| Common Name: | ETHYLENE GLYCOL, PURIFIED, ETHYLENE GLYCOL, PURIFIED |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 3/20/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 39H286 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(TM)
CHEMICAL MFG CORP
S
ISO 9001-2008 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 3/20/2015
REVISION DATE: 3/20/2015
REVISION NUMBER: G1
| 1. PRODUCT IDENTIFIER |  |
PRODUCT CODE: E1052
PRODUCT NAME: ETHYLENE GLYCOL, PURIFIED
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
1,2-DIHYDROXYETHANE
1,2-ETHANDIOL
1,2-ETHANEDIOL
ETHANE-1,2-DIOL
ETHYLENE ALCOHOL
ETHYLENE DIHYDRATE
GLYCOL ALCOHOL
M.E.G.
MONOETHYLENE GLYCOL
NORKOOL
TESCOL
CAS #: 107-21-1
RTECS #: KW2975000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
SOLVENT. ANTIFREEZE IN COOLING AND HEATING SYSTEMS. IN HYDRAULIC BRAKE
FLUIDS AND DEICING SOLUTIONS. HEAT-TRANSFER AGENT.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICALS AND LABORATORY PRODUCTS, INC.
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
ACUTE TOXICITY - ORAL: CATEGORY 4
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED
CAUSES SERIOUS EYE IRRITATION
CAUSES DAMAGE TO ORGANS
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
EXCLAMATION MARK
HEALTH HAZARD
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: CAUSES MILD SKIN IRRITATION
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
WEAR EYE/FACE PROTECTION
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
PRECAUTIONARY STATEMENTS - RESPONSE:
SPECIFIC TREATMENT (SEE.? ON THIS LABEL)
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
RINSE MOUTH
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT % TRADE SECRET
ETHYLENE GLYCOL 107-21-1 100 *
107-21-1
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
POISON INFORMATION CENTERS IN EACH STATE CAPITAL CITY CAN PROVIDE
ADDITIONAL ASSISTANCE FOR SCHEDULED POISONS (13 1126)
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHES AND SHOES. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS.
EYE CONTACT: FLUSH EYE WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES EYE IRRITATION. MILD SKIN IRRITATION. CENTRAL NERVOUS SYSTEM
EFFECTS. INGESTION MAY CAUSE NAUSEA, VOMITING, AND DIARRHEA. MAY CAUSE
METABOLIC ACIDOSIS. IT MAY AFFECT THE KIDNEYS. MAY AFFECT THE LIVER. MAY
AFFECT THE BLOOD. MAY CAUSE HYPOCALCEMIA. MAY AFFECT THE CARDIOVASCULAR
SYSTEM. MAY AFFECT THE BONE MARROW.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
SUPPORT VITAL FUNCTIONS. CORRECT FOR DEHYDRATION AND SHOCK. MANAGE FLUID
BALANCE. CORRECT METABOLIC ACIDOSIS WITH INTRAVENOUS ADMINISTRATION OF
SODIUM BICARBONATE, ADJUSTING THE ADMINISTRATION RATE ACCORDING TO REPEATED
AND FREQUENT MEASUREMENT OF THE ACID/BASE STATUS. THE CURRENTLY RECOMMENDED
MEDICAL MANAGEMENT OF ETHYLENE GLYCOL POISONING INCLULDES THE ELIMINATION
OF ETHYLENE GLYCOL AND METABOLITES. THIS MAY BE ACHIEVED BY THE FOLLOWING
METHODS:
1. EMPTYING THE STOMACH BY GASTRIC LAVAGE. IT IS USEFUL IF INITIATED LESS
THAN 1 HOUR AFTER INGESTION.
2. ADMINISTER ETHANOL (ORALLY OR INTRAVENOUSLY) OR FOMEPIZOLE
(4-METHYLPYRAZOLE OR ANITZOL) THERAPY (INTRAVENOUSLY) AS AN ANTIDOTE TO
INHIBIT THE FORMATION OF TOXIC METABOLITES. HEMODIALYSIS MAYBE AVOIDED IF
PATIENTS ARE DIAGNOSED AND TREATED EARLY WITH THE ABOVE METHODS, AND
ETHANOL OR FOMEPIZOLE THERAPY IS EFFECTIVE, AND METABOLIC ACIDOSIS HAS BEEN
CORRECTED. HOWEVER, ONCE SEVERE ACIDOSIS AND RENAL FAILLURE HAVE OCCURED,
HEMODIALYIS IS NECESSARY TO EFFECTIVELY REMOVE ETHYLENE GLYCOL AND TOXIC
METABOLITES AND CORRECTING METABOLIC ACIDOSIS.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2). DRY CHEMICAL. WATER SPRAY MIST OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE; CARBON DIOXIDE
SPECIFIC HAZARDS:
MAY BE COMBUSTIBLE AT HIGH TEMPERATURES. MAY BE IGNITED BY HEAT, SPARKS OR
FLAMES. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH SKIN, EYES AND CLOTHING. REMOVE ALL SOURCES OF IGNITION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS. IN CASE OF LARGE SPILL,
DIKE IF NEEDED. DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. ABSORB SPILL WITH INERT MATERIAL
(E.G. VERMICULITE, DRY SAND OR EARTH).
METHODS FOR CLEANING UP:
USE APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL
WASTE DISPOSAL CONTAINER. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS OR SPRAY MIST. KEEP AWAY
FROM HEAT AND SOURCES OF IGNITION. HANDLE IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
HYGROSCOPIC. KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED
PLACE. STORE AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE AWAY
FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. ACIDS. CHLOROSULFONIC ACID. OLEUM. ISOCYANATES. ALIPHATIC
AMINES. HYDROXYL COMPOUNDS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS OSHA NIOSH ACGIH AIHA WHEEL
ETHYLENE NONE NONE 100 MG/M3 CEILING NONE
GLYCOL - AEROSOL ONLY
107-21-1
CANADA:
COMPONENTS ALBERTA BRITISH COLUMBIA ONTARIO QUEBEC
ETHYLENE 100 MG/M3 10 MG/M3 TWA 100 MG/M3 CEILING 50 PPM CEILING
GLYCOL - CEILING PARTICULATE AEROSOL ONLY
107-21-1 127 MG/M3
20 MG/M3 STEL CEILING
PARTICULATE
100 MG/M3
CEILING
AEROSOL
50 PPM CEILING
VAPOUR
AUSTRALIA AND MEXICO:
COMPONENTS AUSTRALIA MEXICO
ETHYLENE GLYCOL 40 PPM STEL 100 MG/M3 CEILING
107-21-1 104 MG/M3 STEL
10 MG/M3 TWA
20 PPM TWA
52 MG/M3 TWA
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST
BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES.
SKIN AND BODY PROTECTION:
LONG SLEEVED CLOTHING. CHEMICAL RESISTANT APRON. GLOVES.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS NOT NECESSARY FOR NORMAL HANDLING. GOOD ROOM
VENTILATION OR USE OF LOCAL EXHAUST (FUME HOOD) IS SUFFICIENT. USE A VAPOR
RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE TO THE SUBSTANCE IS APPARENT
(E.G. GENERATION OF HIGH CONCENTRATIONS OF MIST OR VAPOR, INADEQUATE
VENTILATION, DEVELOPMENT OF RESPIRATORY TRACT IRRITATION), AND ENGINEERING
CONTROLS ARE NOT FEASIBLE. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR
OR EQUIVALENT..
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT. WHEN USING, DO NOT EAT, DRINK OR
SMOKE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
APPEARANCE: SYRUPY.
COLOR: CLEAR. COLORLESS.
ODOR: NONE.
TASTE: SWEET.
MOLECULAR/FORMULA WEIGHT: 62.07
FORMULA: C2-H6-O2
FLASH POINT (DEG. C): 111
FLASHPOINT (DEG. C/DEG. F): 111-119 DEG. C/231.8-246.2 DEG. F
FLASH POINT TESTED ACCORDING TO: CLOSED CUP
LOWER EXPLOSION LIMIT (%): 3.2%
UPPER EXPLOSION LIMIT (%): 15.3%
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F):
398-413 DEG. C/748.4-770 DEG. F
PH: NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): -13 TO -11 DEG. C/8.6-12.2 DEG. F
BOILING POINT/RANGE (DEG. C/DEG. F): 196-199 DEG. C/384.8-390.2 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 1.1151-1.1156 @ 20 DEG. C
VAPOR PRESSURE @ 20 DEG. C (KPA): 0.008 TO 0.01
DENSITY (G/CM3): 1.1088-1.115 @ 20 DEG. C
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: 2.14
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): -1.36 TO -1.93
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY:
MISCIBLE WITH WATER
MISCIBLE WITH GLACIAL ACETIC ACID
MISCIBLE WITH ACETONE
MISCIBLE WITH ALDEHYDES
MISCIBLE WITH LOWER ALIPHATIC ALCOHOLS
MISCIBLE WITH GLYCEROL
MISCIBLE WITH PYRIDINE
SOLUBILITY:
SLIGHTLY SOLUBLE IN ETHER
PRACTICALLY INSOLUBLE IN PETROLEUM ETHER
PRACTICALLY INSOLUBLE IN BENZENE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTIVE WITH OXIDIZING AGENTS
REACTIVE WITH ACIDS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID:
HEAT. IGNITION SOURCES. EXPOSURE TO MOIST AIR. EXPOSURE TO MOISTURE.
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. ACIDS. CHLOROSULFONIC ACID. OLEUM. ISOCYANATES. ALIPHATIC
AMINES. HYDROXYL COMPOUNDS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. EYES. INGESTION. RESPIRATORY SYSTEM.
ACUTE TOXICITY:
COMPONENT INFORMATION:
ETHYLENE GLYCOL - 107-21-1:
LD50/ORAL/RAT: 4000 - 10200 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE:
5500 MG/KG (RTECS)
5890-13400 MG/KG (EU COMMISSION IUCLID DATA SET)
LD50/DERMAL/RABBIT:
>2000 MG/KG (EU COMMISSION IUCLID DATASET)
9530 UL/KG (RTECS)
LD50/DERMAL/RAT: 10600 MG/KG
LC50/INHALATION/RAT: >200 MG/M3 4H (RTECS)
LC50/INHALATION/MOUSE: >200 MG/M3 2H (RTECS)
OTHER LD50 OR LC50 INFORMATION:
6610 MG/KG ORAL LD50 GUINEA PIG
5500 MG/KG ORAL LD50 DOG
1650 MG/KG ORAL LD50 CAT
LETHAL DOSE IN ADULT HUMANS IS 1-1.5 ML/KG OR 1110-1665 MG/KG (MINNESOTA
POISON CONTROL SYSTEM)
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE- ACUTE TOX ORAL: 4000 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: 5500 MG/KG
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: >2000 MG/KG
LD50/DERMAL/RAT:
VALUE -ACUTE TOX DERMAL: 10600 MG/KG
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: >2000 MG/M3 (4-HR.)
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: >2000 MG/M32H
SYMPTOMS:
SKIN CONTACT:
MILD SKIN IRRITATION. IT MAY BE ABSORBED THROUGH THE SKIN. MAY CAUSE MORE
SEVERE RESPONSE IF SKIN IS ABRADED. A SINGLE PROLONGED EXPOSURE IS NOT
LIKELY TO RESULT IN MATERIAL BEING ABSORBED THROUGH THE SKIN IN HARMFUL
AMOUNTS. MASSIVE CONTACT WITH DAMAGED SKIN MAY RESULT IN ABSORPTION OF
POTENTIALLY HARMFUL AMOUNTS.
EYE CONTACT:
CAUSES EYE IRRITATION. VAPORS OR MIST MAY CAUSE MAY CAUSE TEMPORARY EYE
IRRITATION (MILD CONJUNTIVAL INFLAMMATION) AND LACRIMATION. CORNEAL INJURY
IS UNLIKELY.
INHALATION:
MAY CAUSE IRRITATION OF RESPIRATORY TRACT. AT ROOM TEMPERATURE, VAPORS ARE
MINIMAL DUE TO LOW VAPOR PRESSURE. WITH GOOD VENTILATION, A SINGLE EXPOSURE
IS NOT EXPECTED TO CAUSE ADVERSE EFFECTS. IF THE MATERIAL IS HEATED OR
MISTED, OR USED IN AN AREA THAT IS POORLY VENTILATED, VAPOR OR MIST MAY
ACCUMULATE AND CONCENTRATIONS MAY BE ATTAINED THAT ARE SUFFICIENT TO CAUSE
RESPIRATORY TRACT AND MUCOUS MEMBRANE IRRITATION.
SYMPTOMS MAY INCLUDE THE FOLLOWING:
A BURNING SENSATION IN THE THROAT, COUGHING, HEADACHE. INHALATION OF HIGH
CONCENTRATIONS OF MIST OR VAPORS MAY CAUSE HYPERMOTILITY, DIARRHEA. IT MAY
ALSO AFFECT THE KIDNEYS, AND CENTRAL NERVOUS SYSTEM (MUSCLE CONTRACTION OR
SPASTICITY). INHALATION OF HIGH CONCENTRATIONS OF ETHYLENE GLYCOL VAPOR MAY
ALSO CAUSE EPISODES OF NYSTAGMUS, AND LOSS OF CONCIOUSNESS.
INGESTION:
HARMFUL IF SWALLOWED. IT IS RAPIDLY ABSORBED FROM THE GASTROINTESTINAL
TRACT. ORAL TOXICITY IS EXPECTED TO BE MODERATE IN HUMANS THOUGH TESTS WITH
ANIMALS SHOW A LOWER DEGREE OF TOXICITY. INGESTION MAY CAUSE NAUSEA,
VOMITING, DIARRHEA. MAY CAUSE ABDOMINAL PAIN. IT CAN AFFECT
BEHAVIOR/CENTRAL NERVOUS SYSTEM WITHIN 0.5 TO 12 HOURS AFTER INGESTION. A
TRANSIENT INEBRIATION WITH EXCITEMENT, STUPOR, HEADACHE, SLURRED SPEECH,
ATAXIA, SOMNOLENCE, AND EUHORIA, SIMILAR TO ETHANOL INTOXICATION, CAN OCCUR
WITHIN THE FIRST SEVERAL HOURS. AS THE ETHYLENE GLYCOL IS METABOLILZED,
METABOLIC ACIDOSIS AND FURTHER CENTRAL NERVOUS SYSTEM DEPRESSION
(CONVULSIONS, MUSCLE WEAKNESS) DEVELOP. SERIOUS INTOXICATION MAY DEVELOP
CAUSING COMA, HYPTONIA, HYPOREFLEXIA, AND LESS COMMONLY SEIZURES. 12 TO 24
HOURS AFTER INGESTION, CARDIOVASCULAR SYMPTOMS SUCH AS TACHYCARDIA AND
HYPERTENSION MAY OCCUR AS WELL AS HYPOXIA, HYPERVENTILATION, CARDIOMEGALY,
MYOCARDITIS PROGRESSING TO CARDIOGENIC SHOCK AND CONGESTIVE HEART FAILURE.
24 TO 72 HOURS AFTER INGESTION, ALBUMINURIA, OLIGURIA, HEMATURIA,
PROTEINURIA, ACUTE TUBULAR NECROSIS, RENAL FAILURE AND OCCASIONALLY BONE
MARROW SUPRESSION OCCUR. CALCIUM OXALATE CRYSTALS MAY BE DETECTED, BUT
ABSENCE OF THEM DOES NOT RULE OUT THE DIAGNOSIS. HYPOCALCEMIA MAY OCCUR.
SERIOUS HEPATIC INJURY IS UNCOMMON. MYDRIASIS INVOLUNTARY EYE
MOVEMENTS(NYASTIGMUS) AND EFFECTS ON THE BLOOD (PANCYTOPENIA, LEUKOCYTOSIS,
LYMPHOCYTOSIS) MAY ALSO OCCUR.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED OR REPEATED INHALATION MAY CAUSE HEADACHE. PROLONGED OR REPEATED
INHALATION MAY AFFECT THE LIVER. PROLONGED OR REPEATED INHALATION MAY
AFFECT THE KIDNEYS. PROLONGED OR REPEATED INHALATION MAY AFFECT THE BRAIN.
PROLONGED OR REPEATED INHALATION MAY AFFECT METABOLISM (WEIGHT LOSS).
PROLONGED OR REPEATED INGESTION MAY CAUSE WEIGHT LOSS. PROLONGED OR
REPEATED INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. PROLONGED OR
REPEATED INHALATION MAY AFFECT RESPIRATION. PROLONGED OR REPEATED
INHALATION MAY CAUSE MORE PRONOUNCED IRRITATION OF THE UPPER RESPIRATORY
TRACT. REPEATED EXCESSIVE INGESTION MAY AFFECT THE KIDNEYS (KIDNEY DAMAGE,
WITH OR WITHOUT DEPOSITS OF CALCIUM OXALATE IN THE KIDNEYS), AND THE LIVER
(HEPATITIS, HEPATOCELLULAR NECROSIS). PROLONGED OR REPEATED INGESTION MAY
AFFECT THE BLOOD (CHANGES IN SERUM COMPOSITION).
SENSITIZATION: NO INFORMATION AVAILABLE
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
MUTAGENIC EFFECTS IN MAMMALIAN SOMATIC CELLS
EXPERIMENTS WITH ANIMAL LYMPHOCYTES HAVE SHOWN MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
COMPONENTS ACGIH - CARCINOGENS IARC NTP
ETHYLENE GLYCOL A4: NOT LISTED NOT LISTED
NOT CLASSIFIABLE
AS A HUMAN CARCINOGEN
COMPONENTS OSHA HCS - AUSTRALIA - PROHIBITED AUSTRALIA - NOTIFIABLE
CARCINOGENS CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
ETHYLENE NOT LISTED NOT LISTED NOT LISTED
GLYCOL
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS):
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS:
MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS BASED ON ANIMAL DATA. IT HAS NOT
BEEN SHOWN TO AFFECT REPRODUCTION IN HUMANS.
DEVELOPMENTAL EFFECTS:
MAY CAUSE ADVERSE DEVELOPMENTAL EFFECTS BASED ON ANIMAL DATA NO INFORMATION
ON DEVELOPMENTAL TOXICITY EFFECTS ON HUMANS WAS FOUND
TERATOGENIC EFFECTS:
MAY CAUSE BIRTH DEFECTS (TERATOGENIC EFFECTS) BASED ON ANIMAL TEST DATA
THERE ARE NO ADEQUATE AND WELL-CONTROLLED STUDIES IN HUMANS
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE
TARGET ORGANS: KIDNEYS. CENTRAL NERVOUS SYSTEM. BRAIN. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
ETHYLENE GLYCOL - 107-21-1:
FRESHWATER ALGAE DATA:
6500 - 13000 MG/L EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA 96 H
FRESHWATER FISH SPECIES DATA:
14 - 18 ML/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
40000 - 60000 MG/L LC50 PIMEPHALES PROMELAS 96 H STATIC 1
16000 MG/L LC50 POECILIA RETICULATA 96 H STATIC 1
27540 MG/L LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1
40761 MG/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
41000 MG/L LC50 ONCORHYNCHUS MYKISS 96 H 1
WATER FLEA DATA: 46300 MG/L EC50 DAPHNIA MAGNA 48 H
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE
MOBILITY: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
ETHYLENE GLYCOL NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NOT APPLICABLE
PACKING GROUP: NONE
ERG NO: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
CEFIC TREMCARD NO: NO INFORMATION AVAILABLE
IMO / IMDG:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
IMDG PAGE: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
MFAG: NO INFORMATION AVAILABLE
MAXIMUM QUANTITY: NO INFORMATION AVAILABLE
RID:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ICAO:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
IATA:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS U.S. TSCA KOREA KECL PHILIPPINES JAPAN ENCS
(PICCS)
ETHYLENE GLYCOL PRESENT PRESENT KE- PRESENT PRESENT (2)-
13169 230
COMPONENTS CHINA AUSTRALIA EINECS-NO.
(AICS)
ETHYLENE GLYCOL PRESENT PRESENT PRESENT 203-473-3
U.S. REGULATIONS:
ETHYLENE GLYCOL:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: PRESENT
NEW JERSEY (EHS) LIST: PRESENT
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: 1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
5000 LB FINAL RQ
2270 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
ETHYLENE GLYCOL NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY HAZARDOUS EXTREMELY HAZARDOUS
THEIR REPORTABLE SUBSTANCES AND TPQS SUBSTANCES AND RQS
QUANTITIES
ETHYLENE 5000 LB FINAL RQ NONE NONE
GLYCOL 2270 KG FINAL RQ
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
ETHYLENE GLYCOL NONE 1.0% DE MINIMIS CONCENTRATION
U.S. TSCA:
COMPONENTS TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH AND SAFETY
CHEMICALS WITH REPORTING
SIGNIFICANT NEW USE
RULES (SNURS)
ETHYLENE GLYCOL NOT APPLICABLE NOT APPLICABLE
CANADA:
WHMIS HAZARD CLASS:
D1B: TOXIC MATERIALS
D2A: VERY TOXIC MATERIALS
ETHYLENE GLYCOL:
D1B
D2A
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST
ETHYLENE GLYCOL 1%
INVENTORY:
COMPONENTS CANADA (DSL) CANADA (NDSL)
ETHYLENE GLYCOL PRESENT NOT LISTED
COMPONENTS CEPA SCHEDULE I - CEPA - 2010 GREENHOUSE GASES
TOXIC SUBSTANCES SUBJECT TO MANDITORY REPORTING
ETHYLENE GLYCOL NOT LISTED NOT LISTED
EU CLASSIFICATION:
R-PHRASE(S):
R22: HARMFUL IF SWALLOWED.
S-PHRASE(S):
S2: KEEP OUT OF THE REACH OF CHILDREN.
COMPONENTS CLASSIFICATION CONCENTRATION LIMITS SAFETY PHRASES
ETHYLENE GLYCOL XN; R22 NO INFORMATION S2
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XN: HARMFUL.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 3/20/2015
REVISION DATE: 3/20/2015
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.
SPECTRUM(TM)
CHEMICAL MFG CORP
S
ISO 9001-2008 REGISTERED
MATERIAL SAFETY DATA SHEET
NFPA:
2
1
0
HMIS:
HEALTH HAZARD 1
FIRE HAZARD 1
REACTIVITY 0
PERSONAL PROTECTIVE EQUIPMENT:
CHEMICAL GOGGLES
APRON
GLOVES
SEE SECTION 8.
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT CODE: E1052
PRODUCT NAME: ETHYLENE GLYCOL, PURIFIED
CHEMICAL NAME: ETHYLENE GLYCOL
SYNONYMS:
1,2-DIHYDROXYETHANE
1,2-ETHANDIOL
1,2-ETHANEDIOL
ETHANE-1,2-DIOL
ETHYLENE ALCOHOL
ETHYLENE DIHYDRATE
GLYCOL ALCOHOL
M.E.G.
MONOETHYLENE GLYCOL
NORKOOL
TESCOL
RECOMMENDED USE:
SOLVENT. ANTIFREEZE IN COOLING AND HEATING SYSTEMS. IN HYDRAULIC BRAKE
FLUIDS AND DEICING SOLUTIONS. HEAT-TRANSFER AGENT.
CAS #: 107-21-1
FORMULA: C2-H6-O2
RTECS #: KW2975000
CI#: NOT AVAILABLE
SUPPLIER:
SPECTRUM CHEMICALS AND LABORATORY PRODUCTS, INC.
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: REGINA WACHENHEIM (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
MAY CAUSE SKIN AND EYE IRRITATION. MAY CAUSE IRRITATION OF RESPIRATORY
TRACT.
ODOR: NONE.
PHYSICAL STATE: LIQUID.
APPEARANCE: SYRUPY.
COLOR: CLEAR. COLORLESS.
OSHA REGULATORY STATUS:
THIS MATERIAL IS NOT CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 1910.1200)
POTENTIAL HEALTH EFFECTS:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. EYES. INGESTION. RESPIRATORY SYSTEM.
ACUTE POTENTIAL HEALTH EFFECTS:
SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. IT MAY BE ABSORBED THROUGH THE SKIN.
EYE CONTACT: MAY CAUSE EYE IRRITATION.
INHALATION:
MAY CAUSE IRRITATION OF RESPIRATORY TRACT. IT MAY AFFECT THE BRAIN. MAY
CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. MAY AFFECT THE LIVER. MAY AFFECT THE
URINARY SYSTEM. MAY AFFECT RESPIRATION.
INGESTION:
HARMFUL IF SWALLOWED. INGESTION MAY CAUSE NAUSEA, VOMITING, AND DIARRHEA.
MAY CAUSE METABOLIC ACIDOSIS. IT MAY AFFECT THE BRAIN. MAY CAUSE CENTRAL
NERVOUS SYSTEM EFFECTS. IT MAY AFFECT THE KIDNEYS. MAY AFFECT THE LIVER.
MAY AFFECT RESPIRATION. MAY AFFECT THE BONE MARROW. MAY AFFECT THE
CARDIOVASCULAR SYSTEM. MAY AFFECT THE BLOOD. MAY CAUSE HYPOCALCEMIA.
CHRONIC POTENTIAL HEALTH EFFECTS:
COMPONENT CARCINOGEN STATUS
ETHYLENE GLYCOL A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN BY ACGIH
107-21-1 (100)
TARGET ORGANS: KIDNEYS. CENTRAL NERVOUS SYSTEM. BRAIN. RESPIRATORY SYSTEM.
TERATOGENIC EFFECTS: MAY CAUSE BIRTH DEFECTS (TERATOGENIC EFFECTS)
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
MUTAGENIC EFFECTS IN MAMMALIAN SOMATIC CELLS
EXPERIMENTS WITH ANIMAL LYMPHOCYTES HAVE SHOWN MUTAGENIC EFFECTS
AGGRAVATED MEDICAL CONDITIONS:
PERSONS WITH PRE-EXISTING KIDNEY, RESPIRATORY, EYE OR NEUROLOGICAL PROBLEMS
MIGHT BE MORE SENSITIVE TO ETHYLENE GLYCOL.
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION
POTENTIAL ENVIRONMENTAL EFFECTS: NO INFORMATION AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
ETHYLENE GLYCOL 107-21-1 100
| 4. FIRST AID MEASURES | |
GENERAL ADVICE:
POISON INFORMATION CENTRES IN EACH STATE CAPITAL CITY CAN PROVIDE
ADDITIONAL ASSISTANCE FOR SCHEDULED POISONS (13 1126)
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHES AND SHOES. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS.
EYE CONTACT:
FLUSH EYE WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION
OCCURS. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. CONSULT A PHYSICIAN IF NECESSARY.
NOTES TO PHYSICIAN:
SUPPORT VITAL FUNCTIONS
CORRECT FOR DEHYDRATION AND SHOCK
MANAGE FLUID BALANCE
CORRECT METABOLIC ACIDOSIS WITH INTRAVENOUS ADMINISTRATION OF SODIUM
BICARBONATE, ADJUSTING THE ADMINISTRATION RATE ACCORDING TO REPEATED AND
FREQUENT MEASUREMENT OF THE ACID/BASE STATUS
THE CURRENTLY RECOMMENDED MEDICAL MANAGEMENT OF ETHYLENE GLYCOL POISONING
INCLULDES THE ELIMINATION OF ETHYLENE GLYCOL AND METABOLITES. THIS MAY BE
ACHIEVED BY THE FOLLOWING METHODS:
1. EMPTYING THE STOMACH BY GASTRIC LAVAGE. IT IS USEFUL IF INITIATED LESS
THAN 1 HOUR AFTER INGESTION.
2. ADMINISTER ETHANOL (ORALLY OR INTRAVENOUSLY) OR FOMEPIZOLE
(4-METHYLPYRAZOLE OR ANITZOL) THERAPY (INTRAVENOUSLY) AS AN ANTIDOTE TO
INHIBIT THE FORMATION OF TOXIC METABOLITES.
HEMODIALYSIS MAYBE AVOIDED IF PATIENTS ARE DIAGNOSED AND TREATED EARLY WITH
THE ABOVE METHODS, AND ETHANOL OR FOMEPIZOLE THERAPY IS EFFECTIVE, AND
METABOLIC ACIDOSIS HAS BEEN CORRECTED. HOWEVER, ONCE SEVERE ACIDOSIS AND
RENAL FAILLURE HAVE OCCURED, HEMODIALYIS IS NECESSARY TO EFFECTIVELY REMOVE
ETHYLENE GLYCOL AND TOXIC METABOLITES AND CORRECTING METABOLIC ACIDOSIS
| 5. FIRE-FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
FLASHPOINT (DEG. C/DEG. F): NOT APPLICABLE
FLASH POINT TESTED ACCORDING TO: CLOSED CUP
LOWER EXPLOSION LIMIT (%): 3.2%
UPPER EXPLOSION LIMIT (%): 15.3%
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): 398-413 DEG. C/748.4-770 DEG. F
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2). DRY CHEMICAL. WATER SPRAY MIST OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE; CARBON DIOXIDE
SPECIFIC HAZARDS:
MAY BE COMBUSTIBLE AT HIGH TEMPERATURES. MAY BE IGNITED BY HEAT, SPARKS OR
FLAMES. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH SKIN, EYES AND CLOTHING. REMOVE ALL SOURCES OF IGNITION.
ENVIRONMENTAL PRECAUTIONS: NO INFORMATION AVAILABLE.
METHODS FOR CLEANING UP:
ABSORB SPILL WITH INERT MATERIAL (E.G. VERMICULITE, DRY SAND OR EARTH),
THEN PLACE IN A SUITABLE CHEMICAL WASTE CONTAINER. CLEAN CONTAMINATED
SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS OR SPRAY MIST. KEEP AWAY
FROM HEAT AND SOURCES OF IGNITION. HANDLE IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
STORAGE:
TECHNICAL MEASURES/STORAGE CONDITIONS:
HYGROSCOPIC. KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED
PLACE. STORE AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE AWAY
FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS. OLEUM.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST
BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES. SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN AND BODY PROTECTION:
LONG SLEEVED CLOTHING. CHEMICAL RESISTANT APRON. GLOVES.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS NOT NECESSARY FOR NORMAL HANDLING. GOOD ROOM
VENTILATION OR USE OF LOCAL EXHAUST (FUME HOOD) IS SUFFICIENT. USE A VAPOR
RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE TO THE SUBSTANCE IS APPARENT
(E.G. GENERATION OF HIGH CONCENTRATIONS OF MIST OR VAPOR, INADEQUATE
VENTILATION, DEVELOPMENT OF RESPIRATORY TRACT IRRITATION), AND ENGINEERING
CONTROLS ARE NOT FEASIBLE. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR
OR EQUIVALENT..
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT. WHEN USING, DO NOT EAT, DRINK OR
SMOKE.
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS OSHA NIOSH ACGIH AIHA WHEEL
ETHYLENE GLYCOL - NONE NONE 100 MG/M3 CEILING NONE
107-21-1 AEROSOL ONLY
CANADA:
COMPONENTS ALBERTA BRITISH COLUMBIA ONTARIO QUEBEC
ETHYLENE 100 MG/M3 10 MG/M3 TWA 100 MG/M3 CEILING 50 PPM CEILING
GLYCOL CEILING PARTICULATE AEROSOL ONLY
107-21-1 127 MG/M3
20 MG/M3 STEL CEILING
PARTICULATE
100 MG/M3 CEILING
AEROSOL
50 PPM CEILING
VAPOUR
AUSTRALIA AND MEXICO:
COMPONENTS AUSTRALIA MEXICO
ETHYLENE GLYCOL 40 PPM STEL 1%
107-21-1 104 MG/M3 STEL 100 MG/M3 PEAK
10 MG/M3 TWA
20 PPM TWA
52 MG/M3 TWA
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
APPEARANCE: SYRUPY.
COLOR: CLEAR. COLORLESS.
ODOR: NONE.
TASTE: SWEET.
MOLECULAR/FORMULA WEIGHT: 62.07
FLASH POINT (DEG. C): 111
LOWER EXPLOSION LIMIT (%): 3.2%
UPPER EXPLOSION LIMIT (%): 15.3%
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): 398-413 DEG. C/748.4-770 DEG. F
PH: NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): -13 TO -11 DEG. C/8.6-12.2 DEG. F
BOILING POINT/RANGE (DEG. C/DEG. F): 196-199 DEG. C/384.8-390.2 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): 1.1088-1.115 @ 20 DEG. C
BULK DENSITY: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): 0.008 TO 0.01
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: 2.14
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): -1.36 TO -1.93
MISCIBILITY:
MISCIBLE WITH WATER
MISCIBLE WITH GLACIAL ACETIC ACID
MISCIBLE WITH ACETONE
MISCIBLE WITH ALDEHYDES
MISCIBLE WITH LOWER ALIPHATIC ALCOHOLS
MISCIBLE WITH GLYCEROL
MISCIBLE WITH PYRIDINE
SOLUBILITY:
SLIGHTLY SOLUBLE IN ETHER
PRACTICALLY INSOLUBLE IN PETROLEUM ETHER
PRACTICALLY INSOLUBLE IN BENZENE
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS
CONDITIONS TO AVOID: HEAT. IGNITION SOURCES.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS. OLEUM.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE.
POSSIBILITY OF HAZARDOUS REACTIONS: NO INFORMATION AVAILABLE
POLYMERIZATION: HAZARDOUS POLYMERISATION DOES NOT OCCUR
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
COMPONENT INFORMATION:
ETHYLENE GLYCOL - 107-21-1:
LD50/ORAL/RAT:
4000 MG/KG ORAL LD50 RAT (LOLI)
4700 MG/KG (RTECS)
LD50/ORAL/MOUSE: 5500 MG/KG
LD50/DERMAL/RABBIT: 9530 (MICRO)L/KG DERMAL LD50 RABBIT
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: >200 MG/M3 4H (RTECS)
LC50/INHALATION/MOUSE: >200 MG/M3 2H (RTECS)
OTHER LD50 OR LC50 INFORMATION:
6610 MG/KG ORAL LD50 GUINEA PIG
5500 MG/KG ORAL LD50 DOG
1650 MG/KG ORAL LD50 CAT
PRODUCT INFORMATION:
LC50/INHALATION/RAT: >200 MG/M3 4H (RTECS)
LC50/INHALATION/MOUSE: >200 MG/M3 2H (RTECS)
LD50/DERMAL/RABBIT: 9530 (MICRO)L/KG
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE: 5500 MG/KG
LD50/ORAL/RAT:
4000 MG/KG (LOLI)
4700 MG/KG (RTECS)
LOCAL EFFECTS:
SKIN IRRITATION: MAY CAUSE SKIN IRRITATION. MILD SKIN IRRITATION.
EYE IRRITATION:
CONTACT WITH EYES MAY CAUSE IRRITATION. MILD EYE IRRITATION. MAY CAUSE
CONJUNCTIVIAL IRRITATION.
INHALATION:
MAY CAUSE IRRITATION OF RESPIRATORY TRACT. AT ROOM TEMPERATURE, VAPORS ARE
MINIMAL DUE TO LOW VAPOR PRESSURE. WITH GOOD VENTILATION, A SINGLE EXPOSURE
IS NOT EXPECTED TO CAUSE ADVERSE EFFECTS. IF THE MATERIAL IS HEATED OR
MISTED, OR USED IN AN AREA THAT IS POORLY VENTILATED, VAPOR OR MIST MAY
ACCUMULATE AND CONCENTRATIONS MAY BE ATTAINED THAT ARE SUFFICIENT TO CAUSE
RESPIRATORY TRACT AND MUCOUS MEMBRANE IRRITATION.
SYMPTOMS MAY INCLUDE THE FOLLOWING:
A BURNING SENSATION IN THE THROAT, COUGHING, HEADACHE. INHALATION OF HIGH
CONCENTRATIONS OF MIST OR VAPORS MAY CAUSE HYPERMOTILITY, DIARRHEA. IT MAY
ALSO AFFECT THE KIDNEYS, AND CENTRAL NERVOUS SYSTEM (MUSCLE CONTRACTION OR
SPASTICITY). INHALATION OF HIGH CONCENTRATIONS OF ETHYLENE VAPOR MAY ALSO
CAUSE EPISODES OF NYSTAGMUS, AND LOSS OF CONCIOUSNESS.
INGESTION:
HARMFUL IF SWALLOWED. INGESTION MAY CAUSE NAUSEA, VOMITING, DIARRHEA. MAY
CAUSE ABDOMINAL PAIN. IT MAY A AFFECT RESPIRATION (HYPOXIA,
HYPERVENTILATION). MAY CAUSE METABOLIC ACIDOSIS. MAY AFFECT LIVER. IT MAY
AFFECT THE KIDNEYS (ALBUMINURIA, OLIGURIA, HEMATURIA, PROTEINURIA, ACUTE
TUBULAR NECROSIS, RENAL FAILURE). CALCIUM OXALATE CRYSTALS MAY BE DETECTED,
BUT THEIR ABSENCE DOES NOT RULE OUT THE DIAGNOSIS. HYPOCALCEMIA, DUE TO
CHELATION AS CALCIUM OXALATE MAY OCCUR. IT MAY AFFECT THE BRAIN. MAY AFFECT
BEHAVIOR/CENTRAL NERVOUS SYSTEM (GENERAL ANESTHETIC). MAY AFFECT
BEHAVIOR/CENTRAL NERVOUS SYSTEM (EUPHORIA, SLURRED SPEECH, STUPOR). MAY
AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (EXCITEMENT, HEADACHE, DIZZINESS,
DROWSINESS, SOMNOLENCE, TREMOR, MUSCLE WEAKNESS, CONVULSIONS). MAY AFFECT
BEHAVIOR/CENTRAL NERVOUS SYSTEM (ATAXIA, IRRITABILITY, SOMNOLENCE).
INGESTION OF LARGE AMOUNTS MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM
(COMA). MAY AFFECT THE CARDIOVASCULAR SYSTEM (TACHYCARDIA). MAY AFFECT THE
CARDIOVASCULAR SYSTEM (HYPERTENSION). IT MAY AFFECT THE CARDIOVASCULAR
SYSTEM (CARDIOMEGALY, MYCARDITIS, HYPOTENSION, CARDIOGENIC SHOCK,
CONGESTIVE HEART FAILURE). IT MAY AFFECT THE BONE MARROW (BONE MARROW
DEPRESSION). IT MAY AFFECT THE BLOOD (PANTOCYTOPENIA, LEUKOCYTOSIS,
LYMPHOCYTOSIS).
SENSITIZATION: NO INFORMATION AVAILABLE
CHRONIC TOXICITY:
CHRONIC TOXICITY:
PROLONGED OR REPEATED INHALATION MAY CAUSE HEADACHE. PROLONGED OR REPEATED
INHALATION MAY AFFECT THE LIVER. PROLONGED OR REPEATED INHALATION MAY
AFFECT THE KIDNEYS. PROLONGED OR REPEATED INHALATION MAY AFFECT THE BRAIN.
PROLONGED OR REPEATED INHALATION MAY AFFECT METABOLISM (WEIGHT LOSS).
PROLONGED OR REPEATED INGESTION MAY CAUSE WEIGHT LOSS. PROLONGED OR
REPEATED INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. PROLONGED OR
REPEATED INHALATION MAY AFFECT RESPIRATION. PROLONGED OR REPEATED
INHALATION MAY CAUSE MORE PRONOUNCED IRRITATION OF THE UPPER RESPIRATORY
TRACT. REPEATED EXCESSIVE INGESTION MAY AFFECT THE KIDNEYS (KIDNEY DAMAGE,
WITH OR WITHOUT DEPOSITS OF CALCIUM OXALATE IN THE KIDNEYS), AND THE LIVER
(HEPATITIS, HEPATOCELLULAR NECROSIS). PROLONGED OR REPEATED INGESTION MAY
AFFECT THE BLOOD (CHANGES IN SERUM COMPOSITION).
CARCINOGENIC EFFECTS: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
COMPONENTS NTP IARC OSHA HCS -
CARCINOGENS
ETHYLENE GLYCOL NOT LISTED NOT LISTED NOT LISTED
COMPONENTS ACGIH - AUSTRALIA - PROHIBITED AUSTRALIA - NOTIFIABLE
CARCINOGENS CARCINOGENIC SUBSTANCES CARCINOGENIC SUBSTANCES
ETHYLENE A4: NOT LISTED NOT LISTED
GLYCOL NOT
CLASSIFIABLE
AS A HUMAN
CARCINOGEN
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
MUTAGENIC EFFECTS IN MAMMALIAN SOMATIC CELLS
EXPERIMENTS WITH ANIMAL LYMPHOCYTES HAVE SHOWN MUTAGENIC EFFECTS
REPRODUCTIVE EFFECTS: MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS
TERATOGENIC EFFECTS: MAY CAUSE BIRTH DEFECTS (TERATOGENIC EFFECTS)
TARGET ORGANS: KIDNEYS. CENTRAL NERVOUS SYSTEM. BRAIN. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
TOXICITY TO TERRESTRIAL AND AQUATIC PLANTS AND ANIMALS:
INFORMATION GIVEN IS BASED ON DATA ON THE COMPONENTS AND THE ECOTOXICOLOGY
OF SIMILAR PRODUCTS
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
AQUATIC TOXICITY:
ETHYLENE GLYCOL - 107-21-1:
FRESHWATER ALGAE DATA:
6500 - 13000 MG/L EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA 96 H
FRESHWATER FISH SPECIES DATA:
14 - 18 ML/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
40000 - 60000 MG/L LC50 PIMEPHALES PROMELAS 96 H STATIC 1
16000 MG/L LC50 POECILIA RETICULATA 96 H STATIC 1
27540 MG/L LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1
40761 MG/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
41000 MG/L LC50 ONCORHYNCHUS MYKISS 96 H 1
WATER FLEA DATA: 46300 MG/L EC50 DAPHNIA MAGNA 48 H
MOBILITY: NO INFORMATION AVAILABLE
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
ETHYLENE GLYCOL NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NONE
SUBSIDIARY RISK: NOT APPLICABLE
MARINE POLLUTANT: NO DATA AVAILABLE
ERG NO: NO INFORMATION AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
CEFIC TREMCARD NO: NO INFORMATION AVAILABLE
IMO / IMDG:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
IMDG PAGE: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
MFAG: NO INFORMATION AVAILABLE
MAXIMUM QUANTITY: NO INFORMATION AVAILABLE
RID:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ICAO:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
IATA:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS U.S. TSCA PHILIPPINES KOREA KECL JAPAN ENCS
(PICCS)
ETHYLENE GLYCOL T PRESENT KE-13169 2-230
COMPONENTS CHINA AUSTRALIA EINECS-NO.
(AICS)
ETHYLENE GLYCOL PRESENT PRESENT 203-473-3
U.S. REGULATIONS:
ETHYLENE GLYCOL:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: PRESENT
NEW JERSEY (EHS) LIST: PRESENT
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: 1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
5000 LB FINAL RQ
2270 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
ETHYLENE GLYCOL NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY HAZARDOUS EXTREMELY HAZARDOUS
THEIR REPORTABLE SUBSTANCES AND TPQS SUBSTANCES AND RQS
QUANTITIES
ETHYLENE 5000 LB FINAL RQ NONE NONE
GLYCOL 2270 KG FINAL RQ
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
ETHYLENE GLYCOL NONE 1.0% DE MINIMIS CONCENTRATION
U.S. TSCA:
COMPONENTS TSCA SECTION 5(A)2 - TSCA 8(D) -HEALTH AND
CHEMICALS WITH SIGNIFICANT SAFETY REPORTING
NEW USE RULES (SNURS)
ETHYLENE GLYCOL NOT APPLICABLE NOT APPLICABLE
CANADA:
WHMIS HAZARD CLASS:
D1B: TOXIC MATERIALS
D2A: VERY TOXIC MATERIALS
ETHYLENE GLYCOL:
D1B
D2A
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST
ETHYLENE GLYCOL 1%
INVENTORY:
COMPONENTS CANADA (DSL) CANADA (NDSL)
ETHYLENE GLYCOL PRESENT NOT LISTED
COMPONENTS CEPA SCHEDULE I - CEPA - 2010 GREENHOUSE GASES
TOXIC SUBSTANCES SUBJECT TO MANDITORY REPORTING
ETHYLENE GLYCOL NOT LISTED NOT LISTED
EU CLASSIFICATION:
R-PHRASE(S)
R22: HARMFUL IF SWALLOWED.
S-PHRASE(S):
S2: KEEP OUT OF THE REACH OF CHILDREN.
COMPONENTS CLASSIFICATION SAFETY PHRASES
ETHYLENE GLYCOL XN; R22 S2
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XN: HARMFUL.
| 16. OTHER INFORMATION | |
THE MSDS FORMAT COMPLIES WITH ANSI Z400.1-2004 STANDARDS.
PREPARATION DATE: 09-NOV-2012
REASON FOR REVISION: NOT APPLICABLE
PREPARED BY: SONIA OWEN
LITERATURE REFERENCE: NO INFORMATION AVAILABLE
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS MATERIAL SAFETY DATA SHEET (MSDS) APPLIES ONLY TO THE MATERIAL AS
PACKAGED. IF THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES,
OR BECOMES CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS MSDS.
THE PHYSICAL PROPERTIES REPORTED IN THIS MSDS ARE OBTAINED FROM THE
LITERATURE AND DO NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION
CONTAINED HEREIN DOES NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY, MERCHANTABILITY OR FITNESS OF THE GOODS FOR A
PARTICULAR PURPOSE. SPECTRUM CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES
NO RESPONSIBILITY FOR RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL
DAMAGES, INCLUDING LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO
WARRANTY AGAINST INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE
OR IMPLIED. IT SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS
OF HANDLING AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE.
WHILE THIS MSDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM
ASSUMES NO RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE
INFORMATION CONTAINED HEREIN.