| Common Name: | SIMPLE GREEN CONCRETE & DRIVEWAY CLEANER (PRESSURE WASHER CONCENTRATE) |
| Manufacturer: | SUNSHINE MAKERS |
| SDS Revision Date: | 11/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3ANW6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET:
SIMPLE GREEN(R*) CONCRETE & DRIVEWAY CLEANER (PRESSURE WASHER CONCENTRATE)
VERSION NO.: 18202-15A
ISSUE DATE: NOVEMBER 24, 2015
SUPERSEDES DATE: OCTOBER 21, 2014
OSHA HCS-2012 / GHS
| SECTION 1: IDENTIFICATION |  |
PRODUCT NAME:
SIMPLE GREEN(R*) CONCRETE & DRIVEWAY CLEANER (PRESSURE WASHER CONCENTRATE)
ADDITIONAL NAMES:
MANUFACTURER'S PART NUMBER: *PLEASE REFER TO SECTION 16
RECOMMENDED USE:
DILUTE 1:10 FOR MANUAL OR PRESSURE WASHER APPLICATION TO CLEAN CONCRETE AND
DRIVEWAY SURFACES
RESTRICTIONS ON USE: DO NOT USE ON NON-RINSABLE SURFACES.
COMPANY:
SUNSHINE MAKERS, INC.
15922 PACIFIC COAST HIGHWAY
HUNTINGTON BEACH, CA 92649
USA
TELEPHONE:
800-228-0709
562-795-6000
MON - FRI, 8AM - 5PM PST
FAX: 562-592-3830
EMAIL: INFO@SIMPLEGREEN.COM
EMERGENCY PHONE:
CHEM-TEL 24-HOUR EMERGENCY SERVICE: 800-255-3924
| SECTION 2: HAZARDS IDENTIFICATION | |
THIS PRODUCT IS CLASSIFIED AS HAZARDOUS (EYE CORROSION/IRRITATION -
CATEGORY 2B) UNDER 2012 OSHA HAZARD COMMUNICATION STANDARDS (29 CFR
1910.1200).
OSHA HCS 2012: LABEL ELEMENTS
SIGNAL WORD: WARNING
HAZARD SYMBOL(S)/PICTOGRAM(S): NONE REQUIRED
HAZARD STATEMENTS:
H320: CAUSES EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NONE
OTHER INFORMATION: NONE KNOWN
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT CAS NUMBER PERCENT RANGE
WATER 7732-18-5 >90.99%*
ETHOXYLATED ALCOHOL 68439-46-3 <5%*
SODIUM CITRATE 6132-04-3 <1%*
SODIUM CARBONATE 497-19-8 <1%*
1-PROPANAMINIUM, 3-AMINO-N- 61789-39-7 <1%*
(CARBOXYMETHYL)-N,N-DIMETHYL-,
N-COCO ACYL DERIVATIVES,
CHLORIDES, SODIUM SALTS
ALKYL IMINO DIPROPIONIC ACID, PROPRIETARY <1%*
MONOSODIUM SALT
COLORANT PROPRIETARY <0.01%*
*SPECIFIC PERCENTAGES OF COMPOSITION ARE BEING WITHHELD AS A TRADE SECRET
| SECTION 4: FIRST-AID MEASURES | |
INHALATION:
NOT EXPECTED TO CAUSE RESPIRATORY IRRITATION. IF ADVERSE EFFECT OCCURS,
MOVE TO FRESH AIR.
SKIN CONTACT:
NOT EXPECTED TO CAUSE SKIN IRRITATION. IF ADVERSE EFFECT OCCURS, MOVE TO
FRESH AIR.
EYE CONTACT:
CAUSES EYE IRRITATION. IF IN EYES RINSE CAUTIOUSLY WITH WATER FOR SEVERAL
MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE
RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
INGESTION:
MAY CAUSE UPSET STOMACH. DRINK PLENTY OF WATER TO DILUTE. SEE SECTION 11.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED: NONE KNOWN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY: TREAT SYMPTOMATICALLY
| SECTION 5: FIRE-FIGHTING MEASURES | |
SUITABLE & UNSUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY OR "ALCOHOL" FOAM. AVOID HIGH VOLUME JET
WATER.
SPECIFIC HAZARDS ARISING FROM CHEMICAL:
IN EVENT OF FIRE, FIRE CREATED CARBON OXIDES MAY BE FORMED.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS; WEAR FULL
PROTECTIVE CLOTHING.
THIS PRODUCT IS NON-FLAMMABLE. SEE SECTION 9 FOR PHYSICAL PROPERTIES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL: SEE SECTION 8 - PERSONAL PROTECTION.
FOR EMERGENCY RESPONDERS:
AVOID EYE CONTACT. SAFETY GOGGLES SUGGESTED IF SPLASHING OR MISTING IS
LIKELY TO OCCUR.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW INTO OPEN WATERWAYS AND GROUND WATER SYSTEMS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN UP:
DIKE OR SOAK UP WITH INERT ABSORBENT MATERIAL. SEE SECTION 13 FOR DISPOSAL
CONSIDERATIONS.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ENSURE ADEQUATE VENTILATION. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM
HEAT, SPARKS, OPEN FLAME AND DIRECT SUNLIGHT. DO NOT PIERCE ANY PART OF THE
CONTAINER. DO NOT MIX OR CONTAMINATE WITH ANY OTHER CHEMICAL. DO NOT EAT,
DRINK OR SMOKE WHILE USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE INCLUDING INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED. KEEP IN COOL DRY AREA. AVOID PROLONGED
EXPOSURE TO SUNLIGHT. DO NOT STORE AT TEMPERATURES ABOVE 109 DEG. F
(42.7 DEG. C) OR FREEZING TEMPERATURES.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMIT VALUES:
NO COMPONENTS LISTED WITH TWA OR STEL VALUES UNDER OSHA OR ACGIH.
APPROPRIATE ENGINEERING CONTROLS:
SHOWERS, EYEWASH STATIONS, VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES / PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE CONTACT:
USE PROTECTIVE GLASSES OR SAFETY GOGGLES IF SPLASHING OR SPRAY-BACK IS
LIKELY.
RESPIRATORY:
USE IN WELL VENTILATED AREAS OR LOCAL EXHAUST VENTILATION WHEN CLEANING
SMALL SPACES.
SKIN CONTACT:
USE PROTECTIVE GLOVES (ANY MATERIAL) WHEN USED FOR PROLONGED PERIODS OR
DERMALLY SENSITIVE.
GENERAL HYGIENE CONSIDERATIONS:
WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: PURPLE LIQUID
ODOR: NO ADDED FRAGRANCE
ODOR THRESHOLD: NOT DETERMINED
PH: 10.0 - 11.5
FREEZING POINT: 0 DEG. C (32 DEG. F)
BOILING POINT & RANGE: 101 DEG. C (213.8 DEG. F)
FLASH POINT: >212 DEG. F
EVAPORATION RATE: NOT DETERMINED
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT APPLICABLE
VAPOR PRESSURE: NOT DETERMINED
VAPOR DENSITY: NOT DETERMINED
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NON-FLAMMABLE
DECOMPOSITION TEMPERATURE: 109 DEG. F
VISCOSITY: LIKE WATER
SPECIFIC GRAVITY: 1.00 - 1.02
VOCS: **WATER & FRAGRANCE EXEMPTION IN CALCULATION
SCAQMD 304-91 / EPA 24: NOT TESTED
CARB METHOD 310**:
3.5 G/L
0.03 LB/GAL
0.35%
SCAQMD METHOD 313: NOT TESTED
VOC COMPOSITE PARTIAL PRESSURE: NOT DETERMINED
RELATIVE DENSITY: 8.34 - 8.50
SOLUBILITY: 100% IN WATER
| SECTION 10: STABILITY AND REACTIVITY | |
REACTIVITY: NON-REACTIVE.
CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS 70 DEG. F (21 DEG. C) AND 14.7 PSIG
(760 MMHg).
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
CONDITIONS TO AVOID: EXCESSIVE HEAT OR COLD.
INCOMPATIBLE MATERIALS:
DO NOT MIX WITH OXIDIZERS, ACIDS, BATHROOM CLEANERS, OR DISINFECTING
AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: NORMAL PRODUCTS OF COMBUSTION - CO, CO2.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE:
INHALATION: OVEREXPOSURE MAY CAUSE HEADACHE.
SKIN CONTACT:
NOT EXPECTED TO CAUSE IRRITATION, REPEATED CONTACT MAY CAUSE DRY SKIN.
EYE CONTACT: CAUSES EYE IRRITATION.
INGESTION: MAY CAUSE UPSET STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS: NO SYMPTOMS EXPECTED UNDER TYPICAL USE CONDITIONS.
DELAYED AND IMMEDIATE EFFECTS AND OR CHRONIC EFFECTS FROM SHORT TERM
EXPOSURE: NO SYMPTOMS EXPECTED UNDER TYPICAL USE CONDITIONS.
DELAYED AND IMMEDIATE EFFECTS AND OR CHRONIC EFFECTS FROM LONG TERM
EXPOSURE: HEADACHE, DRY SKIN, OR SKIN IRRITATION MAY OCCUR.
INTERACTIVE EFFECTS: NOT KNOWN.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY:
ORAL LD50 (RAT): >5 G/KG BODY WEIGHT
DERMAL LD50 (RABBIT): >5 G/KG BODY WEIGHT
CALCULATED VIA OSHA HCS 2012 / GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION
AND LABELLING OF CHEMICALS
SKIN CORROSION/IRRITATION:
NON-IRRITANT PER DERMAL IRRITECTION(R*) ASSAY MODELING. NO ANIMAL TESTING
PERFORMED.
EYE DAMAGE/IRRITATION:
CAUSES EYE IRRITATION PER OCULAR IRRITECTION(R*) ASSAY MODELING. NO ANIMAL
TESTING PERFORMED. (GHS HAZARD CATEGORY 2B)
GERM CELL MUTAGENICITY: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
CARCINOGENICITY:
NO INGREDIENTS TRIGGER OR CLASSIFY UNDER THIS CATEGORY UNDER NTP, IARC OR
OSHA.
REPRODUCTIVE TOXICITY: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
STOT-SINGLE EXPOSURE: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
STOT-REPEATED EXPOSURE: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
ASPIRATION HAZARD: MIXTURE DOES NOT CLASSIFY UNDER THIS CATEGORY.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY:
VOLUME OF INGREDIENTS USED DOES NOT TRIGGER TOXICITY CLASSIFICATIONS UNDER
THE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF
CHEMICALS.
AQUATIC: NOT TESTED ON FINISHED FORMULATION.
TERRESTRIAL: NOT TESTED ON FINISHED FORMULATION.
PERSISTENCE AND DEGRADABILITY:
INHERENTLY BIODEGRADABLE FORMULA:
>60% DEGRADATION IN 28 DAYS, WITH MAXIMUM TESTED 90% DEGRADATION IN 54 DAYS
(OECD 301D)
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
UNUSED OR USED LIQUID:
MAY BE CONSIDERED HAZARDOUS IN YOUR AREA DEPENDING ON USAGE AND TONNAGE OF
DISPOSAL - CHECK WITH LOCAL, REGIONAL, AND OR NATIONAL REGULATIONS FOR
APPROPRIATE METHODS OF DISPOSAL.
EMPTY CONTAINERS: MAY BE OFFERED FOR RECYCLING.
NEVER DISPOSE OF USED DEGREASING RINSATES INTO LAKES, STREAMS, AND OPEN
BODIES OF WATER OR STORM DRAINS.
| SECTION 14: TRANSPORT INFORMATION | |
U.N. NUMBER: NOT APPLICABLE
U.N. PROPER SHIPPING NAME: CLEANING COMPOUND, LIQUID NOI
TRANSPORT HAZARD CLASS(ES): NOT APPLICABLE
NMFC NUMBER: 48580-3
PACKING GROUP: NOT APPLICABLE
CLASS: NOT APPLICABLE
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
TRANSPORT IN BULK (ACCORDING TO ANNEX II OF MARPOL 73/78 AND IBC CODE):
UNKNOWN.
SPECIAL PRECAUTIONS WHICH USER NEEDS TO BE AWARE OF/COMPLY WITH, IN
CONNECTION WITH TRANSPORT OR CONVEYANCE EITHER WITHIN OR OUTSIDE THEIR
PREMISES: NONE KNOWN.
U.S. (DOT) / CANADIAN TDG: NOT REGULATED FOR SHIPPING.
ICAO/ IATA: NOT CLASSIFIED AS HAZARDOUS
IMO / IDMG: NOT CLASSIFIED AS HAZARDOUS
ADR/RID: NOT CLASSIFIED AS HAZARDOUS
| SECTION 15: REGULATORY INFORMATION | |
ALL COMPONENTS ARE LISTED ON: TSCA AND DSL INVENTORY.
SARA TITLE III:
SECTIONS 311/312 HAZARD CATEGORIES: NOT APPLICABLE.
SECTIONS 313 SUPERFUNDS AMENDMENTS AND REAUTHORIZATIONS ACT OF 1986:
NOT APPLICABLE.
SECTIONS 302: NOT APPLICABLE.
CLEAN AIR ACT (CAA): NOT APPLICABLE.
CLEAN WATER ACT (CWA): NOT APPLICABLE
STATE RIGHT TO KNOW LISTS: NO INGREDIENTS LISTED
CALIFORNIA PROPOSITION 65: NO INGREDIENTS LISTED
TEXAS ESL:
SODIUM CARBONATE 497-19-8:
5 (MICRO)G/M3 LONG TERM
50 (MICRO)G/M3 SHORT TERM
ETHOXYLATED ALCOHOL 68439-46-3:
60 (MICRO)G/M3 LONG TERM
600 (MICRO)G/M3 SHORT TERM
| SECTION 16: OTHER INFORMATION | |
SIZE ITEM NUMBER UPC
1 GALLON 2300000118202 043318182020
1 GALLON, 4 PER CASE 18202 & 2310000418202 043318182020
& 2380100418202
USA ITEMS LISTED ONLY. NOT ALL ITEMS LISTED. USA ITEMS MAY NOT BE VALID FOR
INTERNATIONAL SALE.
NFPA:
HEALTH 1 - EYE IRRITANT
STABILITY 0 - STABLE
FLAMMABILITY 0 - NON-FLAMMABLE
SPECIAL 0 - NONE
ACRONYMS:
NTP: NATIONAL TOXICOLOGY PROGRAM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
CPSC: CONSUMER PRODUCT SAFETY COMMISSION
TSCA: TOXIC SUBSTANCES CONTROL ACT
DSL: DOMESTIC SUBSTANCES LIST
PREPARED / REVISED BY: SUNSHINE MAKERS, INC., REGULATORY DEPARTMENT.
THIS SDS HAS BEEN REVISED IN THE FOLLOWING SECTIONS:
SECTION 12 OECD 301D TEST DATA
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT TO BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH
MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS,
UNLESS SPECIFIED IN THE TEXT.