| Common Name: | SPECSEAL LCI SEALANT |
| Manufacturer: | SPECIFIED TECHNOLOGIES |
| SDS Revision Date: | 10/13/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 3BE58, 3PA75, 3PA76 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
STI(R*)
SAFETY DATA SHEET
PREPARED TO U.S. OSHA, CMA, ANSI, CANADIAN WHMIS, THE KOREAN ISHA
(NOTICE 2009-68), THE JAPANESE INDUSTRIAL STANDARD JIS Z 7250: 2000,
MEXICAN NOM018-STPS 2000, SPRING SINGAPORE, AND THE GLOBAL HARMONIZATION
STANDARD
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY UNDERTAKING
IDENTIFICATION OF THE MIXTURE:
TRADE/MATERIAL NAME: SPECSEAL(R*) LCI SEALANT
CHEMICAL NAMES: ACRYLATE POLYMER MIXTURE
SYNONYMS: NONE
RELEVANT USE OF THE SUBSTANCE: SEALANT
USES ADVISED AGAINST: OTHER THAN RELEVANT USE
SUPPLIER/MANUFACTURER'S NAME (USA/CANADA): SPECIFIED TECHNOLOGIES, INC.
ADDRESS:
210 EVANS WAY
SOMERVILLE, NEW JERSEY 08876
BUSINESS PHONE: (908) 526-8000 (8:00AM TO 5:00PM EASTERN STANDARD TIME)
EMERGENCY PHONE:
U.S., CANADA: 1-800-255-3924 (24 HRS)
INTERNATIONAL: +1-813-248-0585 (COLLECT-24 HRS)
SUPPLIER/IMPORTER'S NAME (ASIA):
ADDRESS:
BUSINESS PHONE:
EMAIL OF COMPETENT PERSON FOR INFORMATION ON SDS: TECHSERV@STIFIRESTOP.COM
NOTE:
ALL UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION STANDARD
(29 CFR 1910.1200), U.S. STATE EQUIVALENT STANDARDS, CANADIAN WHMIS
[CONTROLLED PRODUCTS REGULATIONS], MEXICAN NOM018-STPS 2000, SPRING
SINGAPORE, AND JAPANESE JIS Z7250 REQUIRED INFORMATION IS INCLUDED IN
APPROPRIATE SECTIONS BASED ON THE U.S. ANSI Z400.1-2010 FORMAT. THIS
PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE
COUNTRIES LISTED ABOVE.
| 2. HAZARD IDENTIFICATION | |
GLOBAL HARMONIZATION AND JAPANESE JIS Z7253 LABELING AND CLASSIFICATION:
THIS PRODUCT HAS BEEN CLASSIFIED PER UN GHS STANDARDS UNDER U.S., JAPANESE
AND OTHER APPLICABLE REGULATIONS THAT REQUIRE GLOBAL HARMONIZATION
COMPLIANCE.
CLASSIFICATION:
CARCINOGENIC CAT. 2, EYE IRRITATION CAT. 2A, STOT (INHALATION-RESPIRATORY
IRRITATION) SE CAT. 3
SIGNAL WORD: WARNING
HAZARD STATEMENT CODES: H351, H319, H335
PRECAUTIONARY STATEMENT CODES:
P201, P202, P261, P271, P280, P308 + P313, P305 + P351 + P338, P337 + P313,
P304 + P340, P312, P321, P403 + P233 + P405, P501
HAZARD SYMBOLS:
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
KOREAN ISHA (NOTICE 2009-68) LABELING AND CLASSIFICATION:
CLASSIFIED IN ACCORDANCE WITH ISHA NOTICE 2009-68. UNDER ISHA,
NO DIFFERENCES IN CLASSIFICATION ARE APPLICABLE.
EMERGENCY OVERVIEW:
PRODUCT DESCRIPTION: THIS PRODUCT IS A TAN PASTE WITH A MILD ACRYLIC ODOR.
HEALTH HAZARDS:
MAY BE HARMFUL IF ACCIDENTALLY INGESTED. INHALATION OF VAPORS OR FUME IF
PRODUCT IS HEATED MAY CAUSE HEADACHE, NAUSEA AND RESPIRATORY IRRITATION.
EYE CONTACT WITH VAPORS OR FUME MAY ALSO CAUSE IRRITATION. BRIEF SKIN
CONTACT IS NOT EXPECTED TO CAUSE ADVERSE EFFECT. PROLONGED SKIN CONTACT MAY
CAUSE IRRITATION. THIS PRODUCT CONTAINS A KNOWN HUMAN CARCINOGEN IN TRACE
AMOUNT; HOWEVER, THIS HAZARD IS NOT EXPECTED TO BE SIGNIFICANT DUE TO
VISCOSITY OF THE PRODUCT.
FLAMMABILITY HAZARDS:
THIS PRODUCT IS FORMULATED TO BE NON-FLAMMABLE AND NON-COMBUSTIBLE. IF
INVOLVED IN A FIRE, THIS PRODUCT WILL RELEASE SMOKE, ACRID VAPORS AND TOXIC
GASES (E.G., ALUMINUM, CALCIUM, CARBON, AND SULFUR OXIDES, AND ACRYLIC
MONOMERS).
REACTIVITY HAZARDS: THIS PRODUCT IS NOT REACTIVE.
ENVIRONMENTAL HAZARDS:
THIS PRODUCT HAS NOT BEEN TESTED FOR POTENTIAL HAZARDS IF RELEASED TO THE
ENVIRONMENT. ALL RELEASE SHOULD BE AVOIDED.
EMERGENCY CONSIDERATIONS:
EMERGENCY RESPONDERS SHOULD WEAR APPROPRIATE PROTECTION FOR THE SITUATION
TO WHICH THEY RESPOND.
| 3. COMPOSITION AND INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS # WT%
PROPRIETARY ACRYLATE COATING 35-50%
ALUMINUM TRIHYDRATE 21645-51-2 15-25%
GROUND LIMESTONE 1317-65-3 10-18%
GLASS OXIDE 65997-17-3 8-12%
SULFURIC ACID COMPOUND WITH GRAPHITE 12777-87-6 2-5%
PROPRIETARY ACRYLIC COPOLYMER IN AQUEOUS DISPERSION 1-2%
CRYSTALLINE SILICA 14808-60-7 0.1-0.2%
WATER AND OTHER TRACE INGREDIENTS BALANCE
CHEMICAL NAME CHINESE IECSC JAPANESE ENCS # KOREAN ECL # TAIWAN
INVENTORY NESCI ECS
PROPRIETARY NOT DETERMINED NOT DETERMINED NOT DETERMINED NOT
ACRYLATE DETERMINED
COATING
ALUMINUM LISTED 1-17 KE-00980
TRIHYDRATE
GROUND LISTED EXCEPTED AS KE-21996
LIMESTONE MINERAL
GLASS OXIDE LISTED NOT LISTED KE-17630
SULFURIC ACID NOT LISTED NOT LISTED KE-32585
COMPOUND WITH
GRAPHITE
PROPRIETARY NOT DETERMINED NOT DETERMINED NOT DETERMINED NOT
ACRYLIC DETERMINED
COPOLYMER IN
AQUEOUS
DISPERSION
CRYSTALLINE LISTED 1-548 KE-29983
SILICA
WATER AND
OTHER TRACE
INGREDIENTS
CHEMICAL NAME LABEL ELEMENTS
GHS & JAPANESE JIS Z7253 CLASSIFICATION
KOREAN ISHA CLASSIFICATION
GHS HAZARD CODES
PROPRIETARY ACRYLATE COATING CLASSIFICATION NOT APPLICABLE
ALUMINUM TRIHYDRATE SELF CLASSIFICATION
GHS & JAPANESE JIS Z7253, KOREAN ISHA:
CLASSIFICATION: EYE IRRITATION CAT. 2A
HAZARD CODES: H319
GROUND LIMESTONE CLASSIFICATION: NOT APPLICABLE
GLASS OXIDE CLASSIFICATION: NOT APPLICABLE
SULFURIC ACID COMPOUND WITH SELF CLASSIFICATION
GRAPHITE GHS & JAPANESE JIS Z7253, KOREAN ISHA:
CLASSIFICATION: CARCINOGENIC CAT. 2
HAZARD CODES: H351I
PROPRIETARY ACRYLIC COPOLYMER CLASSIFICATION: NOT APPLICABLE
IN AQUEOUS DISPERSION
CRYSTALLINE SILICA SELF CLASSIFICATION
GHS & JAPANESE JIS Z7253, KOREAN ISHA:
CLASSIFICATION:
CARCINOGENIC CAT. 1, STOT
(INHALATION-LUNGS) RE CAT. 2
HAZARD STATEMENT CODES: H350, H373
WATER AND OTHER TRACE CLASSIFICATION: NOT APPLICABLE
INGREDIENTS
SEE SECTION 16 FOR FULL TEXT OF CLASSIFICATION
| 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
CONTAMINATED INDIVIDUALS MUST BE TAKEN FOR MEDICAL ATTENTION IF ANY ADVERSE
EFFECTS OCCUR. REMOVE CONTAMINATED CLOTHING AND SHOES. TAKE A COPY OF THIS
SDS TO HEALTH PROFESSIONAL WITH VICTIM. WASH CLOTHING AND THOROUGHLY CLEAN
SHOES BEFORE REUSE. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. TAKE A COPY OF LABEL AND SDS TO
PHYSICIAN OR HEALTH PROFESSIONAL WITH THE CONTAMINATED INDIVIDUAL.
SKIN EXPOSURE:
IF ADVERSE SKIN EFFECTS OCCUR, DISCONTINUE USE AND FLUSH CONTAMINATED AREA.
SEEK MEDICAL ATTENTION IF ADVERSE EFFECT OCCURS AFTER FLUSHING.
INHALATION:
IF FUMES OR VAPORS ARE INHALED, REMOVE VICTIM TO FRESH AIR. IF NECESSARY,
USE ARTIFICIAL RESPIRATION TO SUPPORT VITAL FUNCTIONS. SEEK MEDICAL
ATTENTION IF ADVERSE EFFECT CONTINUES AFTER REMOVAL TO FRESH AIR.
EYE EXPOSURE:
IF THIS PRODUCT CONTAMINATES THE EYES, RINSE EYES UNDER GENTLY RUNNING
WATER. USE SUFFICIENT FORCE TO OPEN EYELIDS AND THEN "ROLL" EYES WHILE
FLUSHING. MINIMUM FLUSHING IS FOR 20 MINUTES. THE CONTAMINATED INDIVIDUAL
MUST SEEK MEDICAL ATTENTION IF ANY ADVERSE EFFECT CONTINUES AFTER RINSING.
INGESTION:
IF THIS PRODUCT IS SWALLOWED, CALL PHYSICIAN OR POISON CONTROL CENTER FOR
MOST CURRENT INFORMATION. IF PROFESSIONAL ADVICE IS NOT AVAILABLE, DO NOT
INDUCE VOMITING. NEVER INDUCE VOMITING OR GIVE DILUENTS (MILK OR WATER) TO
SOMEONE WHO IS UNCONSCIOUS, HAVING CONVULSIONS, OR UNABLE TO SWALLOW. IF
VICTIM IS CONVULSING, MAINTAIN AN OPEN AIRWAY AND OBTAIN IMMEDIATE MEDICAL
ATTENTION.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PRE-EXISTING RESPIRATORY DISORDERS MAY BE AGGRAVATED BY OVEREXPOSURES TO
THIS PRODUCT.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT IF NEEDED:
TREAT SYMPTOMS AND ELIMINATE EXPOSURE.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: 338 DEG. C (640 DEG. F)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABLE LIMITS (IN AIR BY VOLUME, %): NOT APPLICABLE.
FIRE EXTINGUISHING MEDIA:
USE EXTINGUISHING MATERIALS SUITABLE FOR THE SURROUNDING AREA.
UNSUITABLE FIRE EXTINGUISHING MEDIA: NONE KNOWN.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
THIS PRODUCT IS FORMULATED TO BE NON-FLAMMABLE AND NON-COMBUSTIBLE. WHEN
INVOLVED IN A FIRE, THIS MATERIAL MAY DECOMPOSE AND PRODUCE IRRITATING
VAPORS AND TOXIC GASES (E.G., ALUMINUM, CALCIUM, CARBON, AND SULFUR OXIDES,
AND ACRYLIC MONOMERS).
EXPLOSION SENSITIVITY TO MECHANICAL IMPACT: NOT SENSITIVE.
EXPLOSION SENSITIVITY TO STATIC DISCHARGE: NOT SENSITIVE.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
INCIPIENT FIRE RESPONDERS SHOULD WEAR EYE PROTECTION. STRUCTURAL
FIREFIGHTERS MUST WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL
PROTECTIVE EQUIPMENT. CHEMICAL RESISTANT CLOTHING MAY BE NECESSARY. MOVE
CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK TO PERSONNEL.
WATER SPRAY CAN BE USED TO COOL FIRE-EXPOSED CONTAINERS. WATER FOG OR SPRAY
CAN ALSO BE USED BY TRAINED FIREFIGHTERS TO DISPERSE THIS PRODUCT'S VAPORS
AND TO PROTECT PERSONNEL. IF POSSIBLE, PREVENT RUNOFF WATER FROM ENTERING
STORM DRAINS, BODIES OF WATER, OR OTHER ENVIRONMENTALLY SENSITIVE AREAS.
NFPA RATING:
HEALTH 1
FLAMMABILITY 0
INSTABILITY 0
OTHER
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS AND EMERGENCY PROCEDURES:
UNCONTROLLED RELEASES SHOULD BE RESPONDED TO BY TRAINED PERSONNEL USING
PRE-PLANNED PROCEDURES. PROPER PROTECTIVE EQUIPMENT SHOULD BE USED. CALL
CHEMTREC (1-800-424-9300) FOR EMERGENCY ASSISTANCE. OR IF IN CANADA, CALL
CANUTEC (613-996-6666). THE ATMOSPHERE MUST AT LEAST 19.5 PERCENT OXYGEN
BEFORE NON-EMERGENCY PERSONNEL CAN BE ALLOWED IN THE AREA WITHOUT
SELF-CONTAINED BREATHING APPARATUS AND FIRE PROTECTION.
PERSONAL PROTECTIVE EQUIPMENT:
PROPER PROTECTIVE EQUIPMENT SHOULD BE USED. USE ONLY NON-SPARKING TOOLS AND
EQUIPMENT.
SMALL SPILLS:
WEAR RUBBER GLOVES, SPLASH GOGGLES, AND APPROPRIATE BODY PROTECTION.
LARGE SPILLS:
MINIMUM PERSONAL PROTECTIVE EQUIPMENT SHOULD BE RUBBER GLOVES, RUBBER
BOOTS, FACE SHIELD, AND TYVEK SUIT. MINIMUM LEVEL OF PERSONAL PROTECTIVE
EQUIPMENT FOR RELEASES IN WHICH THE LEVEL OF OXYGEN IS LESS THAN 19.5% OR
IS UNKNOWN MUST BE LEVEL B:
TRIPLE-GLOVES (RUBBER GLOVES AND NITRILE GLOVES OVER LATEX GLOVES), BOOTS,
TYVEK OR SIMILAR PROTECTIVE CLOTHING, HARD HAT, AND SELF-CONTAINED
BREATHING APPARATUS.
METHODS FOR CLEAN-UP AND CONTAINMENT:
SPILLS OF THIS PRODUCT PRESENT MINIMAL HAZARD.
SMALL SPILLS:
SMALL RELEASES CAN BE CAREFULLY SWEPT UP OR CLEANED UP USING A DAMP SPONGE
OR POLYPADS.
LARGE SPILLS:
ACCESS TO THE SPILL AREA SHOULD BE RESTRICTED. FOR LARGE SPILLS, DIKE OR
OTHERWISE CONTAIN SPILL AND SWEEP-UP OR VACUUM WITH NON-SPARKING VACUUM.
ALL SPILLS:
PLACE ALL SPILL RESIDUE IN A DOUBLE PLASTIC BAG OR OTHER CONTAINMENT AND
SEAL. CLOSE OFF SEWERS AND TAKE OTHER MEASURES TO PROTECT HUMAN HEALTH AND
THE ENVIRONMENT AS NECESSARY. RINSE AREA WITH SOAP AND WATER SOLUTION AND
FOLLOW WITH A WATER RINSE. DECONTAMINATE THE AREA THOROUGHLY. DO NOT MIX
WITH WASTES FROM OTHER MATERIALS. DISPOSE OF IN ACCORDANCE WITH APPLICABLE
FEDERAL, STATE, AND LOCAL PROCEDURES (SEE SECTION 13, DISPOSAL
CONSIDERATIONS). FOR SPILLS ON WATER, CONTAIN, MINIMIZE DISPERSION AND
COLLECT. DISPOSE OF RECOVERED MATERIAL AND REPORT SPILL PER REGULATORY
REQUIREMENTS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. RUN-OFF WATER MAY BE CONTAMINATED BY
OTHER MATERIALS AND SHOULD BE CONTAINED TO PREVENT POSSIBLE ENVIRONMENTAL
DAMAGE.
REFERENCE TO OTHER SECTIONS:
SEE INFORMATION IN SECTION 8 (EXPOSURE CONTROLS - PERSONAL PROTECTION) AND
SECTION 13 (DISPOSAL CONSIDERATIONS) FOR ADDITIONAL INFORMATION.
| 7. HANDLING AND USE | |
PRECAUTIONS FOR SAFE HANDLING:
AS WITH ALL CHEMICALS, AVOID GETTING THIS MATERIAL ON YOU OR IN YOU. DO NOT
EAT, DRINK, SMOKE, OR APPLY COSMETICS WHILE HANDLING THIS PRODUCT. WASH
HANDS THOROUGHLY AFTER HANDLING THIS PRODUCT OR CONTAINERS OF THIS PRODUCT.
AVOID BREATHING FUMES OR VAPORS GENERATED BY THIS PRODUCT. USE IN A
WELL-VENTILATED LOCATION.
CONDITIONS FOR SAFE STORAGE:
STORE CONTAINERS IN A COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT,
SOURCES OF INTENSE HEAT. CONTAINERS SHOULD BE GROUNDED AND SEPARATED FROM
OXIDIZING MATERIALS BY A MINIMUM DISTANCE OF 20 FT. OR BY A BARRIER OF
NON-COMBUSTIBLE MATERIAL AT LEAST 5 FT. HIGH HAVING A FIRE-RESISTANCE
RATING OF AT LEAST 0.5 HOURS. STORAGE AREAS SHOULD BE MADE OF FIRE
RESISTANT MATERIALS. POST WARNING AND "NO SMOKING" SIGNS IN STORAGE AND
USE AREAS AS APPROPRIATE. HAVE APPROPRIATE EXTINGUISHING EQUIPMENT IN THE
STORAGE AREA (E.G., SPRINKLER SYSTEM, PORTABLE FIRE EXTINGUISHERS). DO NOT
STORE ABOVE 55 DEG. C (131 DEG. F)
SPECIFIC END USE(S):
THIS PRODUCT IS FOR USE AS A SEALANT. FOLLOW ALL INDUSTRY STANDARDS FOR USE
OF THIS PRODUCT.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT:
FOLLOW PRACTICES INDICATED IN SECTION 6 (ACCIDENTAL RELEASE MEASURES).
MAKE CERTAIN THAT APPLICATION EQUIPMENT IS LOCKED AND TAGGED-OUT SAFELY,
IF NECESSARY. COLLECT ALL RINSATES AND DISPOSE OF ACCORDING TO APPLICABLE
FEDERAL, STATE, AND LOCAL PROCEDURES.
| 8. EXPOSURE CONTROLS - PERSONAL PROTECTION | |
EXPOSURE LIMITS/CONTROL PARAMETERS:
VENTILATION AND ENGINEERING CONTROLS:
USE WITH ADEQUATE VENTILATION TO ENSURE EXPOSURE LEVELS ARE MAINTAINED
BELOW THE LIMITS PROVIDED BELOW (IF APPLICABLE). EXHAUST DIRECTLY TO THE
OUTSIDE, TAKING NECESSARY PRECAUTIONS FOR ENVIRONMENTAL PROTECTION.
WORKPLACE EXPOSURE LIMITS/CONTROL PARAMETERS:
CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR
ACGIH-TLVS OSHA-PELS
TWA STEL TWA STEL
MG/M3 MG/M3 MG/M3 MG/M3
ALUMINUM 21645-51-2 NE NE NE NE
TRIHYDRATE
CRYSTALLINE SILICA 14808-60-7 0.025 NE 30 MG/M3 (TOTAL DUST)/
(QUARTZ) (RESP. % SO2 + 2
FRACT.)
0.1 (VACATED 1989 PEL)
250 MPPCF
(RESP. DUST) /
% SiO2 + 5
OR
10 MG/M3 (RESP. DUST)/
% SO2 + 2
GLASS OXIDE 65997-17-3 NE NE NE NE
GROUND LIMESTONE 1317-65-3 NE NE 15 (TOTAL DUST) NE
1 (RESP.
FRACT.)
PROPRIETARY NE NE NE NE
ACRYLATE COATING
PROPRIETARY ACRYLIC NE NE NE NE
COPOLYMER IN
AQUEOUS DISPERSION
SULFURIC ACID 12777-87-6 NE NE NE NE
COMPOUND WITH
GRAPHITE
CHEMICAL NAME EXPOSURE LIMITS IN AIR
NIOSH-RELS NIOSH OTHER
TWA STEL IDLH MG/M3
MG/M3 MG/M3 MG/M3
ALUMINUM TRIHYDRATE NE NE NE DFG MAKS:
TWA:
4 MG/M3
(INHALABLE FRACTION);
1.5 MG/M3
(RESPIRABLE FRACTION)
DFG MAK PREGNANCY RISK
CLASSIFICATION: D
CRYSTALLINE SILICA 0.05 NE 50 CARCINOGEN:
(QUARTZ) (RESP. IARC-1, MAK-1
DUST) (RESPIRABLE FRACTION),
NOSH-CA, NTP-K
(RESPIRABLE FRACTION),
TLV-A2
GLASS OXIDE NE NE NE NE
GROUND LIMESTONE 10 NE NE NE
(TOTAL
DUST)
1
(RESP.
FRACT.)
PROPRIETARY ACRYLATE NE NE NE NE
COATING
PROPRIETARY ACRYLIC NE NE NE NE
COPOLYMER IN AQUEOUS
DISPERSION
SULFURIC ACID COMPOUND NE NE NE NE
WITH GRAPHITE
NE = NOT ESTABLISHED.
SEE SECTION 16 FOR DEFINITIONS OF OTHER TERMS USED
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS:
CURRENTLY, THE FOLLOWING ADDITIONAL EXPOSURE LIMIT VALUES HAVE BEEN
ESTABLISHED BY VARIOUS COUNTRIES FOR THE COMPONENTS OF THIS MIXTURE. MORE
CURRENT LIMITS MAY BE AVAILABLE; INDIVIDUAL COUNTRIES SHOULD BE CONSULTED
TO DETERMINE IF NEWER LIMITS ARE AVAILABLE.
ALUMINUM HYDROXIDE:
AUSTRALIA:
TWA: 2 MG(Al)/M3, JUL 2008
BELGIUM:
TWA: 2 MG(Al)/M3, MAR 2002
FINLAND:
TWA: 2 MG(Al)/M3, NOV 2011
FRANCE:
VME: 2 MG(Al)/M3, FEB 2006
KOREA:
TWA: 2 MG(Al)/M3, 2006
NEW ZEALAND:
TWA: 2 MG(Al)/M3, JAN 2002
RUSSIA:
TWA: 6 MG/M3, JUN 2003
SWEDEN:
TWA: 1 MG(Al)/M3, JUN 2005
SWITZERLAND:
MAK-W: 3 MG/M3, RESP, JAN 2011
UNITED KINGDOM:
TWA: 2 MG(Al)/M3, OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
CRYSTALLINE SILICA:
AUSTRALIA:
TWA: 0.1 MG/M3, JUL 2008
BELGIUM:
TWA: 0.1 MG/M3 (RESP. DUST), MAR 2002
DENMARK:
TWA: 0.1 MG/M3 (RESPIRABLE), CARC, MAY 2011
DENMARK:
TWA: 0.1 MG/M3 (RESP.), CARC, MAY 2011
DENMARK:
TWA: 0.3 MG/M3 (TOTAL), MAY 2011
FINLAND:
TWA: 0.05 MG/M3, RESP. DUST, SEP 2009
FRANCE:
VME: 0.1 MG/M3, (RESP), FEB 2006
ICELAND:
TWA: 0.1 MG/M3 (RESP. DUST), NOV 2011
JAPAN:
OEL-C: 0.03 MG/M3 (RESPIRABLE), APR 2007
KOREA:
TWA: 0.1 MG/M3, 2006
MEXICO:
TWA: 0.1 MG/M3 (RESPIRABLE), 2004
THE NETHERLANDS:
MAC-TGG: 0.075 MG/M3, 2003
NEW ZEALAND:
TWA: 0.2 MG/M3 (RESPIRABLE DUST), JAN 2002
NORWAY:
TWA: 0.1 MG/M3 (RESP. DUST), JAN 1999
NORWAY:
TWA: 0.3 MG/M3 (TOTAL DUST), JAN 1999
PERU:
TWA: 0.05 MG/M3, JUL 2005
RUSSIA:
TWA: 1 MG/M3
STEL: 3 MG/M3, JUN 2003
SWEDEN:
TWA: 0.1 MG/M3 (RESP. DUST), JUN 2005
SWITZERLAND:
MAK-W: 0.15 MG/M3, DEC 2006
THAILAND:
TWA: 10 MG/M3 (RESP. DUST), JAN 1993
THAILAND:
TWA: 30 MG/M3 (TOTAL DUST), JAN 1993
UNITED KINGDOM:
TWA: 0.1 MG/M3 (RESP. DUST), OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
GROUND LIMESTONE:
BELGIUM:
TWA: 10 MG/M3, MAR 2002
HUNGARY:
TWA: 10 MG/M3, SEP 2000
JAPAN:
OEL: 2 MG/M3 (RESP. DUST), 84 MG/M3 (TOTAL DUST), MAY 2012
KOREA:
TWA: 10 MG/M3, 2006
MEXICO:
TWA: 10 MG/M3
STEL: 20 MG/M3 (INHALABLE), 2004
THE NETHERLANDS:
MAC-TGG: 10 MG/M3, 2003
NEW ZEALAND:
TWA: 10 MG/M3 (INSPIRABLE DUST), JAN 2002
POLAND:
MAC(TWA) DUST: 10 MG/M3, JAN 1999
RUSSIA:
STEL: 6 MG/M3, JUN 2003
SWITZERLAND:
MAK-W: 3 MG/M3, RESP, JAN 2011
UNITED KINGDOM:
TWA: 10 MG/M3 (INHAL. DUST), OCT 2007
UNITED KINGDOM:
TWA: 4 MG/M3 (RESPIRABLE DUST), OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
PROTECTIVE EQUIPMENT:
THE FOLLOWING INFORMATION ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT IS
PROVIDED TO ASSIST EMPLOYERS IN COMPLYING WITH OSHA REGULATIONS FOUND IN
29 CFR SUBPART I (BEGINNING AT 1910.132, INCLUDING U.S. FEDERAL OSHA
RESPIRATORY PROTECTION (29 CFR 1910.134), OSHA EYE PROTECTION 29 CFR
1910.133, OSHA HARD PROTECTION 29 CFR 1910.138, OSHA FOOT PROTECTION 29 CFR
1910.136 AND OSHA BODY PROTECTION 29 CFR1910.132), EQUIVALENT STANDARDS OF
CANADA (INCLUDING CSA RESPIRATORY STANDARD Z94.4-02, Z94.3-M1982,
INDUSTRIAL EYE AND FACE PROTECTORS AND CSA STANDARD Z195-02, PROTECTIVE
FOOTWEAR), OR STANDARDS OF JAPAN (INCLUDING JIS T 8116:2005 FOR GLOVE
SELECTION, JIS T 8150:2006 FOR RESPIRATORY PPE, JIS T 8147:2003 FOR EYE
PROTECTORS, AND JIS T 8030:2005 FOR PROTECTIVE CLOTHING). PLEASE REFERENCE
APPLICABLE REGULATIONS AND STANDARDS FOR RELEVANT DETAILS.
RESPIRATORY PROTECTION:
MAINTAIN AIRBORNE CONTAMINANT CONCENTRATIONS BELOW EXPOSURE LIMITS LISTED
ABOVE. FOR MATERIALS WITHOUT LISTED EXPOSURE LIMITS, MINIMIZE RESPIRATORY
EXPOSURE. IF NECESSARY, USE ONLY RESPIRATORY PROTECTION AUTHORIZED UNDER
APPROPRIATE REGULATIONS. OXYGEN LEVELS BELOW 19.5% ARE CONSIDERED IDLH BY
U.S. OSHA. IN SUCH ATMOSPHERES, USE OF A FULL-FACEPIECE PRESSURE/DEMAND
SCBA OR A FULL FACEPIECE, SUPPLIED AIR RESPIRATOR WITH AUXILIARY
SELF-CONTAINED AIR SUPPLY IS REQUIRED UNDER U.S. OSHA'S RESPIRATORY
PROTECTION STANDARD (1910.134-1998).
EYE PROTECTION:
WEAR SPLASH GOGGLES OR SAFETY GLASSES AS APPROPRIATE FOR THE TASK.
HAND PROTECTION:
WASH HANDS AND WRISTS BEFORE PUTTING ON AND AFTER REMOVING GLOVES. DURING
MANUFACTURE OR OTHER SIMILAR OPERATIONS, WEAR THE APPROPRIATE HAND
PROTECTION FOR THE PROCESS. USE DOUBLE GLOVES FOR SPILL RESPONSE, AS STATED
IN SECTION 6 (ACCIDENTAL RELEASE MEASURES) OF THIS SDS. BECAUSE ALL GLOVES
ARE TO SOME EXTENT PERMEABLE AND THEIR PERMEABILITY INCREASES WITH TIME,
THEY SHOULD BE CHANGED REGULARLY (HOURLY IS PREFERABLE) OR IMMEDIATELY IF
TORN OR PUNCTURED. IF NECESSARY REFER TO APPROPRIATE REGULATIONS.
SKIN PROTECTION:
USE APPROPRIATE PROTECTIVE CLOTHING FOR THE TASK (E.G., LAB COAT, ETC.).
IF NECESSARY, REFER TO THE U.S. OSHA TECHNICAL MANUAL (SECTION VII:
PERSONAL PROTECTIVE EQUIPMENT) OR OTHER APPROPRIATE REGULATIONS. FULL-BODY
CHEMICAL PROTECTIVE CLOTHING IS RECOMMENDED FOR EMERGENCY RESPONSE
PROCEDURES. IF A HAZARD OF INJURY TO THE FEET EXISTS DUE TO FALLING
OBJECTS, ROLLING OBJECTS, WHERE OBJECTS MAY PIERCE THE SOLES OF THE FEET
OR WHERE EMPLOYEE'S FEET MAY BE EXPOSED TO ELECTRICAL HAZARDS, USE FOOT
PROTECTION, AS DESCRIBED IN U.S. OSHA AND CANADIAN STANDARDS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM: PASTE.
COLOR: TAN.
MOLECULAR FORMULA: MIXTURE.
MOLECULAR WEIGHT: MIXTURE.
ODOR: MILD ACRYLIC.
ODOR THRESHOLD: NOT AVAILABLE.
FLAMMABLE LIMITS (IN AIR BY VOLUME, %): NOT APPLICABLE.
OXIDIZING PROPERTIES: NOT APPLICABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
PERCENT VOLATILE: 22
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
FREEZING/MELTING POINT: NOT AVAILABLE.
BOILING POINT: >100 DEG. C (>212 DEG. F)
VAPOR PRESSURE: NOT AVAILABLE.
SPECIFIC GRAVITY (WATER = 1): 1.38
VAPOR DENSITY (AIR = 1): NOT AVAILABLE.
CARB VOC: 0.2.29 WT % (CALC.)
EVAPORATION RATE (N-BUAC = 1): >1
SCAQMD (U.S. EPA METHOD 24): 33 GM/L
SOLUBILITY IN WATER: INSOLUBLE.
SOLUBILITY IN SOLVENTS: NOT AVAILABLE.
COEFFICIENT WATER/OIL DISTRIBUTION: NOT ESTABLISHED.
PH: NOT AVAILABLE.
HOW TO DETECT THIS SUBSTANCE (WARNING PROPERTIES IN EVENT OF ACCIDENTAL
RELEASE):
THE APPEARANCE MAY BE CHARACTERISTICS TO DISTINGUISH A RELEASE OF THIS
PRODUCT.
| 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
THIS PRODUCT IS STABLE WHEN PROPERLY STORED AT NORMAL TEMPERATURE AND
PRESSURES (SEE SECTION 7, HANDLING AND STORAGE).
DECOMPOSITION PRODUCTS:
COMBUSTION:
IF EXPOSED TO EXTREMELY HIGH TEMPERATURES, THERMAL DECOMPOSITION MAY
GENERATE IRRITATING FUMES AND TOXIC GASES (E.G., ALUMINUM, CALCIUM,
CARBON, AND SULFUR OXIDES, AND ACRYLIC MONOMERS).
HYDROLYSIS: NONE KNOWN.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE:
THIS PRODUCT IS INCOMPATIBLE WITH STRONG OXIDIZERS.
POSSIBILITY OF HAZARDOUS POLYMERIZATION OR REACTION: WILL NOT OCCUR.
CONDITIONS TO AVOID:
AVOID EXPOSURE TO OR CONTACT WITH EXTREME TEMPERATURES AND INCOMPATIBLE
CHEMICALS.
| 11. TOXICOLOGICAL INFORMATION | |
SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE:
THE HEALTH HAZARD INFORMATION PROVIDED BELOW IS PERTINENT TO EMPLOYEES
USING THIS PRODUCT IN AN OCCUPATIONAL SETTING. THE FOLLOWING PARAGRAPHS
DESCRIBE THE SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE.
INHALATION:
INHALATION OF FUMES OR VAPORS MAY CAUSE IRRITATION OF THE NOSE, THROAT,
AND LUNGS AND CAUSE COUGHING. REMOVAL TO FRESH AIR SHOULD RELIEVE SYMPTOMS.
THE TRACE CRYSTALLINE SILICA COMPONENT IS A KNOWN HUMAN CARCINOGEN. DUE TO
THE FORM OF THIS PRODUCT, THIS HAZARD IS NOT AS SIGNIFICANT AS A POWDERED
OR SOLID PRODUCTS, HOWEVER, ALL INHALATION EXPOSURE MUST BE AVOIDED IN
ORDER TO MITIGATE CARCINOGENIC POTENTIAL.
CONTACT WITH SKIN OR EYES:
DIRECT EYE CONTACT MAY CAUSE IRRITATION, REDNESS, AND TEARING FROM
MECHANICAL IRRITATION. PROLONGED OR REPEATED SKIN EXPOSURES MAY CAUSE
DERMATITIS (DRY RED SKIN).
SKIN ABSORPTION:
COMPONENTS ARE NOT KNOWN TO BE ABSORBED THROUGH INTACT SKIN.
INGESTION:
INGESTION IS NOT A SIGNIFICANT ROUTE OF OCCUPATIONAL EXPOSURE AND IS
UNLIKELY TO OCCUR. IF THIS PRODUCT IS SWALLOWED, IRRITATION OF THE MOUTH,
THROAT, ESOPHAGUS AND OTHER TISSUES OF THE DIGESTIVE SYSTEM MAY OCCUR.
SYMPTOMS OF INGESTION MAY INCLUDE NAUSEA, VOMITING, AND DIARRHEA.
INJECTION:
ACCIDENTAL INJECTION OF THIS PRODUCT, VIA LACERATION OR PUNCTURE BY A
CONTAMINATED OBJECT CAN CAUSE REDNESS AT THE SITE OF INJECTION. ANIMAL
DATA FOR THE CRYSTALLINE SILICA COMPONENT INDICATE THAT IT MAY CAUSE
CARCINOGENIC EFFECTS BY THIS ROUTE OF EXPOSURE.
HEALTH EFFECTS OR RISKS FROM EXPOSURE:
AN EXPLANATION IN LAY TERMS.
EXPOSURE TO THIS PRODUCT MAY CAUSE THE FOLLOWING HEALTH EFFECTS:
ACUTE:
INHALATION OF FUMES OR VAPORS MAY CAUSE IRRITATION OF RESPIRATORY SYSTEM.
EYE CONTACT MAY CAUSE MECHANICAL IRRITATION.
CHRONIC:
PROLONGED OR REPEATED SKIN EXPOSURE MAY CAUSE DERMATITIS (DRY RED SKIN).
THIS PRODUCT CONTAINS CRYSTALLINE SILICA, A KNOWN HUMAN CARCINOGEN.
TARGET ORGANS:
ACUTE: SKIN, EYES, RESPIRATORY SYSTEM.
CHRONIC: SKIN.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM:
HEALTH HAZARD (BLUE) 1*
FLAMMABILITY HAZARD (RED) 0
PHYSICAL HAZARD (YELLOW) 0
PROTECTIVE EQUIPMENT:
EYES: CHEMICAL GOGGLES
RESPIRATORY: SEE SECTION 8
HANDS: GLOVES
BODY: SEE SECTION 8
FOR ROUTINE INDUSTRIAL USE AND HANDLING APPLICATIONS
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
* = CHRONIC HAZARD
TOXICITY DATA:
CURRENTLY, THE FOLLOWING TOXICOLOGICAL DATA ARE AVAILABLE FOR COMPONENTS
OF 1% OR MORE CONCENTRATION.
ALUMINUM TRIHYDRATE:
TDLO (ORAL-CHILD) 79 GM/KG/2 YEARS-INTERMITTENT:
BEHAVIORAL:
CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY), MUSCLE CONTRACTION OR
SPASTICITY
MUSCULOSKELETAL: OSTEOMALACIA
TDLO (ORAL-CHILD) 122 GM/KG/4 DAYS:
GASTROINTESTINAL: OTHER CHANGES
NUTRITIONAL AND GROSS METABOLIC: BODY TEMPERATURE INCREASE
TDLO (ORAL-WOMAN) 84 GM/KG:
FEMALE 1-40 WEEK(S) AFTER CONCEPTION:
REPRODUCTIVE:
EFFECTS ON NEWBORN: PHYSICAL
TDLO (ORAL-INFANT) 68040 MG/KG/24 WEEKS-INTERMITTENT:
MUSCULOSKELETAL: OSTEOPOROSIS
NUTRITIONAL AND GROSS METABOLIC:
WEIGHT LOSS OR DECREASED WEIGHT GAIN, CHANGES IN PHOSPHORUS
TDLO (ORAL-WOMAN) 73912.5 MG/KG/26 WEEKS-INTERMITTENT:
BLOOD: CHANGES IN SERUM COMPOSITION (E.G. TP, BILIRUBIN, CHOLESTEROL)
MUSCULOSKELETAL: OSTEOPOROSIS
NUTRITIONAL AND GROSS:
METABOLIC: CHANGES IN PHOSPHORUS
TDLO (UNREPORTED-INFANT) 39 GM/KG/24 DAYS-INTERMITTENT:
MUSCULOSKELETAL: OSTEOMALACIA
TDLO (ORAL-RAT) 15 MG/KG:
GASTROINTESTINAL: OTHER CHANGES
TDLO (ORAL-RAT) 8040 MG/KG/67 DAYS-CONTINUOUS:
BLOOD: CHANGES IN SERUM COMPOSITION (E.G. TP, BILIRUBIN, CHOLESTEROL)
NUTRITIONAL AND GROSS METABOLIC: CHANGES IN PHOSPHORUS
TDLO (ORAL-MOUSE) 80,880 MG/KG/23 WEEKS-CONTINUOUS:
LIVER: OTHER CHANGES
MUSCULOSKELETAL: OTHER CHANGES
NUTRITIONAL AND GROSS METABOLIC: CHANGES IN METALS, NOT OTHERWISE SPECIFIED
TDLO (INTRAPERITONEAL-RAT) 150 MG/KG
TDLO (INTRAPERITONEAL-RAT) 6240 MG/KG/26 WEEKS-INTERMITTENT:
BLOOD: PIGMENTED OR NUCLEATED RED BLOOD CELLS
NUTRITIONAL AND GROSS METABOLIC:
WEIGHT LOSS OR DECREASED WEIGHT GAIN, CHANGES IN IRON
TDLO (INTRAPERITONEAL-RAT) 1920 MG/KG/8 WEEKS-INTERMITTENT:
BLOOD: MICROCYTOSIS WITH OR WITHOUT ANEMIA
TDLO (INTRAPERITONEAL-RAT) 960 MG/KG/4 WEEKS-INTERMITTENT:
BLOOD: CHANGES IN ERYTHROCYTE (RBC) COUNT
GROUND LIMESTONE:
TDLO (INTRAVENOUS-RAT) 30 MG/KG:
VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION
LUNGS, THORAX, OR RESPIRATION: CHANGES IN LUNG WEIGHT
BLOOD: OTHER CHANGES
TCLO (INHALATION-RAT) 84 MG/M3/4 HOURS/40 WEEKS-INTERMITTENT:
LUNGS, THORAX, OR RESPIRATION: FIBROSIS (INTERSTITIAL)
LIVER: OTHER CHANGES
KIDNEY/URETER/BLADDER: OTHER CHANGES
TCLO (INHALATION-RAT) 250 MG/M3/2 HOURS/24 WEEKS-INTERMITTENT:
LUNGS, THORAX, OR RESPIRATION: FIBROSIS, FOCAL (PNEUMOCONIOSIS)
IRRITANCY OF PRODUCT:
INHALATION OF FUMES OR VAPORS MAY CAUSE RESPIRATORY IRRITATION. EYE CONTACT
MAY CAUSE IRRITATION. PROLONGED SKIN CONTACT MAY CAUSE IRRITATION.
SENSITIZATION OF PRODUCT:
THIS PRODUCT IS NOT CURRENTLY KNOWN TO CAUSE ALLERGIC SKIN OR RESPIRATORY
REACTION.
CARCINOGENIC POTENTIAL OF COMPONENTS:
COMPONENTS OF THIS PRODUCT ARE LISTED BY AGENCIES TRACKING THE CARCINOGENIC
POTENTIAL OF CHEMICAL COMPOUNDS, AS FOLLOWS:
CRYSTALLINE SILICA:
ACGIH-TLV-A2 (SUSPECTED HUMAN CARCINOGEN)
IARC-1 (CARCINOGENIC TO HUMANS)
MAK-1 (SUBSTANCES THAT CAUSE CANCER IN MAN AND CAN BE ASSUMED TO MAKE A
SIGNIFICANT CONTRIBUTION TO CANCER RISK)
NIOSH-CA (POTENTIAL OCCUPATIONAL CARCINOGEN WITH NO FURTHER CATEGORIZATION)
NTP-K (KNOWN TO BE A HUMAN CARCINOGEN)
THE REMAINING COMPONENTS ARE NOT FOUND ON THE FOLLOWING LISTS: U.S. EPA,
U.S. NTP, U.S. OSHA, U.S. NIOSH, GERMAN MAK, IARC, OR ACGIH AND THEREFORE
IS NEITHER CONSIDERED TO BE NOR SUSPECTED TO BE A CANCER-CAUSING AGENT BY
THESE AGENCIES.
REPRODUCTIVE TOXICITY INFORMATION:
COMPONENTS OF THIS PRODUCT HAVE NO REPORTED MUTAGENIC, EMBRYOTOXIC,
TERATOGENIC OR REPRODUCTIVE TOXICITY.
ACGIH BIOLOGICAL EXPOSURE INDICES (BEIS):
CURRENTLY, THERE ARE NO ACGIH BIOLOGICAL EXPOSURE INDICES (BEIS)
DETERMINED FOR THIS MATERIAL.
DEGREE OF EFFECT TO THE HEALTH OF THE POLLUTING AGENT OF ENVIRONMENT OF
WORK (PER MEXICAN NOM-010 STPS-1999): 0
| 12. ECOLOGICAL INFORMATION | |
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL
CONTAMINATION.
MOBILITY: THIS PRODUCT HAS NOT BEEN TESTED FOR MOBILITY IN SOIL.
PERSISTENCE AND BIODEGRADABILITY:
THIS PRODUCT HAS NOT BEEN TESTED FOR PERSISTENCE OR BIODEGRADABILITY.
THE MINERAL COMPONENTS ARE NOT EXPECTED TO BIODEGRADE TO GREAT EXTENT.
BIO-ACCUMULATION POTENTIAL:
THIS PRODUCT HAS NOT BEEN TESTED FOR BIO-ACCUMULATION POTENTIAL.
ECOTOXICITY:
THIS PRODUCT HAS NOT BEEN TESTED FOR AQUATIC OR ANIMAL TOXICITY. ALL
RELEASES TO TERRESTRIAL, ATMOSPHERIC AND AQUATIC ENVIRONMENTS SHOULD BE
AVOIDED.
OTHER ADVERSE EFFECTS:
THIS MATERIAL IS NOT LISTED AS HAVING OZONE DEPLETION POTENTIAL.
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE
TO WATERWAYS.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
IT IS THE RESPONSIBILITY OF THE GENERATOR TO DETERMINE AT THE TIME OF
DISPOSAL WHETHER THE PRODUCT MEETS THE CRITERIA OF A HAZARDOUS WASTE PER
REGULATIONS OF THE AREA IN WHICH THE WASTE IS GENERATED AND/OR DISPOSED OF.
WASTE DISPOSAL MUST BE IN ACCORDANCE WITH APPROPRIATE FEDERAL, STATE, AND
LOCAL REGULATIONS. THIS PRODUCT, IF UNALTERED BY USE, MAY BE DISPOSED OF BY
TREATMENT AT A PERMITTED FACILITY OR AS ADVISED BY YOUR LOCAL HAZARDOUS
WASTE REGULATORY AUTHORITY. SHIPMENT OF WASTES MUST BE DONE WITH
APPROPRIATELY PERMITTED AND REGISTERED TRANSPORTERS.
DISPOSAL CONTAINERS:
WASTE MATERIALS MUST BE PLACED IN AND SHIPPED IN APPROPRIATE 5-GALLON OR
55-GALLON POLY OR METAL WASTE PAILS OR DRUMS. PERMEABLE CARDBOARD
CONTAINERS ARE NOT APPROPRIATE AND SHOULD NOT BE USED. ENSURE THAT ANY
REQUIRED MARKING OR LABELING OF THE CONTAINERS BE DONE TO ALL APPLICABLE
REGULATIONS.
PRECAUTIONS TO BE FOLLOWED DURING WASTE HANDLING:
WEAR PROPER PROTECTIVE EQUIPMENT WHEN HANDLING WASTE MATERIALS.
U.S. EPA WASTE NUMBER: NOT APPLICABLE.
| 14. TRANSPORTATION INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER U.S. DOT
REGULATIONS, UNDER 49 CFR 172.101.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER REGULATIONS OF
TRANSPORT CANADA.
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS UNDER RULES OF IATA.
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS BY THE INTERNATIONAL
MARITIME ORGANIZATION.
OFFICIAL MEXICAN STANDARD; REGULATION FOR THE TRANSPORT OF DANGEROUS GOODS
AND RESIDUES:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER TRANSPORT
REGULATIONS OF MEXICO.
SINGAPORE STANDARD 286:
PART A:
THIS PRODUCT HAS NO REQUIREMENTS UNDER THE SPECIFICATION FOR CAUTION
LABELING FOR HAZARDOUS SUBSTANCES, PART 4:
MARKING OF PACKAGES, CONTAINERS AND VEHICLES, AS IT DOES NOT MEET THE
CRITERIA FOR ANY HAZARD CLASS UNDER THIS REGULATION.
TRANSPORT IN BULK ACCORDING TO THE IBC CODE:
SEE THE INFORMATION UNDER THE INDIVIDUAL JURISDICTION LISTINGS FOR IBC
INFORMATION.
ENVIRONMENTAL HAZARDS:
THIS MATERIAL DOES NOT MEET THE CRITERIA OF ENVIRONMENTALLY HAZARDOUS
ACCORDING TO THE CRITERIA OF THE UN MODEL REGULATIONS (AS REFLECTED IN THE
IMDG CODE, ADR, RID, AND ADN) AND IS NOT LISTED IN ANNEX III UNDER MARPOL
73/78.
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS OF SECTIONS 302,
304, AND 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT.
U.S. SARA HAZARD CATEGORIES (SECTION 311/312, 40 CFR 370-21):
ACUTE: YES
CHRONIC: YES
FIRE: NO
REACTIVE: NO
SUDDEN RELEASE: NO
U.S. SARA THRESHOLD PLANNING QUANTITY (TPQ):
THERE ARE NO SPECIFIC THRESHOLD PLANNING QUANTITIES FOR COMPONENTS. THE
DEFAULT FEDERAL SDS SUBMISSION AND INVENTORY REQUIREMENT FILING THRESHOLD
OF 10,000 LB (4,540 KG) MAY APPLY, PER 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): NOT APPLICABLE.
U.S. TSCA INVENTORY STATUS:
COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
THE CRYSTALLINE SILICA COMPONENT IS ON THE CALIFORNIA PROPOSITION 65 LISTS.
WARNING!
THIS PRODUCT CONTAINS A COMPOUND KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS:
COMPONENTS ARE ON THE DSL OR NDSL INVENTORIES.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS:
COMPONENTS ARE NOT ON THE CEPA PRIORITIES SUBSTANCES LISTS.
CANADIAN WHMIS CLASSIFICATION AND SYMBOLS:
THIS PRODUCT WOULD BE CATEGORIZED AS A CONTROLLED PRODUCT, D2B (OTHER TOXIC
EFFECTS-POTENTIAL CARCINOGENIC EFFECT, IRRITATION) AS PER THE CONTROLLED
PRODUCT REGULATIONS.
CHINESE REGULATIONS:
CHINESE INVENTORY OF EXISTING CHEMICAL SUBSTANCES STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE CHINESE INVENTORY OF EXISTING
CHEMICAL SUBSTANCES (IECSC), OR ARE NOT LISTED, PER INFORMATION IN
SECTION 2.
JAPANESE REGULATIONS:
JAPANESE ENCS:
COMPONENTS LISTED BY CAS# ARE ON THE ENCS INVENTORY, ARE EXCEPTED, OR ARE
NOT LISTED, PER INFORMATION IN SECTION 2.
JAPANESE MINISTRY OF ECONOMY, TRADE, AND INDUSTRY (METI) STATUS:
COMPONENTS ARE NOT LISTED AS CLASS I SPECIFIED CHEMICAL SUBSTANCES,
CLASS II SPECIFIED CHEMICAL SUBSTANCES, OR DESIGNATED CHEMICAL SUBSTANCES
BY THE JAPANESE METI.
POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW:
COMPONENTS ARE NOT LISTED AS A SPECIFIED POISONOUS SUBSTANCE UNDER THE
POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW.
KOREAN REGULATIONS:
KOREAN EXISTING CHEMICALS LIST (ECL) STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE KOREAN ECL INVENTORY, OR ARE
NOT LISTED, PER INFORMATION IN SECTION 2.
MEXICAN REGULATIONS:
MEXICAN WORKPLACE REGULATIONS (NOM-018-STPS-2000):
THIS PRODUCT IS CLASSIFIED AS HAZARDOUS.
SINGAPORE REGULATIONS:
LIST OF CONTROLLED HAZARDOUS SUBSTANCES:
COMPONENTS LISTED BY CAS# ARE NOT LISTED ON THE SINGAPORE LIST OF
CONTROLLED SUBSTANCES.
CODE OF PRACTICE ON POLLUTION CONTROL REQUIREMENTS:
THE COMPONENTS IDENTIFIED BY CAS# IN SECTION 2 (COMPOSITION AND
INFORMATION ON INGREDIENTS) NOT ARE SUBJECT TO THE REQUIREMENTS
UNDER THE SINGAPORE CODE OF PRACTICE ON POLLUTION CONTROL.
TAIWANESE REGULATIONS:
TAIWAN EXISTING CHEMICAL SUBSTANCES INVENTORY STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE TAIWAN EXISTING CHEMICALS LIST.
| 16. OTHER INFORMATION | |
LABELING (PRECAUTIONARY STATEMENTS) ANSI LABELING (Z129.1):
CAUTION!
MAY CAUSE MILD IRRITATION BY INHALATION AND EYE CONTACT. PROLONGED SKIN
CONTACT MAY CAUSE IRRITATION. CONTAINS TRACE AMOUNT OF CRYSTALLINE SILICA,
A KNOWN HUMAN CARCINOGEN. AVOID BREATHING FUMES OR VAPORS. DO NOT TASTE OR
SWALLOW. KEEP CONTAINER CLOSED. USE ONLY WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. WEAR APPROPRIATE EYE, HAND, AND BODY PROTECTION.
AVOID EXPOSURE TO ELEVATED TEMPERATURES.
FIRST-AID:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN OR EYES WITH PLENTY OF WATER FOR
AT LEAST 20 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET
MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. IF INHALED, REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.
IN CASE OF FIRE: USE WATER FOG, FOAM, DRY CHEMICAL, OR CO2.
IN CASE OF SPILL:
SWEEP OR VACUUM SPILLED MATERIAL, AVOIDING GENERATION OF DUSTS AND PLACE IN
SUITABLE CONTAINER. PLACE RESIDUAL IN APPROPRIATE CONTAINER AND SEAL.
DISPOSE OF IN ACCORDANCE WITH U.S. FEDERAL, STATE, AND LOCAL HAZARDOUS
WASTE DISPOSAL REGULATIONS. CONSULT SAFETY DATA SHEET FOR ADDITIONAL
INFORMATION.
GLOBAL HARMONIZATION AND JAPANESE JIS Z7253 LABELING AND CLASSIFICATION:
THIS PRODUCT HAS BEEN CLASSIFIED PER UN GHS STANDARDS UNDER U.S., JAPANESE
AND OTHER APPLICABLE REGULATIONS THAT REQUIRE GLOBAL HARMONIZATION
COMPLIANCE.
CLASSIFICATION:
CARCINOGENIC CATEGORY 2, EYE IRRITATION CATEGORY 2A, SPECIFIC TARGET ORGAN
TOXICITY (INHALATION-RESPIRATORY IRRITATION) SINGLE EXPOSURE CATEGORY 3
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H351: SUSPECTED OF CAUSING CANCER.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P261: AVOID BREATHING VAPORS, FUME.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE GLOVES, CLOTHING, EYE PROTECTION AND FACE PROTECTION.
P284: WEAR RESPIRATORY PROTECTION.
RESPONSE:
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P304 + P340:
IF INHALED, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION
COMFORTABLE FOR BREATHING.
P312: CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
P321: SPECIFIC TREATMENT (REMOVE FROM EXPOSURE AND TREAT SYMPTOMS).
STORAGE:
P403 + P233 + P405:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINERS IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARD SYMBOLS: GHS07, GHS08
KOREAN ISHA (NOTICE 2009-68) LABELING AND CLASSIFICATION:
CLASSIFIED IN ACCORDANCE WITH ISHA NOTICE 2009-68. UNDER ISHA, NO
DIFFERENCES IN CLASSIFICATION ARE APPLICABLE.
COMPONENT CLASSIFICATION:
LABELING AND CLASSIFICATION FULL TEXT UNDER GHS:
ALUMINUM TRIHYDRATE: THIS IS A SELF-CLASSIFICATION.
CLASSIFICATION: EYE IRRITATION CATEGORY 2A
HAZARD STATEMENTS:
H319: CAUSES SERIOUS EYE IRRITATION.
CRYSTALLINE SILICA: THIS IS A SELF-CLASSIFICATION.
CLASSIFICATION:
CARCINOGENIC CATEGORY 1, SPECIFIC TARGET ORGAN TOXICITY (INHALATION-LUNGS)
REPEATED EXPOSURE CATEGORY 2
HAZARD STATEMENTS:
H350: MAY CAUSE CANCER.
H373:
MAY CAUSE DAMAGE TO LUNGS THROUGH PROLONGED OR REPEATED EXPOSURE BY
INHALATION.
REVISION DETAILS: NEW.
REFERENCES AND DATA SOURCES: CONTACT THE SUPPLIER FOR INFORMATION.
METHODS OF EVALUATING INFORMATION FOR THE PURPOSE OF CLASSIFICATION:
CRITERIA OF THE GHS WERE USED FOR CLASSIFICATION.
PREPARED BY:
CHEMICAL SAFETY ASSOCIATES, INC.
PO BOX 1961
HILO, HI 96721-1961
(800) 441-3365
DATE OF PRINTING: MAY 29, 2015
REVISION HISTORY: NEW.
EFFECTIVE DATE: OCTOBER 13, 2014