| Common Name: | ETHYL ACETATE, NF |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 9/14/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 39H294, 39H297 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001:2015
REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 5/1/2014
REVISION DATE: 9/14/2018
REVISION NUMBER: G3
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: ET105
PRODUCT NAME: ETHYL ACETATE, NF
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
ACETIC ETHER
ACETIDIN
ACETOXYETHANE
ETHYL ACETIC ESTER
ETHYL ETHANOATE
VINEGAR NAPHTHA
ETHYLE (ACETATE D') (FRENCH)
ACETATE D'ETHYLE (FRENCH)
ACETATE ETHYLIQUE (FRENCH)
ACETATO DE ETILO (SPANISH)
CAS #: 141-78-6
RTECS #: AH5425000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
SOLVENT. PERFUMING AGENT. IN PHOTOGRAPHIC FILMS AND PLATES.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS):
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
FLAMMABLE LIQUIDS: CATEGORY 2
LABEL ELEMENTS:
DANGER
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS
HIGHLY FLAMMABLE LIQUID AND VAPOR
EXCLAMATION MARK
FLAME
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/.../EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
KEEP COOL
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM TO EXTINGUISH.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
PRECAUTIONARY STATEMENTS - STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
ETHYL ACETATE 141-78-6 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS.
EYE CONTACT: FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. CONSULT A PHYSICIAN IF NECESSARY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES EYE IRRITATION
COUGHING AND WHEEZING
DYSPNEA (DIFFICULTY BREATHING AND SHORTNESS OF BREATH)
CENTRAL NERVOUS SYSTEM EFFECTS
DIZZINESS
DROWSINESS
NARCOSIS
MAY CAUSE CARDIOVASCULAR EFFECTS
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION
MAY CAUSE NAUSEA AND VOMITING
MAY CAUSE METABOLIC ACIDOSIS
SWEATING AND FLUSHING OF SKIN
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2). DRY CHEMICAL. ALCOHOL-RESISTANT FOAM. WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID (STRAIGHT) WATER STREAM AS IT MAY SCATTER AND SPREAD
FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE.
SPECIFIC HAZARDS:
HIGHLY FLAMMABLE. MAY BE IGNITED BY HEAT, SPARKS OR FLAMES. CONTAINER
EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED. VAPOR MAY TRAVEL
CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. VAPORS MAY
FORM EXPLOSIVE MIXTURES WITH AIR. MOST VAPORS ARE HEAVIER THAN AIR. THEY
WILL SPREAD ALONG THE GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). FIRE MAY PRODUCE IRRITATING, CORROSIVE AND/OR TOXIC
GASES.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS:
WATER MIST MAY BE USED TO COOL CLOSED CONTAINERS. FOR LARGER FIRES, USE
WATER SPRAY OR FOG. COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER
UNTIL WELL AFTER FIRE IS OUT.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. USE PERSONAL
PROTECTIVE EQUIPMENT. REMOVE ALL SOURCES OF IGNITION. PAY ATTENTION TO
FLASHBACK. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. IN CASE OF LARGE SPILL, WATER SPRAY
OR VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS, BUT MAY NOT
PREVENT IGNITION IN CLOSED SPACES.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS. IN CASE OF LARGE SPILL,
DIKE IF NEEDED. DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. ABSORB SPILL WITH INERT MATERIAL
(E.G. VERMICULITE, DRY SAND OR EARTH).
METHODS FOR CLEANING UP:
USE APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL
WASTE DISPOSAL CONTAINER. USE ONLY NON-SPARKING TOOLS. CLEAN CONTAMINATED
SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. REMOVE ALL
SOURCES OF IGNITION. TO AVOID IGNITION OF VAPORS BY STATIC ELECTRICITY
DISCHARGE, ALL METAL PARTS OF THE EQUIPMENT MUST BE GROUNDED. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. USE ONLY IN WELL-VENTILATED AREAS.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. KEEP AWAY FROM HEAT AND
SOURCES OF IGNITION. DO NOT BREATHE VAPORS OR SPRAY MIST. DO NOT INGEST.
WHEN USING DO NOT SMOKE. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE
AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE
AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. KEEP AWAY FROM HEAT AND
SOURCES OF IGNITION. STORE IN A SEGREGATED AND APPROVED AREA. MOISTURE
SENSITIVE. PROTECT FROM MOISTURE. STORE AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
ACIDS
BASES
CHLOROSULFONIC ACID
OLEUM
POTASSIUM T-BUTOXIDE
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS CAS-NO. OSHA NIOSH ACGIH AIHA
WEEL
ETHYL ACETATE 141-78-6 400 PPM TWA 400 PPM TWA 400 PPM TWA NONE
1400 MG/M3 TWA 1400 MG/M3 TWA
CANADA:
COMPONENTS CAS-NO. CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
ETHYL ACETATE 141-78-6 400 PPM 150 PPM NONE NONE
TWA TWA
1440 MG/M3
TWA
AUSTRALIA AND MEXICO:
COMPONENTS CAS-NO. AUSTRALIA MEXICO
ETHYL ACETATE 141-78-6 400 PPM STEL 400 PPM TWA
1440 MG/M3 STEL 1400 MG/M3 TWA
200 PPM TWA
720 MG/M3 TWA
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS
AND MIST BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
LONG SLEEVED CLOTHING
GLOVES
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: CLEAR. COLORLESS.
ODOR: ETHER-LIKE. FRUITY.
TASTE: BITTERSWEET. WINE-LIKE. BURNING.
FORMULA: C4-H8-O2
MOLECULAR/FORMULA WEIGHT (G/MOLE): 88.11
FLAMMABILITY: HIGHLY FLAMMABLE
FLASHPOINT (DEG. C/DEG. F):
-4.4 DEG. C/24 DEG. F
7.2 DEG. C/44.96 DEG. F
FLASH POINT TESTED ACCORDING TO:
CLOSED CUP
OPEN CUP
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): 426.6 DEG. C/800 DEG. F
LOWER EXPLOSION LIMIT (%): 2-2.2%
UPPER EXPLOSION LIMIT (%): 9-11.5%
MELTING POINT/RANGE (DEG. C/DEG. F): -83 DEG. C/-117.4 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F): 77 DEG. C/170.6 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY:
0.9003 @ 20 DEG. C
0.894-0.898 @ 25 DEG. C
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA):
9.71-10.11
(12.4 KPA @ 25 DEG. C)
EVAPORATION RATE: 6.2 (BUTYL ACETATE = 1)
VAPOR DENSITY: 3.04
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): 1.0-4.0
PARTITION COEFFICIENT (N-OCTANOL/WATER): 0.73
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: MISCIBLE WITH CHLOROFORM
SOLUBILITY:
SOLUBLE IN ETHER
SOLUBLE IN HOT ALCOHOL
SOLUBLE IN ACETONE
SOLUBLE IN BENZENE
VERY SOLUBLE IN WATER
SOLUBILITY IN WATER:
64-80 G/L @ 25 DEG. C
83.1 G/L @ 20 DEG. C
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTIVE WITH OXIDIZING AGENTS
REACTS WITH STRONG BASES
REACTIVE WITH ACIDS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID:
HEAT. INCOMPATIBLE MATERIALS. MOISTURE SENSITIVE. EXPOSURE TO MOIST AIR.
SLOWLY DECOMPOSED BY MOISTURE.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
ACIDS
BASES
CHLOROSULFONIC ACID
OLEUM
POTASSIUM T-BUTOXIDE
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. WHEN HEATED TO DECOMPOSITION IT EMITS
ACRID SMOKE AND IRRITATING FUMES.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. SKIN. EYES. INHALATION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
ETHYL ACETATE:
CAS-NO.: 141-78-6
LD50/ORAL/RAT: 5620 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: 4100 MG/KG
LD50/DERMAL/RABBIT: 20 ML/KG DERMAL
LD50 RABBIT: >18000 MG/KG
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: 16000 PPM 6 HR 4000 PPM 4 HR
LC50/INHALATION/MOUSE: 45000 MG/M3 2HR 1500 PPM 4HR
OTHER LD50 OR LC50 INFORMATION:
4935 MG/KG LD50 ORAL RABBIT 5500 MG/KG LD50 ORAL GUINEA PIG
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE- ACUTE TOX ORAL: 5620 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: 4100 MG/KG
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: >18000 MG/KG
LD50/DERMAL/RAT:
VALUE -ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: 4000 PPM (4-HR)
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. IT MAY BE ABSORBED THROUGH THE SKIN. IF
ABSORBED THROUGH SKIN IT MAY CAUSE SYSTEMIC EFFECTS.
EYE CONTACT: CAUSES EYE IRRITATION. CAUSES CONJUNCTIVAL IRRITATION.
INHALATION:
IRRITATING TO RESPIRATORY SYSTEM. INHALATION OF HIGH CONCENTRATIONS OF
VAPOR MAY CAUSE ANESTHETIC EFFECTS. INHALATION OF HIGH CONCENTRATIONS OF
VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. IT MAY CAUSE PULMONARY EDEMA.
IT MAY AFFECT THE LIVER. MAY AFFECT THE KIDNEYS. SYMPTOMS MAY INCLUDE SORE
THROAT, SHORTNESS OF BREATH, COUGHING, WHEEZING, INFLAMMATION OF THE NASAL
PASSAGES. MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (SOMNOLENCE).
INGESTION:
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION. INGESTION MAY CAUSE
NAUSEA, VOMITING. MAY CAUSE FLUSHING AND SWEATING. ASPIRATION HAZARD IF
SWALLOWED. ASPIRATION INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS. MAY
CAUSE METABOLIC ACIDOSIS. MAY AFFECT THE CARDIOVASCULAR SYSTEM
(TACHYCARDIA). MAY AFFECT THE CARDIOVASCULAR SYSTEM (HYPOTENSION). MAY
AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (SOMNOLENCE, CONVULSIONS). MAY
AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (ATAXIA). IT MAY AFFECT
BEHAVIOR/CENTRAL NERVOUS SYSTEM (BOASTFULNESS, TALKATIVENESS, BELLIGERENCY,
IRRITABILITY, SLURRED SPEECH, DIPLOPIA, VERTIGO, DROWSINESS, COMA).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS AND DEFATTING,
DRYNESS, AND CRACKING OF THE SKIN. PROLONGED OR REPEATED INGESTION MAY
AFFECT THE LIVER. PROLONGED OR REPEATED INHALATION MAY AFFECT THE KIDNEYS.
PROLONGED OR REPEATED INHALATION MAY AFFECT THE LIVER. PROLONGED OR
REPEATED INHALATION MAY PRODUCE CHANGES IN PULMONARY FUNCTION AND/OR
CHRONIC BRONCHITIS. REPEATED EXPOSURE MAY CAUSE BRONCHITIS TO DEVELOP
WITH COUGH, PHLEGM, AND /OR SHORTNESS OF BREATH. PROLONGED OR REPEATED
INHALATION MAY AFFECT THE BLOOD (ANEMIA, LEUKOCYTOSIS, REDUCED PLATELET
COUNT). PROLONGED OR REPEATED INHALATION MAY AFFECT THE BLOOD (CHANGES IN
RED BLOOD CELL COUNT). PROLONGED OR REPEATED INHALATION MAY CAUSE CENTRAL
NERVOUS SYSTEM EFFECTS. PROLONGED OR REPEATED INHALATION MAY CAUSE LOSS OF
APPETITE. PROLONGED OR REPEATED EXPOSURE MAY AFFECT THE HEART.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
MAY AFFECT GENETIC MATERIAL
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
ANIMAL EXPERIMENTS SHOWED MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENTS CAS-NO. IARC ACGIH - CARCINOGENS NTP
ETHYL ACETATE 141-78-6 NOT LISTED NOT LISTED NOT LISTED
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
ETHYL ACETATE NOT LISTED NOT LISTED NOT LISTED
ACGIH: (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC: (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP: (NATIONAL TOXICOLOGY PROGRAM)
OSHA:
(OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT OF
LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: RESPIRATORY SYSTEM. CENTRAL NERVOUS SYSTEM.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS:
SKIN. CENTRAL NERVOUS SYSTEM. LIVER. KIDNEYS. LUNGS. RESPIRATORY SYSTEM.
HEART.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
ETHYL ACETATE - 141-78-6:
FRESHWATER ALGAE DATA: 3300 MG/L EC50 DESMODESMUS SUBSPICATUS 48 H
FRESHWATER FISH SPECIES DATA:
220 - 250 MG/L LC50 PIMEPHALES PROMELAS 96 H FLOW-THROUGH 1 484 MG/L LC50
ONCORHYNCHUS MYKISS 96 H FLOW-THROUGH 1 352 - 500 MG/L LC50 ONCORHYNCHUS
MYKISS 96 H SEMI-STATIC 1
WATER FLEA DATA: 560 MG/L EC50 DAPHNIA MAGNA 48 H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS CAS-NO. RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
ETHYL ACETATE 141-78-6 NONE NONE NONE U112 IGNITABLE
WASTE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: ETHYL ACETATE
HAZARD CLASS: 3
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
EMERGENCY RESPONSE GUIDE NUMBER: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
SYMBOL(S):
[DOT]:
(R5) - IDENTIFIES A MATERIAL THAT IS A HAZARDOUS SUBSTANCE THAT HAS A
REPORTABLE QUANTITY (RQ) OF 5000 POUNDS (2270 KILOGRAMS).
DESCRIPTION: UN1173,ETHYL ACETATE, 3,, PG II
TDG (CANADA):
UN-NO: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
HAZARD CLASS: 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: ETHYL ACETATE,3,UN1173,PG II
ADR:
UN-NO: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
HAZARD CLASS: 3
PACKING GROUP: II
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: UN1173 ETHYL ACETATE,3,II
IMO / IMDG:
UN-NO: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
HAZARD CLASS: 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-E
RID:
UN-NO: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
HAZARD CLASS: 3
SUBSIDIARY RISK: 3
PACKING GROUP: II
DESCRIPTION: UN1173 ETHYL ACETATE,3,II,RID
ICAO:
UN-NO: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
HAZARD CLASS: 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: ETHYL ACETATE,3,UN1173,PG II
IATA:
UN-NO: UN1173
PROPER SHIPPING NAME: ETHYL ACETATE
HAZARD CLASS: 3
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
ERG CODE: 3L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1173,ETHYL ACETATE,3,PG II
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
ETHYL ACETATE 141-78-6 PRESENTACTIVE PRESENT PRESENT
KE-00047
COMPONENTS JAPAN ENCS CHINA AUSTRALIA EINECS-NO.
(AICS)
ETHYL ACETATE PRESENT PRESENT PRESENT PRESENT
(2)-726 205-500-4
U.S. REGULATIONS:
ETHYL ACETATE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 0841
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
5000 LB RQ
1 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
5000 LB FINAL RQ
2270 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 182.60
FDA - DIRECT FOOD ADDITIVES: 21 CFR 173.228
FDA - 21 CFR - TOTAL FOOD ADDITIVES:
172.560, 172.859, 173.228, 175.320, 177.1200, 182.60, 73.1
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CAS-NO. CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
ETHYL 141-78-6 NOT LISTED NOT LISTED NOT LISTED NOT LISTED
ACETATE
CERCLA/SARA:
COMPONENTS CAS-NO. CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
ETHYL ACETATE 141-78-6 5000 LB FINAL RQ NONE NONE
2270 KG FINAL RQ
COMPONENTS SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
ETHYL ACETATE NONE NONE
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH
CHEMICALS WITH SIGNIFICANT AND SAFETY REPORTING
NEW USE RULES (SNURS)
ETHYL ACETATE 141-78-6 NOT APPLICABLE NOT APPLICABLE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
ETHYL ACETATE FLAMMABLE LIQUIDS - CATEGORY 2:
141-78-6 H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
(100)
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST
ETHYL ACETATE 1%
INVENTORY:
COMPONENTS CAS-NO. CANADA (DSL) CANADA (NDSL)
ETHYL ACETATE 141-78-6 PRESENT NOT LISTED
COMPONENTS CAS-NO. CEPA SCHEDULE I - TOXIC SUBSTANCES
ETHYL ACETATE 141-78-6 NOT LISTED
COMPONENTS CAS-NO. CEPA - 2010 GREENHOUSE GASES SUBJECT
TO MANDATORY REPORTING
ETHYL ACETATE 141-78-6 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENTS CAS-NO. EU GHS - SV - CLP (1272/2008)
ETHYL ACETATE 141-78-6 FLAMMABLE LIQUIDS - FLAM. LIQ. 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
SERIOUS EYE DAMAGE/EYE IRRITATION - EYE
IRRIT. 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - STOT SE 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
SUPPLEMENTAL HAZARDS:
EUH066:
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS
OR CRACKING. 607-022-00-5
EU - CLP (1272/2008):
R-PHRASE(S):
R11: HIGHLY FLAMMABLE.
R36: IRRITATING TO EYES.
R66: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
R67: VAPORS MAY CAUSE DROWSINESS AND DIZINESS.
S-PHRASE(S):
S16: KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
S33: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
COMPONENTS CAS-NO. CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
ETHYL ACETATE 141-78-6 F; R11 NO INFORMATION S16 S26 S33
XI; R36
R66
R67
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
F - HIGHLY FLAMMABLE.
XI - IRRITANT.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 5/1/2014
REVISION DATE: 9/14/2018
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR
RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING
LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.