| Common Name: | POTASSIUM FLUORIDE, DIHYDRATE, CRYSTAL, REAGENT |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 12/27/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39G731 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 12/27/2019
REVISION DATE: 12/27/2019
REVISION NUMBER: G1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: P1310
PRODUCT NAME: POTASSIUM FLUORIDE, DIHYDRATE, CRYSTAL, REAGENT
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NO INFORMATION AVAILABLE
CAS #: 13455-21-5
RTECS #: TT0700000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: TOM TYNER (USA - WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (USA - EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 3
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
TOXIC IF SWALLOWED
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
SKULLS AND CROSSBONES
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
WEAR PROTECTIVE GLOVES
WEAR EYE/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN
RINSE MOUTH
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT IN
ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS
AS APPLICABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO WEIGHT-%
POTASSIUM FLUORIDE, DIHYDRATE 13455-21-5 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT: FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. WARNING! IT MAY BE HAZARDOUS TO THE
PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION WHEN THE INHALED
OR INGESTED MATERIAL IS TOXIC, INFECTIOUS OR CORROSIVE. DO NOT USE
MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED OR INHALED THE SUBSTANCE;
INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH
A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY MEDICAL DEVICE. IMMEDIATE
MEDICAL ATTENTION IS REQUIRED.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IMMEDIATE MEDICAL ATTENTION IS REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES SKIN IRRITATION
MODERATE SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
MODERATE TO SEVERE EYE IRRITATION
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION
MAY CAUSE LOSS OF APPETITE
COUGHING AND WHEEZING
SHALLOW RESPIRATION
RESPIRATORY DEPRESSION
MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA
DYSPNEA (SHORTNESS OF BREATH AND DIFFICULTY BREATHING)
MAY AFFECT THE CARDIOVASCULAR SYSTEM
MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS
IT MAY AFFECT THE KIDNEYS
PARESTHESIA (NUMBNESS AND TINGLING OF THE EXTREMITIES)
INGESTION OF VERY LARGE AMOUNTS CAN CAUSE FLUORIDE POISONING WITH WEAKNESS,
CONVULSIONS, COLLAPSE AND DEATH
INGESTION OF VERY LARGE AMOUNTS MAY CAUSE FLUOROSIS
CAN CAUSE DISCOLORATION OF TEETH AND MOTTLED ENAMEL
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH
THE FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS:
IF IT IS INVOLVED IN A FIRE THE FOLLOWING CAN BE RELEASED:
HYDROGEN FLUORIDE GAS.
SPECIFIC HAZARDS: FIRE MAY PRODUCE IRRITATING AND/OR TOXIC GASES.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN,
EYES AND CLOTHING. AVOID BREATHING DUST. DO NOT TOUCH DAMAGED CONTAINERS
OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS. PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED
AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. CLEAN
CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. AVOID DUST
FORMATION. KEEP AWAY FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. AVOID DUST FORMATION. DO NOT INGEST. DO NOT BREATHE DUST. HANDLE
IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
DELIQUESCENT. PROTECT FROM MOISTURE. KEEP CONTAINER TIGHTLY CLOSED IN A
DRY AND WELL-VENTILATED PLACE. STORE AT ROOM TEMPERATURE IN THE ORIGINAL
CONTAINER. STORE IN A SEGREGATED AND APPROVED AREA. STORE AWAY FROM
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: ACIDS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENT CAS NO OSHA NIOSH ACGIH AIHA WEEL
POTASSIUM 13455-21-5 2.5 MG/M3 NONE 2.5 MG/M3 NONE
FLUORIDE, TWA (AS F) TWA (AS F)
DIHYDRATE
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
POTASSIUM 13455-21-5 2.5 MG/M3 2.5 MG/M3 2.5 MG/M3 2.5 MG/M3
FLUORIDE, TWA (AS F) TWA (AS F) TWA (AS F) TWAEV (AS F)
DIHYDRATE
AUSTRALIA AND MEXICO:
COMPONENT CAS NO AUSTRALIA MEXICO
POTASSIUM FLUORIDE, DIHYDRATE 13455-21-5 2.5 MG/M3 2.5 MG/M3
TWA (AS F) TWA (AS F)
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF USER
OPERATIONS GENERATE DUST, FUME OR MIST, USE VENTILATION TO KEEP EXPOSURE
TO AIRBORNE CONTAMINANTS BELOW THE EXPOSURE LIMIT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS. OR GOGGLES
SKIN AND BODY PROTECTION:
LONG SLEEVED CLOTHING
CHEMICAL RESISTANT APRON
GLOVES
RESPIRATORY PROTECTION:
EFFECTIVE DUST MASK. OR. WEAR RESPIRATOR WITH DUST FILTER. USE A DUST
RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE TO THE SUBSTANCE IS APPARENT
(E.G. GENERATION OF HIGH CONCENTRATION OF DUST (DUST CLOUDS), INADEQUATE
VENTILATION, DEVELOPMENT OF RESPIRATORY TRACT IRRITATION), AND ENGINEERING
CONTROLS ARE NOT FEASIBLE. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR
OR EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALS.
COLOR: WHITE.
ODOR: NO INFORMATION AVAILABLE.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: KF.H2O
MOLECULAR/FORMULA WEIGHT (G/MOLE): 94.13
FLAMMABILITY (SOLID, GAS): NON-FLAMMABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): 41 DEG. C/105 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F): 156 DEG. C/313 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 2.454
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
SOLUBLE IN WATER
SOLUBILITY IN WATER: 349.3 G/100 ML AT 18 DEG. C
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: REACTS WITH ACIDS TO FORM HYDROGEN FLUORIDE
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID:
INCOMPATIBLE MATERIALS. AVOID DUST FORMATION. EXPOSURE TO MOISTURE.
EXPOSURE TO MOIST AIR.
INCOMPATIBLE MATERIALS: ACIDS
HAZARDOUS DECOMPOSITION PRODUCTS: HYDROGEN FLUORIDE.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. INHALATION.
ACUTE TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
COMPONENT INFORMATION:
POTASSIUM FLUORIDE, DIHYDRATE:
CAS: NO 13455-21-5
LD50/ORAL/RAT: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION:
245 MG/KG LD50 ORAL RAT (HSDB AND RTECS) FOR ANHYDROUS CAS NUMBER 7789-23-3
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOXICITY: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE - ACUTE TOXICITY: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE - VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT: CAUSES SKIN IRRITATION. MODERATE SKIN IRRITATION.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. CAUSES MODERATE TO SEVERE EYE IRRITATION.
INHALATION:
MAY CAUSE IRRITATION OF RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE BURNING
SENSATION IN THE NOSE AND THROAT, COUGHING, WHEEZING, SHORTNESS OF BREATH
AND POSSIBLY PULMONARY EDEMA.
INGESTION:
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION. MAY CAUSE LOSS OF
APPETITE. MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA. ACUTE
INGESTION OF FLUORIDES MAY CAUSE NERVOUS SYSTEM EFFECTS WITH NEUROLOGICAL
SYMPTOMS SUCH AS HEADACHE, TREMORS OR SPASMS OF THE EXTREMITIES,
SEIZURES/CONVULSIONS, TETANIC CONTRACTIONS, MUSCLE SPASMS, MUSCLE
WEAKNESS. MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (DIZZINESS, HEADACHE).
MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (ATAXIA). FLUORIDE IONS CAN
REDUCE SERUM CALCIUM LEVELS POSSIBLY CAUSING FATAL HYPOCALCEMIA,
HYPOMAGNESEMIA, METABOLIC AND/OR RESPIRATORY ACIDOSIS, AND SOMETIMES
HYPERKALEMIA. MAY CAUSE SALIVATION. MAY CAUSE THIRST. MAY CAUSE EXCESSIVE
SWEATING. MAY AFFECT RESPIRATION (RESPIRATORY DEPRESSION). OTHER SYMPTOMS
OF ACUTE ORAL POISONING INCLUDE: SHALLOW RESPIRATION, SALIVATION,
NERVOUSNESS, CONVULSION, MUSCLE PAIN, HYPOTENSION. MAY CAUSE MUSCLE
WEAKNESS AND/OR MUSCLE PAIN. MAY AFFECT RESPIRATION (DIFFICULT OR LABORED
BREATHING RESULTING IN SHORTNESS OF BREATH). MAY CAUSE RESPIRATORY
PARALYSIS/RESPIRATORY FAILURE. MAY CAUSE TINGLING, PRICKING FEELING, OR
NUMBNESS IN THE EXTREMITIES. MAY AFFECT CARDIOVASCULAR SYSTEM (WEAK PULSE,
CHANGE IN HEART RATE). MAY AFFECT THE CARDIOVASCULAR SYSTEM (CARDIAC
ARRHYTHMIAS). MAY AFFECT URINARY SYSTEM (KIDNEYS). MAY CAUSE VISION
DISTURBANCES.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT
AND LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
CHRONIC INGESTION OF HIGH LEVELS OF FLUORIDES MAY AFFECT THE KIDNEYS.
CHRONIC INHALATION AND INGESTION MAY CAUSE FLUOROSIS (CHRONIC FLUORIDE
POISONING) WITH SKELETAL ABNORMALITIES. FLUORISIS IS CHARACTERIZED BY
NAUSEA, VOMITING, LOSS OF APPETITE, DIARRHEA, CONSTIPATION, ANEMIA,
WEAKNESS, BRITTLE BONES, STIFFNESS OF JOINTS. CAN ALSO RESULT IN
OSTEOSCLEROSIS (AN INCREASE OF BONE DENSITY IN CHARACTERISTIC PATTERNS.
CAN ALSO CAUSE DISCOLORATION OF TEETH/MOTTLED ENAMEL, AND MAY CAUSE
KIDNEY DAMAGE. PROLONGED OR REPEATED INGESTION MAY CAUSE MUSCLE AND JOINT
PAIN AND STIFFNESS, MUSCLE WEAKNESS. CHRONIC EXPOSURE MAY CAUSE CENTRAL
NERVOUS SYSTEM EFFECTS.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENTS CAS NO IARC ACGIH - NTP
CARCINOGENS
POTASSIUM FLUORIDE, 13455-21-5 NOT LISTED GROUP A4 - NOT NOT LISTED
DIHYDRATE CLASSIFIABLE
AS A HUMAN
CARCINOGEN
(LISTED UNDER
FLUORIDES)
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
POTASSIUM FLUORIDE, NOT LISTED NOT LISTED NOT LISTED
DIHYDRATE
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: NO DATA AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
POTASSIUM FLUORIDE, 13455-215 NONE NONE NONE NONE
DIHYDRATE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1812
PROPER SHIPPING NAME: POTASSIUM FLUORIDE, SOLID
HAZARD CLASS: 6.1
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: III
EMERGENCY RESPONSE GUIDE NUMBER: 154
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: IB8, IP3, T1, TP33
SYMBOL(S): NO INFORMATION AVAILABLE
DESCRIPTION: UN1812, POTASSIUM FLUORIDE, SOLID, 6.1, III
TDG (CANADA):
UN-NO: UN1812
PROPER SHIPPING NAME: POTASSIUM FLUORIDE, SOLID
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: UN1812, POTASSIUM FLUORIDE, SOLID, 6.1, III
ADR:
UN NUMBER: UN1812
PROPER SHIPPING NAME: POTASSIUM FLUORIDE, SOLID
TRANSPORT HAZARD CLASS(ES): 6.1
PACKING GROUP: III
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: UN1812, POTASSIUM FLUORIDE, SOLID, 6.1, III
IMDG:
UN-NO: UN1812
PROPER SHIPPING NAME: POTASSIUM FLUORIDE, SOLID
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
DESCRIPTION: UN1812, POTASSIUM FLUORIDE, SOLID, 6.1, III
RID:
UN NUMBER: UN1812
PROPER SHIPPING NAME: POTASSIUM FLUORIDE, SOLID
TRANSPORT HAZARD CLASS(ES): 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION: UN1812, POTASSIUM FLUORIDE, SOLID, 6.1, III
ICAO (AIR):
UN-NO: UN1812
PROPER SHIPPING NAME: POTASSIUM FLUORIDE, SOLID
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION: UN1812, POTASSIUM FLUORIDE, SOLID, 6.1, III
IATA:
UN NUMBER: UN1812
PROPER SHIPPING NAME: POTASSIUM FLUORIDE, SOLID
TRANSPORT HAZARD CLASS(ES): 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
PRECAUTIONARY STATEMENTS - RESPONSE: 6L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1812, POTASSIUM FLUORIDE, SOLID, 6.1, III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENT CAS NO U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
POTASSIUM FLUORIDE, 13455-21-5 NOT LISTED. NOT PRESENT NOT PRESENT
DIHYDRATE IT IS
EXEMPT FROM
LISTING ON
THE TSCA 8(B)
INVENTORY
SINCE IT IS
A HYDRATE.
HOWEVER, THE
ANHYDROUS
FORM
(CAS NUMBER
7789-23-3)
IS LISTED AS
ACTIVE ON THE
TSCA 8(B)
INVENTORY.
COMPONENT JAPAN ENCS CHINA IECSC AUSTRALIA (AICS) EINECS-NO.
POTASSIUM NOT PRESENT NOT LISTED PRESENT NOT PRESENT
FLUORIDE,
DIHYDRATE
U.S. REGULATIONS:
POTASSIUM FLUORIDE, DIHYDRATE:
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: SN 0936 (LISTED UNDER FLUORIDES)
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT (LISTED UNDER FLUORIDES)
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES:
PRESENT (LISTED UNDER FLUORIDES)
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENT CAS
POTASSIUM FLUORIDE, DIHYDRATE 13455-21-5
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
POTASSIUM NOT LISTED NOT LISTED NOT LISTED NOT LISTED
FLUORIDE,
DIHYDRATE
CERCLA/SARA:
COMPONENTS CAS NO CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
POTASSIUM FLUORIDE, 13455-21-5 NONE NONE NONE
DIHYDRATE
COMPONENTS SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
POTASSIUM FLUORIDE, NONE NONE
DIHYDRATE
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION TSCA 8(D) - HEALTH
5(A)2 - CHEMICALS AND SAFETY REPORTING
WITH SIGNIFICANT NEW
USE RULES (SNURS)
POTASSIUM 13455-21-5 NOT APPLICABLE NOT APPLICABLE
FLUORIDE,
DIHYDRATE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
THE WHMIS 2015 CLASSIFICATION OF THIS PRODUCT HAS NOT BEEN VALIDATED OR
REVIEWED YET.
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS NOT BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF
THE HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
DSL/NDSL:
COMPONENT CAS NO CANADA (DSL) CANADA (NDSL)
POTASSIUM FLUORIDE, DIHYDRATE 13455-21-5 NOT LISTED NOT LISTED
COMPONENT CAS NO CEPA SCHEDULE I - TOXIC SUBSTANCES
POTASSIUM FLUORIDE, 13455-21-5 NOT LISTED
DIHYDRATE
COMPONENT CAS NO CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
POTASSIUM FLUORIDE, 13455-21-5 NOT LISTED
DIHYDRATE
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENT CAS NO EU GHS - SV - CLP (1272/2008)
POTASSIUM FLUORIDE, 13455-21-5
DIHYDRATE
EU - CLP (1272/2008):
R-PHRASE(S):
R23/24/25: TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED
S-PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE)
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
POTASSIUM 13455-21-5 NO INFORMATION
FLUORIDE,
DIHYDRATE
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
T: TOXIC
| 16. OTHER INFORMATION | |
PREPARATION DATE: 12/27/2019
REVISION DATE: 12/27/2019
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO
NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES
NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR
RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING
LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES
NO RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.