| Common Name: | CHLOROFORM |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 1/22/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39H219 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 1/23/2014
REVISION DATE: 1/22/2019
REVISION NUMBER: G3
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: C1121
PRODUCT NAME: CHLOROFORM
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
CHLOROFORME (FRENCH)
CHLOROFORMO (TRICLOROMETANO) (SPANISH)
FORMYL TRICHLORIDE
METHANE TRICHLORIDE
METHANE, TRICHLORO-
METHENYL CHLORIDE
METHENYL TRICHLORIDE
METHYL TRICHLORIDE
TRICHLOROFORM
TRICHLOROMETHANE
CAS #: 67-66-3
RTECS #: FS9100000
CI #: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: SOLVENT. CHEMICAL INTERMEDIATE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: TOM TYNER (USA - WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (USA - EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
LABEL ELEMENTS:
WARNING:
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
SUSPECTED OF CAUSING CANCER
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
EXCLAMATION MARK
HEALTH HAZARD
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: HARMFUL TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS - PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
WEAR EYE/FACE PROTECTION
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF SWALLOWED:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL RINSE MOUTH
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO WEIGHT-%
CHLOROFORM 67-66-3 99-99.5
ETHYL ALCOHOL 200 PROOF 64-17-5 0.5-1
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SYMPTOMS
PERSIST, CALL A PHYSICIAN.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES SERIOUS EYE IRRITATION
MODERATE EYE IRRITATION
CAUSES SKIN IRRITATION
MODERATE SKIN IRRITATION
IRRITATING TO RESPIRATORY SYSTEM
CENTRAL NERVOUS SYSTEM EFFECTS
DROWSINESS
DIZZINESS
ATAXIA
FATIGUE
HEADACHE
NARCOSIS
MAY CAUSE CARDIOVASCULAR EFFECTS
MAY AFFECT RESPIRATION
NAUSEA
VOMITING
IT MAY AFFECT THE KIDNEYS
MAY AFFECT THE LIVER
MAY CAUSE DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH THE
FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS:
CHLOROFORM DOES NOT BURN, BUT MAY DECOMPOSE UPON HEATING TO PRODUCE THE
FOLLOWING IF INVOLVED IN A FIRE: CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN
CHLORIDE AND CHLORINE.
SPECIFIC HAZARDS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN,
EYES AND CLOTHING. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL
UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. ABSORB SPILL WITH INERT MATERIAL
(E.G. VERMICULITE, DRY SAND OR EARTH).
METHODS FOR CLEANING UP:
USE APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL
WASTE DISPOSAL CONTAINER. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT BREATHE VAPORS OR SPRAY MIST. DO NOT INGEST. HANDLE IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. PROTECT FROM LIGHT. SENSITIVE
TO LIGHT. STORE IN LIGHT-RESISTANT CONTAINERS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
ACIDS
ALKALIS
ALUMINUM
POTASSIUM T-BUTOXIDE
ALKALI METALS
LITHIUM
SODIUM
POTASSIUM
ALKALINE EARTH METALS
MAGNESIUM SULFATE
CHLOROFORM REACTS VIOLENTLY WITH OR MAY EXPLODE IF IT COMES IN CONTACT WITH
THE FOLLOWING:
PERCHLORIC ACID + METHANOL; SODIUM + METHANOL; SODIUM METHYLATE + METHANOL;
SODIUM HYDROXIDE + METHANOL; ACETONE; CARBON TETRACHLORIDE; DISILANE;
NITROGEN TETROXIDE; SODIUM METHYLATE; SODIUM-POTASSIUM ALLOY; TRIISOPROPYL
PHOSPHINE; 2-NITROPHENYLACETYL CHLORIDE; PERCHLORIC ACID + PHOSPHORUS
PENTOXIDE
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENT CAS NO OSHA NIOSH ACGIH AIHA WEEL
CHLOROFORM 67-66-3 50 PPM 2 PPM STEL 10 PPM TWA NONE
CEILING
240 MG/M3 9.78 MG/M3
CEILING STEL
ETHYL ALCOHOL 64-17-5 1000 PPM 1000 PPM TWA 1000 PPM NONE
200 PROOF TWA STEL
1900 MG/M3 1900 MG/M3
TWA TWA
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
CHLOROFORM 67-66-3 10 PPM TWA 2 PPM TWA NONE NONE
49 MG/M3 TWA
ETHYL ALCOHOL 64-17-5 1000 PPM TWA 1000 PPM STEL 1000 PPM NONE
200 PROOF 1880 MG/M3 TWA STEL
AUSTRALIA AND MEXICO:
COMPONENT CAS NO AUSTRALIA MEXICO
CHLOROFORM 67-66-3 2 PPM TWA 10 PPM TWA
10 MG/M3 TWA 50 MG/M3 TWA
50 PPM STEL
225 MG/M3 STEL
ETHYL ALCOHOL 200 PROOF 64-17-5 1000 PPM TWA 1000 PPM TWA
1880 MG/M3 TWA 1900 MG/M3 TWA
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE
AIRBORNE CONCENTRATIONS OF VAPORS AND MIST BELOW THEIR RESPECTIVE THRESHOLD
LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
LONG SLEEVED CLOTHING
GLOVES
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS AND FACE BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING
THE PRODUCT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: NO INFORMATION AVAILABLE.
ODOR: PLEASANT. ETHERIC. NON-IRRITATING.
TASTE: SWEET.
FORMULA: CHCl3
MOLECULAR/FORMULA WEIGHT (G/MOLE): 119.38
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLASHPOINT (DEG. C / DEG. F): NO INFORMATION AVAILABLE
FLASH POINT TESTED ACCORDING TO: NOT APPLICABLE
AUTOIGNITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C / DEG. F): -64 TO -63 DEG. C/-83.26-81.4 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C / DEG. F): 61-62 DEG. C/141.8-143.6 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): 1.48-1.49
SPECIFIC GRAVITY:
1.484 @ 20 DEG. C
1.476-1.488 @ 25 DEG. C
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA):
21.2-21.3 @ 20 DEG. C
26.3 @ 25 DEG. C.
EVAPORATION RATE: 11.6 (BUTYL ACETATE = 1)
VAPOR DENSITY: 4.12-4.36
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): 85
PARTITION COEFFICIENT (N-OCTANOL/WATER):
LOG KOW: 1.97
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY:
MISCIBLE WITH CARBON DISULFIDE
MISCIBLE WITH CARBON TETRACHLORIDE
MISCIBLE WITH BENZENE
MISCIBLE WITH ALCOHOL
MISCIBLE WITH ACETONE
MISCIBLE WITH PETROLEUM ETHER
MISCIBLE WITH MANY ORGANIC SOLVENTS
MISCIBLE WITH ETHER
SOLUBILITY:
SLIGHTLY SOLUBLE IN WATER
SOLUBLE IN ETHER
SOLUBLE IN BENZENE
SOLUBLE IN HOT ALCOHOL
SOLUBLE IN ACETONE
SOLUBLE IN CARBON TETRACHLORIDE
SOLUBLE IN ORGANIC SOLVENTS
SOLUBLE IN PETROLEUM ETHER
SOLUBLE IN CARBON DISULFIDE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTIVE WITH OXIDIZING AGENTS
REACTIVE WITH ACIDS
REACTIVE WITH ALKALIS
REACTS WITH ALKALI METALS
REACTS WITH ALKALINE EARTH METALS
CHLOROFORM REACTS VIOLENTLY WITH OR MAY EXPLODE IF IT COMES IN CONTACT WITH
THE FOLLOWING:
PERCHLORIC ACID + METHANOL; SODIUM + METHANOL; SODIUM METHYLATE + METHANOL;
SODIUM HYDROXIDE + METHANOL; ACETONE; CARBON TETRACHLORIDE; DISILANE;
NITROGEN TETROXIDE; SODIUM METHYLATE; SODIUM-POTASSIUM ALLOY; TRIISOPROPYL
PHOSPHINE; 2-NITROPHENYLACETYL CHLORIDE; PERCHLORIC ACID + PHOSPHORUS
PENTOXIDE
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: HEAT. EXPOSURE TO LIGHT. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
ACIDS
ALKALIS
ALUMINUM
POTASSIUM T-BUTOXIDE
ALKALI METALS
LITHIUM
SODIUM
POTASSIUM
ALKALINE EARTH METALS
MAGNESIUM SULFATE
CHLOROFORM REACTS VIOLENTLY WITH OR MAY EXPLODE IF IT COMES IN CONTACT WITH
THE FOLLOWING:
PERCHLORIC ACID + METHANOL; SODIUM + METHANOL; SODIUM METHYLATE + METHANOL;
SODIUM HYDROXIDE + METHANOL; ACETONE; CARBON TETRACHLORIDE; DISILANE;
NITROGEN TETROXIDE; SODIUM METHYLATE; SODIUM-POTASSIUM ALLOY; TRIISOPROPYL
PHOSPHINE; 2-NITROPHENYLACETYL CHLORIDE; PERCHLORIC ACID + PHOSPHORUS
PENTOXIDE
HAZARDOUS DECOMPOSITION PRODUCTS:
HYDROGEN CHLORIDE GAS. CHLORINE. CARBON DIOXIDE. CARBON MONOXIDE.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE:
INHALATION. INGESTION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
CHLOROFORM:
CAS NO: 67-66-3
LD50/ORAL/RAT:
450 MG/KG ORAL LD50 RAT
695 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE:
36 MG/KG (RTECS)
36-460 MG/KG (EUROPEAN COMMISSION IUCLID DATASET)
353-1366 MGKG (EUROPEAN COMMISSION IUCLID DATASET)
LD50/DERMAL/RABBIT:
>20 G/KG DERMAL LD50 RABBIT
>3980 MG/KG (LOLI; EUROPEAN COMMISSION IUCLID DATASET)
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 47702 MG/M3 INHALATION LC50 RAT 4 H
LC50/INHALATION/MOUSE:
17200 MG/M3 2 H
6000 MG/M3 6 H
OTHER LD50 OR LC50 INFORMATION: 820 MG/KG ORAL LD50 GUINEA PIG
ETHYL ALCOHOL 200 PROOF:
CAS NO: 64-17-5
LD50/ORAL/RAT: 7060 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: 3450 MG/KG ORAL LD50 MOUSE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 124.7 MG/L INHALATION LC50 RAT 4 H
LC50/INHALATION/MOUSE: 39000 MG/M3 4 H
OTHER LD50 OR LC50 INFORMATION:
>60000 PPM INHALATION LC50 MOUSE 1 H
5900 MG/M3 INHALATION LC50 RAT 6 H
20000 PPM INHALATION LC50 RAT 10 H
5560 MG/KG ORAL LD50 GUINEA PIG
6300 MG/KG ORAL LD50 RABBIT
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX: 695 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: 353-1366 MG/KG
LD50/DERMAL/RABBIT:
VALUE - ACUTE TOX: >3980 MG/KG
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: 47.7 MG/L (4-HR)
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR:
17200 MG/M3 2 H
6000 MG/M3 6 H
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
CAUSES SKIN IRRITATION. MILDLY TO HIGHLY IRRITATING. IT MAY BE ABSORBED
THROUGH THE SKIN.
EYE CONTACT:
CAUSES EYE IRRITATION. MODERATELY IRRITATING TO THE EYES. CAUSES
CONJUNCTIVITIS. MAY CAUSE REVERSIBLE EYE DAMAGE.
INHALATION:
IRRITATING TO RESPIRATORY SYSTEM. MAY CAUSE NAUSEA, VOMITING. MAY CAUSE
SALIVATION. MAY CAUSE DRY MOUTH, THIRST. MAY CAUSE DIZZINESS AND HEADACHE.
INHALATION OF HIGH CONCENTRATIONS OF VAPOR MAY CAUSE ANESTHETIC EFFECTS.
MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (EXCITATON, FOLLOWED BY CENTRAL
NERVOUS SYSTEM DEPRESSION, NERVOUSNESS, IRRITABILITY, HALUCINATIONS,
DELIRUM, EUPHORIA, APATHY, ATAXIA, LOSS OF JUDGEMENT, DISORIENTATON,
INEBRIATION, FATIGUE, LASSITUDE, MENTAL DULLNESS, WEAKNESS, NARCOSIS,
FAINTING SENSATION, UNCONCIOUSNESS (ANESTHESIA), COMA). IT MAY AFFECT THE
CARDIOVASCULAR SYSTEM (HYPOTENSION, CARDIAC ARRHYTHMIAS, CARDIAC ARREST).
MAY AFFECT RESPIRATION (RESPIRATORY DEPRESSION). MAY AFFECT RESPIRATION
(ANOXIA, INCREASE IN RATE AND DEPTH OF RESPIRATION). MAY CAUSE ANOREXIA. IT
MAY AFFECT THE LIVER. MAY AFFECT THE KIDNEYS. MAY PRODUCE A SENSATION OF
BODILY WARMTH. MAY CAUSE PUPILARY DILATION WITH DECREASED REACTION TO
LIGHT.
INGESTION:
HARMFUL IF SWALLOWED. CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION.
IT CAUSES IRRITATION OR A BURNING SENSATION OF THE MOUTH AND THROAT. MAY
AFFECT URINARY SYSTEM (KIDNEYS). MAY AFFECT LIVER. IT MAY AFFECT THE BLOOD
(LEUKOCYTOSIS, FALL IN THE PLAMSA PROTHROMBIN LEVEL AND AN INCREASE IN TIME
FOR THE BLOOD TO CLOT).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED OR REPEATED INHALATION MAY CAUSE PEUMOCONIOSIS. PROLONGED OR
REPEATED INHALATION MAY CAUSE DRY MOUTH, THIRST, GASTROENTERITIS, NAUSEA,
VOMITING, DIARRHEA, LOSS OF APPETITE OR ANOREXIA, WEIGHT LOSS. PROLONGED OR
REPEATED INHALATION MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (HEADACHE,
HALLUCINATIONS, ATAXIA, LOSS OF REFLEXES, PSYCHOTIC BEHAVIOR, DYSARTHRIA
(MOTOR SPEECH DISORDER)), AND CAUSE DEGENERATIVE CHANGES OF THE BRAIN.
PROLONGED OR REPEATED INHALATION MAY AFFECT THE LIVER. PROLONGED OR
REPEATED INHALATION MAY AFFECT THE KIDNEYS. PROLONGED OR REPEATED
INHALATION MAY AFFECT THE HEART. PROLONGED OR REPEATED INGESTION MAY AFFECT
THE LIVER, AND KIDNEYS. PROLONGED OR REPEATED INGESTION MAY CAUSE LOSS OF
APPETITE. PROLONGED OR REPEATED INGESTION MAY CAUSE WEIGHT LOSS. PROLONGED
OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS AND DEFATTING, DRYNESS, AND
CRACKING OF THE SKIN. PROLONGED OR REPEATED INHALATION MAY AFFECT THE BLOOD
(CHANGES IN WHITE BLOOD CELL COUNT). PROLONGED OR REPEATED INHALATION MAY
AFFECT THE BLOOD (CHANGE IN CLOTTING FACTORS). PROLONGED OR REPEATED
INHALATION MAY AFFECT THE SPLEEN. PROLONGED OR REPEATED INHALATION MAY
CAUSE HYPERGLYCEMIA. PROLONGED OR REPEATED INHALATION MAY CAUSE KETOSIS
(KETONE BODIES FORMED IN THE BLOOD WHEN LIVER GLYCOGEN STORES ARE
DEPLETED).
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
MUTATIONS IN MICROORGANISMS
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
MUTAGENIC EFFECTS IN MAMMALIAN SOMATIC CELLS
ANIMAL EXPERIMENTS SHOWED MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS:
MAY CAUSE CANCER BASED ON ANIMAL TEST DATA. LIMITED EVIDENCE OF A
CARCINOGENIC EFFECT. POSSIBLY CARCINOGENIC TO HUMANS.
COMPONENT CAS NO IARC ACGIH - NTP
CARCINOGENS
CHLOROFORM 67-66-3 GROUP 2B - A3 CONFIRMED REASONABLY
POSSIBLY ANIMAL ANTICIPATED TO
CARCINOGENIC TO CARCINOGEN BE A HUMAN
HUMANS - WITH UNKNOWN CARCINOGEN
MONOGRAPH 73 RELEVANCE TO
[1999] HUMANS
ETHYL ALCOHOL 64-17-5 GROUP 1 - A3 CONFIRMED NOT LISTED
200 PROOF MONOGRAPH ANIMAL
100E [2012] IN CARCINOGEN
ALCOHOLIC WITH UNKNOWN
BEVERAGES RELEVANCE TO
MONOGRAPH 96 HUMANS
[2010] IN
ALCOHOLIC
BEVERAGES
COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
CHLOROFORM PRESENT NOT LISTED NOT LISTED
ETHYL ALCOHOL 200 PROOF PRESENT NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT OF
LABOR)
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS:
MAY CAUSE ADVERSE DEVELOPMENTAL EFFECTS
POSSIBLE RISK OF HARM TO THE UNBORN CHILD
TERATOGENIC EFFECTS:
MAY CAUSE BIRTH DEFECTS (TERATOGENIC EFFECTS) BASED ON ANIMAL TEST DATA
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: RESPIRATORY SYSTEM. CENTRAL NERVOUS SYSTEM.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
TARGET ORGANS:
CENTRAL NERVOUS SYSTEM. RESPIRATORY SYSTEM. KIDNEYS. LIVER. SKIN. HEART.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
CHLOROFORM - 67-66-3:
ALGAE/AQUATIC PLANTS: 560 MG/L EC50 DESMODESMUS SUBSPICATUS 48 H
FISH:
71 MG/L LC50 PIMEPHALES PROMELAS 96 H FLOW-THROUGH 1
18 MG/L LC50 ONCORHYNCHUS MYKISS 96 H FLOW-THROUGH 1
18 MG/L LC50 LEPOMIS MACROCHIRUS 96 H FLOW-THROUGH 1
300 MG/L LC50 POECILIA RETICULATA 96 H STATIC 1
CRUSTACEA: 29 MG/L EC50 DAPHNIA MAGNA 48 H
ETHYL ALCOHOL 200 PROOF - 64-17-5:
FISH:
12.0 - 16.0 ML/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
100 MG/L LC50 PIMEPHALES PROMELAS 96 H STATIC 1
13400 - 15100 MG/L LC50 PIMEPHALES PROMELAS 96 H FLOW-THROUGH 1
CRUSTACEA:
9268 - 14221 MG/L LC50 DAPHNIA MAGNA 48 H
2 MG/L EC50 DAPHNIA MAGNA 48 H
10800 MG/L EC50 DAPHNIA MAGNA 24 H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENT CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
CHLOROFORM 67-66-3 NONE NONE NONE U044
ETHYL ALCOHOL 200 PROOF 64-17-5 NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1888
PROPER SHIPPING NAME: CHLOROFORM
HAZARD CLASS: 6.1
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: III
EMERGENCY RESPONSE GUIDE NUMBER: 151
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: IB3, N36, T7, TP2
SYMBOL(S):
[DOT]:
(R2) - IDENTIFIES A MATERIAL THAT IS A HAZARDOUS SUBSTANCE THAT HAS A
REPORTABLE QUANTITY (RQ) OF 10 POUNDS (4.54 KILOGRAMS).
DESCRIPTION: UN1888, CHLOROFORM, 6.1, III
TDG (CANADA):
UN-NO: UN1888
PROPER SHIPPING NAME: CHLOROFORM
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: UN1888, CHLOROFORM, 6.1, III
ADR:
UN NUMBER: UN1888
PROPER SHIPPING NAME: CHLOROFORM
TRANSPORT HAZARD CLASS(ES): 6.1
PACKING GROUP: III
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: UN1888, CHLOROFORM, 6.1, III
IMDG:
UN-NO: UN1888
PROPER SHIPPING NAME: CHLOROFORM
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
DESCRIPTION: UN1888, CHLOROFORM, 6.1, III
RID:
UN NUMBER: UN1888
PROPER SHIPPING NAME: CHLOROFORM
TRANSPORT HAZARD CLASS(ES): 6.1
SUBSIDIARY RISK: 6.1
PACKING GROUP: III
DESCRIPTION: UN1888, CHLOROFORM, 6.1, III
ICAO (AIR):
UN-NO: UN1888
PROPER SHIPPING NAME: CHLOROFORM
HAZARD CLASS: 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION: UN1888, CHLOROFORM, 6.1, III
IATA:
UN NUMBER: UN1888
PROPER SHIPPING NAME: CHLOROFORM
TRANSPORT HAZARD CLASS(ES): 6.1
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
PRECAUTIONARY STATEMENTS - RESPONSE: 6A
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1888, CHLOROFORM, 6.1, III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENT CAS NO U.S. TSCA KOREA KECL PHILIPPINES (PICCS)
CHLOROFORM 67-66-3 PRESENT ACTIVE PRESENT PRESENT
KE-34076
ETHYL ALCOHOL 64-17-5 PRESENT KE-13217 PRESENT
200 PROOF (ACTIVE)
COMPONENT JAPAN ENCS CHINA AUSTRALIA EINECS-NO.
IECSC AICS
CHLOROFORM PRESENT (2)-37 PRESENT PRESENT PRESENT
200-663-8
ETHYL ALCOHOL 200 PROOF (2)-202 PRESENT PRESENT PRESENT
200-578-6
U.S. REGULATIONS:
CHLOROFORM:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0388
NEW JERSEY (EHS) LIST: 0388 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
NEW JERSEY TCPA - EHS: 20000 LB TQ
PENNSYLVANIA RTK:
ENVIRONMENTAL HAZARD
SPECIAL HAZARDOUS SUBSTANCE
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
PENNSYLVANIA RTK - SPECIAL HAZARDOUS SUBSTANCES: PRESENT
MICHIGAN - CRITICAL MATERIALS LIST: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
10 LB RQ
1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
10 LB FINAL RQ
4.54 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
175.105, 177.1580, 177.1585
ETHYL ALCOHOL 200 PROOF:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0844
PENNSYLVANIA RTK: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
PRESENT (LISTED AS VOLATILE ORGANIC COMPOUNDS)
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1293
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
169.175, 169.176, 169.177, 169.181, 172.340, 172.560, 172.580, 175.105,
176.180, 176.200, 177.1200, 177.1650, 178.1010, 184.1293, 73.30, 73.345,
73.615
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING (SEE TABLE BELOW) WHICH
IS (ARE) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE
INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING (SEE TABLE BELOW) WHICH
IS (ARE) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
COMPONENT CAS NO
CHLOROFORM 67-66-3
ETHYL ALCOHOL 200 PROOF 64-17-5
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
CHLOROFORM CARCINOGEN DEVELOPMENTAL NOT LISTED NOT LISTED
TOXICITY
ETHYL ALCOHOL CARCINOGEN DEVELOPMENTAL NOT LISTED NOT LISTED
200 PROOF (ETHANOL IN TOXICITY
ALCOHOLIC (ETHYL ALCOHOL
BEVERAGES) IN ALCOHOLIC
BEVERAGES)
CERCLA/SARA:
COMPONENTS CAS NO CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY EXTREMELY
THEIR REPORTABLE HAZARDOUS HAZARDOUS
QUANTITIES SUBSTANCES AND SUBSTANCES AND
TPQS RQS
CHLOROFORM 67-66-3 10 LB FINAL RQ 10 LB EPCRA RQ NONE
4.54 KG FINAL RQ
ETHYL ALCOHOL 64-17-5 NONE NONE NONE
200 PROOF
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
CHLOROFORM NONE 0.1 % DE MINIMIS CONCENTRATION
ETHYL ALCOHOL NONE NONE
200 PROOF
U.S. TSCA:
COMPONENT CAS NO TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH AND
CHEMICALS WITH SAFETY REPORTING
SIGNIFICANT NEW USE
RULES (SNURS)
CHLOROFORM 67-66-3 NOT APPLICABLE NOT APPLICABLE
ETHYL ALCOHOL 64-17-5 NOT APPLICABLE NOT APPLICABLE
200 PROOF
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
CHLOROFORM ACUTE TOXICITY - ORAL - CATEGORY 4:
67-66-3 (99-99.5) H302: HARMFUL IF SWALLOWED.
ACUTE TOXICITY - INHALATION - CATEGORY 3:
H331: TOXIC IF INHALED.
SKIN CORROSION/IRRITATION - CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
CARCINOGENICITY - CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER.
REPRODUCTIVE TOXICITY - CATEGORY 2:
H361:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN
CHILD.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - CATEGORY 1:
H372:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE.
ETHYL ALCOHOL 200 PROOF FLAMMABLE LIQUIDS - CATEGORY 2:
64-17-5 (0.5-1) H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
SERIOUS EYE DAMAGE/EYE IRRITATION -
CATEGORY 2B:
H320: CAUSES EYE IRRITATION.
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
DSL/NDSL:
COMPONENT CAS NO CANADA (DSL) CANADA (NDSL)
CHLOROFORM 67-66-3 PRESENT NOT LISTED
ETHYL ALCOHOL 200 PROOF 64-17-5 PRESENT NOT LISTED
COMPONENT CAS NO CEPA SCHEDULE I - TOXIC SUBSTANCES
CHLOROFORM 67-66-3 NOT LISTED
ETHYL ALCOHOL 200 PROOF 64-17-5 NOT LISTED
COMPONENT CAS NO CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
CHLOROFORM 67-66-3 NOT LISTED
ETHYL ALCOHOL 200 PROOF 64-17-5 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENT CAS NO EU GHS - SV - CLP (1272/2008)
CHLOROFORM 67-66-3 ACUTE TOXICITY - ORAL - ACUTE TOX. 4:
H302:
HARMFUL IF SWALLOWED. (MINIMUM
CLASSIFICATION)
ACUTE TOXICITY -INHALATION - ACUTE
TOX. 3:
H331: TOXIC IF INHALED.
SKIN CORROSION/IRRITATION - SKIN
IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION -
EYE IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
CARCINOGENICITY - CARC. 2:
H351: SUSPECTED OF CAUSING CANCER.
REPRODUCTIVE TOXICITY - REPR. 2:
H361D:
SUSPECTED OF DAMAGING THE UNBORN
CHILD.
SPECIFIC TARGET ORGAN TOXICITY -
REPEATED EXPOSURE - STOT RE 1:
H372:
CAUSES DAMAGE TO ORGANS THROUGH
PROLONGED OR REPEATED
EXPOSURE. 602-006-00-4
ETHYL ALCOHOL 200 PROOF 64-17-5 FLAMMABLE LIQUIDS - FLAM. LIQ. 2:
H225:
HIGHLY FLAMMABLE LIQUID AND
VAPOUR. 603-002-00-5
EU - CLP (1272/2008):
R-PHRASE(S):
R40: LIMITED EVIDENCE OF A CARCINOGENIC EFFECT
R63: POSSIBLE RISK OF HARM TO THE UNBORN CHILD
R20/22: HARMFUL BY INHALATION AND IF SWALLOWED
R48/20:
HARMFUL:
DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE THROUGH INHALATION
R36/38: IRRITATING TO EYES AND SKIN
S-PHRASE(S):
S2: KEEP OUT OF THE REACH OF CHILDREN.
S36/37: WEAR SUITABLE PROTECTIVE CLOTHING AND GLOVES
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
CHLOROFORM 67-66-3 XN; R20/22-48/20 5%<=C XN; R22 S: (2)-36/37
XI; R36/38 5%<=C XN;
CARC. CAT. 3; R40 R48/20/22
REPR.CAT.3; R63
ETHYL ALCOHOL 64-17-5 F; R11 NO INFORMATION S (2) S7 S16
200 PROOF
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XN: HARMFUL
XI: IRRITANT
XN: HARMFUL OR IRRITANT
XI: HARMFUL OR IRRITANT
| 16. OTHER INFORMATION | |
PREPARATION DATE: 1/23/2014
REVISION DATE: 1/22/2019
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.