| Common Name: | KNOCK'ER LOOSE PENETRATING SOLVENT - 13 OZ NO. 03020 (ITEM 1003220) |
| Manufacturer: | CRC INDUSTRIES |
| SDS Revision Date: | 4/1/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 3EED4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: KNOCK'ER LOOSE(R*) PENETRATING SOLVENT - 13 OZ
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: NO. 03020 (ITEM# 1003270)
RECOMMENDED USE: PENETRANT
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18924
US
TELEPHONE:
GENERAL INFORMATION: 215-624-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-222-4620
24-HOUR EMERGENCY (CHEMTREC): 800-424-9300 (US)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
GASES UNDER PRESSURE: COMPRESSED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1A
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS. CAUSES SKIN IRRITATION. MAY CAUSE AN
ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. TOXIC TO AQUATIC
LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
DO NOT PUNCTURE OR INCINERATE CONTAINER. DO NOT EXPOSE TO HEAT OR STORE AT
TEMPERATURES ABOVE 49 DEG. C/120 DEG. F. USE WITH ADEQUATE VENTILATION.
OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY
DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS
LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA. AVOID
BREATHING MIST/VAPOR. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR EYE PROTECTION/FACE
PROTECTION. WEAR PROTECTIVE GLOVES. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION. COLLECT SPILLAGE.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
EXPOSURE TO HIGH TEMPERATURE MAY CAUSE CAN TO BURST.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
DISTILLATES (PETROLEUM), 64742-46-7 40 - 50
HYDROTREATED MIDDLE
DIPROPYLENE GLYCOL 88917-22-0 5 - 10
METHYL ETHER ACETATE
DIPROPYLENE GLYCOL 29911-27-1 5 - 10
N-PROPYL ETHER
TURPENTINE, OIL 8006-64-2 5 - 10
2,6-DIMETHYL-4-HEPTANONE 108-83-8 3 - 5
FATTY ESTER PROPRIETARY 3 - 5
CARBON DIOXIDE 124-38-9 1 - 3
DISTILLATES (PETROLEUM), 64742-47-8 1 - 3
HYDROTREATED LIGHT
NAPHTHA (PETROLEUM), 64742-48-9 1 - 3
HYDROTREATED HEAVY
PINE OIL 8002-09-3 1 - 3
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. CALL A PHYSICIAN IF SYMPTOMS DEVELOP OR PERSIST.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS:
SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
PRESSURIZED CONTAINER MAY RUPTURE WHEN EXPOSED TO HEAT OR FLAME. DURING
FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO
WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP.
GENERAL FIRE HAZARDS:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY RUPTURE WHEN EXPOSED TO
HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND
WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. AVOID BREATHING MIST/VAPORS. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. THIS PRODUCT IS MISCIBLE IN WATER. PREVENT PRODUCT FROM
ENTERING DRAINS. STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. WIPE
UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY
TO REMOVE RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE SECTION 13 OF
THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS,
WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE
IS THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. USE
CAUTION AROUND ENERGIZED EQUIPMENT. THE METAL CONTAINER WILL CONDUCT
ELECTRICITY IF IT CONTACTS A LIVE SOURCE. THIS MAY RESULT IN INJURY TO
THE USER FROM ELECTRICAL SHOCK AND/OR FLASH FIRE. AVOID BREATHING
MIST/VAPORS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED
EXPOSURE. USE ONLY IN WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING. AVOID RELEASE
TO THE ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. FOR PRODUCT
USAGE INSTRUCTIONS, SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 1 AEROSOL.
CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE AT TEMPERATURES
ABOVE 120 DEG. F/49 DEG. C AS CAN MAY BURST. DO NOT PUNCTURE, INCINERATE
OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES
OF IGNITION. STORE IN TIGHTLY CLOSED CONTAINER. STORE IN A WELL-VENTILATED
PLACE. STORED CONTAINERS SHOULD BE PERIODICALLY CHECKED FOR GENERAL
CONDITION AND LEAKAGE. STORE AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
2,6-DIMETHYL-4-HEPTANONE PEL 290 MG/M3
(CAS 108-83-8) 50 PPM
CARBON DIOXIDE PEL 9000 MG/M3
(CAS 124-38-9) 5000 PPM
DISTILLATES (PETROLEUM), PEL 5 MG/M3 MIST.
HYDROTREATED MIDDLE
(CAS 64742-46-7)
TURPENTINE, OIL PEL 560 MG/M3
(CAS 8006-64-2) 100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
2,6-DIMETHYL-4-HEPTANONE TWA 25 PPM
(CAS 108-83-8)
CARBON DIOXIDE STEL 30000 PPM
(CAS 124-38-9)
TWA 5000 PPM
DISTILLATES (PETROLEUM), TWA 5 MG/M3 INHALABLE FRACTION.
HYDROTREATED MIDDLE
(CAS 64742-46-7)
TURPENTINE, OIL TWA 20 PPM
(CAS 8006-64-2)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
2,6-DIMETHYL-4-HEPTANONE TWA 150 MG/M3
(CAS 108-83-8) 25 PPM
CARBON DIOXIDE STEL 54000 MG/M3
(CAS 124-38-9) 30000 PPM
TWA 9000 MG/M3
5000 PPM
DISTILLATES (PETROLEUM), TWA 100 MG/M3
HYDROTREATED LIGHT
(CAS 64742-47-8)
DISTILLATES (PETROLEUM), STEL 10 MG/M3 MIST.
HYDROTREATED MIDDLE
(CAS 64742-46-7) TWA 5 MG/M3 MIST.
TURPENTINE, OIL TWA 560 MG/M3
(CAS 8006-64-2) 100 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS
TO AN ACCEPTABLE LEVEL. PROVIDE EYEWASH STATION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. RUBBER.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: RED.
ODOR: PLEASANT PINE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -121 DEG. F (-85 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
300 DEG. F (148.9 DEG. C) ESTIMATED
FLASH POINT: 147 DEG. F (63.9 DEG. C) SETAFLASH
EVAPORATION RATE: MODERATE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 0.6% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 8.3% ESTIMATED
VAPOR PRESSURE: 1958.8 HPA ESTIMATED
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: 0.86
SOLUBILITY(IES):
SOLUBILITY (WATER): NEGLIGIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 401 DEG. F (205 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
PERCENT VOLATILE: 96.4% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. AVOID TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. CHLORINE.
HAZARDOUS DECOMPOSITION PRODUCTS:
ALDEHYDES. KETONES. ORGANIC ACIDS. CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
COMPONENTS SPECIES TEST RESULTS
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8):
ACUTE:
DERMAL:
LD50 RABBIT 16200 MG/KG
INHALATION:
LC50 RAT >5 MG/L, 4 HOURS
ORAL:
LD50 RAT 5285 MG/KG
CARBON DIOXIDE (CAS 124-38-9):
ACUTE:
INHALATION:
GAS:
LC50 RAT 470000 PPM, 30 MINUTES
DIPROPYLENE GLYCOL N-PROPYL ETHER (CAS 29911-27-1):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
5340 MG/KG
ORAL:
LD50 RAT >2000 MG/KG
1475 MG/KG
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG
INHALATION:
LC50 RAT >5.2 MG/L, 4 HOURS
ORAL:
LD50 RAT >5000 MG/KG, 2.5 HOURS
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
ORAL:
LD50 RAT >5000 MG/KG
FTURPENTINE, OIL (CAS 8006-64-2):
ACUTE:
INHALATION:
LC50 RAT 3590 MG/L, 1 HOURS
ORAL:
LD50 RAT 5760 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
ACGIH SENSITIZATION:
TURPENTINE AND SELECTED MONOTERPENES (CAS 8006-64-2): DERMAL SENSITIZATION
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY: NOT LISTED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
DIPROPYLENE GLYCOL N-PROPYL ETHER (CAS 29911-27-1):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >100 MG/L, 48 HOURS
FISH LC50 RAINBOW TROUT,DONALDSON TROUT >100 MG/L, 96 HOURS
(ONCORHYNCHUS MYKISS)
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >1000 MG/L, 48 HOURS
FISH LC50 RAINBOW TROUT,DONALDSON TROUT >1000 MG/L, 96 HOURS
(ONCORHYNCHUS MYKISS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
DIPROPYLENE GLYCOL N-PROPYL ETHER:
0.87 OECD 107
0.88 OECD 107
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
THE DISPENSED LIQUID PRODUCT IS NOT A RCRA HAZARDOUS WASTE (SEE 40 CFR
PART 261.20 - 261.33). EMPTY CONTAINER CAN BE RECYCLED. CONTENTS UNDER
PRESSURE. DO NOT PUNCTURE, INCINERATE OR CRUSH. DO NOT ALLOW THIS MATERIAL
TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS
OR DITCHES WITH CHEMICAL OR USED CONTAINER. DISPOSE IN ACCORDANCE WITH ALL
APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE: NOT REGULATED.
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK:
LABEL(S): 2.2
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ERG CODE: 2L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES, BUT EXEMPT FROM THE REGULATIONS.
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
DOT; IMDG: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
NOT LISTED.
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE
ITS RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (EAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8):
OTHER FLAVORING SUBSTANCES WITH OSHA PEL'S
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
CLASSIFIED HAZARD CATEGORIES:
GAS UNDER PRESSURE
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
RESPIRATORY OR SKIN SENSITIZATION
ASPIRATION HAZARD
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING): NOT REGULATED.
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
CARBON DIOXIDE (CAS 124-38-9)
PINE OIL (CAS 8002-09-3)
TURPENTINE, OIL (CAS 8006-64-2)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
CARBON DIOXIDE (CAS 124-38-9)
TURPENTINE, OIL (CAS 8006-64-2)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
CARBON DIOXIDE (CAS 124-38-9)
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9)
US. RHODE ISLAND RTK:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
CARBON DIOXIDE (CAS 124-38-9)
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7)
TURPENTINE, OIL (CAS 8006-64-2)
CALIFORNIA PROPOSITION 65:
WARNING: CANCER AND REPRODUCTIVE HARM - WWW.P65WARNINGS.CA.GOV
CALIFORNIA PROPOSITION 65 - CRT:
LISTED DATE/CARCINOGENIC SUBSTANCE:
BENZENE (CAS 71-43-2):
LISTED: FEBRUARY 27, 1987
ETHYLBENZENE (CAS 100-41-4):
LISTED: JUNE 11, 2004
NAPHTHALENE (CAS 91-20-3):
LISTED: APRIL 19, 2002
CALIFORNIA PROPOSITION 65 - CRT:
LISTED DATE/DEVELOPMENTAL TOXIN:
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
TOLUENE (CAS 108-88-3):
LISTED: JANUARY 1, 1991
CALIFORNIA PROPOSITION 65 - CRT:
LISTED DATE/MALE REPRODUCTIVE TOXIN:
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9)
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 98.4%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A PENETRANT. THIS PRODUCT IS COMPLIANT FOR USE
IN ALL 50 STATES.
VOC CONTENT (CA): 23.6%
VOC CONTENT (OTC): 23.6%
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL NO
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND NO
CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN CHEMICAL SUBSTANCE INVENTORY NO
(TCSI)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 04-01-2019
PREPARED BY: ALLISON YOON
VERSION #: 01
FURTHER INFORMATION: CRC # 548A/1002565
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC'S KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC TO BE
ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS ON
THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON THIS
(M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR
CRC INDUSTRIES, INC..
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: KNOCK'ER LOOSE(R*) PENETRATING SOLVENT - 13 OZ
SDS US