| Common Name: | TERGITOL TMN-6 (90 PERCENT AQUEOUS), SURFACTANT |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 10/17/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39H102 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET:
PREPARATION DATE: 6/16/2016
REVISION DATE: 10/17/2018
REVISION NUMBER: G2
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: T1303
PRODUCT NAME:
TERGITOL(R*) TMN-6 (90 PERCENT AQUEOUS), SURFACTANT (TERGITOL(R*) IS A
REGISTERED TRADEMARK OF THE DOW CHEMICAL COMPANY)
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
POLY(OXY-1,2-ETHANEDIYL),
.ALPHA.-[3,5-DIMETHYL-1-(2-METHYLPROPYL)HEXYL]-.OMEGA.-HYDROXY-
POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER
POLYOXYETHYLENE 2,6,8-TRIMETHYL-4-NONYL ETHER
POLYOXYETHYLENE TRIMETHYLNONYL ETHER
CAS #: 60828-78-6
RTECS # WZ6210000
CI #: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248 (310)
516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE DAMAGE
CORROSION
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES
WEAR EYE/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN: WASH WITH PLENTY OF WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
PRECAUTIONARY STATEMENTS - STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER 60828-78-6 =>87
WATER 7732-18-5 10
POLYETHYLENE GLYCOL 25322-68-3 <=3
ETHYLENE OXIDE 75-21-8 <=0.0020
ACETALDEHYDE 75-07-0 <=0.0006
1,4-DIOXANE 123-91-1 <=0.0005
FORMALDEHYDE 50-00-0 <=0.0004
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT: FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES SKIN IRRITATION
SEVERE EYE IRRITATION
MAY CAUSE CORNEAL INJURY
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION
MAY CAUSE NAUSEA AND VOMITING
MAY CAUSE DIARRHEA
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS: AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES
AND OTHER NECESSARY PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING
AND EQUIPMENT AS BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH THE
FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. USE PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT FROM ENTERING
INTO SOIL, DITCHES, SEWERS, WATERWAYS, AND/OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. ABSORB SPILL WITH INERT MATERIAL
(E.G. VERMICULITE, DRY SAND OR EARTH). IN CASE OF LARGE SPILL, DIKE IF
NEEDED. DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
USE APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL
WASTE DISPOSAL CONTAINER. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. AVOID DUST
FORMATION. KEEP AWAY FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP AWAY FROM HEAT AND SOURCES OF IGNITION. DO NOT INGEST. DO
NOT BREATHE VAPORS OR SPRAY MIST. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL
HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE AWAY FROM INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG OXIDIZING AGENTS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS CAS-NO. OSHA NIOSH ACGIH AIHA
WEEL
POLYETHYLENE 60828-78-6 NONE NONE NONE NONE
GLYCOL
TRIMETHYLNONYL
ETHER
WATER 7732-18-5 NONE NONE NONE NONE
POLYETHYLENE 25322-68-3 NONE NONE NONE 10 MG/M3
GLYCOL TWA
ETHYLENE OXIDE 75-21-8 1 PPM 0.1 PPM 1 PPM NONE
TWA TWA TWA
5 PPM 0.18 MG/M3 5 PPM
STEL TWA CEILING
10 MIN/DAY
9 MG/M3
CEILING
10 MIN/DAY
ACETALDEHYDE 75-07-0 200 PPM NONE =25 PPM NONE
TWA CEILING
360 MG/M3
TWA
1,4-DIOXANE 123-91-1 100 PPM 1 PPM 20 PPM NOT
TWA CEILING TWA DETERMINED
360 MG/M3 3.6 MG/M3
TWA CEILING
FORMALDEHYDE 50-00-0 0.75 PPM 0.016 PPM 0.3 PPM NONE
TWA TWA STEL
2 PPM 0.1 PPM 0.1 PPM
STEL CEILING TWA
15 MIN
CANADA:
COMPONENTS CAS-NO. CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
POLYETHYLENE 60828-78-6 NONE NONE NONE NONE
GLYCOL
TRIMETHYLNONYL
ETHER
WATER 7732-18-5 NONE NONE NONE NONE
POLYETHYLENE 25322-68-3 NONE NONE NONE NONE
GLYCOL
ETHYLENE OXIDE 75-21-8 1 PPM 0.1 PPM 1 PPM 1 PPM
TWA TWA TWA TWAEV
1.8 MG/M3 1 PPM 1.8 MG/M3 1.8 MG/M3
TWA STEL TWA TWAEV
10 PPM
STEL
18 MG/M3
STEL
ACETALDEHYDE 75-07-0 =25 PPM =25 PPM 25 PPM 25 PPM
CEILING CEILING CEILING CEILING
=45 MG/M3 45 MG/M3
CEILING CEILING
1,4-DIOXANE 123-91-1 20 PPM TWA 20 PPM TWA NONE NONE
72 MG/M3
TWA
FORMALDEHYDE 50-00-0 1 PPM 0.3 PPM 1.5 PPM 2 PPM
CEILING TWA CEILING CEILING
1.3 MG/M3 1 PPM 1 PPM 3 MG/M3
CEILING CEILING STEL CEILING
0.75 PPM
TWA
0.9 MG/M3
TWA
AUSTRALIA AND MEXICO:
COMPONENTS CAS-NO. AUSTRALIA MEXICO
POLYETHYLENE GLYCOL 60828-78-6 NONE NONE
TRIMETHYLNONYL ETHER
WATER 7732-18-5 NONE NONE
POLYETHYLENE GLYCOL 25322-68-3 NONE NONE
ETHYLENE OXIDE 75-21-8 1 PPM TWA 1 PPM TWA
1.8 MG/M3 TWA 2 MG/M3 TWA
ACETALDEHYDE 75-07-0 91 MG/M3 STEL =25 PPM PEAK
50 PPM STEL =45 MG/M3 PEAK
20 PPM TWA
36 MG/M3 TWA
1,4-DIOXANE 123-91-1 10 PPM TWA 25 PPM TWA
36 MG/M3 TWA 90 MG/M3 TWA
100 PPM STEL
360 MG/M3 STEL
FORMALDEHYDE 50-00-0 1 PPM/1.2 MG/M3 TWA 2 PPM CEILING
2 PPM/2.5 MG/M3 STEL 3 MG/M3 CEILING
PROBABLE CARCINOGEN
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST
BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
LONG SLEEVED CLOTHING
GLOVES
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS NOT NECESSARY FOR NORMAL HANDLING. GOOD ROOM
VENTILATION OR USE OF LOCAL EXHAUST (FUME HOOD) IS SUFFICIENT. USE A VAPOR
RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE TO THE SUBSTANCE IS APPARENT
(E.G. GENERATION OF HIGH CONCENTRATIONS OF MIST OR VAPOR, INADEQUATE
VENTILATION, DEVELOPMENT OF RESPIRATORY TRACT IRRITATION), AND ENGINEERING
CONTROLS ARE NOT FEASIBLE. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR
OR EQUIVALENT.
HYGIENE MEASURES: AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: YELLOW.
ODOR: PUNGENT.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: C12H26O(CH2CH2O)N (FOR POLYETHYLENE GLYCOL TIMETHYLNONYL ETHER)
MOLECULAR/FORMULA WEIGHT (G/MOLE):
AV. MOLECULAR WEIGHT = 540 (FOR POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER)
FLAMMABILITY: NO
FLASHPOINT (DEG. C / DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C / DEG. F): 106 DEG. C/223 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 1.024
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: 4.8 (CALCULATED)
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY: SOLUBLE IN WATER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTIVE WITH STRONG ACIDS
REACTIVE WITH STRONG OXIDIZING AGENTS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS: NO INFORMATION AVAILABLE.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INHALATION. INGESTION. SKIN.
ACUTE TOXICITY:
COMPONENT INFORMATION:
POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER:
CAS-NO.: 60828-78-6
LD50/ORAL/RAT:
5650 MG/KG ORAL LD50 RAT
7460 (MICRO)L/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
8480 UL/KG
4780 UL/KG
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
WATER:
CAS-NO.: 7732-18-5
LD50/ORAL/RAT: >90 ML/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
POLYETHYLENE GLYCOL:
CAS-NO.: 25322-68-3
LD50/ORAL/RAT:
22 G/KG ORAL LD50 RAT
28 G/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
>20 ML/KG
>20 G/KG
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
ETHYLENE OXIDE:
CAS-NO.: 75-21-8
LD50/ORAL/RAT: 72 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 800 PPM INHALATION LC50 RAT 4 H
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
ACETALDEHYDE:
CAS-NO.: 75-07-0
LD50/ORAL/RAT: 660 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: 900 MG/KG
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 13300 PPM INHALATION LC50 RAT 4 H
LC50/INHALATION/MOUSE: 23000 MG/M3 4HR.
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
1,4-DIOXANE:
CAS-NO.: 123-91-1
LD50/ORAL/RAT:
5170 MG/KG ORAL LD50 RAT
4200 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: 7600 GL/KG DERMAL LD50 RABBIT
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 46 G/M3 INHALATION LC50 RAT 2 H
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
FORMALDEHYDE:
CAS-NO.: 50-00-0
LD50/ORAL/RAT: 100 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE:
500 MG/KG (RTECS)
385 MG/KG (RTECS)
42 MG/KG (RTECS)
LD50/DERMAL/RABBIT: 270 MG/KG DERMAL LD50 RABBIT
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 0.578 MG/L INHALATION LC50 RAT 4 H
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: 260 MG/KG ORAL LD50 GUINEA PIG
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE-ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT:
SEVERE EYE IRRITATION. CAUSES CONJUNCTIVITIS. REDNESS AND PAIN. MAY CAUSE
CORNEAL INJURY.
INHALATION:
INHALATION OF MIST OR VAPORS MAY CAUSE RESPIRATORY TRACT IRRITATION. AT
ROOM TEMPERATURE, EXPOSURE TO VAPOR IS MINIMAL DUE TO LOW VOLATILITY. A
SINGLE EXPOSURE IS NOT LIKELY TO BE HAZARDOUS.
INGESTION:
MAY CAUSE DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION WITH NAUSEA,
VOMITING, DIARRHEA.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY: NO INFORMATION AVAILABLE.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENT CAS NO IARC ACGIH - NTP
CARCINOGENS
POLYETHYLENE GLYCOL 60828-78-6 NOT LISTED NOT LISTED NOT LISTED
TRIMETHYLNONYL ETHER
WATER 7732-18-5 NOT LISTED NOT LISTED NOT LISTED
POLYETHYLENE GLYCOL 25322-68-3 NOT LISTED NOT LISTED NOT LISTED
ETHYLENE OXIDE 75-21-8 GROUP 1 - A2 SUSPECTED KNOWN HUMAN
CARCINOGENIC HUMAN CARCINOGEN
TO HUMANS - CARCINOGEN
MONOGRAPH
100F [2012]
MONOGRAPH
97 [2008]
MONOGRAPH
60 [1994]
OVERALL
EVALUATION
UPGRADED FROM
GROUP 2A TO
GROUP 1
BASED ON
MECHANISTIC
AND OTHER
RELEVANT DATA
ACETALDEHYDE 75-07-0 GROUP 1 - A2 - REASONABLY
CARCINOGENIC SUSPECTED ANTICIPATED
TO HUMANS - HUMAN TO BE A
MONOGRAPH CARCINOGEN HUMAN
100E [2012] CARCINOGEN
ASSOCIATED
WITH
CONSUMPTION
OF ALCOHOLIC
BEVERAGES
GROUP 2B -
POSSIBLY
CARCINOGENIC
TO HUMANS -
MONOGRAPH
71 [1999]
SUPPLEMENT
7 [1987]
MONOGRAPH
36 [1985]
1,4-DIOXANE 123-91-1 GROUP 2B - A3 REASONABLY
POSSIBLY CONFIRMED ANTICIPATED
CARCINOGENIC ANIMAL TO BE A
TO HUMANS - CARCINOGEN HUMAN
MONOGRAPH WITH UNKNOWN CARCINOGEN
71 [1999] RELEVANCE TO
SUPPLEMENT HUMANS
7 [1987]
MONOGRAPH
11 [1976]
FORMALDEHYDE 50-00-0 GROUP 1 - A1 CONFIRMED KNOWN HUMAN
CARCINOGENIC HUMAN CARCINOGEN
TO HUMANS - CARCINOGEN
MONOGRAPH
100F [2012]
MONOGRAPH
88 [2006]
MONOGRAPH
62 [1995]
SUPPLEMENT
7 [1987]
COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
POLYETHYLENE GLYCOL NOT LISTED NOT LISTED NOT LISTED
TRIMETHYLNONYL ETHER
WATER NOT LISTED NOT LISTED NOT LISTED
POLYETHYLENE GLYCOL NOT LISTED NOT LISTED NOT LISTED
ETHYLENE OXIDE PRESENT NOT LISTED NOT LISTED
SEE 29 CFR
1910.1047
ACETALDEHYDE PRESENT NOT LISTED NOT LISTED
1,4-DIOXANE PRESENT NOT LISTED NOT LISTED
FORMALDEHYDE PRESENT NOT LISTED NOT LISTED
SEE 29 CFR
1910.1048
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
POLYETHYLENE GLYCOL - 25322-68-3:
FRESHWATER FISH SPECIES DATA: 5000 MG/L LC50 CARASSIUS AURATUS 24 H 1
ETHYLENE OXIDE - 75-21-8:
FRESHWATER FISH SPECIES DATA: 73 - 96 MG/L LC50 PIMEPHALES PROMELAS 96 H 1
WATER FLEA DATA: 137 - 300 MG/L LC50 DAPHNIA MAGNA 48 H
ACETALDEHYDE - 75-07-0:
FRESHWATER ALGAE DATA: 237 - 249 MG/L EC50 NITZSCHIA LINEARIS 120 H
FRESHWATER FISH SPECIES DATA:
1.8-2.4 MG/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
28.0-34.0 MG/L LC50 PIMEPHALES PROMELAS 96 H FLOW-THROUGH 1
39.8-46.8 MG/L LC50 PIMEPHALES PROMELAS 96 H STATIC 1
53 MG/L LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1
WATER FLEA DATA:
3.64 - 6.15 MG/L EC50 DAPHNIA MAGNA 48 H
48.3 MG/L EC50 DAPHNIA MAGNA 48 H
1,4-DIOXANE - 123-91-1:
FRESHWATER FISH SPECIES DATA:
10000 MG/L LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1
10000 MG/L LC50 LEPOMIS MACROCHIRUS 96 H SEMI-STATIC 1
9850 MG/L LC50 PIMEPHALES PROMELAS 96 H FLOW-THROUGH 1
10306 - 14742 MG/L LC50 PIMEPHALES PROMELAS 96 H STATIC 1
9850 MG/L LC50 PIMEPHALES PROMELAS 96 H 1
WATER FLEA DATA: 163 MG/L EC50 WATER FLEA 48 H
FORMALDEHYDE - 50-00-0:
FRESHWATER FISH SPECIES DATA:
22.6 - 25.7 MG/L LC50 PIMEPHALES PROMELAS 96 H FLOW-THROUGH 1
1510 (MICRO)G/L LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1
41 MG/L LC50 BRACHYDANIO RERIO 96 H STATIC 1
0.032 - 0.226 ML/L LC50 ONCORHYNCHUS MYKISS 96 H FLOW-THROUGH 1
100 - 136 MG/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
23.2 - 29.7 MG/L LC50 PIMEPHALES PROMELAS 96 H STATIC 1
WATER FLEA DATA:
2 MG/L LC50 DAPHNIA MAGNA 48 H
11.3 - 18 MG/L EC50 DAPHNIA MAGNA 48 H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES/UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENT CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
POLYETHYLENE 60828-78-6 NONE NONE NONE NONE
GLYCOL
TRIMETHYLNONYL
ETHER
WATER 7732-18-5 NONE NONE NONE NONE
POLYETHYLENE 25322-68-3 NONE NONE NONE NONE
GLYCOL
ETHYLENE OXIDE 75-21-8 NONE NONE NONE U115
IGNITABLE
WASTE, TOXIC
WASTE
ACETALDEHYDE 75-07-0 NONE NONE NONE U001
IGNITABLE
WASTE
1,4-DIOXANE 123-91-1 NONE NONE NONE U108
FORMALDEHYDE 50-00-0 NONE NONE NONE U122
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
EMERGENCY RESPONSE GUIDE NUMBER: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
SYMBOL(S): NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
IMO/IMDG:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
RID:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
ICAO:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
IATA:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
ERG CODE: NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
POLYETHYLENE GLYCOL 60828-78-6 PRESENT ACTIVE PRESENT PRESENT
TRIMETHYLNONYL ETHER KE-11551
WATER 7732-18-5 PRESENT ACTIVE PRESENT PRESENT
KE-35400
POLYETHYLENE GLYCOL 25322-68-3 PRESENT ACTIVE PRESENT PRESENT
KE-20228
ETHYLENE OXIDE 75-21-8 PRESENT ACTIVE PRESENT PRESENT
KE-27537
ACETALDEHYDE 75-07-0 PRESENT T PRESENT PRESENT
KE-00003
1,4-DIOXANE 123-91-1 PRESENT ACTIVE PRESENT PRESENT
KE-10463
FORMALDEHYDE 50-00-0 PRESENT PRESENT PRESENT
(ACTIVE) KE-17074
COMPONENTS JAPAN ENCS CHINA AUSTRALIA EINECS-NO.
(AICS)
POLYETHYLENE GLYCOL NOT PRESENT PRESENT PRESENT NOT PRESENT
TRIMETHYLNONYL ETHER
WATER NOT PRESENT PRESENT PRESENT PRESENT
231-791-2
POLYETHYLENE GLYCOL PRESENT PRESENT PRESENT NOT PRESENT
(7)-129
ETHYLENE OXIDE PRESENT PRESENT PRESENT PRESENT
(2)-218 200-849-9
ACETALDEHYDE PRESENT PRESENT PRESENT PRESENT
(2)-485 200-836-8
1,4-DIOXANE PRESENT PRESENT PRESENT PRESENT
(5)-839 204-661-8
FORMALDEHYDE PRESENT PRESENT PRESENT PRESENT
(2)-482 200-001-8
U.S. REGULATIONS:
POLYETHYLENE GLYCOL:
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
FDA - DIRECT FOOD ADDITIVES:
21 CFR 172.210, 21 CFR 172.820, 21 CFR 173.310, 21 CFR 173.340 (MOLECULAR
WEIGHT 200-9500)
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
172.210, 172.820, 173.310, 173.340, 175.105, 175.300, 176.180, 178.3750,
73.1 (MOLECULAR WEIGHT 200-9500)
ETHYLENE OXIDE:
MASSACHUSETTS RTK: PRESENT
MASSACHUSETTS EHS: CARCINOGEN; EXTRAORDINARILY HAZARDOUS
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0882
NEW JERSEY (EHS) LIST: 0882 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
NEW JERSEY TCPA - EHS: 2700 LB TQ
PENNSYLVANIA RTK:
ENVIRONMENTAL HAZARD
SPECIAL HAZARDOUS SUBSTANCE
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
PENNSYLVANIA RTK - SPECIAL HAZARDOUS SUBSTANCES: PRESENT
MICHIGAN PSM HHC: =5000 LB TQ
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: 10 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS: LISTED
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
172.710, 172.808, 175.105, 176.180, 176.210, 177.2470, 178.3520
ACETALDEHYDE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0001
NEW JERSEY (EHS) LIST: 0001 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
NEW JERSEY TCPA - EHS: =4900 LB TQ
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
PENNSYLVANIA RTK - SPECIAL HAZARDOUS SUBSTANCES: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: =1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS: LISTED
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 182.60
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
177.2410 182.60
1,4-DIOXANE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0789
NEW JERSEY (EHS) LIST: 0789 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK:
ENVIRONMENTAL HAZARD
SPECIAL HAZARDOUS SUBSTANCE
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
PENNSYLVANIA RTK - SPECIAL HAZARDOUS SUBSTANCES: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
100 LB RQ
1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
100 LB FINAL RQ
45.4KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FORMALDEHYDE:
MASSACHUSETTS RTK: PRESENT
MASSACHUSETTS EHS: CARCINOGEN; EXTRAORDINARILY HAZARDOUS
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0946
NEW JERSEY (EHS) LIST: 0946 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
NEW JERSEY TCPA - EHS:
175 LB TQ
15000 LB TQ
PENNSYLVANIA RTK:
ENVIRONMENTAL HAZARD
SPECIAL HAZARDOUS SUBSTANCE
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
PENNSYLVANIA RTK - SPECIAL HAZARDOUS SUBSTANCES: PRESENT
MICHIGAN PSM HHC: =1000 LB TQ
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
100 LB RQ
1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
100 LB FINAL RQ
45.4 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - DIRECT FOOD ADDITIVES: 21 CFR 173.340
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
173.340, 175.105, 175.210, 175.300, 176.170, 176.180, 176.200, 177.1200,
177.2410, 178.3120, 573.460
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING (SEE TABLE BELOW) WHICH
IS (ARE) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE
INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING (SEE TABLE BELOW) WHICH
IS (ARE) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
COMPONENTS CAS-NO.
POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER 60828-78-6
WATER 7732-18-5
POLYETHYLENE GLYCOL 25322-68-3
ETHYLENE OXIDE 75-21-8
ACETALDEHYDE 75-07-0
1,4-DIOXANE 123-91-1
FORMALDEHYDE 50-00-0
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
POLYETHYLENE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
GLYCOL
TRIMETHYLNONYL
ETHER
WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED
POLYETHYLENE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
GLYCOL
ETHYLENE OXIDE CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
ACETALDEHYDE CARCINOGEN NOT LISTED NOT LISTED NOT LISTED
1,4-DIOXANE CARCINOGEN NOT LISTED NOT LISTED NOT LISTED
FORMALDEHYDE CARCINOGEN NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CAS NO CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY EXTREMELY
THEIR REPORTABLE HAZARDOUS HAZARDOUS
QUANTITIES SUBSTANCES SUBSTANCES
AND TPQS AND RQS
POLYETHYLENE 60828-78-6 NONE NONE NONE
GLYCOL
TRIMETHYLNONYL
ETHER
WATER 7732-18-5 NONE NONE NONE
POLYETHYLENE 25322-68-3 NONE NONE NONE
GLYCOL
ETHYLENE OXIDE 75-21-8 10 LB FINAL RQ 1000 LB TPQ NONE
4.54 KG FINAL RQ
10 LB EPCRA
RQ
ACETALDEHYDE 75-07-0 =1000 LB FINAL RQ NONE NONE
=454 KG FINAL RQ
1,4-DIOXANE 123-91-1 100 LB FINAL RQ NONE NONE
45.4 KG FINAL RQ
FORMALDEHYDE 50-00-0 100 LB FINAL RQ 100 LB EPCRA NONE
45.4 KG FINAL RQ RQ
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
POLYETHYLENE GLYCOL NONE NONE
TRIMETHYLNONYL ETHER
WATER NONE NONE
POLYETHYLENE GLYCOL NONE NONE
ETHYLENE OXIDE NONE 0.1% DE MINIMIS CONCENTRATION
ACETALDEHYDE NONE 0.1% DE MINIMIS CONCENTRATION
1,4-DIOXANE NONE 0.1% DE MINIMIS CONCENTRATION
FORMALDEHYDE NONE 0.1% DE MINIMIS CONCENTRATION
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH
CHEMICALS WITH AND SAFETY REPORTING
SIGNIFICANT NEW USE
RULES (SNURS)
POLYETHYLENE 60828-78-6 NOT APPLICABLE NOT APPLICABLE
GLYCOL
TRIMETHYLNONYL
ETHER
WATER 7732-18-5 NOT APPLICABLE NOT APPLICABLE
POLYETHYLENE 25322-68-3 NOT APPLICABLE NOT APPLICABLE
GLYCOL
ETHYLENE OXIDE 75-21-8 NOT APPLICABLE 10/04/1982 10/04/1992
ACETALDEHYDE 75-07-0 NOT APPLICABLE 09/30/199106/30/1998
1,4-DIOXANE 123-91-1 NOT APPLICABLE NOT APPLICABLE
FORMALDEHYDE 50-00-0 NOT APPLICABLE NOT APPLICABLE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
THE WHMIS 2015 CLASSIFICATION OF THIS PRODUCT HAS NOT BEEN VALIDATED OR
REVIEWED YET.
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
WATER NOT A DANGEROUS PRODUCT ACCORDING TO HPR
7732-18-5 (10) CLASSIFICATION CRITERIA
ETHYLENE OXIDE FLAMMABLE GASES - CATEGORY 1:
75-21-8 (<=0.0020) H220: EXTREMELY FLAMMABLE GAS.
GASES UNDER PRESSURE - LIQUEFIED GAS:
H280:
CONTAINS GAS UNDER PRESSURE, MAY EXPLODE WHEN
HEATED.
ACUTE TOXICITY - INHALATION - CATEGORY 3:
H331: TOXIC IF INHALED.
SKIN CORROSION/IRRITATION - CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION -
CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZERS - CATEGORY 1B:
H334:
MAY CAUSE ALLERGIC OR ASTHMATIC SYMPTOMS OR
BREATHING DIFFICULTIES IF INHALED.
SKIN SENSITIZERS - CATEGORY 1B:
H317: MAY CAUSE ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY - CATEGORY 1B:
H340: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY - CATEGORY 1B:
H350: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY - CATEGORY 1:
H360:
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - CATEGORY 1:
H372:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE.
ACETALDEHYDE FLAMMABLE LIQUIDS - CATEGORY 1:
75-07-0 (<=0.0006) H224: EXTREMELY FLAMMABLE LIQUID AND VAPOUR.
ACUTE TOXICITY - ORAL - CATEGORY 4:
H302: HARMFUL IF SWALLOWED.
SERIOUS EYE DAMAGE/EYE IRRITATION -
CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZERS - CATEGORY 1B:
H317: MAY CAUSE ALLERGIC SKIN REACTION.
CARCINOGENICITY - CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
1,4-DIOXANE FLAMMABLE LIQUIDS - CATEGORY 2:
123-91-1 (<=0.0005) H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
SERIOUS EYE DAMAGE/EYE IRRITATION -
CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
CARCINOGENICITY - CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER.
FORMALDEHYDE FLAMMABLE GASES - CATEGORY 1:
50-00-0 (<=0.0004) H220: EXTREMELY FLAMMABLE GAS.
FLAMMABLE LIQUIDS - CATEGORY 3:
H226:
FLAMMABLE LIQUID AND VAPOUR. (SOLUTION, 37%)
CORROSIVE TO METALS - CATEGORY 1:
H290:
MAY BE CORROSIVE TO METALS. (SOLUTION, 37%)
ACUTE TOXICITY - ORAL - CATEGORY 4:
H302: HARMFUL IF SWALLOWED. (SOLUTION, 37%)
ACUTE TOXICITY - DERMAL - CATEGORY 3:
H311:
TOXIC IN CONTACT WITH SKIN. (SOLUTION, 37%)
ACUTE TOXICITY - INHALATION - CATEGORY 2:
H330: FATAL IF INHALED.
SKIN CORROSION/IRRITATION - CATEGORY 2:
H315: CAUSES SKIN IRRITATION. (SOLUTION, 37%)
SERIOUS EYE DAMAGE/EYE IRRITATION -
CATEGORY 1:
H318:
CAUSES SERIOUS EYE DAMAGE. (SOLUTION, 37%)
SERIOUS EYE DAMAGE/EYE IRRITATION -
CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZERS - CATEGORY 1A:
H317:
MAY CAUSE ALLERGIC SKIN REACTION. (SOLUTION,
37%)
GERM CELL MUTAGENICITY - CATEGORY 2:
H341: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY - CATEGORY 1A:
H350: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY - CATEGORY 1:
H360:
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
(SOLUTION, 37%; CONTAINS 16% OF A SUBSTANCE
THAT IS TOXIC TO REPRODUCTION
(METHYL ALCOHOL))
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - CATEGORY 2:
H371:
MAY CAUSE DAMAGE TO ORGANS. (SOLUTION, 37%)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - CATEGORY 3:
H336:
MAY CAUSE DROWSINESS OR DIZZINESS. (SOLUTION,
37%)
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST
ETHYLENE OXIDE 0.1%
ACETALDEHYDE 1%
1,4-DIOXANE 0.1%
FORMALDEHYDE 0.1%
INVENTORY:
COMPONENTS CAS-NO. CANADA (DSL) CANADA (NDSL)
POLYETHYLENE GLYCOL 60828-78-6 PRESENT NOT LISTED
TRIMETHYLNONYL ETHER
WATER 7732-18-5 PRESENT NOT LISTED
POLYETHYLENE GLYCOL 25322-68-3 PRESENT NOT LISTED
ETHYLENE OXIDE 75-21-8 PRESENT NOT LISTED
ACETALDEHYDE 75-07-0 PRESENT NOT LISTED
1,4-DIOXANE 123-91-1 PRESENT NOT LISTED
FORMALDEHYDE 50-00-0 PRESENT NOT LISTED
COMPONENTS CAS-NO. CEPA SCHEDULE I - TOXIC SUBSTANCES
POLYETHYLENE GLYCOL 60828-78-6 NOT LISTED
TRIMETHYLNONYL ETHER
WATER 7732-18-5 NOT LISTED
POLYETHYLENE GLYCOL 25322-68-3 NOT LISTED
ETHYLENE OXIDE 75-21-8 PRESENT
ACETALDEHYDE 75-07-0 PRESENT
1,4-DIOXANE 123-91-1 NOT LISTED
FORMALDEHYDE 50-00-0 PRESENT
COMPONENTS CAS-NO. CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
POLYETHYLENE GLYCOL 60828-78-6 NOT LISTED
TRIMETHYLNONYL ETHER
WATER 7732-18-5 NOT LISTED
POLYETHYLENE GLYCOL 25322-68-3 NOT LISTED
ETHYLENE OXIDE 75-21-8 NOT LISTED
ACETALDEHYDE 75-07-0 NOT LISTED
1,4-DIOXANE 123-91-1 NOT LISTED
FORMALDEHYDE 50-00-0 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENTS CAS-NO. EU GHS - SV - CLP (1272/2008)
POLYETHYLENE GLYCOL 60828-78-6
TRIMETHYLNONYL ETHER
WATER 7732-18-5
POLYETHYLENE GLYCOL 25322-68-3
ETHYLENE OXIDE 75-21-8 FLAMMABLE GASES - FLAM. GAS 1:
H220: EXTREMELY FLAMMABLE GAS.
GASES UNDER PRESSURE:
H280:
CONTAINS GAS UNDER PRESSURE, MAY
EXPLODE WHEN HEATED.
ACUTE TOXICITY - INHALATION -
ACUTE TOX. 3:
H331:
TOXIC IF INHALED. (MINIMUM
CLASSIFICATION)
SKIN CORROSION/IRRITATION - SKIN
IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE
IRRITATION - EYE IRRIT. 2:
H319:
CAUSES SERIOUS EYE IRRITATION.
GERM CELL MUTAGENICITY -
MUTA. 1B:
H340: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY - CARC. 1B:
H350: MAY CAUSE CANCER.
SPECIFIC TARGET ORGAN TOXICITY -
SINGLE EXPOSURE - STOT SE 3:
H335:
MAY CAUSE RESPIRATORY IRRITATION.
603-023-00-X
ACETALDEHYDE 75-07-0
1,4-DIOXANE 123-91-1 FLAMMABLE LIQUIDS - FLAM. LIQ. 2:
H225:
HIGHLY FLAMMABLE LIQUID AND
VAPOUR.
SERIOUS EYE DAMAGE/EYE
IRRITATION - EYE IRRIT. 2:
H319:
CAUSES SERIOUS EYE IRRITATION.
CARCINOGENICITY - CARC. 2:
H351:
SUSPECTED OF CAUSING CANCER.
SPECIFIC TARGET ORGAN TOXICITY -
SINGLE EXPOSURE - STOT SE 3:
H335:
MAY CAUSE RESPIRATORY IRRITATION.
SUPPLEMENTAL HAZARDS:
EUH019:
MAY FORM EXPLOSIVE PEROXIDES.
SUPPLEMENTAL HAZARDS:
EUH066:
REPEATED EXPOSURE MAY CAUSE SKIN
DRYNESS OR CRACKING. 603-024-00-5
FORMALDEHYDE 50-00-0 ACUTE TOXICITY - ORAL - ACUTE
TOX. 3:
H301:
TOXIC IF SWALLOWED. (MINIMUM
CLASSIFICATION)
ACUTE TOXICITY - DERMAL - ACUTE
TOX. 3:
H311:
TOXIC IN CONTACT WITH SKIN.
(MINIMUM CLASSIFICATION)
ACUTE TOXICITY - INHALATION -
ACUTE TOX. 3:
H331:
TOXIC IF INHALED. (MINIMUM
CLASSIFICATION)
SKIN CORROSION/IRRITATION - SKIN
CORR. 1B:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. (C >=25%; CONCENTRATION
LIMITS FOR ACUTE TOXICITY CANNOT
BE TRANSLATED INTO GHS FROM THE
DSD ESPECIALLY WHEN MINIMUM
CLASSIFICATIONS ARE GIVEN)
SKIN SENSITIZERS - SKIN SENS. 1:
H317:
MAY CAUSE ALLERGIC SKIN REACTION.
(C >= 0.2%; CONCENTRATION
LIMITS FOR ACUTE TOXICITY CANNOT
BE TRANSLATED INTO GHS FROM THE
DSD ESPECIALLY WHEN MINIMUM
CLASSIFICATIONS ARE GIVEN)
GERM CELL MUTAGENICITY - MUTA. 2:
H341:
SUSPECTED OF CAUSING GENETIC
DEFECTS.
CARCINOGENICITY - CARC. 1B:
H350:
MAY CAUSE CANCER. 605-001-00-5
SKIN CORROSION/IRRITATION - SKIN
CORR. 1B:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. (C >= 25%; CONCENTRATION
LIMITS FOR ACUTE TOXICITY CANNOT
BE TRANSLATED INTO GHS FROM THE
DSD ESPECIALLY WHEN MINIMUM
CLASSIFICATIONS ARE GIVEN)
SKIN CORROSION/IRRITATION - SKIN
IRRIT. 2:
H315:
CAUSES SKIN IRRITATION. (5% <=C
<25%; CONCENTRATION LIMITS FOR
ACUTE TOXICITY CANNOT BE
TRANSLATED INTO GHS FROM THE DSD
ESPECIALLY WHEN MINIMUM
CLASSIFICATIONS ARE GIVEN)
SERIOUS EYE DAMAGE/EYE
IRRITATION - EYE IRRIT. 2:
H319:
CAUSES SERIOUS EYE IRRITATION.
(5% <=C <25%; CONCENTRATION
LIMITS FOR ACUTE TOXICITY CANNOT
BE TRANSLATED INTO GHS FROM THE
DSD ESPECIALLY WHEN MINIMUM
CLASSIFICATIONS ARE GIVEN)
SKIN SENSITIZERS - SKIN SENS. 1:
H317:
MAY CAUSE ALLERGIC SKIN REACTION.
(C >=0.2%; CONCENTRATION LIMITS
FOR ACUTE TOXICITY CANNOT BE
TRANSLATED INTO GHS FROM THE DSD
ESPECIALLY WHEN MINIMUM
CLASSIFICATIONS ARE GIVEN)
SPECIFIC TARGET ORGAN TOXICITY -
SINGLE EXPOSURE - STOT SE 3:
H335:
MAY CAUSE RESPIRATORY IRRITATION.
(C >=5%; CONCENTRATION LIMITS
FOR ACUTE TOXICITY CANNOT BE
TRANSLATED INTO GHS FROM THE DSD
ESPECIALLY WHEN MINIMUM
CLASSIFICATIONS ARE GIVEN)
605-001-00-5
EU - CLP (1272/2008):
R-PHRASE(S):
R38: IRRITATING TO SKIN.
R41: RISK OF SERIOUS DAMAGE TO EYES.
S-PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S37: WEAR SUITABLE GLOVES.
S39: WEAR EYE/FACE PROTECTION.
COMPONENTS CAS-NO. CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
POLYETHYLENE 60828-78-6 NO INFORMATION
GLYCOL
TRIMETHYLNONYL
ETHER
WATER 7732-18-5 NO INFORMATION
POLYETHYLENE 25322-68-3 NO INFORMATION
GLYCOL
ETHYLENE OXIDE 75-21-8 F+; R12 NO INFORMATION S: 53-45
T; R23
XI; R36/37/38
CARC. CAT. 2;
R45
MUTA. CAT. 2;
R46 R6
ACETALDEHYDE 75-07-0 F+; R12 NO INFORMATION S2 S16 S33
XI; R36/37 S36/37
CARC. CAT. 3;
R40
1,4-DIOXANE 123-91-1 F; R11-19 NO INFORMATION S2 S9 S16
XI; R36/37 S36/37 S46
CARC. CAT. 3;
R40 R66
FORMALDEHYDE 50-00-0 T; R23/24/25 0.2% <=C <1% S(1/2)-
C; R34 XI; R43 S26-S36/37/39-
CARC.CAT.2; 1% <=C <5% S45-S51
R45 XN; R40-43
R43 25% <=C
MUTA. CAT. 3; T; R23/24/25-
R68 34-40-43
5% <=C <25%
XN; R20/21/22-
36/37/3
8-40-43
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XI: IRRITANT.
XI: HARMFUL OR IRRITANT
| 16. OTHER INFORMATION | |
PREPARATION DATE: 6/16/2016
REVISION DATE: 10/17/2018
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
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