| Common Name: | NATURAL DEGREASER CITRUS-BASED DEGREASER 14007, 14008 |
| Manufacturer: | CRC |
| SDS Revision Date: | 12/1/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 3APL6, 3EEC5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 14007, 14008
RECOMMENDED USE: GENERAL PURPOSE DEGREASER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 4
HEALTH HAZARDS:
ACUTE TOXICITY, INHALATION: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SENSITIZATION, SKIN: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 3
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
COMBUSTIBLE LIQUID. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES
SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. HARMFUL IF INHALED.
MAY CAUSE DROWSINESS OR DIZZINESS. TOXIC TO AQUATIC LIFE. HARMFUL TO
AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE WITH
ADEQUATE VENTILATION. OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A
FRESH AIR SUPPLY DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE
ANY SYMPTOMS LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA.
AVOID BREATHING MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED
WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES/EYE PROTECTION/FACE PROTECTION. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE
REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IN CASE OF FIRE:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
STORAGE:
KEEP COOL. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
16% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE INHALATION
TOXICITY.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
DIPROPYLENE GLYCOL MONOMETHYL 88917-22-0 50 - 60
ETHER ACETATE
DISTILLATES (PETROLEUM), 64742-47-8 30 - 40
HYDROTREATED LIGHT
SOYBEAN OIL, METHYL ESTER 67784-80-9 10 - 20
D-LIMONENE 5989-27-5 1 - 3
DIPENTENE 68956-56-9 <1
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. CALL A POISON CENTER
OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS:
SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
EYE CONTACT:
RINSE WITH WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND
PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
DIARRHEA. MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING.
IRRITATION OF EYES AND MUCOUS MEMBRANES. IRRITATION OF NOSE AND THROAT.
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. RASH. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
WARM. KEEP VICTIM UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM. WATER FOG. DRY CHEMICAL POWDER. DRY CHEMICALS.
CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THE PRODUCT IS COMBUSTIBLE, AND HEATING MAY GENERATE VAPORS WHICH MAY FORM
EXPLOSIVE VAPOR/AIR MIXTURES. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE
FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS FROM
FIRE AREA IF YOU CAN DO SO WITHOUT RISK. COOL CONTAINERS EXPOSED TO HEAT
WITH WATER SPRAY AND REMOVE CONTAINER, IF NO RISK IS INVOLVED.
GENERAL FIRE HAZARDS: COMBUSTIBLE LIQUID.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. ELIMINATE ALL IGNITION SOURCES (NO
SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE
PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEAN-UP. AVOID INHALATION OF
VAPORS AND SPRAY MISTS. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL
UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE ADEQUATE
VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES
CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. THIS MATERIAL IS CLASSIFIED AS A WATER POLLUTANT UNDER
THE CLEAN WATER ACT AND SHOULD BE PREVENTED FROM CONTAMINATING SOIL OR
FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS WHICH LEAD TO WATERWAYS.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. USE WATER SPRAY TO
REDUCE VAPORS OR DIVERT VAPOR CLOUD DRIFT. DIKE THE SPILLED MATERIAL, WHERE
THIS IS POSSIBLE. COVER WITH PLASTIC SHEET TO PREVENT SPREADING. USE A
NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP THE
PRODUCT AND PLACE INTO A CONTAINER FOR LATER DISPOSAL. FOLLOWING PRODUCT
RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE IF
SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE
GROUND. INFORM APPROPRIATE MANAGERIAL OR SUPERVISORY PERSONNEL OF ALL
ENVIRONMENTAL RELEASES.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. WHEN
USING DO NOT SMOKE. AVOID BREATHING VAPOR. AVOID CONTACT WITH EYES, SKIN,
AND CLOTHING. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE
ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. FOR PRODUCT USAGE
INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION. STORE IN A COOL, DRY PLACE
OUT OF DIRECT SUNLIGHT. STORE IN ORIGINAL TIGHTLY CLOSED CONTAINER. STORE
IN A WELL-VENTILATED PLACE. KEEP IN AN AREA EQUIPPED WITH SPRINKLERS. STORE
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT TWA 100 MG/M3
(CAS 64742-47-8)
US. AIHA WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
D-LIMONENE TWA 165.5 MG/M3
(CAS 5989-27-5) 30 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. NEOPRENE.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: CLEAR.
ODOR: CITRUS.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -139.9 DEG. F (-95.5 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
304 DEG. F (151.1 DEG. C) ESTIMATED
FLASH POINT: 172 DEG. F (77.8 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: SLOW.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 0.6% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 5.5% ESTIMATED
VAPOR PRESSURE: 0.4 HPA ESTIMATED
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: 0.88
SOLUBILITY (WATER): SLIGHTLY SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 456.8 DEG. F (236 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 100% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. AVOID
TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
INHALATION:
HARMFUL IF INHALED. MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA,
VOMITING.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
DIARRHEA. MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING.
IRRITATION OF NOSE AND THROAT. ASPIRATION MAY CAUSE PULMONARY EDEMA AND
PNEUMONITIS. RASH. IRRITATION OF EYES AND MUCOUS MEMBRANES. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. HARMFUL IF INHALED. NARCOTIC
EFFECTS. MAY CAUSE AN ALLERGIC SKIN REACTION.
PRODUCT SPECIES TEST RESULTS
NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER:
ACUTE:
DERMAL:
LD50 RABBIT 2072.5388 MG/KG ESTIMATED
INHALATION:
LC50 RAT 6.5315 MG/L, 4 HOURS ESTIMATED
ORAL:
LD50 RAT 5181.3472 MG/KG ESTIMATED
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
D-LIMONENE (CAS 5989-27-5):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. IF ASPIRATED INTO LUNGS
DURING SWALLOWING OR VOMITING, MAY CAUSE CHEMICAL PNEUMONIA, PULMONARY
INJURY OR DEATH.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
TOXIC TO AQUATIC LIFE. HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRODUCT SPECIES TEST RESULTS
NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER:
AQUATIC:
CRUSTACEA EC50 DAPHNIA 2651.4287 MG/L,
48 HOURS ESTIMATED
ACUTE:
FISH LC50 FISH 6.3146 MG/L,
96 HOURS ESTIMATED
COMPONENTS SPECIES TEST RESULTS
DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE (CAS 88917-22-0):
AQUATIC:
ACUTE:
CRUSTACEA LC50 WATER FLEA (DAPHNIA MAGNA) 2701 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW 151 MG/L, 96 HOURS
(PIMEPHALES PROMELAS)
RAINBOW TROUT, DONALDSON 111 MG/L, 96 HOURS
TROUT (ONCORHYNCHUS MYKISS)
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
AQUATIC:
ACUTE:
FISH LC50 BLUEGILL 2.2 MG/L, 96 HOURS
(LEPOMIS MACROCHIRUS)
D-LIMONENE (CAS 5989-27-5):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA PULEX) 69.6 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW 0.619 - 0.796 MG/L,
(PIMEPHALES PROMELAS) 96 HOURS
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE: 0.61 OECD 107
D-LIMONENE: 4.232
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
THIS PRODUCT IS NOT A RCRA HAZARDOUS WASTE (SEE 40 CFR PART
261.20 - 261.33). EMPTY CONTAINERS MAY BE RECYCLED. COLLECT AND RECLAIM
OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE DISPOSAL SITE. DO NOT
ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE
PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE: NOT REGULATED.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED AS DANGEROUS GOODS.
IATA: NOT REGULATED AS DANGEROUS GOODS.
IMDG: NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
NOT LISTED.
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312 HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. CALIFORNIA CONTROLLED SUBSTANCES. CA DEPARTMENT OF JUSTICE
(CALIFORNIA HEALTH AND SAFETY CODE SECTION 11100): NOT LISTED.
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)
US. MASSACHUSETTS RTK - SUBSTANCE LIST: NONE.
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)
US. RHODE ISLAND RTK: NONE.
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/DEVELOPMENTAL TOXIN
METHANOL (CAS 67-56-1) LISTED: MARCH 16, 2012
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 100%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A GENERAL PURPOSE DEGREASER (NON-AEROSOL).
THIS PRODUCT IS NOT COMPLIANT TO BE SOLD FOR USE IN CALIFORNIA. THIS
PRODUCT IS COMPLIANT IN ALL OTHER STATES.
VOC CONTENT (CA): 4%
VOC CONTENT (OTC): 4%
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL YES
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS NO
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 12-01-2014
PREPARED BY: ALLISON CHO
VERSION #: 01
FURTHER INFORMATION: CRC # 695
HMIS(R*) RATINGS:
HEALTH 1
FLAMMABILITY 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 2
INSTABILITY 0
NFPA RATINGS:
1
2
0
DISCLAIMER:
CRC CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS INFORMATION AND ITS
PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN COMBINATION WITH ITS
PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY TO ENSURE SAFE
CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE PRODUCT, AND TO ASSUME
LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO IMPROPER USE. THE
INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC MATERIAL AS
SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED IN
COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO THE
BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC
TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS
ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON
THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR
CRC INDUSTRIES.
MATERIAL NAME: NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER
SDS: US