| Common Name: | ROHPER 1-GL 2PK TRAFFIC BLACK, 246774 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 9/5/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 3AEH8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 9/5/2014
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: ROHPER 1-GL 2PK TRAFFIC BLACK
PRODUCT IDENTIFIER: 246774
PRODUCT USE/CLASS: TRAFFIC BLACK/WB ACRYLIC
REVISION DATE: 9/5/2014
SUPERCEDES DATE: NEW SDS
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
USE VENTILATION NECESSARY TO KEEP EXPOSURES BELOW RECOMMENDED EXPOSURE
LIMITS, IF ANY. MAY CAUSE EYE, SKIN, OR RESPIRATORY TRACT IRRITATION. KEEP
OUT OF REACH OF CHILDREN. HARMFUL IF INHALED. CAUSES EYE IRRITATION.
CLASSIFICATION:
SYMBOL(S) OF PRODUCT: HEALTH HAZARD
SIGNAL WORD: WARNING
GHS HAZARD STATEMENTS:
ACUTE TOXICITY, DERMAL, CATEGORY 5:
H313: MAY BE HARMFUL IN CONTACT WITH SKIN.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
ASPIRATION HAZARD, CATEGORY 2:
H305: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS.
SKIN IRRITATION, CATEGORY 3:
H316: CAUSES MILD SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2B:
H320: CAUSES EYE IRRITATION.
GHS PRECAUTIONARY STATEMENTS:
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH ... THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P335: BRUSH OFF LOOSE PARTICLES FROM SKIN.
P351: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
P374: FIGHT FIRE WITH NORMAL PRECAUTIONS FROM A REASONABLE DISTANCE.
P402: STORE IN A DRY PLACE.
P321: SPECIFIC TREATMENT (SEE ... ON THIS LABEL).
P352: WASH WITH PLENTY OF SOAP AND WATER.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P302+P350:
IF ON SKIN: GENTLY WASH WITH PLENTY OF SOAP AND WATER.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
LIMESTONE 1317-65-3 25-50
CARBON BLACK 1333-86-4 1.0-2.5 GHS02 H251
CRYSTALLINE SILICA 14808-60-7 0.1-1.0 GHS07 H302
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"16. OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM. FOR LARGER
AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF WATER TO
DRINK AND GET MEDICAL ATTENTION. IF SWALLOWED, RINSE MOUTH WITH WATER. IF
FEELING UNWELL, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA: DRY CHEMICAL, DRY SAND, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F. NO UNUSUAL FIRE
OR EXPLOSION HAZARDS NOTED. KEEP CONTAINERS TIGHTLY CLOSED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM.
IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS.
DO NOT INCINERATE CLOSED CONTAINERS. IF SPILLED, CONTAIN SPILLED MATERIAL
AND REMOVE WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED ABSORBENT,
CONTAINER, AND UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. AVOID CONTACT
WITH EYES. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY
WITH ADEQUATE VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID
BREATHING FUMES, VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING.
STORAGE:
KEEP FROM FREEZING. KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A DRY,
WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
LIMESTONE 1317-65-3 35.0
CARBON BLACK 1333-86-4 5.0
CRYSTALLINE SILICA 14808-60-7 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
LIMESTONE 5 MG/M3 N.E. 15 MG/M3 N.E.
(NIOSH, [TOTAL DUST]
RESPIRABLE
DUST)
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
(INHALABLE
DUST)
CRYSTALLINE SILICA 0.025 MG/M3 N.E. 0.1 MG/M3 N.E.
[RESPIRABLE [RESPIRABLE
DUST] DUST]
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: MILD
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.307
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: MISCIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: NO INFORMATION
DECOMPOSITION TEMP., DEG. C: NO INFORMATION
BOILING RANGE, DEG. C: 115 - 566
EXPLOSIVE LIMITS, VOL%: 1.3 - 36.0
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 100
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: NO INFORMATION
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: ND
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
CAUSES EYE IRRITATION. IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED
PROMPTLY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. LOW HAZARD FOR USUAL INDUSTRIAL
HANDLING OR COMMERCIAL HANDLING BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
LOW HAZARD FOR USUAL INDUSTRIAL HANDLING OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF
INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST.
EFFECTS OF OVEREXPOSURE - INGESTION: SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG FIBROSIS, AND LUNG TUMORS
HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF
TIME TO EXCESSIVE CONCENTRATIONS OF CARBON BLACK AND SEVERAL INSOLUBLE FINE
DUST PARTICLES. TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES
(I.E., MOUSE AND HAMSTER) UNDER SIMILAR CIRCUMSTANCES AND STUDY CONDITIONS.
EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO EVIDENCE OF
CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO OCCUPATIONAL EXPOSURE
TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
14808-60-7 CRYSTALLINE SILICA 500 MG/KG RAT N.I. N.I.
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. N.A. N.A. N.A.
PROPER SHIPPING NOT NOT NOT NOT
NAME REGULATED REGULATED REGULATED REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA COMPONENTS EXIST IN THIS PRODUCT.
INVENTORY INFORMATION:
COUNTRY VALUE
USA (TSCA) NO INFORMATION
CANADA (DSL) NO INFORMATION
MEXICO (INSQ) NO INFORMATION
EUROPE (EINECS) NO INFORMATION
JAPAN (ENCS) NO INFORMATION
PHILIPPINES (PICCS) NO INFORMATION
CHINA (IECSC) NO INFORMATION
AUSTRALIA (AICS) NO INFORMATION
KOREA (KECI) NO INFORMATION
NEW ZEALAND (NZIOC) NO INFORMATION
NO INFORMATION
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCTS CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
CHEMICAL NAME CAS-NO.
CARBON BLACK 1333-86-4
ACID FUNCTIONAL ACRYLIC COPOLYMER, AMMONIUM SALT PROPRIETARY
CRYSTALLINE SILICA 14808-60-7
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CHEMICAL NAME CAS-NO.
METHANOL 67-56-1
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
CANADIAN WHMIS CLASS: D2B
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 45
MSDS REVISION DATE: 9/5/2014
REASON FOR REVISION: NO INFORMATION
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H251:
SELF-HEATING: MAY CATCH FIRE.
H302: HARMFUL IF SWALLOWED.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS07: EXCLAMATION MARK
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.