| Common Name: | SODIUM DICHROMATE, GRANULAR, TECHNICAL |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 5/15/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 39G920 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(TM) CHEMICAL MFG CORP
ISO 9001-2008
S
REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 5/15/2015
REVISION DATE: 5/15/2015
REVISION NUMBER: G1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: S1268
PRODUCT NAME: SODIUM DICHROMATE, GRANULAR, TECHNICAL
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
SODIUM BICHROMATE DIHYDRATE
CHROMIC ACID (H2CR2O7), DISODIUM SALT, DIHYDRATE
DICHROMIC ACID, DISODIUM SALT, DIHYDRATE
CAS #: 7789-12-0
RTECS #: HX7750000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICALS AND LABORATORY PRODUCTS, INC.
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
ACUTE TOXICITY - ORAL: CATEGORY 2
ACUTE TOXICITY - DERMAL: CATEGORY 3
ACUTE TOXICITY - INHALATION (GASES): CATEGORY 1
ACUTE TOXICITY - INHALATION (DUSTS/MISTS): CATEGORY 2
SKIN CORROSION/IRRITATION: CATEGORY 1SUB-CATEGORY B
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
RESPIRATORY SENSITIZATION: CATEGORY 1
SKIN SENSITIZATION: CATEGORY 1
GERM CELL MUTAGENICITY: CATEGORY 1B
CARCINOGENICITY: CATEGORY 1A
REPRODUCTIVE TOXICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1
OXIDIZING SOLIDS: CATEGORY 2
LABEL ELEMENTS:
DANGER
HAZARD STATEMENTS:
FATAL IF SWALLOWED
TOXIC IN CONTACT WITH SKIN
FATAL IF INHALED
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED
MAY CAUSE AN ALLERGIC SKIN REACTION
MAY CAUSE GENETIC DEFECTS
MAY CAUSE CANCER
MAY DAMAGE FERTILITY OR THE UNBORN CHILD
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
MAY INTENSIFY FIRE; OXIDIZER
CORROSION
SKULLS AND CROSSBONES
FLAME OVER CIRCLE
HEALTH HAZARD
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
WEAR RESPIRATORY PROTECTION
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP/STORE AWAY FROM CLOTHING/ .? /COMBUSTIBLE MATERIALS
TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES .?
PRECAUTIONARY STATEMENTS - RESPONSE:
SPECIFIC TREATMENT (SEE .? ON THIS LABEL)
SPECIFIC TREATMENT IS URGENT (SEE .? ON THIS LABEL)
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
SPECIFIC TREATMENT (SEE .? ON THIS LABEL)
IN CASE OF FIRE:
USE WATER TO EXTINGUISH. DO NOT USE DRY CHEMICALS OR FOAMS. CO2OR HALON
MAY PROVIDE LIMITED CONTROL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
RINSE MOUTH
DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT % TRADE SECRET
SODIUM DICHROMATE, DIHYDRATE 7789-12-0 100 *
7789-12-0
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
POISON INFORMATION CENTERS IN EACH STATE CAPITAL CITY CAN PROVIDE
ADDITIONAL ASSISTANCE FOR SCHEDULED POISONS (13 1126)
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED CLOTHES
AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR
POISON CONTROL CENTRE IMMEDIATELY.
EYE CONTACT:
FLUSH EYE WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS
OR CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED
OR INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF
A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR
POISON CONTROL CENTER IMMEDIATELY. FATAL IF SWALLOWED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SEVERE SKIN AND EYE IRRITATION OR BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
SEVERE IRRITATION OF THE UPPER RESPIRATORY TRACT. MAY CAUSE ALLERGIC
RESPIRATORY REACTION. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED. MAY AFFECT THE LIVER. IT MAY AFFECT THE KIDNEYS.
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION. CAN BURN MOUTH,
THROAT, AND STOMACH. MAY CAUSE GASTROINTESTINAL (DIGESTIVE) TRACT BURNS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER. CO2 MAY BE OF NO VALUE IN EXTINGUISHING FIRES INVOLVING OXIDIZERS
AND MAY ONLY PROVIDE LIMITED CONTROL.
UNSUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL. FOAM. HALONS.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS:
OXIDIZER. KEEP AWAY FROM COMBUSTIBLE MATERIALS (WOOD, PAPER, OIL,
CLOTHING, ETC.)
THE PRODUCT IS NOT FLAMMABLE, BUT IT MAY CAUSE FIRE WHEN IN CONTACT WITH
OTHER MATERIAL
CONTACT WITH COMBUSTIBLE OR ORGANIC MATERIALS MAY CAUSE FIRE
WILL ACCELERATE BURNING WHEN INVOLVED IN A FIRE
CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS:
FOR LARGE FIRES, FLOOD FIRE AREA WITH WATER FROM A DISTANCE. COOL AFFECTED
CONTAINERS WITH FLOODING QUANTITIES OF WATER. DO NOT GET WATER INSIDE
CONTAINERS. DO NOT USE COMBUSTIBLE MATERIALS SUCH AS SAWDUST.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. AVOID DUST
FORMATION. REMOVE ALL SOURCES OF IGNITION. KEEP COMBUSTIBLES (WOOD,
PAPER, OIL, CLOTHING, ETC.) AWAY FROM SPILLED MATERIAL.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS. PREVENT ENTRY INTO WATERWAYS, SEWERS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. DO NOT USE
COMBUSTIBLE MATERIALS SUCH AS PAPER TOWELS, SAWDUST, CLOTHING, ETC. TO
CLEAN UP SPILL. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. AVOID DUST
FORMATION. KEEP AWAY FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP AWAY FROM COMBUSTIBLE MATERIAL. DO NOT BREATHE
VAPOURS/DUST. DO NOT INGEST. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL
HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
DELIQUESCENT. KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED
PLACE. STORE AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE IN A
SEGRATED AND APPROVED AREA. DO NOT STORE NEAR COMBUSTIBLE MATERIALS. STORE
AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
REDUCING AGENTS. COMBUSTIBLE MATERIALS. ORGANIC MATERIALS. POWDERED
METALS. ACIDS. BASES.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS OSHA NIOSH ACGIH AIHA WHEEL
SODIUM DICHROMATE, 2.5 UG/M3TWA 15 MG/M3 IDLH 0.05 NONE
DIHYDRATE - 7789-12-0 (CHROMIUM VI (AS Cr(VI)- MG/M3TWA
COMPOUNDS) CHROMATES) (CHROMIUM
ACTION LEVEL POTENTIAL VI WATER
5 UG/M3 TWA OCCUPATIONAL SOLUBLE
(CHROMIUM VI CARCINOGEN INORGANIC
COMPOUNDS) COMPOUNDS)
CANADA:
COMPONENTS ALBERTA BRITISH COLUMBIA ONTARIO QUEBEC
SODIUM 0.05 MG/M3 0.025 MG/M3TWA 0.05 MG/M3TWA 0.05 MG/M3
DICHROMATE, TWA (CHROMIUM VI (CHROMIUM VI TWAEV
DIHYDRATE - (CHROMIUM WATER SOLUBLE WATER SOLUBLE (CHROMIUM VI
7789-12-0 VI WATER INORGANIC INORGANIC WATER SOLUBLE
SOLUBLE COMPOUNDS) COMPOUNDS) INORGANIC
COMPOUNDS) 0.1 MG/M3 COMPOUNDS)
CEILING (CHROMIUM
VI WATER SOLUBLE
INORGANIC
COMPOUNDS)
AUSTRALIA AND MEXICO:
COMPONENTS AUSTRALIA MEXICO
SODIUM DICHROMATE, 0.05 MG/M3TWA (CHROMIUM VI 0.05 MG/M3TWA (CHROMIUM VI
DIHYDRATE WATER SOLUBLE COMPOUNDS) WATER SOLUBLE COMPOUNDS)
7789-12-0
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. IF USER OPERATIONS GENERATE DUST, FUME OR
MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE
EXPOSURE LIMIT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON. LONG SLEEVED CLOTHING. GLOVES.
RESPIRATORY PROTECTION: WEAR RESPIRATOR WITH DUST FILTER..
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT. WHEN USING, DO NOT EAT, DRINK OR
SMOKE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID.
APPEARANCE: GRANULAR. CRYSTALS.
COLOR: RED. REDDISH-ORANGE.
ODOR: ODORLESS.
TASTE: NO INFORMATION AVAILABLE
MOLECULAR/FORMULA WEIGHT: 298.00
FORMULA: Na2Cr2O7.2H2O
FLASH POINT (DEG. C): NO DATA AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
PH: NO INFORMATION AVAILABLE
MELTING POINT/RANGE(DEG. C/DEG. F): 357 DEG. C/674.6 DEG. F
BOILING POINT/RANGE(DEG. C/DEG. F): NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE(DEG. C/DEG. F): 400 DEG. C/752 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): 2.35
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
EASILY SOLUBLE IN COLD WATER
INSOLUBLE IN ALCOHOL
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
IT MAY REACT VIOLENTLY WITH HYDRAZINE.
SODIUM DICHROMATE, ANHYDROUS, FORMS A VIOLENT REACTION OR IGNITION WITH
THE FOLLOWING:
BORON + SILICON (PYROTECHNIC)
ORGANIC RESIDUES + SULFURIC ACID
2-PROPANOL + SULFURIC ACID
SULFURIC ACID + TRINITROTOLUENE
SODIUM DICHROMATE IS INCOMPATIBLE WITH HYDROXYLAMINE, ACETIC ANHYDRIDE.
SODIUM DICHROMATE FORMS POTENTIALLY EXPLOSIVE REACTIONS WITH THE
FOLLOWING:
ACETIC ANHYDRIDE
ETHANOL + SULFURIC ACID + HEAT
HYDRAZINE
REACTIVE WITH ACIDS
REACTS WITH BASES
REACTS VIOLENTLY WITH COMBUSTIBLES
REACTIVE WITH ORGANIC MATERIALS
REACTIVE WITH METALS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID:
AVOID DUST FORMATION. CONTACT WITH COMBUSTIBLE MATERIALS (WOOD, PAPER,
OIL, CLOTHING, ETC.). EXPOSURE TO MOIST AIR. EXPOSURE TO MOISTURE.
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
REDUCING AGENTS. COMBUSTIBLE MATERIALS. ORGANIC MATERIALS. POWDERED
METALS. ACIDS. BASES.
HAZARDOUS DECOMPOSITION PRODUCTS: NITROGEN OXIDES (NOx). SODIUM OXIDES.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. INHALATION. SKIN.
ACUTE TOXICITY:
COMPONENT INFORMATION:
SODIUM DICHROMATE, DIHYDRATE - 7789-12-0:
LD50/ORAL/RAT:
46-50 MG/KG (FOR SODIUM DICHROMATE ANHYDROUS (CAS NUMBER 10588-01-9)
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
80 MG/MG (FOR SODIUM DICHROMATE ANHYDROUS (CAS NUMBER 10588-01-9)
LD50/DERMAL/RABBIT:
960-1000 MG/KG (FOR SODIUM CHROMATE ANHYDROUS (CAS NUMBER 10588-01-9)
LC50/INHALATION/RAT:
0.124 MG/L 4 H (FOR SODIUM DICHROMATE ANHYDROUS (CAS NUMBER 10588-01-9)
LC50/INHALATION/MOUSE: NO INFOMATION AVAILABLE
OTHER LD50 OR LC50INFORMATION: NO INFORMATION AVAILABLE
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE- ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE -ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
CAN SEVERELY IRRITATE AND BURN THE SKIN.. TOXIC IN CONTACT WITH SKIN.
EYE CONTACT:
CAN SEVERELY IRRITATE AND BURN THE EYES WITH POSSIBLE EYE DAMAGE..
INHALATION:
FATAL IF INHALED. CAN IRRITATE THE NOSE, THROAT AND LUNGS CAUSING
COUGHING, WHEEZING, AND/OR SHORTNESS OF BREATH. MAY CAUSE ULCERATION AND
PERFORATION OF THE NASAL SEPTUM IF INHALED IN LARGE QUANTITIES.
INGESTION:
FATAL IF SWALLOWED. CAUSES GASTROINTESTINAL TRACT IRRITATION AND BURNS.
MAY AFFECT LIVER AND URINARY SYSTEM (KIDNEY DAMAGE).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE BLISTERS, AND DEEP ULCERS
AND MAY CAUSE SKIN SENSITIZATION, AN ALLERGIC REACTION.
PROLONGED OR REPEATED INHALATION MAY CAUSE ASTHMA-LIKE ALLERGY. FUTURE
EXPOSURES CAN CAUSE ASTHMA ATTACKS WITH SHORTNESS OF BREATH, WHEEZING,
COUGH, AND/OR CHEST TIGHTNESS.
REPEATED OR PROLONGED INGESTION MAY CAUSE KIDNEY DAMAGE AND AFFECT THE
LIVER..
SENSITIZATION: MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
MUTATIONS IN MICROORGANISMS
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
EXPERIMENTS WITH HUMAN LYMPHOCYTES HAVE SHOWN MUTAGENIC EFFECTS
SISTER CHROMATID EXCHANGEE: HAMSTER OVARY (RTECS)
CARCINOGENIC EFFECTS: CARCINOGENIC.
COMPONENTS ACGIH - IARC NTP OSHA HCS -
CARCINOGENS CARCINOGENS
SODIUM A1- CONFIRMED GROUP 1- CLEAR PRESENT
DICHROMATE, HUMAN CARCINOGEN MONOGRAPH EVIDENCE (CHROMIUM VI
DIHYDRATE (CHROMIUM VI 100C [2012]; OF COMPOUNDS)
WATER SOLUBLE MONOGRAPH 49 CARCINOGENICITY
INORGANIC [1990]
COMPOUNDS (EVALUATED
AS GROUP -
CHROMIUM VI
COMPOUNDS)
COMPONENTS AUSTRALIA - PROHIBITED AUSTRALIA - NOTIFIABLE
CARCINOGENIC SUBSTANCES CARCINOGENIC SUBSTANCES
SODIUM DICHROMATE, NOT LISTED NOT LISTED
DIHYDRATE
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
REPRODUCTIVE EFFECTS:
MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS. MAY IMPAIR FERTILITY.
DEVELOPMENTAL EFFECTS:
MAY CAUSE ADVERSE DEVELOPMENTAL EFFECTS
MAY CAUSE HARM TO THE UNBORN CHILD
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE
STOT - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
TARGET ORGANS: KIDNEYS. LIVER. HEART. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: NO DATA AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE
MOBILITY: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS RCRA - F RCRA - K RCRA - P RCRA - U
SERIES WASTES SERIES WASTES SERIES WASTES SERIES WASTES
SODIUM NONE NONE NONE NONE
DICHROMATE,
DIHYDRATE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN3087
PROPER SHIPPING NAME: OXIDIZING SOLID, TOXIC, N.O.S. (SODIUM DICHROMATE)
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
ERG NO: 141
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SYMBOL(S): G
TDG (CANADA):
UN-NO: UN3087
PROPER SHIPPING NAME: OXIDIZING SOLID, TOXIC, N.O.S.
HAZARD CLASS: 5.1
SUBSIDIARY RISK: (6.1)
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: UN3087
PROPER SHIPPING NAME: OXIDIZING SOLID, TOXIC, N.O.S.
HAZARD CLASS: 5.1
PACKING GROUP: II
SUBSIDIARY RISK: 6.1
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
CEFIC TREMCARD NO: NO INFORMATION AVAILABLE
IMO / IMDG:
UN-NO: UN3087
PROPER SHIPPING NAME: OXIDIZING SOLID, TOXIC, N.O.S.
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IMDG PAGE: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
MFAG: NO INFORMATION AVAILABLE
MAXIMUM QUANTITY: NO INFORMATION AVAILABLE
RID:
UN-NO: UN3087
PROPER SHIPPING NAME: OXIDIZING SOLID, TOXIC, N.O.S.
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ICAO:
UN-NO: UN3087
PROPER SHIPPING NAME: OXIDIZING SOLID, TOXIC, N.O.S.
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IATA:
UN-NO: UN3087
PROPER SHIPPING NAME: OXIDIZING SOLID, TOXIC, N.O.S.
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
ERG CODE: 5P
DESCRIPTION: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS U.S. TSCA KOREA KECL PHILIPPINES (PICCS) JAPAN ENCS
SODIUM NOT LISTED NOT PRESENT PRESENT NOT PRESENT
DICHROMATE,
DIHYDRATE
COMPONENTS CHINA AUSTRALIA (AICS) EINECS-NO.
SODIUM DICHROMATE, DIHYDRATE PRESENT PRESENT NOT PRESENT
U.S. REGULATIONS:
SODIUM DICHROMATE, DIHYDRATE:
MASSACHUSETTS EHS: CARCINOGEN; EXTRAORDINARILY HAZARDOUS
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST:
SN 2245 (AS CHROMIUM COMPOUNDS)
SN 3575 (AS CHROMIUM VI COPOUONDS)
NEW JERSEY (EHS) LIST: SN 2245 500 LB TPQ (AS CHROMIUM COMPOUNDS)
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES:
PRESENT (AS CHROMIUM COMPOUNDS)
PENNSYLVANIA RTK: PRESENT (AS CHROMIUM COMPOUNDS)
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST:
PRESENT (CHROMIUM COMPOUNDS AND CHROMIUM VI COMPOUNDS)
PENNSYLVANIA RTK - SPECIAL HAZARDOUS SUBSTANCES:
PRESENT (CHROMIUM VI COMPOUNDS)
MINNESOTA - HAZARDOUS SUBSTANCE LIST:
CARCINOGEN (AS CHROMIUM VI COMPOUNDS)
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
100 LB. RQ (AS CHROMIUM COMPOUNDS)
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES:
PRESENT (AS CHROMIUM VI COMPOUNDS)
CALIFORNIA PROP. 65:
SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM (SEE TABLE BELOW)
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
SODIUM PRESENT (AS PRESENT (AS PRESENT (AS PRESENT (AS
DICHROMATE, CHROMIUM CHROMIUM CHROMIUM CHROMIUM
DIHYDRATE HEXAVALENT HEXAVALENT HEXAVALENT HEXAVALENT
COMPOUNDS) COMPOUNDS) COMPOUNDS) COMPOUNDS)
CERCLA/SARA:
COMPONENTS CERCLA - SECTION 302 SECTION 302 SECTION SECTION 313
HAZARDOUS EXTREMELY EXTREMELY 313 - - REPORTING
SUBSTANCES HAZARDOUS HAZARDOUS CHEMICAL DE MINIMIS
AND THEIR SUBSTANCES SUBSTANCES CATEGORY
REPORTABLE AND TPQS AND RQS
QUANTITIES
SODIUM NONE NONE NONE NONE 0.1% DE
DICHROMATE, MINIMUS
DIHYDRATE CONCENTRATON
(CHROMIUM VI
COMPOUNDS)
U.S. TSCA:
COMPONENTS TSCA SECTION 5(A)2 - CHEMICALS TSCA 8(D) -HEALTH
WITH SIGNIFICANT NEW USE RULES AND SAFETY REPORTING
(SNURS)
SODIUM DICHROMATE, NOT APPLICABLE NOT APPLICABLE
DIHYDRATE
CANADA:
WHMIS HAZARD CLASS:
C: OXIDIZING MATERIALS
D1A: VERY TOXIC MATERIALS
D2A: VERY TOXIC MATERIALS
D2B: TOXIC MATERIALS
SODIUM DICHROMATE, DIHYDRATE:
C
D1A
D2A
D2B
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
SODIUM DICHROMATE, DIHYDRATE:
INVENTORY:
COMPONENTS CANADA (DSL) CANADA (NDSL)
SODIUM DICHROMATE, DIHYDRATE NOT LISTED NOT LISTED
COMPONENTS CEPA SCHEDULE I - TOXIC CEPA - 2010 GREENHOUSE
SUBSTANCES GASES SUBJECT TO MANDITORY
REPORTING
SODIUM DICHROMATE, NOT LISTED NOT LISTED
DIHYDRATE
EU CLASSIFICATION:
R-PHRASE(S):
R 8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R21: HARMFUL IN CONTACT WITH SKIN.
R25: TOXIC IF SWALLOWED.
R26: VERY TOXIC BY INHALATION.
R34: CAUSES BURNS.
R45: MAY CAUSE CANCER.
R46: MAY CAUSE HERITABLE GENETIC DAMAGE.
R60: MAY IMPAIR FERTILITY.
R61: MAY CAUSE HARM TO THE UNBORN CHILD.
R49: MAY CAUSE CANCER BY INHALATION.
R50: VERY TOXIC TO AQUATIC ORGANISMS.
R53: MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
R42/43: MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.
R48/23:
TOXIC:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH
INHALATION.
S -PHRASE(S):
S53: AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
S60:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
S61:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY
DATA SHEETS.
COMPONENTS CLASSIFICATION CONCENTRATION LIMITS SAFETY PHRASES
SODIUM O; R8CAT.2;R45CAT.2; 10%<=C: C; R34 S53-S45-S60-S61
DICHROMATE, R60-61 MUTA. CAT.2; 5%<=C<10%: XI;
DIHYDRATE R46 N;R50-53 R42/43; R:36/37/38
25-48/23 T+;R26 T; 0.2%<=C: R42/43
R25 XN;R21 C; R34
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
T+: VERY TOXIC.
T: TOXIC
XN: HARMFUL.
XI: IRRITANT.
O: OXIDISING.
N: ENVIRONMENT
| 16. OTHER INFORMATION | |
PREPARATION DATE: 5/15/2015
REVISION DATE: 5/15/2015
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED.
IF THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR
BECOMES CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS.
THE PHYSICAL PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE
LITERATURE AND DO NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION
CONTAINED HEREIN DOES NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY, MERCHANTABILITY OR FITNESS OF THE GOODS FOR
A PARTICULAR PURPOSE. SPECTRUM CHEMICALS & LABORATORY PRODUCTS, INC.
ASSUMES NO RESPONSIBILITY FOR RESULTS OBTAINED OR FOR INCIDENTAL OR
CONSEQUENTIAL DAMAGES, INCLUDING LOST PROFITS, ARISING FROM THE USE
OF THESE DATA. NO WARRANTY AGAINST INFRINGEMENT OF ANY PATENT,
COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT SHALL BE THE USER'S
RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING AND PERSONAL
PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS SDS IS
BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.