| Common Name: | SPRAY-N-BOND (4369-75) |
| Manufacturer: | NU-CALGON |
| SDS Revision Date: | 5/2/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3CFP5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: SPRAY-N-BOND (4369-75)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: ADHESIVE.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER INFORMATION:
NU-CALGON
2611 SCHUETZ ROAD
ST. LOUIS, MO 63043
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
SUPPLIER: SEE ABOVE.
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
HEALTH HAZARDS:
GASES UNDER PRESSURE: LIQUEFIED GAS
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SENSITIZATION, SKIN: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
WHMIS 2015 DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN
IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE
IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. SUSPECTED OF DAMAGING
FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION
SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH THOROUGHLY AFTER
HANDLING. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
PROTECTION. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD. AVOID BREATHING GAS.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE. SPECIFIC TREATMENT (SEE INFORMATION ON THIS LABEL).
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F. STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
WHMIS 2015:
HEALTH HAZARD(S) NOT OTHERWISE CLASSIFIED (HHNOC): NONE KNOWN
WHMIS 2015:
PHYSICAL NONE KNOWN HAZARD(S) NOT OTHERWISE CLASSIFIED (PHNOC): NONE KNOWN
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
ACETONE 67-64-1 20-30
PROPANE 74-98-6 20-30
BUTANE 106-97-8 10-30
NAPHTHA (PETROLEUM), 64742-49-0 10-30
HYDROTREATED LIGHT
1,3-BUTADIENE, 2-METHYL-, 841251-34-1 1-5
HOMOPOLYMER, MALEATED
METHYL ACETATE 79-20-9 1-5
ALL CONCENTRATIONS ARE IN PERCENT BY WEIGHT UNLESS INGREDIENT IS A GAS. GAS
CONCENTRATIONS ARE IN PERCENT BY VOLUME.
COMPOSITION COMMENTS:
US GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
| 4. FIRST AID MEASURES | |
INHALATION:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE. SPECIFIC TREATMENT (SEE INFORMATION ON THIS LABEL).
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. DO NOT INDUCE
VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. MAY CAUSE DROWSINESS
AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE IRRITATION. SYMPTOMS
MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED VISION. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. SYMPTOMS MAY
BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW
THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS
SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. WASH CONTAMINATED CLOTHING
BEFORE REUSE. AVOID CONTACT WITH EYES AND SKIN. KEEP OUT OF REACH OF
CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. ALCOHOL RESISTANT FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
NOT AVAILABLE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. DO NOT MOVE CARGO OR VEHICLE IF CARGO HAS BEEN
EXPOSED TO HEAT. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE
BUILD UP. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR
MONITOR NOZZLES, IF POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE
FIRE IS OUT. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY EXPLODE WHEN EXPOSED TO HEAT OR FLAME.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND
WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. AVOID BREATHING GAS. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. STOP LEAK
IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN AREA IF
THE LEAK IS IRREPARABLE. ISOLATE AREA UNTIL GAS HAS DISPERSED. ELIMINATE
ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE
AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. COVER WITH PLASTIC SHEET TO PREVENT SPREADING. ABSORB IN
VERMICULITE, DRY SAND OR EARTH AND PLACE INTO CONTAINERS. FOLLOWING
PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE
SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DO NOT
DISCHARGE INTO LAKES, STREAMS, PONDS OR PUBLIC WATERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. -NO SMOKING. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED
SURFACE IS THOROUGHLY DRY. PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN,
EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS MISSING OR DEFECTIVE. DO NOT
SPRAY ON A NAKED FLAME OR ANY OTHER INCANDESCENT MATERIAL. DO NOT CUT,
WELD, SOLDER, DRILL, GRIND, OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, OR
OTHER SOURCES OF IGNITION. ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT
MUST BE GROUNDED. DO NOT RE-USE EMPTY CONTAINERS. AVOID BREATHING GAS.
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. PREGNANT OR BREASTFEEDING
WOMEN MUST NOT HANDLE THIS PRODUCT. USE ONLY IN WELL-VENTILATED AREAS.
AVOID PROLONGED EXPOSURE. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
WASH THOROUGHLY AFTER HANDLING. USE GOOD INDUSTRIAL HYGIENE PRACTICES IN
HANDLING THIS MATERIAL. WHEN USING DO NOT EAT OR DRINK.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT HANDLE OR
STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES OF IGNITION. DO NOT
PUNCTURE, INCINERATE OR CRUSH. STORE IN A WELL-VENTILATED PLACE. CYLINDERS
SHOULD BE STORED UPRIGHT, WITH VALVE PROTECTION CAP IN PLACE, AND FIRMLY
SECURED TO PREVENT FALLING OR BEING KNOCKED OVER. KEEP OUT OF REACH OF
CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
CANADA. ALBERTA OELS (OCCUPATIONAL HEALTH & SAFETY CODE, SCHEDULE 1,
TABLE 2):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 1800 MG/M3
750 PPM
TWA 1200 MG/M3
500 PPM
BENZENE, ETHENYL- STEL 170 MG/M3
(CAS 100-42-5) 40 PPM
TWA 85 MG/M3
20 PPM
BUTANE (CAS 106-97-8) TWA 1000 PPM
METHYL ACETATE STEL 757 MG/M3
(CAS 79-20-9) 250 PPM
TWA 606 MG/M3
200 PPM
NAPHTHA (PETROLEUM), TWA 1590 MG/M3
HYDROTREATED LIGHT 400 PPM
(CAS 64742-49-0)
PROPANE (CAS 74-98-6) TWA 1000 PPM
CANADA. BRITISH COLUMBIA OELS. (OCCUPATIONAL EXPOSURE LIMITS FOR CHEMICAL
SUBSTANCES, OCCUPATIONAL HEALTH AND SAFETY REGULATION 296/97, AS AMENDED):
COMPONENTS TYPE VALUE VALUE
ACETONE (CAS 67-64-1) STEL 500 PPM
TWA 250 PPM
BENZENE, ETHENYL- STEL 75 PPM
(CAS 100-42-5) TWA 50 PPM
BUTANE (CAS 106-97-8) STEL 750 PPM
TWA 600 PPM
METHYL ACETATE STEL 250 PPM
(CAS 79-20-9) TWA 200 PPM
PROPANE (CAS 74-98-6) TWA 1000 PPM
CANADA. MANITOBA OELS (REG. 217/2006, THE WORKPLACE SAFETY AND HEALTH ACT):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 500 PPM
TWA 250 PPM
BENZENE, ETHENYL- STEL 40 PPM
(CAS 100-42-5) TWA 20 PPM
BUTANE (CAS 106-97-8) STEL 1000 PPM
METHYL ACETATE STEL 250 PPM
(CAS 79-20-9) TWA 200 PPM
CANADA. ONTARIO OELS. (CONTROL OF EXPOSURE TO BIOLOGICAL OR CHEMICAL
AGENTS):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 750 PPM
TWA 500 PPM
BENZENE, ETHENYL- STEL 100 PPM
(CAS 100-42-5) TWA 35 PPM
BUTANE (CAS 106-97-8) TWA 800 PPM
METHYL ACETATE STEL 250 PPM
(CAS 79-20-9) TWA 200 PPM
PROPANE (CAS 74-98-6) TWA 1000 PPM
CANADA. QUEBEC OELS. (MINISTRY OF LABOR - REGULATION RESPECTING THE QUALITY
OF THE WORK ENVIRONMENT):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 2380 MG/M3
1000 PPM
TWA 1190 MG/M3
500 PPM
BENZENE, ETHENYL- STEL 426 MG/M3
(CAS 100-42-5) 100 PPM
TWA 213 MG/M3
50 PPM
BUTANE (CAS 106-97-8) TWA 1900 MG/M3
800 PPM
METHYL ACETATE STEL 757 MG/M3
(CAS 79-20-9) 250 PPM
TWA 606 MG/M3
200 PPM
NAPHTHA (PETROLEUM), TWA 1590 MG/M3
HYDROTREATED LIGHT 400 PPM
(CAS 64742-49-0)
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
METHYL ACETATE PEL 610 MG/M3
(CAS 79-20-9) 200 PPM
NAPHTHA (PETROLEUM), PEL 400 MG/M3
HYDROTREATED LIGHT 100 PPM
(CAS 64742-49-0)
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
BENZENE, ETHENYL- (CAS 100-42-5) CEILING 200 PPM
TWA 100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 500 PPM
TWA 250 PPM
BENZENE, ETHENYL- STEL 40 PPM
(CAS 100-42-5) TWA 20 PPM
BUTANE (CAS 106-97-8) STEL 1000 PPM
METHYL ACETATE (CAS 79-20-9) STEL 250 PPM
TWA 200 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) TWA 590 MG/M3
250 PPM
BENZENE, ETHENYL- STEL 425 MG/M3
(CAS 100-42-5) 100 PPM
TWA 215 MG/M3
50 PPM
BUTANE (CAS 106-97-8) TWA 1900 MG/M3
800 PPM
METHYL ACETATE STEL 760 MG/M3
(CAS 79-20-9) 250 PPM
TWA 610 MG/M3
200 PPM
NAPHTHA (PETROLEUM), TWA 400 MG/M3
HYDROTREATED LIGHT 100 PPM
(CAS 64742-49-0)
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
ACETONE 25 MG/L ACETONE URINE *
(CAS 67-64-1)
BENZENE, ETHENYL- 40 (MICRO)G/L STYRENE URINE *
(CAS 100-42-5) 400 MG/G MANDELIC ACID CREATININE *
PLUS IN URINE
PHENYLGLYOXY-
LIC ACID
*: FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
CANADA - ALBERTA OELS: SKIN DESIGNATION
BENZENE (CAS 71-43-2): CAN BE ABSORBED THROUGH THE SKIN.
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
NAPHTHALENE (CAS 91-20-3): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
TOLUENE (CAS 108-88-3): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - BRITISH COLUMBIA OELS: SKIN DESIGNATION
BENZENE (CAS 71-43-2): CAN BE ABSORBED THROUGH THE SKIN.
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
NAPHTHALENE (CAS 91-20-3): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - MANITOBA OELS: SKIN DESIGNATION
BENZENE (CAS 71-43-2): CAN BE ABSORBED THROUGH THE SKIN.
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
NAPHTHALENE (CAS 91-20-3): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - ONTARIO OELS: SKIN DESIGNATION
BENZENE (CAS 71-43-2): CAN BE ABSORBED THROUGH THE SKIN.
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
NAPHTHALENE (CAS 91-20-3): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - QUEBEC OELS: SKIN DESIGNATION
BENZENE, ETHENYL- (CAS 100-42-5): CAN BE ABSORBED THROUGH THE SKIN.
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
TOLUENE (CAS 108-88-3): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - SASKATCHEWAN OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
NAPHTHALENE (CAS 91-20-3): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
TOLUENE (CAS 108-88-3): CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES: SKIN DESIGNATION
BENZENE (CAS 71-43-2): CAN BE ABSORBED THROUGH THE SKIN.
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
NAPHTHALENE (CAS 91-20-3): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
BENZENE, (1-METHYLETHYL)-(CAS 98-82-8): CAN BE ABSORBED THROUGH THE SKIN.
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
BENZENE, (1-METHYLETHYL)-(CAS 98-82-8): CAN BE ABSORBED THROUGH THE SKIN.
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS
TO AN ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: IMPERVIOUS GLOVES. CONFIRM WITH REPUTABLE SUPPLIER FIRST.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED. AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR. RESPIRATOR SHOULD BE SELECTED BY AND USED UNDER THE DIRECTION
OF A TRAINED HEALTH AND SAFETY PROFESSIONAL FOLLOWING REQUIREMENTS FOUND
IN OSHA'S RESPIRATOR STANDARD (29 CFR 1910.134), CAN/CSA-Z94.4 AND ANSI'S
STANDARD FOR RESPIRATORY PROTECTION (Z88.2).
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WHEN USING DO NOT EAT OR DRINK.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: GAS.
FORM: SPRAY
COLOR: YELLOW
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.84
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: -156.0 DEG. F (-104.4 DEG. C) (PROPELLANT)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE:
135 - 155 PSI @ 130 DEG. F
65-85 PSI @ 70 DEG. F
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: 7 - 200 CPS
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
FLAME PROJECTION: 32 IN
FLAMMABILITY (FLASH BACK): 2 YES
HEAT OF COMBUSTION: >30 KJ/G
OXIDIZING PROPERTIES: NOT OXIDIZING.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. NITRATES. FLUORINE. CHLORINE.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA. MAY CAUSE STOMACH
DISTRESS, NAUSEA OR VOMITING.
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED
INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. MAY CAUSE DROWSINESS
AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE IRRITATION. SYMPTOMS
MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED VISION. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. NARCOTIC EFFECTS. MAY CAUSE
AN ALLERGIC SKIN REACTION.
COMPONENTS SPECIES TEST RESULTS
1,3-BUTADIENE, 2-METHYL-, HOMOPOLYMER, MALEATED (CAS 841251-34-1):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
ACETONE (CAS 67-64-1):
ACUTE:
DERMAL:
LD50 RABBIT 15800 MG/KG
20 ML/KG
INHALATION:
LC50 MOUSE 44000 MG/M3/4H
RAT 76 MG/L, 4 HOURS
50.1 MG/L, 8 HOURS
39 MG/L/4H
ORAL:
LD50 HUMAN 2857 MG/KG
MOUSE 3000 MG/KG
RABBIT 5340 MG/KG
RAT 5800 MG/KG
BUTANE (CAS 106-97-8):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 MOUSE 539600 PPM, 120 MINUTES, ECHA
520400 PPM, 120 MINUTES, ECHA
1237 MG/L, 120 MINUTES
680 MG/L, 2 HOURS, HSDB
57%, 120 MINUTES, ECHA
52%, 120 MINUTES
RAT >800000 PPM, 10 MINUTES, ECHA
1442738 MG/M3, 10 MINUTES, ECHA
1354944 MG/M3, 10 MINUTES, ECHA
570000 PPM, 10 MINUTES, ECHA
276000 PPM, 4 HOURS, CCOHS
1443 MG/L, 10 MINUTES, ECHA
1355 MG/L, 10 MINUTES
ORAL:
LD50 NOT AVAILABLE
METHYL ACETATE (CAS 79-20-9):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
INHALATION:
LC50 RAT >16000 PPM
ORAL:
LD50 RABBIT 3705 MG/KG
3.7 G/KG
RAT >5000 MG/KG
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0):
ACUTE:
DERMAL:
LD50 RABBIT 3160 MG/KG
INHALATION:
LC50 RAT 61 MG/L, 4 HOURS
20 PPM
20 MG/L/4H
ORAL:
LD50 RAT >25 ML/KG
5000 MG/KG
PROPANE (CAS 74-98-6):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 MOUSE 539600 PPM, 120 MINUTES, ECHA
520400 PPM, 120 MINUTES, ECHA
1237 MG/L, 120 MINUTES
57%, 120 MINUTES, ECHA
52%, 120 MINUTES
RAT >12000000 PPM, 4 HOURS
>800000 PPM, 10 MINUTES, ECHA
>1464 MG/L, 15 MINUTES, HSDB
1442738 MG/M3, 10 MINUTES, ECHA
1354944 MG/M3, 10 MINUTES, ECHA
570000 PPM, 10 MINUTES, ECHA
1355 MG/L, 10 MINUTES
ORAL:
LD50 NOT AVAILABLE
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
CANADA - ALBERTA OELS: IRRITANT
ACETALDEHYDE (CAS 75-07-0): IRRITANT
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL-(CAS 128-37-0): IRRITANT
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: SEE BELOW.
ACGIH CARCINOGENS:
ACETALDEHYDE (CAS 75-07-0): A2 SUSPECTED HUMAN CARCINOGEN.
BENZENE (CAS 71-43-2): A1 SUSPECTED HUMAN CARCINOGEN.
BENZENE, ETHYL-(CAS 100-41-4):
A3 CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
NAPHTHALENE (CAS 91-20-3):
A3 CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
CANADA - ALBERTA OELS: CARCINOGEN CATEGORY
BENZENE (CAS 71-43-2): CONFIRMED HUMAN CARCINOGEN.
CANADA - MANITOBA OELS: CARCINOGENICITY
ACETALDEHYDE (CAS 75-07-0): SUSPECTED HUMAN CARCINOGEN.
ACETONE (CAS 67-64-1): NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
BENZENE (CAS 71-43-2): CONFIRMED HUMAN CARCINOGEN.
BUTYLATED HYDROXYTOLUENE (BHT), INHALABLE FRACTION AND VAPOR (CAS
128-37-0): NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
ETHYL BENZENE (CAS 100-41-4):
CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
NAPHTHALENE (CAS 91-20-3):
CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
PHENOL (CAS 108-95-2): NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
STYRENE, MONOMER (CAS 100-42-5): NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
TOLUENE (CAS 108-88-3): NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
CANADA - QUEBEC OELS: CARCINOGEN CATEGORY
ACETALDEHYDE (CAS 75-07-0): DETECTED CARCINOGENIC EFFECT IN ANIMALS.
BENZENE (CAS 71-43-2): DETECTED CARCINOGENIC EFFECT IN HUMANS.
BENZENE, ETHENYL- (CAS 100-42-5): DETECTED CARCINOGENIC EFFECT IN ANIMALS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
ACETALDEHYDE (CAS 75-07-0):
VOLUME 36, SUPPLEMENT 7, VOLUME 71 - 2B POSSIBLY CARCINOGENIC TO HUMANS.
BENZENE (CAS 71-43-2):
VOLUME 29, SUPPLEMENT 7, VOLUME 100F 1 CARCINOGENIC TO HUMANS.
BENZENE, (1-METHYLETHYL)-(CAS 98-82-8):
VOLUME 101 - 2B POSSIBLY CARCINOGENIC TO HUMANS.
BENZENE, ETHENYL- (CAS 100-42-5):
VOLUME 60, VOLUME 82 - 2B POSSIBLY CARCINOGENIC TO HUMANS.
BENZENE, ETHYL-(CAS 100-41-4):
VOLUME 77 - 2B POSSIBLY CARCINOGENIC TO HUMANS.
NAPHTHALENE (CAS 91-20-3):
VOLUME 82 - 2B POSSIBLY CARCINOGENIC TO HUMANS.
PHENOL (CAS 108-95-2):
VOLUME 47, VOLUME 71 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL-(CAS 128-37-0):
VOLUME 40, SUPPLEMENT 7 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO
HUMANS.
TOLUENE (CAS 108-88-3):
VOLUME 47, VOLUME 71 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
ACETALDEHYDE (CAS 75-07-0)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)-(CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
NAPHTHALENE (CAS 91-20-3)
US NTP REPORT ON CARCINOGENS: ANTICIPATED CARCINOGEN
ACETALDEHYDE (CAS 75-07-0):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
BENZENE, (1-METHYLETHYL)-(CAS 98-82-8):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
BENZENE, ETHENYL- (CAS 100-42-5):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
NAPHTHALENE (CAS 91-20-3):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
US NTP REPORT ON CARCINOGENS: KNOWN CARCINOGEN
BENZENE (CAS 71-43-2): KNOWN TO BE HUMAN CARCINOGEN.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
BENZENE (CAS 71-43-2): CANCER
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
ECOTOXICOLOGICAL DATA:
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
CRUSTACEA EC50 DAPHNIA 13999 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 10294 - 17704 MG/L,
48 HOURS
FISH LC50 RAINBOW TROUT, DONALDSON 4740 - 6330 MG/L,
TROUT (ONCORHYNCHUS 96 HOURS
MYKISS)
METHYL ACETATE (CAS 79-20-9):
ALGAE IC50 ALGAE 120 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 1026.7 MG/L, 48 HOURS
AQUATIC:
FISH LC50 FATHEAD MINNOW (PIMEPHALES 295 - 348 MG/L,
PROMELAS) 96 HOURS
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA PULEX) 2.7 - 5.1 MG/L,
48 HOURS
FISH LC50 RAINBOW TROUT, DONALDSON 8.8 MG/L, 96 HOURS
TROUT (ONCORHYNCHUS MYKISS) 8.8 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
TRANSPORT OF DANGEROUS GOODS (TDG) PROOF OF CLASSIFICATION:
IN ACCORDANCE WITH PART 2.2.1 (SOR/2014-152) OF THE TRANSPORTATION OF
DANGEROUS GOODS REGULATIONS, WE CERTIFY THAT THE CLASSIFICATION OF THIS
PRODUCT IS CORRECT AS OF THE SDS DATE OF ISSUE.
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
HAZARD CLASS: LIMITED QUANTITY - US
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - CANADA
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - IATA
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS: LIMITED QUANTITY - IMDG
DOT; IMDG; TDG:
LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA:
LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE HPR AND THE SDS CONTAINS ALL THE INFORMATION REQUIRED BY THE HPR.
CANADA CEPA SCHEDULE I: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0): LISTED.
BENZENE (CAS 71-43-2): LISTED.
NAPHTHALENE (CAS 91-20-3): LISTED.
CANADA DSL CHALLENGE SUBSTANCES: LISTED SUBSTANCE
BUTANE (CAS 106-97-8): LISTED.
NAPHTHALENE (CAS 91-20-3): LISTED.
CANADA NPRI VOCS WITH ADDITIONAL REPORTING REQUIREMENTS: MASS REPORTING
THRESHOLD/IDENTIFICATION NUMBER
BENZENE (CAS 71-43-2): 1 TONNES
BENZENE, ETHENYL- (CAS 100-42-5): 1 TONNES
BUTANE (CAS 106-97-8): 1 TONNES
METHANOL (CAS 67-56-1): 1 TONNES
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0): 1 TONNES
PROPANE (CAS 74-98-6): 1 TONNES
TOLUENE (CAS 108-88-3): 1 TONNES
CANADA PRIORITY SUBSTANCES LIST (SECOND LIST): LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0): LISTED.
PHENOL (CAS 108-95-2): LISTED.
EXPORT CONTROL LIST (CEPA 1999, SCHEDULE 3): NOT LISTED.
GREENHOUSE GASES: NOT LISTED.
PRECURSOR CONTROL REGULATIONS:
ACETONE (CAS 67-64-1): CLASS B
TOLUENE (CAS 108-88-3): CLASS B
WHMIS 2015 EXEMPTIONS: NOT APPLICABLE
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
ACETALDEHYDE (CAS 75-07-0): 0.1% ONE-TIME EXPORT NOTIFICATION ONLY.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETALDEHYDE (CAS 75-07-0): LISTED.
ACETONE (CAS 67-64-1): LISTED.
BENZENE (CAS 71-43-2): LISTED.
BENZENE, (1-METHYLETHYL)-(CAS 98-82-8): LISTED.
BENZENE, ETHENYL- (CAS 100-42-5): LISTED.
BENZENE, ETHYL-(CAS 100-41-4): LISTED.
BUTANE (CAS 106-97-8): LISTED.
CYCLOHEXANE (CAS 110-82-7): LISTED.
METHANOL (CAS 67-56-1): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
NAPHTHALENE (CAS 91-20-3): LISTED.
PHENOL (CAS 108-95-2): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US EPCRA SECTION 304 EXTREMELY HAZ. SUBS. & CERCLA HAZ. SUBS.: SECTION 304
EHS REPORTABLE QUANTITY
PHENOL (CAS 108-95-2): 1000 LBS
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
BENZENE (CAS 71-43-2):
CANCER
CENTRAL NERVOUS SYSTEM
BLOOD
ASPIRATION
SKIN
EYE
RESPIRATORY TRACT IRRITATION
FLAMMABILITY
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
ACETALDEHYDE (CAS 75-07-0)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)-(CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
METHANOL (CAS 67-56-1)
NAPHTHALENE (CAS 91-20-3)
PHENOL (CAS 108-95-2)
TOLUENE (CAS 108-88-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
ACETALDEHYDE (CAS 75-07-0)
BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
US STATE REGULATIONS: SEE BELOW
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S): LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0): LISTED.
ACETONE (CAS 67-64-1): LISTED.
BENZENE (CAS 71-43-2): LISTED.
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8): LISTED.
BENZENE, ETHENYL- (CAS 100-42-5): LISTED.
BENZENE, ETHYL-(CAS 100-41-4): LISTED.
BUTANE (CAS 106-97-8): LISTED.
CYCLOHEXANE (CAS 110-82-7): LISTED.
METHANOL (CAS 67-56-1): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0): LISTED.
NAPHTHALENE (CAS 91-20-3): LISTED.
PHENOL (CAS 108-95-2): LISTED.
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL- (CAS 128-37-0): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0)
ACETONE (CAS 67-64-1)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
METHANOL (CAS 67-56-1)
METHYL ACETATE (CAS 79-20-9)
NAPHTHALENE (CAS 91-20-3)
PHENOL (CAS 108-95-2)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US - LOUISIANA SPILL REPORTING: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0): LISTED.
ACETONE (CAS 67-64-1): LISTED.
BENZENE (CAS 71-43-2): LISTED.
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8): LISTED.
BENZENE, ETHENYL- (CAS 100-42-5): LISTED.
BENZENE, ETHYL-(CAS 100-41-4): LISTED.
BUTANE (CAS 106-97-8): LISTED.
CYCLOHEXANE (CAS 110-82-7): LISTED.
METHANOL (CAS 67-56-1): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
NAPHTHALENE (CAS 91-20-3): LISTED.
PHENOL (CAS 108-95-2): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US - MICHIGAN CRITICAL MATERIALS REGISTER: PARAMETER NUMBER
BENZENE (CAS 71-43-2): BENZENE
BENZENE, ETHENYL- (CAS 100-42-5): STYRENE (MONOMER)
TOLUENE (CAS 108-88-3): TOLUENE
US - MINNESOTA HAZ SUBS: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0): LISTED.
ACETONE (CAS 67-64-1): LISTED.
BENZENE (CAS 71-43-2): LISTED.
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8): LISTED.
BENZENE, ETHENYL- (CAS 100-42-5): LISTED.
BENZENE, ETHYL-(CAS 100-41-4): LISTED.
BUTANE (CAS 106-97-8): LISTED.
CYCLOHEXANE (CAS 110-82-7): LISTED.
METHANOL (CAS 67-56-1): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0): LISTED.
NAPHTHALENE (CAS 91-20-3): LISTED.
PHENOL (CAS 108-95-2): LISTED.
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL- (CAS 128-37-0): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0)
ACETONE (CAS 67-64-1)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
METHANOL (CAS 67-56-1)
METHYL ACETATE (CAS 79-20-9)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
NAPHTHALENE (CAS 91-20-3)
PHENOL (CAS 108-95-2)
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL- (CAS 128-37-0)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US - NORTH CAROLINA TOXIC AIR POLLUTANTS: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0)
BENZENE (CAS 71-43-2)
BENZENE, ETHENYL- (CAS 100-42-5)
PHENOL (CAS 108-95-2)
TOLUENE (CAS 108-88-3)
US - PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES: SPECIAL HAZARD
BENZENE (CAS 71-43-2)
US - TEXAS EFFECTS SCREENING LEVELS HAZARD DATA: SIMPLE ASPHYXIANT
PROPANE (CAS 74-98-6)
US - TEXAS EFFECTS SCREENING LEVELS: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0): LISTED.
ACETONE (CAS 67-64-1): LISTED.
BENZENE (CAS 71-43-2): LISTED.
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8): LISTED.
BENZENE, ETHENYL- (CAS 100-42-5): LISTED.
BENZENE, ETHYL-(CAS 100-41-4): LISTED.
BUTANE (CAS 106-97-8): LISTED.
CYCLOHEXANE (CAS 110-82-7): LISTED.
METHANOL (CAS 67-56-1): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0): LISTED.
NAPHTHALENE (CAS 91-20-3): LISTED.
PHENOL (CAS 108-95-2) LISTED.
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL- (CAS 128-37-0): LISTED.
PROPANE (CAS 74-98-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
US - WASHINGTON CHEMICAL OF HIGH CONCERN TO CHILDREN: LISTED SUBSTANCE
ACETALDEHYDE (CAS 75-07-0)
BENZENE (CAS 71-43-2)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
PHENOL (CAS 108-95-2)
TOLUENE (CAS 108-88-3)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ACETALDEHYDE (CAS 75-07-0)
ACETONE (CAS 67-64-1)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
METHANOL (CAS 67-56-1)
METHYL ACETATE (CAS 79-20-9)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
NAPHTHALENE (CAS 91-20-3)
PHENOL (CAS 108-95-2)
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL- (CAS 128-37-0)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
ACETALDEHYDE (CAS 75-07-0)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
METHANOL (CAS 67-56-1)
NAPHTHALENE (CAS 91-20-3)
PHENOL (CAS 108-95-2)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
ACETALDEHYDE (CAS 75-07-0)
ACETONE (CAS 67-64-1)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
METHANOL (CAS 67-56-1)
METHYL ACETATE (CAS 79-20-9)
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-49-0)
NAPHTHALENE (CAS 91-20-3)
PHENOL (CAS 108-95-2)
PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYL- (CAS 128-37-0)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. RHODE ISLAND RTK:
ACETALDEHYDE (CAS 75-07-0)
ACETONE (CAS 67-64-1)
BENZENE (CAS 71-43-2)
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8)
BENZENE, ETHENYL- (CAS 100-42-5)
BENZENE, ETHYL-(CAS 100-41-4)
BUTANE (CAS 106-97-8)
CYCLOHEXANE (CAS 110-82-7)
METHANOL (CAS 67-56-1)
NAPHTHALENE (CAS 91-20-3)
PHENOL (CAS 108-95-2)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. CALIFORNIA PROPOSITION 65:
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
ACETALDEHYDE (CAS 75-07-0):
LISTED: APRIL 1, 1988
BENZENE (CAS 71-43-2):
LISTED: FEBRUARY 27, 1987
BENZENE, (1-METHYLETHYL)- (CAS 98-82-8):
LISTED: APRIL 6, 2010
BENZENE, ETHENYL- (CAS 100-42-5):
LISTED: APRIL 22, 2016
BENZENE, ETHYL-(CAS 100-41-4):
LISTED: JUNE 11, 2004
NAPHTHALENE (CAS 91-20-3):
LISTED: APRIL 19, 2002
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
METHANOL (CAS 67-56-1):
LISTED: MARCH 16, 2012
TOLUENE (CAS 108-88-3):
LISTED: JANUARY 1, 1991
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/MALE REPRODUCTIVE TOXIN
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
INVENTORY STATUS:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY YES
PUERTO RICO
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH
THE INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
4
0
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 02-MAY-2017
VERSION #: 01
EFFECTIVE DATE: 02-MAY-2017
PREPARED BY: NU-CALGON TECHNICAL SERVICE
PHONE: (314) 469-7000
OTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN
SECTION 1 OF THIS DOCUMENT.
#27962
4369-75 (CANADA/US GHS)