-70-0 5 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET.
| 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE: SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
INHALATION: REMOVE TO FRESH AIR.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. GET MEDICAL ATTENTION IMMEDIATELY IF SYMPTOMS
OCCUR.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. KEEP EYE WIDE OPEN WHILE RINSING. DO NOT RUB AFFECTED
AREA. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER WHILE REMOVING ALL
CONTAMINATED CLOTHES AND SHOES. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS AND PERSISTS.
INGESTION:
DO NOT INDUCE VOMITING. CLEAN MOUTH WITH WATER AND DRINK AFTERWARDS PLENTY
OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A
PHYSICIAN.
SELF-PROTECTION OF THE FIRST AIDER:
REMOVE ALL SOURCES OF IGNITION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF
THE MATERIAL(S) INVOLVED, TAKE PRECAUTIONS TO PROTECT THEMSELVES AND
PREVENT SPREAD OF CONTAMINATION. USE PERSONAL PROTECTIVE EQUIPMENT AS
REQUIRED. SEE SECTION 8 FOR MORE INFORMATION. AVOID CONTACT WITH SKIN, EYES
OR CLOTHING.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
MAY CAUSE REDNESS AND TEARING OF THE EYES. BURNING SENSATION. INHALATION OF
HIGH VAPOR CONCENTRATIONS MAY CAUSE SYMPTOMS LIKE HEADACHE, DIZZINESS,
TIREDNESS, NAUSEA AND VOMITING.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL. CARBON DIOXIDE (CO2). WATER SPRAY. ALCOHOL RESISTANT FOAM.
LARGE FIRE:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT SCATTER SPILLED MATERIAL WITH HIGH PRESSURE WATER STREAMS.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
RISK OF IGNITION. KEEP PRODUCT AND EMPTY CONTAINER AWAY FROM HEAT AND
SOURCES OF IGNITION. IN THE EVENT OF FIRE, COOL TANKS WITH WATER SPRAY.
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED
OF IN ACCORDANCE WITH LOCAL REGULATIONS.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: YES.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL
FIREFIGHTING TURNOUT GEAR. USE PERSONAL PROTECTION EQUIPMENT.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
EVACUATE PERSONNEL TO SAFE AREAS. USE PERSONAL PROTECTIVE EQUIPMENT AS
REQUIRED. SEE SECTION 8 FOR MORE INFORMATION. AVOID CONTACT WITH SKIN, EYES
OR CLOTHING. ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND
OF SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS
OR FLAMES IN IMMEDIATE AREA). PAY ATTENTION TO FLASHBACK. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. ALL EQUIPMENT USED WHEN
HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL.
OTHER INFORMATION:
VENTILATE THE AREA. REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND
8.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. DO NOT TOUCH OR WALK THROUGH
SPILLED MATERIAL. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS.
DIKE FAR AHEAD OF SPILL TO COLLECT RUNOFF WATER. KEEP OUT OF DRAINS,
SEWERS, DITCHES AND WATERWAYS. ABSORB WITH EARTH, SAND OR OTHER NON-
COMBUSTIBLE MATERIAL AND TRANSFER TO CONTAINERS FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. DAM UP. SOAK UP
WITH INERT ABSORBENT MATERIAL. PICK UP AND TRANSFER TO PROPERLY LABELED
CONTAINERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
USE PERSONAL PROTECTION EQUIPMENT. AVOID BREATHING VAPORS OR MISTS. KEEP
AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. USE GROUNDING AND BONDING CONNECTION WHEN TRANSFERRING
THIS MATERIAL TO PREVENT STATIC DISCHARGE, FIRE OR EXPLOSION. USE WITH
LOCAL EXHAUST VENTILATION. USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF
EQUIPMENT. KEEP IN AN AREA EQUIPPED WITH SPRINKLERS. USE ACCORDING TO
PACKAGE LABEL INSTRUCTIONS. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL
HYGIENE AND SAFETY PRACTICE. AVOID CONTACT WITH SKIN, EYES OR CLOTHING. DO
NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. REMOVE CONTAMINATED
CLOTHING AND SHOES. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
KEEP AT TEMPERATURES BELOW 30 DEG. C / 86 DEG. F. KEEP AWAY FROM HEAT,
SPARKS, FLAME AND OTHER SOURCES OF IGNITION (I.E., PILOT LIGHTS, ELECTRIC
MOTORS AND STATIC ELECTRICITY). KEEP IN PROPERLY LABELED CONTAINERS. DO NOT
STORE NEAR COMBUSTIBLE MATERIALS. KEEP IN AN AREA EQUIPPED WITH SPRINKLERS.
STORE IN ACCORDANCE WITH THE PARTICULAR NATIONAL REGULATIONS. STORE IN
ACCORDANCE WITH LOCAL REGULATIONS. KEEP OUT OF THE REACH OF CHILDREN. STORE
LOCKED UP.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS:
THE FOLLOWING INGREDIENTS ARE THE ONLY INGREDIENTS OF THE PRODUCT ABOVE THE
CUT-OFF LEVEL (OR LEVEL THAT CONTRIBUTES TO THE HAZARD CLASSIFICATION OF
THE MIXTURE) WHICH HAVE AN EXPOSURE LIMIT APPLICABLE IN THE REGION FOR
WHICH THIS SAFETY DATA SHEET IS INTENDED OR OTHER RECOMMENDED LIMIT. AT
THIS TIME, THE OTHER RELEVANT CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS
FROM THE SOURCES LISTED HERE.
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
ETHYL ETHER NO DATA AVAILABLE 400 PPM TWA
60-29-7 1200 MG/M3 TWA
ETHANOL NO DATA AVAILABLE 1000 PPM TWA
64-17-5 1900 MG/M3 TWA
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: TIGHT SEALING SAFETY GOGGLES.
HAND PROTECTION: WEAR SUITABLE GLOVES. IMPERVIOUS GLOVES.
SKIN AND BODY PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING. LONG SLEEVED CLOTHING. CHEMICAL
RESISTANT APRON. ANTISTATIC BOOTS.
RESPIRATORY PROTECTION:
NO PROTECTIVE EQUIPMENT IS NEEDED UNDER NORMAL USE CONDITIONS. IF EXPOSURE
LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, VENTILATION AND
EVACUATION MAY BE REQUIRED.
GENERAL HYGIENE CONSIDERATIONS:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. REGULAR CLEANING OF
EQUIPMENT, WORK AREA AND CLOTHING IS RECOMMENDED. WASH HANDS BEFORE BREAKS
AND IMMEDIATELY AFTER HANDLING THE PRODUCT. WEAR SUITABLE GLOVES AND
EYE/FACE PROTECTION. AVOID CONTACT WITH SKIN, EYES OR CLOTHING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR AND VISCOUS
COLOR: COLORLESS; LIGHT YELLOW
ODOR: ETHEREAL
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS - METHOD
PH NEUTRAL NONE KNOWN
MELTING POINT / NO DATA AVAILABLE NONE KNOWN
FREEZING POINT
BOILING POINT / 36.1 DEG. C / NONE KNOWN
BOILING RANGE 97 DEG. F
FLASH POINT -45 DEG. C / NONE KNOWN
-49 DEG. F
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY NO DATA AVAILABLE NONE KNOWN
(SOLID, GAS)
FLAMMABILITY LIMIT NONE KNOWN
IN AIR
UPPER FLAMMABILITY 36%
OR EXPLOSIVE LIMITS
LOWER FLAMMABILITY 1.9%
OR EXPLOSIVE LIMITS
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY >1 NONE KNOWN
RELATIVE DENSITY 0.765 - 0.775 NONE KNOWN
WATER SOLUBILITY VERY SLIGHTLY NONE KNOWN
SOLUBLE IN COLD
WATER
SOLUBILITY(IES) NO DATA AVAILABLE NONE KNOWN
PARTITION NO DATA AVAILABLE NONE KNOWN
COEFFICIENT
AUTOIGNITION NO DATA AVAILABLE NONE KNOWN
TEMPERATURE
DECOMPOSITION NONE KNOWN
TEMPERATURE
KINEMATIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
DYNAMIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
OTHER INFORMATION:
EXPLOSIVE PROPERTIES NO INFORMATION
AVAILABLE
OXIDIZING PROPERTIES NO INFORMATION
AVAILABLE
SOFTENING POINT NO INFORMATION
AVAILABLE
MOLECULAR WEIGHT NO INFORMATION
AVAILABLE
VOC CONTENT (%) NO INFORMATION
AVAILABLE
LIQUID DENSITY NO INFORMATION
AVAILABLE
BULK DENSITY NO INFORMATION
AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO INFORMATION AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG BASES. STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. MAY CAUSE
IRRITATION OF RESPIRATORY TRACT. MAY CAUSE DROWSINESS OR DIZZINESS.
EYE CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE.
IRRITATING TO EYES. (BASED ON COMPONENTS). CAUSES SERIOUS EYE IRRITATION.
SKIN CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. CAUSES
SKIN IRRITATION. (BASED ON COMPONENTS).
INGESTION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. INGESTION
MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
HARMFUL IF SWALLOWED. (BASED ON COMPONENTS).
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS:
REDNESS. MAY CAUSE REDNESS AND TEARING OF THE EYES. INHALATION OF HIGH
VAPOR CONCENTRATIONS MAY CAUSE SYMPTOMS LIKE HEADACHE, DIZZINESS,
TIREDNESS, NAUSEA AND VOMITING.
ACUTE TOXICITY:
NUMERICAL MEASURES OF TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.
ATEMIX (ORAL): 1,608.90 MG/KG
ATEMIX (DERMAL): 14,200.00 MG/KG
UNKNOWN ACUTE TOXICITY:
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE ORAL TOXICITY
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
ETHYL ETHER =1215 MG/KG =20 ML/KG = 32000 PPM
60-29-7 (RAT) (RABBIT) (RAT) 4 H
>20 ML/KG
(RABBIT)
ETHANOL =7060 MG/KG 124.7 MG/L
64-17-5 (RAT) (RAT) 4 H
PYROXYLIN >5 G/KG
9004-70-0 (RAT)
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SKIN CORROSION/IRRITATION:
CLASSIFICATION BASED ON DATA AVAILABLE FOR INGREDIENTS. IRRITATING TO SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
CLASSIFICATION BASED ON DATA AVAILABLE FOR INGREDIENTS. CAUSES SERIOUS EYE
IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NO INFORMATION AVAILABLE.
GERM CELL MUTAGENICITY: NO INFORMATION AVAILABLE.
CARCINOGENICITY: NO INFORMATION AVAILABLE.
THE TABLE BELOW INDICATES WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT AS
A CARCINOGEN.
CHEMICAL NAME ACGIH IARC NTP OSHA
ETHANOL GROUP 1 - MONOGRAPH
64-17-5 100E [2012] IN
ALCOHOLIC BEVERAGES
MONOGRAPH 96 [2010]
IN ALCOHOLIC
BEVERAGES
LEGEND:
REPRODUCTIVE TOXICITY:
CONTAINS A KNOWN OR SUSPECTED REPRODUCTIVE TOXIN. CLASSIFICATION BASED ON
DATA AVAILABLE FOR INGREDIENTS. MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
STOT - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
STOT - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
TARGET ORGAN EFFECTS:
LIVER, RESPIRATORY SYSTEM, EYES, SKIN, CENTRAL NERVOUS SYSTEM, BLOOD,
REPRODUCTIVE SYSTEM.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
INTERACTIVE EFFECTS: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
CHEMICAL NAME ALGAE/AQUATIC FISH TOXICITY CRUSTACEA
PLANTS TO MICRO-
ORGANISMS
ETHYL ETHER LC50: EC50:
60-29-7 =2560 MG/L (96H, =165 MG/L
PIMEPHALES (24H, DAPHNIA
PROMELAS) MAGNA)
LC50:
>10000 MG/L (96H,
LEPOMIS MACRO-
CHIRUS)
ETHANOL LC50: LC50:
64-17-5 12.0 - 16.0 ML/L 9268 - 14221
(96H, ONCOR- MG/L (48H,
HYNCHUS MYKISS) DAPHNIA MAGNA)
LC50: EC50:
13400 - 15100 MG/L =10800 MG/L
(96H, PIMEPHALES (24H, DAPHNIA
PROMELAS) MAGNA)
LC50: EC50:
>100 MG/L (96H, =2 MG/L (48H,
PIMEPHALES DAPHNIA MAGNA)
PROMELAS)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: INHERENTLY BIODEGRADABLE.
COMPONENT INFORMATION:
CHEMICAL NAME PARTITION COEFFICIENT
ETHYL ETHER 0.82
60-29-7
ETHANOL -0.32
64-17-5
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
WASTE FROM RESIDUES/UNUSED PRODUCTS:
SHOULD NOT BE RELEASED INTO THE ENVIRONMENT. DISPOSE OF IN ACCORDANCE WITH
LOCAL REGULATIONS. DISPOSE OF WASTE IN ACCORDANCE WITH ENVIRONMENTAL
LEGISLATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS POSE A POTENTIAL FIRE AND EXPLOSION HAZARD. DO NOT CUT,
PUNCTURE OF WELD CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN/ID NO: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE, SOLUTION, FLAMMABLE
HAZARD CLASS: 3
PACKING GROUP: II
SPECIAL PROVISIONS: 198, IB2, T4, TP1, TP8
MARINE POLLUTANT SEVERE MARINE POLLUTANT
DESCRIPTION: UN2059, NITROCELLULOSE, SOLUTION, FLAMMABLE, 3, II
EMERGENCY RESPONSE GUIDE NUMBER: 127
TDG:
UN-NO: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
HAZARD CLASS: 3
PACKING GROUP: II
DESCRIPTION: UN2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, II
MEX:
UN-NO: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
HAZARD CLASS: 3
SPECIAL PROVISIONS: 198
PACKING GROUP: II
DESCRIPTION: UN2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, II
ICAO (AIR):
UN-NO: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
HAZARD CLASS: 3
PACKING GROUP: I
SPECIAL PROVISIONS: A3, A91
DESCRIPTION: UN2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, I
IATA:
UN NUMBER: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
TRANSPORT HAZARD CLASS(ES): 3
PACKING GROUP: II
DESCRIPTION: UN2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, II
IMDG:
UN NUMBER: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
TRANSPORT HAZARD CLASS(ES): 3
PACKING GROUP: II
EMS-NO: F-E, S-D
SPECIAL PROVISIONS: 198
MARINE POLLUTANT: NP1
DESCRIPTION:
UN2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, II, (-45 DEG. C C.C.)
RID:
UN NUMBER: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
TRANSPORT HAZARD CLASS(ES): 3
PACKING GROUP: II
CLASSIFICATION CODE: D
SPECIAL PROVISIONS: 198, 531, 640C
DESCRIPTION: UN2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, II
LABELS: 3
ADR:
UN NUMBER: 2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
TRANSPORT HAZARD CLASS(ES): 3
PACKING GROUP: II
CLASSIFICATION CODE: D
TUNNEL RESTRICTION CODE: (B)
SPECIAL PROVISIONS: 198, 531, 640C
DESCRIPTION: 2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, II, (B)
LABELS: 3
ADN:
UN/ID NO: UN2059
PROPER SHIPPING NAME: NITROCELLULOSE SOLUTION, FLAMMABLE
TRANSPORT HAZARD CLASS(ES): 3
PACKING GROUP: II
CLASSIFICATION CODE: D
SPECIAL PROVISIONS: 198, 531, 640C
DESCRIPTION: UN2059, NITROCELLULOSE SOLUTION, FLAMMABLE, 3, II
HAZARD LABEL(S): 3
LIMITED QUANTITY (LQ): 1 L
VENTILATION: VE01
EQUIPMENT REQUIREMENTS: PP, EX, A
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL/NDSL: COMPLIES
EINECS/ELINCS: DOES NOT COMPLY
ENCS: THIS PRODUCT COMPLIES WITH ENCS
IECSC: THIS PRODUCT COMPLIES WITH CHINA
KECL: COMPLIES
PICCS: COMPLIES
AICS:
ALL THE CONSTITUENTS OF THIS MATERIAL ARE LISTED ON THE AUSTRALIAN
INVENTORY OF CHEMICAL SUBSTANCES (AICS).
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372.
SARA 311/312 HAZARD CATEGORIES:
SHOULD THIS PRODUCT MEET EPCRA 311/312 TIER REPORTING CRITERIA AT 40 CFR
370, REFER TO SECTION 2 OF THIS SDS FOR APPROPRIATE CLASSIFICATIONS.
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42).
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED AS A
HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302).
CHEMICAL NAME HAZARDOUS SUBSTANCES EXTREMELY HAZARDOUS
RQS SUBSTANCES RQS
ETHYL ETHER 100 LB FINAL RQ
60-29-7 45.4 KG FINAL RQ
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED UNDER APPLICABLE
STATE RIGHT-TO-KNOW REGULATIONS
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 2
FLAMMABILITY 4
INSTABILITY 0
PHYSICAL AND CHEMICAL PROPERTIES
HMIS:
HEALTH HAZARDS 2*
FLAMMABILITY 4
PHYSICAL HAZARDS 0
PERSONAL PROTECTION X
CHRONIC HAZARD STAR LEGEND: * = CHRONIC HEALTH HAZARD
KEY OR LEGEND TO ABBREVIATIONS AND ACRONYMS USED IN THE SAFETY DATA SHEET:
LEGEND SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA: TWA (TIME-WEIGHTED AVERAGE)
STEL: STEL (SHORT TERM EXPOSURE LIMIT)
CEILING: MAXIMUM LIMIT VALUE
KEY LITERATURE REFERENCES AND SOURCES FOR DATA USED TO COMPILE THE SDS:
AGENCY FOR TOXIC SUBSTANCES AND DISEASE REGISTRY (ATSDR)
U.S. ENVIRONMENTAL PROTECTION AGENCY CHEMVIEW DATABASE
EUROPEAN FOOD SAFETY AUTHORITY (EFSA)
EPA (ENVIRONMENTAL PROTECTION AGENCY)
ACUTE EXPOSURE GUIDELINE LEVEL(S) (AEGL(S))
U.S. ENVIRONMENTAL PROTECTION AGENCY FEDERAL INSECTICIDE, FUNGICIDE, AND
RODENTICIDE ACT
U.S. ENVIRONMENTAL PROTECTION AGENCY HIGH PRODUCTION VOLUME CHEMICALS
FOOD RESEARCH JOURNAL
HAZARDOUS SUBSTANCE DATABASE
INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE (IUCLID)
JAPAN GHS CLASSIFICATION
AUSTRALIA NATIONAL INDUSTRIAL CHEMICALS NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS)
NIOSH (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH)
NATIONAL LIBRARY OF MEDICINE'S CHEMID PLUS (NLM CIP)
NATIONAL LIBRARY OF MEDICINE'S PUBMED DATABASE (NLM PUBMED)
NATIONAL TOXICOLOGY PROGRAM (NTP)
NEW ZEALAND'S CHEMICAL CLASSIFICATION AND INFORMATION DATABASE (CCID)
ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT ENVIRONMENT, HEALTH,
AND SAFETY PUBLICATIONS
ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT HIGH PRODUCTION
VOLUME CHEMICALS PROGRAM
ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT SCREENING
INFORMATION DATA SET
WORLD HEALTH ORGANIZATION
REVISION DATE: 16-FEBRUARY-2021
REVISION NOTE: NO INFORMATION AVAILABLE.
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.