| Common Name: | SODIUM CHLORATE, CRYSTAL, REAGENT |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 5/23/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39G895 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 8/25/2015
REVISION DATE: 5/23/2018
REVISION NUMBER: G2
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: S1235
PRODUCT NAME: SODIUM CHLORATE, CRYSTAL, REAGENT
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
CHLORIC ACID, SODIUM SALT
CHLORATE DE SODIUM
CHLORATE SALT OF SODIUM
SODA CHLORATE
SODAKEM
CAS #: 7775-09-9
RTECS #: FO0525000
CI #: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
BLEACHING AGENT. HERBICIDE. AGRICULTURE. PROCESSING AID. MANUFACTURE OF
SUBSTANCES.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 4
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2B
OXIDIZING SOLIDS: CATEGORY 1
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER
EXCLAMATION MARK
FLAME OVER CIRCLE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: CAUSES MILD SKIN IRRITATION
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP/STORE AWAY FROM CLOTHING AND OTHER COMBUSTIBLE MATERIALS
TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES
WEAR PROTECTIVE GLOVES
WEAR EYE/FACE PROTECTION
WEAR FIRE/FLAME RESISTANT/RETARDANT CLOTHING
IN CASE OF MAJOR FIRE AND LARGE QUANTITIES:
EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION.
IN CASE OF FIRE:
USE WATER TO EXTINGUISH. DO NOT USE DRY CHEMICALS OR FOAMS. CO2 OR HALON
MAY PROVIDE LIMITED CONTROL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON CLOTHING:
RINSE IMMEDIATELY CONTAMINATED CLOTHING AND SKIN WITH PLENTY OF WATER
BEFORE REMOVING CLOTHES
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
RINSE MOUTH
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
SODIUM CHLORATE 7775-09-9 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS. CONSULT A PHYSICIAN IF NECESSARY.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SYMPTOMS
PERSIST, CALL A PHYSICIAN.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
HARMFUL IF SWALLOWED. DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CONSULT A PHYSICIAN IF
NECESSARY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
HARMFUL IF SWALLOWED
MILD SKIN IRRITATION
CAUSES EYE IRRITATION
MAY CAUSE CORNEAL OPACITY
MAY CAUSE CONJUNCTIVITIS
NOSE AND THROAT IRRITATION
MAY CAUSE COUGHING AND SHORTNESS OF BREATH
MAY CAUSE PULMONARY EDEMA
MAY CAUSE CHEMICAL PNEUMONITIS
MAY CAUSE METHEMOGLOBINEMIA AND CYANOSIS
MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA
CENTRAL NERVOUS SYSTEM EFFECTS
STAGGERING GAIT
DIZZINESS
FAINTING
CONVULSIONS
COMA
MAY CAUSE CARDIOVASCULAR EFFECTS
MAY CAUSE LIVER INJURY AND HEMOLYTIC ANEMIA
RENAL FAILURE
IT MAY CAUSE DERMATITIS
CHRONIC EXPOSURE MAY AFFECT LIVER, KIDNEYS/URINARY SYSTEM, AND BLOOD
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER. CO2 MAY BE OF NO VALUE IN EXTINGUISHING FIRES INVOLVING OXIDIZERS
AND MAY ONLY PROVIDE LIMITED CONTROL.
UNSUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL. FOAM. HALONS.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS:
IF IT IS INVOLVED IN A FIRE THE FOLLOWING CAN BE RELEASED:
HYDROGEN CHLORIDE GAS. CHLORINE. CHLORINE DIOXIDE.
SODIUM OXIDES.
SPECIFIC HAZARDS:
OXIDIZER. KEEP AWAY FROM COMBUSTIBLE MATERIALS (WOOD, PAPER, OIL, CLOTHING,
ETC.). THE PRODUCT IS NOT FLAMMABLE, BUT IT MAY CAUSE FIRE WHEN IN CONTACT
WITH OTHER MATERIAL. CONTACT WITH COMBUSTIBLE OR ORGANIC MATERIALS MAY
CAUSE FIRE. WILL ACCELERATE BURNING WHEN INVOLVED IN A FIRE. CONTAINER
EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED. IT IS A STRONG
OXIDIZER, REACTING WITH ORGANIC MATERIALS (WOOD, PAPER, OILS, CHLOTHING,
ETC.).
PAPER IMPREGNATED WITH SODIUM CHLORATE CAN BE IGNITED BY STATIC SPARKS.
MAY REACT EXPLOSIVELY WITH HYDROCARBONS (FUELS).
MIXTURES WITH AMMONIUM SALTS, POWDERED METALS, PHOSPHORUS, SILICON, SULFUR,
OR SULFIDES ARE READILY IGNITED. AND POTENTIALLY EXPLOSIVE.
MIXTURES WITH FIBROUS OR ABSORBENT ORGANIC MATERIALS (CHARCOAL, FLOUR,
SHELLAC, SAWDUST, SUGAR) ARE HAZARDOUS AND CAN BE CAUSED TO EXPLODE BY
STATIC FRICTION OR SHOCK.
IT MAY REACT EXPLOSIVELY WITH ALKENES + POSTASSIUM OSMATE, ALUMINUM +
RUBBER, GREASE, LEATHER, SULFIDES, CYANIDES, CYANOBORANE OLIGOMER, ORGANIC
MATTER, PAINT + POLYETHYLENE, SODIUM PHOSPHINATE.
MIXTURES WITH FINELY DIVIDED COMBUSTIBLE MATERIALS CAN REACT EXPLOSIVELY.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS:
WATER MIST MAY BE USED TO COOL CLOSED CONTAINERS. FOR LARGE FIRES, FLOOD
FIRE AREA WITH WATER FROM A DISTANCE. APPLY WATER FROM AS FAR A DISTANCE AS
POSSIBLE. COOL AFFECTED CONTAINERS WITH FLOODING QUANTITIES OF WATER. DO
NOT USE COMBUSTIBLE MATERIALS SUCH AS SAWDUST. DO NOT GET WATER INSIDE
CONTAINERS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH SKIN, EYES AND CLOTHING. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID DUST FORMATION. DO NOT USE
COMBUSTIBLE MATERIALS SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT FROM ENTERING
INTO SOIL, DITCHES, SEWERS, WATERWAYS, AND/OR GROUND WATER. PREVENT PRODUCT
FROM ENTERING DRAINS. DO NOT LET THIS CHEMICAL ENTER THE ENVIRONMENT.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
CLEAN CONTAMINATED SURFACE THOROUGHLY. SWEEP UP AND SHOVEL. USE APPROPRIATE
TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL WASTE DISPOSAL
CONTAINER. DO NOT USE COMBUSTIBLE MATERIALS SUCH AS PAPER TOWELS, SAWDUST,
CLOTHING, ETC. TO CLEAN UP SPILL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. AVOID DUST
FORMATION. KEEP AWAY FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. USE ONLY IN WELL-VENTILATED AREAS. DO NOT BREATHE VAPORS/DUST. DO
NOT INGEST. KEEP AWAY FROM HEAT AND SOURCES OF IGNITION. WHEN USING DO NOT
SMOKE. KEEP AWAY FROM COMBUSTIBLE MATERIAL. HANDLE IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. DO NOT
STORE NEAR COMBUSTIBLE MATERIALS. STORE AT ROOM TEMPERATURE IN THE ORIGINAL
CONTAINER. STORE AWAY FROM INCOMPATIBLE MATERIALS. STORE IN A SEGREGATED
AND APPROVED AREA.
INCOMPATIBLE MATERIALS:
REDUCING AGENTS
COMBUSTIBLE MATERIALS
POWDERED METALS
ORGANIC MATERIALS
STRONG ACIDS
CYANIDES
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS CAS-NO. OSHA NIOSH ACGIH AIHA WEEL
SODIUM CHLORATE 7775-09-9 NONE NONE NONE NONE
CANADA:
COMPONENTS CAS-NO. CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
SODIUM CHLORATE 7775-09-9 NONE NONE NONE NONE
AUSTRALIA AND MEXICO:
COMPONENTS CAS-NO. AUSTRALIA MEXICO
SODIUM CHLORATE 7775-09-9 NONE NONE
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. IF USER OPERATIONS GENERATE DUST, FUME OR
MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE
EXPOSURE LIMIT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES SAFETY GLASSES WITH SIDE-SHIELDS
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
GLOVES
LONG SLEEVED CLOTHING
FLAME RETARDANT PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
EFFECTIVE DUST MASK. USE A DUST RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE
TO THE SUBSTANCE IS APPARENT (E.G. GENERATION OF HIGH CONCENTRATION OF DUST
(DUST CLOUDS), INADEQUATE VENTILATION, DEVELOPMENT OF RESPIRATORY TRACT
IRRITATION), AND ENGINEERING CONTROLS ARE NOT FEASIBLE. BE SURE TO USE AN
APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE SOLID.
COLOR: WHITE TO YELLOWISH. COLORLESS.
ODOR: ODORLESS.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: NaClO3
MOLECULAR/FORMULA WEIGHT: 106.45 G/MOL
FLAMMABILITY: NO INFORMATION AVAILABLE
FLASHPOINT (DEG. C / DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C / DEG. F): 248-261 DEG. C/478-502 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C / DEG. F): 300 DEG. C/572 DEG. F (DEC)
BULK DENSITY: 2.49
DENSITY (G/CM3): 2.49
SPECIFIC GRAVITY: NO INFORMATION AVAILABLE
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY: SOLUBLE IN WATER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
CAN REACT EXPLOSIVELY WITH MANY REDUCING AGENTS
CONTACT WITH POWDERED METALS MAY CAUSE FIRE OR EXPLOSION
HIGHLY REACTIVE WITH COMBUSTIBLE MATERIALS AND ORGANIC MATERIALS
REACTIVE WITH STRONG ACIDS
CONTACT WITH ACIDS OR ACID FUMES MAY EVOLVE HIGHLY TOXIC HYDROGEN CHLORIDE
FUMES
IT IS A STRONG OXIDIZER.
MIXTURES WITH AMMONIUM SALTS, AMMONIUM THIOSULFATE, POWDERED METALS,
PHOSPHORUS, SILICON, SULFUR, ANTIMONY SULFIDE OR SULFIDES ARE READILY
IGNITED AND POTENTIALLY EXPLOSIVE.
PAPER IMPREGNATED WITH SODIUM CHLORATE CAN BE IGNITED BY STATIC SPARKS.
VIOLENT REACTION OR IGNITION WITH ALUMINUM, AMMONIUM SULFATE, Sb2S3,
ARSENIC, ARSENIC TRIOXIDE, 1,3-BIS(TRICHLOROMETHYLBENZENE) + HEAT, MnO2,
PHOSPHORUS, CYANIDES, POTASSIUM CYANIDE, OSMIUM + HEAT, PAPER,
THIOCYANATES, TRIETHYLENE GLYCOL + WOOD, ZINC, ALKENES + POTASSIUM OSMATE,
ALUMINUM + RUBBER, CYANOBORANE OLIGOMER, PAINT + POLYETHYLENE, SODIUM
PHOSPHINATE, GREASE.
IT CAN ALSO REACT VIOLENTLY WITH PAPER, METAL SULFIDES, DIBASIC ORGANIC
ACIDS, ORGANIC MATERIALS, ABSORBENT ORGANIC MATERIALS (CHARCOAL, CARBON,
FLOUR, SHELLAC, SAWDUST, SUGAR), COMBUSTIBLE MATERIALS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID:
AVOID DUST FORMATION. CONTACT WITH COMBUSTIBLE MATERIALS (WOOD, PAPER, OIL,
CLOTHING, ETC.). EXPOSURE TO MOISTURE. EXPOSURE TO MOIST AIR. HEAT, FLAMES
AND SPARKS. INCOMPATIBLE MATERIALS. CONTACT WITH FINELY DIVIDED (POWDERED)
METALS.
INCOMPATIBLE MATERIALS:
REDUCING AGENTS
COMBUSTIBLE MATERIALS
POWDERED METALS
ORGANIC MATERIALS
STRONG ACIDS
CYANIDES
HAZARDOUS DECOMPOSITION PRODUCTS:
SODIUM OXIDES. HYDROGEN CHLORIDE. CHLORINE.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. INHALATION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
SODIUM CHLORATE:
CAS-NO.: 7775-09-9
LD50/ORAL/RAT: =4950 MG/KG
ORAL LD50 RAT: 6250 MG/KG ORAL
LD50 RAT LD50/ORAL/MOUSE:
3600 MG/KG ORAL LD50 MOUSE (RTECS)
7850-8850 MG/KG ORAL LD50 MOUSE (EU CHEMICALS BUREAU IUCLID DATASET)
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
>2000 MG/KG DERMAL LD50
>5.59 MG/L
INHALATION LC50: 4950 MG/KG
ORAL LD50: 6250 MG/KG
ORAL LD50: >28 G/M3
INHALATION LC50: >10 G/KG DERMAL LD50
LC50/INHALATION/RAT: 28 G/M3 INHALATION LC50 RAT 1 H
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION:
7200 MG/KG ORAL LD50 RABBIT
1350 MG/KG ORAL LD50 CAT
700 MG/KG ORAL LD50 DOG
6100 MG/KG ORAL LD50 GUINEA PIG
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE-ACUTE TOX ORAL: 1200 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: 3600 MG/KG
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: 28000 MG/M3 (1-HR)
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT: MILD SKIN IRRITATION.
EYE CONTACT: CAUSES EYE IRRITATION.
INHALATION:
IT CAN IRRITATE THE NOSE AND THROAT AND CAUSE COUGHING AND SHORTNESS OF
BREATH, BUT IT IS NOT CLEAR HOW MUCH CAN BE ABSORBED THROUGH THE LUNGS. IT
MAY CAUSE ULCERATION OF THE NASAL SEPTUM. IT MAY CAUSE PULMONARY EDEMA,
CHEMICAL PNEUMONITIS, AND UPPER AIRWAY OBSTRUCTION CAUSED BY EDEMA.
INGESTION:
MAY CAUSE METHEMOGLOBINEMIA, (THE FORMATION OF METHEMOGLOBIN IN THE BLOOD
WHICH CAUSES DEFICIENT OXYGENATION OF THE BLOOD DUE TO DECREASED AVAILABLE
HEMOGLOBIN). SIGNS AND SYMPTOMS OF METHEMOGLOBINEMIA INCLUDE SHORTNESS OF
BREATH, CYANOSIS (A BLUISH DISCOLORATION OF THE SKIN, LIPS, MUCOUS
MEMBRANES), MENTAL STATUS CHANGES SUCH AS HEADACHE, MENTAL IMPAIRMENT,
FATIGUE, MUSCULAR WEAKNESS, EXERCISE INTOLERANCE, LIGHTHEADEDNESS,
DIZZINESS, INCOORDINATION, SEIZURES, AND LOSS OF CONSCIOUSNESS. ARTERIAL
BLOOD WITH ELEVATED METHEMOGLOBIN LEVELS HAS A CHARACTERISTIC
CHOCOLATE-BROWN COLOR AS COMPARED TO NORMAL BRIGHT RED OXYGEN CONTAINING
ARTERIAL BLOOD. SEVERE METHEMOGLOBINEMIA IS CHARACTERIZED BY BRADYCARDIA OR
TACHYDARDIA (SLOW OR FAST HEART BEAT), DYSRHYTHMIAS, SEIZURES, COMA AND
DEATH. IT ACTS CATALYTICALLY TO INDUCE METHEMOGLOBINEMIA. THE RATE OF
METHEMOGLOBION FORMATION IS FAIRLY SLOW, AND DANGEROUS LEVELS CAN OCCUR
INSIDIOUSLY AND WITHOUT WARNING. EFFECTS OF SODIUM CHLORATE POISONING
INCLUDE GASTROINTESTINAL TRACT IRRITATION WITH NAUSEA, VOMITING, ABDOMINAL
PAIN, DIARRHEA. OTHER SYMPTOMS MAY INCLUDE STAGGERING GAIT, DIZZINESS,
FAINTNESS, CARDIOVASCULAR COLLAPSE, PALLOR, CYANOSIS, SHORTNESS OF BREATH,
MASSIVE HEMOLYSIS, ANEMIA, DARK-COLORED/BLOODY URINE, ANURIA, KIDNEY
FAILURE FROM TUBULAR DEPOSITION OF RED BLOOD CELL BREAKDOWN PRODUCTS, COMA,
AND CONVULSIONS.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
SKIN:
PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE DERMATITIS, AND SKIN LESIONS.
INHALATION/INGESTION:
PROLONGED OR REPEATED INHALATION OR INGESTION MAY CAUSE SORE THROAT,
NAUSEA, SWEATING. PROLONGED OR REPEATED INGESTION MAY ALSO AFFECT THE BLOOD
(CHANGES IN RED BLOOD CELL COUNT, CHANGED IN WHITE BLOOD CELL COUNT),
METABOLISM (LOSS OF APPETITE, WEIGHT LOSS). IT MAY ALSO AFFECT THE KIDNEYS.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
MUTATIONS IN MICROORGANISMS
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENT CAS NO IARC ACGIH - NTP
CARCINOGENS
SODIUM CHLORATE 7775-09-9 NOT LISTED NOT LISTED NOT LISTED
COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
SODIUM CHLORATE NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS:
ALTHOUGH NO INFORMATION HAS BEEN FOUND REGARDING THE REPRODUCTIVE HAZARDS
OF SODIUM CHLORATE, SUBSTANCES WHICH CAN INDUCE METHEMOGLOBINEMIA ARE OF
CONCERN FOR POSSIBLE REPRODUCTIVE EFFECTS SINCE THE FETUS HAS AN INCREASED
OXYGEN DEMAND. FETAL HEMOGLOBIN IS MORE EASILY OXIDIZED TO METHEMOGLOBIN
THAN IS ADULT HEMOGLOBIN, AND FETAL METHEMOGLOBIN IS REDUCED BACK TO NORMAL
MORE SLOWLY THAN THE ADULT FORM
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: LIVER. KIDNEYS. BLOOD. METHEMOGLOBIN FORMATION.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS:
AQUATIC ENVIRONMENT. TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM
ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
SODIUM CHLORATE - 7775-09-9:
FRESHWATER ALGAE DATA:
>3137 MG/L NOEC DESMODESMUS SUBSPICATUS GROWTH INHIBITION
FRESHWATER FISH SPECIES DATA:
13500 MG/L LC50 PIMEPHALES PROMELAS 96 H 1
1750 MG/L LC50 ONCORHYNCHUS MYKISS 96 H 1
7090 MG/L LC50 CYPRINUS CARPIO 96 H 1
4200 MG/L LC50 ONCORHYNCHUS MYKISS 24 H 1
WATER FLEA DATA: 1093 MG/L EC50 DAPHNIA MAGNA 24 H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES/UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENT CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
SODIUM CHLORATE 7775-09-9 NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1495
PROPER SHIPPING NAME: SODIUM CHLORATE
HAZARD CLASS: 5.1
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: II
EMERGENCY RESPONSE GUIDE NUMBER: 140
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: A9, IB8, IP2, IP4, N34, T3, TP33
SYMBOL(S): NO INFORMATION AVAILABLE
DESCRIPTION: UN1495, SODIUM CHLORATE, 5.1, II
TDG (CANADA):
UN-NO: UN1495
PROPER SHIPPING NAME: SODIUM CHLORATE
HAZARD CLASS: 5.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: UN1495, SODIUM CHLORATE, 5.1, II
ADR:
UN-NO: UN1495
PROPER SHIPPING NAME: SODIUM CHLORATE
HAZARD CLASS: 5.1
PACKING GROUP: II
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: UN1495, SODIUM CHLORATE, 5.1, II, ENVIRONMENTALLY HAZARDOUS
IMO/IMDG:
UN-NO: UN1495
PROPER SHIPPING NAME: SODIUM CHLORATE
HAZARD CLASS: 5.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-H
DESCRIPTION: UN1495, SODIUM CHLORATE, 5.1, II, MARINE POLLUTANT
RID:
UN-NO: UN1495
PROPER SHIPPING NAME: SODIUM CHLORATE
HAZARD CLASS: 5.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: UN1495, SODIUM CHLORATE, 5.1, II, ENVIRONMENTALLY HAZARDOUS
ICAO:
UN-NO: UN1495
PROPER SHIPPING NAME: SODIUM CHLORATE
HAZARD CLASS: 5.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: UN1495, SODIUM CHLORATE, 5.1, II
IATA:
UN-NO: UN1495
PROPER SHIPPING NAME: SODIUM CHLORATE
HAZARD CLASS: 5.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
ERG CODE: 5L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1495, SODIUM CHLORATE, 5.1, II
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
SODIUM CHLORATE 7775-09-9 PRESENT ACTIVE PRESENT PRESENT
KE-31386
COMPONENTS JAPAN ENCS CHINA AUSTRALIA EINECS-NO.
(AICS)
SODIUM CHLORATE PRESENT PRESENT PRESENT PRESENT
(1)-239 231-887-4
U.S. REGULATIONS:
SODIUM CHLORATE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 1688
PENNSYLVANIA RTK: PRESENT
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CAS-NO.
SODIUM CHLORATE 7775-09-9
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
SODIUM CHLORATE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CAS NO CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY EXTREMELY
THEIR REPORTABLE HAZARDOUS HAZARDOUS
QUANTITIES SUBSTANCES SUBSTANCES
AND TPQS AND RQS
SODIUM CHLORATE 7775-09-9 NONE NONE NONE
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
SODIUM CHLORATE NONE NONE
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH
CHEMICALS WITH AND SAFETY REPORTING
SIGNIFICANT NEW USE
RULES (SNURS)
SODIUM CHLORATE 7775-09-9 NOT APPLICABLE NOT APPLICABLE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
SODIUM CHLORATE OXIDIZING SOLIDS - CATEGORY 2:
7775-09-9 (100) H272: MAY INTENSIFY FIRE, OXIDIZER.
ACUTE TOXICITY - ORAL - CATEGORY 4:
H302: HARMFUL IF SWALLOWED.
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
WHMIS 1988 HAZARD CLASS:
C: OXIDIZING MATERIALS
D1B: TOXIC MATERIALS
COMPONENTS WHMIS 1988
SODIUM CHLORATE C, D1B
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
INVENTORY:
COMPONENTS CAS-NO. CANADA (DSL) CANADA (NDSL)
SODIUM CHLORATE 7775-09-9 PRESENT NOT LISTED
COMPONENTS CAS-NO. CEPA SCHEDULE I - TOXIC SUBSTANCES
SODIUM CHLORATE 7775-09-9 NOT LISTED
COMPONENTS CAS-NO. CEPA - 2010 GREENHOUSE GASES SUBJECT
TO MANDATORY REPORTING
SODIUM CHLORATE 7775-09-9 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENTS CAS-NO. EU GHS - SV - CLP (1272/2008)
SODIUM CHLORATE 7775-09-9 OXIDIZING SOLIDS - OX. SOL. 1:
H271:
MAY CAUSE FIRE OR EXPLOSION, STRONG
OXIDIZER.
ACUTE TOXICITY - ORAL - ACUTE TOX. 4:
H302:
HARMFUL IF SWALLOWED. (MINIMUM
CLASSIFICATION)
HAZARDOUS TO AQUATIC ENVIRONMENT -
CHRONIC HAZARD - AQUATIC CHRONIC 2:
H411:
TOXIC TO AQUATIC LIFE WITH LONG
LASTING EFFECTS. 017-005-00-9
EU - CLP (1272/2008):
R-PHRASE(S):
R22: HARMFUL IF SWALLOWED.
R9: EXPLOSIVE WHEN MIXED WITH COMBUSTIBLE MATERIAL.
R51/53:
TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
S-PHRASE(S):
S2: KEEP OUT OF THE REACH OF CHILDREN.
S13: KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
S17: KEEP AWAY FROM COMBUSTIBLE MATERIAL.
S46:
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL.
S61:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY DATA
SHEETS.
COMPONENTS CAS-NO. CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
SODIUM CHLORATE 7775-09-9 XN; R22 NO INFORMATION S2 S13 S17 S46
N; R51-53 S61
O; R9
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XN: HARMFUL.
O: OXIDISING.
N: DANGEROUS FOR THE ENVIRONMENT.
XN: HARMFUL OR IRRITANT
O: OXIDISING AGENT
N: DANGEROUS FOR THE ENVIRONMENT
| 16. OTHER INFORMATION | |
PREPARATION DATE: 8/25/2015
REVISION DATE: 5/23/2018
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.