| Common Name: | CYCLOHEXANE, PRACTICAL |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 7/17/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39H227 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(TM)
CHEMICAL MFG CORP
S
ISO 9001-2008 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 6/29/15
REVISION DATE: 07/17/2019
REVISION NUMBER: G2
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: C1456
PRODUCT NAME: CYCLOHEXANE, PRACTICAL
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
BENZENE, HEXAHYDRO-
HEXAHYDROBENZENE
HEXAMETHYLENE
HEXANAPHTHENE
CICLOHEXANO (SPANISH)
CAS #: 110-82-7
RTECS #: GU6300000
CI #: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: SOLVENT.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: TOM TYNER (USA - WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (USA - EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - INHALATION (VAPORS): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
ASPIRATION TOXICITY: CATEGORY 1
FLAMMABLE LIQUIDS: CATEGORY 2
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
HARMFUL IF INHALED
CAUSES SKIN IRRITATION
CAUSES EYE IRRITATION
MAY CAUSE DROWSINESS OR DIZZINESS
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
HIGHLY FLAMMABLE LIQUID AND VAPOR
EXCLAMATION MARK
HEALTH HAZARD
FLAME
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
AVOID BREATHING MIST OR VAPORS
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
KEEP COOL
WEAR PROTECTIVE GLOVES
WEAR EYE/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM TO EXTINGUISH.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN
DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT IN
ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS AS
APPLICABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO WEIGHT-%
CYCLOHEXANE 110-82-7 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION
OCCURS.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. CONSULT A PHYSICIAN IF NECESSARY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES SKIN IRRITATION
CAUSES EYE IRRITATION
MAY CAUSE DROWSINESS OR DIZZINESS
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER THE LUNGS AND CAUSE DAMAGE
MAY CAUSE DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION
INGESTION MAY CAUSE NAUSEA, VOMITING, AND DIARRHEA
MAY CAUSE CHEMICAL PNEUMONITIS
CENTRAL NERVOUS SYSTEM EFFECTS
IT MAY AFFECT THE KIDNEYS
MAY AFFECT THE LIVER
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2). DRY CHEMICAL. WATER SPRAY MIST OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID (STRAIGHT) WATER STREAM AS IT MAY SCATTER AND SPREAD
FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE (CO2).
SPECIFIC HAZARDS:
HIGHLY FLAMMABLE. MAY BE IGNITED BY HEAT, SPARKS OR FLAMES. CONTAINER
EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED. VAPOR MAY TRAVEL
CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. VAPORS MAY FORM
EXPLOSIVE MIXTURES WITH AIR. MOST VAPORS ARE HEAVIER THAN AIR. THEY WILL
SPREAD ALONG THE GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
ASEMENTS, TANKS). FIRE MAY PRODUCE IRRITATING, CORROSIVE AND/OR TOXIC
GASES.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. USE PERSONAL
PROTECTIVE EQUIPMENT. REMOVE ALL SOURCES OF IGNITION. PAY ATTENTION TO
FLASHBACK. ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED.
USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT. IN CASE OF LARGE
SPILL, WATER SPRAY OR VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS,
BUT MAY NOT PREVENT IGNITION IN CLOSED SPACES.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT PRODUCT FROM
ENTERING DRAINS. DO NOT LET THIS CHEMICAL ENTER THE ENVIRONMENT. PREVENT
ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. ABSORB SPILL WITH INERT MATERIAL
(E.G. VERMICULITE, DRY SAND OR EARTH). IN CASE OF LARGE SPILL, DIKE IF
NEEDED. DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
USE APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL
WASTE DISPOSAL CONTAINER. USE ONLY NON-SPARKING TOOLS. CLEAN CONTAMINATED
SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. REMOVE ALL
SOURCES OF IGNITION. TO AVOID IGNITION OF VAPORS BY STATIC ELECTRICITY
DISCHARGE, ALL METAL PARTS OF THE EQUIPMENT MUST BE GROUNDED. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. USE ONLY IN WELL-VENTILATED AREAS.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. KEEP AWAY FROM HEAT AND SOURCES
OF IGNITION. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. DO NOT
BREATHE VAPORS OR SPRAY MIST. DO NOT INGEST. WHEN USING DO NOT SMOKE.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. KEEP AWAY FROM HEAT AND SOURCES
OF IGNITION. STORE IN A SEGREGATED AND APPROVED AREA. STORE AWAY FROM
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
DINITROGEN TETRAOXIDE
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENT CAS NO OSHA NIOSH ACGIH AIHA WEEL
CYCLOHEXANE 110-82-7 300 PPM TWA 300 PPM TWA 100 PPM TWA NONE
1050 MG/M3 TWA 1050 MG/M3 TWA
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
CYCLOHEXANE 110-82-7 100 PPM TWA 100 PPM TWA NONE NONE
344 MG/M3 TWA
AUSTRALIA AND MEXICO:
COMPONENT CAS NO AUSTRALIA MEXICO
CYCLOHEXANE 110-82-7 300 PPM STEL 100 PPM TWA
1050 MG/M3 STEL
100 PPM TWA
350 MG/M3 TWA
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST
BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
LONG SLEEVED CLOTHING
GLOVES
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: CLEAR. COLORLESS.
ODOR:
TASTE:
FORMULA: C6-H12
MOLECULAR/FORMULA WEIGHT (G/MOLE): 84.16
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLASHPOINT (DEG. C / DEG. F): -18 TO -20 DEG. C / -0.4 TO 4 DEG. F
FLASH POINT TESTED ACCORDING TO: CLOSED CUP
AUTOIGNITION TEMPERATURE (DEG. C / DEG. F): 245 DEG. C/473 DEG. F
LOWER EXPLOSION LIMIT (%): 1.3%
UPPER EXPLOSION LIMIT (%): 8.4%
MELTING POINT/RANGE (DEG. C / DEG. F): 6.47 DEG. C/43.6 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C / DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C / DEG. F): 80.7 DEG. C/177.3 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): 0.779-0.784 @ 20 DEG. C
SPECIFIC GRAVITY: 0.7781
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): 10.3-12.9
EVAPORATION RATE:
6.1 (BUTYL ACETATE = 1)
2.6 (ETHER = 1)
VAPOR DENSITY: 2.98
VOC CONTENT (G/L): 778-784
ODOR THRESHOLD (PPM): 25
PARTITION COEFFICIENT (N-OCTANOL/WATER): 3.44
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: MISCIBLE WITH OLIVE OIL
SOLUBILITY:
INSOLUBLE IN WATER
SOLUBLE IN ETHER
SOLUBLE IN HOT ALCOHOL
SOLUBLE IN ACETONE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
IT CAN REACT VIGOROUSLY, VIOLENTLY OR EXPLOSIVELY WITH OXIDIZERS
WHEN MIXED HOT WITH LIQUID DINITROGEN TETRAOXIDE AN EXPLOSION CAN RESULT
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: HEAT. IGNITION SOURCES. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
DINITROGEN TETRAOXIDE
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. WHEN HEATED TO DECOMPOSITION IT EMITS
ACRID SMOKE AND IRRITATING FUMES.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. SKIN. INHALATION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
CYCLOHEXANE:
CAS NO: 1110-82-7
LD50/ORAL/RAT:
12705 MG/KG ORAL LD50 RAT(LOLI)
>5000 MG/KG (RTECS)
LD50/ORAL/MOUSE: 813 MG/KG
LD50/DERMAL/RABBIT: >2000 MG/KG DERMAL LD50RABBIT
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 13.9 MG/L INHALATION LC50 RAT 4 H
LC50/INHALATION/MOUSE: 70000 MG/M3 2 H
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOXICITY: >5000 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX: 813 MG/KG
LD50/DERMAL/RABBIT:
VALUE - ACUTE TOXICITY: >2000 MG/KG
LD50/DERMAL/RAT:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: 13.9 MG/L (4-HR)
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: 70000 MG/M3 2 H
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT: CAUSES SKIN IRRITATION. IT MAY BE ABSORBED THROUGH THE SKIN.
EYE CONTACT: CAUSES EYE IRRITATION.
INHALATION:
MAY CAUSE IRRITATION OF RESPIRATORY TRACT. INHALATION OF HIGH
CONCENTRATIONS OF VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. MAY CAUSE
NAUSEA AND HEADACHE. IT MAY AFFECT RESPIRATION (RESPIRATORY DEPRESSION,
RESPIRATORY PARALYSIS). IT MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM
(ATAXIA, GENERAL ANESTHETIC, DROWSINESS). IT MAY AFFECT BEHAVIOR/CENTRAL
NERVOUS SYSTEM (CONVULSIONS/SEIZURES). MAY AFFECT BEHAVOIR/CENTRAL NERVOUS
SYSTEM (CENTRAL NERVOUS SYSTEM DEPRESSION, SOMNOLENCE, ANALGESIA, HEADACHE,
DIZZINESS, WEAKNESS, FATIGUE, LOSS OF COORDINATION, PERSONALITY CHANGES AND
PASSING OUT). MAY AFFECT VISION (BLURRED VISION). MAY AFFECT THE BRAIN.
INGESTION:
ASPIRATION HAZARD IF SWALLOWED. ASPIRATION INTO THE LUNGS CAN CAUSE
CHEMICAL PNEUMONITIS. INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION,
NAUSEA, VOMITING AND DIARRHEA. IT MAY AFFECT BEHAVIOR/CENTRAL NERVOUS
SYSTEM (DROWSINESS). MAY AFFECT URINARY SYSTEM (KIDNEYS).
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED SKIN CONTACT MAY DEFAT THE SKIN AND PRODUCE DERMATITIS. PROLONGED
OR REPEATED INHALATION MAY AFFECT THE LIVER. PROLONGED OR REPEATED
INHALATION MAY AFFECT THE KIDNEYS. PROLONGED OR REPEATED INGESTION MAY
AFFECT THE KIDNEYS. PROLONGED OR REPEATED INHALATION MAY CAUSE CENTRAL
NERVOUS SYSTEM EFFECTS.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENT CAS NO IARC ACGIH - CARCINOGENS NTP
CYCLOHEXANE 110-82-7 NOT LISTED NOT LISTED NOT LISTED
COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
CYCLOHEXANE NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT OF
LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: CENTRAL NERVOUS SYSTEM.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: SKIN. LIVER. KIDNEYS. CENTRAL NERVOUS SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
CYCLOHEXANE - 110-82-7:
ALGAE/AQUATIC PLANTS:
EC50: >500 MG/L (72H, DESMODESMUS SUBSPICATUS)
FISH:
LC50: 3.96 - 5.18 MG/L (96H, PIMEPHALES PROMELAS)
LC50: 23.03 - 42.07 MG/L (96H, PIMEPHALES PROMELAS)
LC50: 24.99 - 44.69 MG/L (96H, LEPOMIS MACROCHIRUS)
LC50: 48.87 - 68.76 MG/L (96H, POECILIA RETICULATA)
CRUSTACEA:
EC50: >400 MG/L (24H, DAPHNIA MAGNA)
PERSISTENCE AND DEGRADABILITY: IT IS HIGHLY RESISTANT TO BIODEGRADATION
BIOACCUMULATIVE POTENTIAL:
POTENTIAL FOR BIOCONCENTRATION IN AQUATIC ORGANISMS IS MODERATE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENT CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
CYCLOHEXANE 110-82-7 NONE NONE NONE U056 IGNITABLE
WASTE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1145
PROPER SHIPPING NAME: CYCLOHEXANE
HAZARD CLASS: 3
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: II
EMERGENCY RESPONSE GUIDE NUMBER: 128
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): 1000
SPECIAL PROVISIONS: IB2, T4, TP1
SYMBOL(S):
[DOT]:
(R4) - IDENTIFIES A MATERIAL THAT IS A HAZARDOUS SUBSTANCE THAT HAS A
REPORTABLE QUANTITY (RQ) OF 1000 POUNDS (454 KILOGRAMS).
DESCRIPTION: UN1145, CYCLOHEXANE, 3, II
TDG (CANADA):
UN-NO: UN1145
PROPER SHIPPING NAME: CYCLOHEXANE
HAZARD CLASS: 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: UN1145, CYCLOHEXANE, 3, II
ADR:
UN NUMBER: UN1145
PROPER SHIPPING NAME: CYCLOHEXANE
TRANSPORT HAZARD CLASS(ES): 3
PACKING GROUP: II
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: UN1145, CYCLOHEXANE, 3, II, ENVIRONMENTALLY HAZARDOUS
IMDG:
UN-NO: UN1145
PROPER SHIPPING NAME: CYCLOHEXANE
HAZARD CLASS: 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-E
DESCRIPTION: UN1145, CYCLOHEXANE, 3, II, MARINE POLLUTANT
RID:
UN NUMBER: UN1145
PROPER SHIPPING NAME: CYCLOHEXANE
TRANSPORT HAZARD CLASS(ES): 3
SUBSIDIARY RISK: 3
PACKING GROUP: II
DESCRIPTION: UN1145, CYCLOHEXANE, 3, II, ENVIRONMENTALLY HAZARDOUS
ICAO (AIR):
UN-NO: UN1145
PROPER SHIPPING NAME: CYCLOHEXANE
HAZARD CLASS: 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: UN1145, CYCLOHEXANE, 3, II
IATA:
UN NUMBER: UN1145
PROPER SHIPPING NAME: CYCLOHEXANE
TRANSPORT HAZARD CLASS(ES): 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
PRECAUTIONARY STATEMENTS - RESPONSE: 3H
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1145, CYCLOHEXANE, 3, II
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENT CAS NO U.S. TSCA KOREA KECL PHILIPPINES (PICCS)
CYCLOHEXANE 110-82-7 PRESENT ACTIVE PRESENT PRESENT
KE-18562
COMPONENT JAPAN ENCS CHINA IECSC AUSTRALIA EINECS-NO.
(AICS)
CYCLOHEXANE PRESENT PRESENT PRESENT PRESENT
(3)-2233 203-806-2
U.S. REGULATIONS:
CYCLOHEXANE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0565
NEW JERSEY (EHS) LIST: 0565 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
1000 LB RQ
1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
1000 LB FINAL RQ
454 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
175.105, 176.200, 178.3620, 73.1
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENT CAS NO
CYCLOHEXANE 110-82-7
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
CYCLOHEXANE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CAS NO CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY EXTREMELY
THEIR REPORTABLE HAZARDOUS HAZARDOUS
QUANTITIES SUBSTANCES AND SUBSTANCES AND
TPQS RQS
CYCLOHEXANE 110-82-7 1000 LB FINAL RQ NONE NONE
454 KG FINAL RQ
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
CYCLOHEXANE NONE 1.0 % DE MINIMIS CONCENTRATION
U.S. TSCA:
COMPONENT CAS NO TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH AND
CHEMICALS WITH SAFETY REPORTING
SIGNIFICANT NEW USE
RULES (SNURS)
CYCLOHEXANE 110-82-7 NOT APPLICABLE NOT APPLICABLE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
CYCLOHEXANE FLAMMABLE LIQUIDS - CATEGORY 2:
110-82-7 (100) H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
SKIN CORROSION/IRRITATION - CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
ASPIRATION HAZARD - CATEGORY 1:
H304:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
DSL/NDSL:
COMPONENT CAS NO CANADA (DSL) CANADA (NDSL)
CYCLOHEXANE 110-82-7 PRESENT NOT LISTED
COMPONENT CAS NO CEPA SCHEDULE I - TOXIC SUBSTANCES
CYCLOHEXANE 110-82-7 NOT LISTED
COMPONENT CAS NO CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
CYCLOHEXANE 110-82-7 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENT CAS NO EU GHS - SV - CLP (1272/2008)
CYCLOHEXANE 110-82-7 FLAMMABLE LIQUIDS - FLAM. LIQ. 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
SKIN CORROSION/IRRITATION - SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - STOT SE 3:
H336:
MAY CAUSE DROWSINESS OR DIZZINESS.
ASPIRATION HAZARD - ASP. TOX. 1:
H304:
MAY BE FATAL IF SWALLOWED AND ENTERS
AIRWAYS.
HAZARDOUS TO AQUATIC ENVIRONMENT - ACUTE
HAZARD - AQUATIC ACUTE 1:
H400: VERY TOXIC TO AQUATIC LIFE.
HAZARDOUS TO AQUATIC ENVIRONMENT - CHRONIC
HAZARD - AQUATIC CHRONIC 1:
H410:
VERY TOXIC TO AQUATIC LIFE WITH LONG
LASTING EFFECTS. 601-017-00-1
EU - CLP (1272/2008):
R-PHRASE(S):
R11: HIGHLY FLAMMABLE R38 - IRRITATING TO SKIN
R65:
HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED
R67: VAPORS MAY CAUSE DROWSINESS AND DIZINESS.
R50/53:
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN
THE AQUATIC ENVIRONMENT
S-PHRASE(S):
S9: KEEP CONTAINER IN A WELL-VENTILATED PLACE.
S16: KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING
S25: AVOID CONTACT WITH EYES
S33: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES
560: THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE
561:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY DATA
SHEETS.
562:
IF SWALLOWED, DO NOT INDUCE VOMITING: SEEK MEDICAL ADVICE IMMEDIATELY AND
SHOW THIS CONTAINER OR LABEL
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
CYCLOHEXANE 110-82-7 F; R11 NO INFORMATION S9 S16 S25 S33
XI; R38 S60 S61 S62
N; R50-53
XN; R65
R67
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
F: HIGHLY FLAMMABLE
XN: HARMFUL
XI: IRRITANT
N: DANGEROUS FOR THE ENVIRONMENT
| 16. OTHER INFORMATION | |
PREPARATION DATE: 6/29/15
REVISION DATE: 07/17/2019
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.