| Common Name: | ULTRA GREY RIGID HIGH TORQUE RTV 13 OZ, 82195 |
| Manufacturer: | ITW PERMATEX |
| SDS Revision Date: | 3/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3DPU1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PERMATEX(R*)
SAFETY DATA SHEET
REVISION DATE: 02-MAR-2015
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: ULTRA GREY RIGID HIGH TORQUE RTV 13 OZ
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 82195
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: SEALANT
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER ADDRESS:
ITW PERMATEX
10 COLUMBUS BLVD.
HARTFORD, CT 06106
USA
DISTRIBUTOR:
ITW PERMATEX CANADA
35 BROWNRIDGE ROAD UNIT 1
HALTON HILLS, ON L7G 0C6
CANADA
TELEPHONE: (800) 924-6994
COMPANY PHONE NUMBER:
1-87-PERMATEX
(877) 376-2839
24 HOUR EMERGENCY PHONE NUMBER:
CHEM-TEL: 800-255-3924
INTERNATIONAL EMERGENCY: 00+1+813-248-0585
CONTRACT NUMBER: MIS0003453
E-MAIL ADDRESS: MAIL@PERMATEX.COM
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
OSHA REGULATORY STATUS:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
LABEL ELEMENTS:
EMERGENCY OVERVIEW:
WARNING:
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE AN ALLERGIC SKIN REACTION:
SUSPECTED OF CAUSING CANCER
EXCLAMATION MARK
HEALTH HAZARD
APPEARANCE: GRAY
PHYSICAL STATE: PASTE
ODOR: MILD
PRECAUTIONARY STATEMENTS - PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
PRECAUTIONARY STATEMENTS - RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL)
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
WASH CONTAMINATED CLOTHING BEFORE REUSE
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: NOT APPLICABLE
UNKNOWN ACUTE TOXICITY:
32.7506% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE(S):
CHEMICAL NAME CAS NO WEIGHT-% TRADE SECRET
POLY (DIMETHYLSILOXANE), 70131-67-8 30 - 60 *
HYDROXY TERMINATED
CALCIUM CARBONATE 471-34-1 10 - 30 *
GARNET MINERAL 1302-62-1 10 - 30 *
VINYL OXIMINOSILANE 2224-33-1 3 - 7 *
2-BUTANONE OXIME 96-29-7 1 - 5 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
SKIN CONTACT:
IF ON SKIN: WASH SKIN WITH SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
INGESTION:
IF SWALLOWED. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. CALL A PHYSICIAN.
SELF-PROTECTION OF THE FIRST AIDER:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS: SEE SECTION 2 FOR MORE INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2), DRY CHEMICAL, FOAM
UNSUITABLE EXTINGUISHING MEDIA: NONE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE IN PARTICULAR.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. AVOID CONTACT
WITH EYES AND SKIN. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. SEE SECTION 12
FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
ENSURE ADEQUATE VENTILATION. FLOOD WITH WATER TO COMPLETE POLYMERIZATION
AND SCRAPE OFF FLOOR. SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR
DISPOSAL. SLIPPERY, CAN CAUSE FALLS IF WALKED ON.
PREVENTION OF SECONDARY HAZARDS:
CLEAN CONTAMINATED OBJECTS AND AREAS THOROUGHLY OBSERVING ENVIRONMENTAL
REGULATIONS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE
AND SAFETY PRACTICE. AVOID BREATHING VAPORS OR MISTS. AVOID CONTACT WITH
SKIN, EYES OR CLOTHING. WASH THOROUGHLY AFTER HANDLING. WASH CONTAMINATED
CLOTHING BEFORE REUSE. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. PROTECT
FROM MOISTURE.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS, ACIDS, WATER
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
CALCIUM CARBONATE TWA: 10 MG/M3 TOTAL DUST
471-34-1 TWA: 5 MG/M3 RESPIRABLE DUST
NIOSH IDLH: IMMEDIATELY DANGEROUS TO LIFE OR HEALTH
OTHER INFORMATION:
VACATED LIMITS REVOKED BY THE COURT OF APPEALS DECISION IN AFL-CIO V. OSHA,
965 F.2D 962 (11TH CIR., 1992).
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN AND BODY PROTECTION: WEAR PROTECTIVE GLOVES AND PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
USE NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR
CANISTER, AS APPROPRIATE.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
REGULAR CLEANING OF EQUIPMENT, WORK AREA AND CLOTHING IS RECOMMENDED.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: PASTE
APPEARANCE: GRAY
ODOR: MILD
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS - METHOD
PH NO INFORMATION AVAILABLE
MELTING POINT / FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT / BOILING RANGE NOT APPLICABLE POLYMERIZATION
FLASH POINT >93 DEG. C / >199 DEG. F TAG CLOSED CUP
EVAPORATION RATE <1 BUTYL ACETATE = 1
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT: NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT: NO INFORMATION AVAILABLE
VAPOR PRESSURE <5 MMHg @ 70 DEG. F
VAPOR DENSITY >1 AIR = 1
RELATIVE DENSITY 1.47
WATER SOLUBILITY NO INFORMATION AVAILABLE
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
KINEMATIC VISCOSITY NO INFORMATION AVAILABLE
DYNAMIC VISCOSITY NO INFORMATION AVAILABLE
EXPLOSIVE PROPERTIES NO INFORMATION AVAILABLE
OXIDIZING PROPERTIES NO INFORMATION AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO INFORMATION AVAILABLE
MOLECULAR WEIGHT NO INFORMATION AVAILABLE
VOC CONTENT (%) <2%
DENSITY NO INFORMATION AVAILABLE
BULK DENSITY NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: EXCESSIVE HEAT.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS, ACIDS, WATER
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES
NITROGEN OXIDES (NOX)
FORMALDEHYDE
MAY RELEASE 2-BUTANONE OXIME (ETHYL METHYL KETOXIME) AT ELEVATED
TEMPERATURE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: MAY CAUSE IRRITATION OF RESPIRATORY TRACT.
EYE CONTACT:
CONTACT WITH EYES MAY CAUSE IRRITATION. MAY CAUSE REDNESS AND TEARING OF
THE EYES.
SKIN CONTACT:
MAY CAUSE SENSITIZATION BY SKIN CONTACT. MAY CAUSE SKIN IRRITATION AND/OR
DERMATITIS.
INGESTION: INGESTION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES.
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
POLY (DIMETHYLSILOXANE), >16 ML/KG >8750 MG/M3
HYDROXY TERMINATED (RABBIT) (RAT) 7 H
70131-67-8
CALCIUM CARBONATE =6450 MG/KG
471-34-1 (RAT)
2-BUTANONE OXIME =930 MG/KG =0.2 MG/KG =20 MG/L
96-29-7 (RAT) (RABBIT) (RAT) 4 H
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
GERM CELL MUTAGENICITY: NO INFORMATION AVAILABLE.
CARCINOGENICITY: NO INFORMATION AVAILABLE.
TARGET ORGAN EFFECTS: EYES, RESPIRATORY SYSTEM, SKIN.
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
ATEMIX (ORAL): 14587
ATEMIX (DERMAL): 17649
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
99.8106% OF THE MIXTURE CONSISTS OF COMPONENTS(S) OF UNKNOWN HAZARDS TO THE
AQUATIC ENVIRONMENT
CHEMICAL NAME ALGAE/AQUATIC PLANTS FISH CRUSTACEA
2-BUTANONE OXIME 83: 777 - 914: 750:
96-29-7 72 H DESMODESMUS 96 H PIMEPHALES 48 H DAPHNIA
SUBSPICATUS PROMELAS MG/L MAGNA MG/L EC50
MG/L EC50 LC50 FLOW-THROUGH
320 - 1000:
96 H LEUCISCUS
IDUS MG/L LC50
STATIC
760:
96 H POECILIA
RETICULATA
MG/L LC50 STATIC
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
CHEMICAL NAME PARTITION COEFFICIENT
2-BUTANONE OXIME 0.65
96-29-7
OTHER ADVERSE EFFECTS NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING: DO NOT REUSE CONTAINER.
US EPA WASTE NUMBER: NOT APPLICABLE
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME: NOT REGULATED
IATA:
PROPER SHIPPING NAME: NOT REGULATED
IMDG:
PROPER SHIPPING NAME: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
DSL/NDSL: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
EINECS/ELINCS: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
ENCS: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
IECSC: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
KECL: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
PICCS: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
AICS: NOT LISTED.
CONTAINS: NATURAL SUBSTANCE(S)
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
ALUMINIUM POWDER X X X
7429-90-5
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OF THE LAST REVISION
NFPA:
HEALTH HAZARDS 2
FLAMMABILITY 1
INSTABILITY 0
HMIS:
HEALTH HAZARDS 2
FLAMMABILITY 1
PHYSICAL HAZARDS 0
PERSONAL PROTECTION B
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION)
HMIS (HAZARDOUS MATERIAL INFORMATION SYSTEM)
REVISION DATE: 02-MAR-2015
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET IS CORRECT TO
THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE
VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.