| Common Name: | NATURAL DEGREASER CITRUS-BASED DEGREASER 14005 |
| Manufacturer: | CRC |
| SDS Revision Date: | 4/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3EED6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 14005
RECOMMENDED USE: GENERAL PURPOSE DEGREASER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 RESPIRATORY TRACT IRRITATION
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES
SERIOUS EYE IRRITATION. MAY CAUSE RESPIRATORY IRRITATION. TOXIC TO AQUATIC
LIFE. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT APPLY WHILE
EQUIPMENT IS ENERGIZED.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. EXTINGUISH ALL FLAMES, PILOT LIGHTS
AND HEATERS. VAPORS WILL ACCUMULATE READILY AND MAY IGNITE. USE ONLY WITH
ADEQUATE VENTILATION; MAINTAIN VENTILATION DURING USE AND UNTIL ALL VAPORS
ARE GONE. OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR
SUPPLY DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY
SYMPTOMS LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA.
AVOID BREATHING MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED
WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES/EYE PROTECTION/FACE PROTECTION. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE
REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION. COLLECT SPILLAGE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. STORE LOCKED UP. PROTECT FROM SUNLIGHT.
DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. EXPOSURE TO
HIGH TEMPERATURE MAY CAUSE CAN TO BURST.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
DIPROPYLENE GLYCOL MONOPROPYL 29911-27-1 60 - 70
ETHER (DPMP)
DIPROPYLENE GLYCOL MONOMETHYL 88917-22-0 20 - 30
ETHER ACETATE
D-LIMONENE 5989-27-5 5 - 10
CARBON DIOXIDE 124-38-9 3 - 5
DIPENTENE 68956-56-9 1 - 3
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS:
SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
IF INGESTION OF A LARGE AMOUNT DOES OCCUR, CALL A POISON CONTROL CENTER
IMMEDIATELY. RINSE MOUTH.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. MAY CAUSE RESPIRATORY IRRITATION. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY RUPTURE WHEN EXPOSED TO
HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO
SO WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY RUPTURE WHEN EXPOSED TO HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY VAPORS ARE HEAVIER THAN AIR AND
WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. AVOID BREATHING MIST OR VAPOR. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. THIS MATERIAL IS CLASSIFIED AS A WATER POLLUTANT UNDER
THE CLEAN WATER ACT AND SHOULD BE PREVENTED FROM CONTAMINATING SOIL OR
FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS WHICH LEAD TO WATERWAYS. STOP
THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. WIPE UP WITH ABSORBENT
MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE IF
SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE
GROUND. INFORM APPROPRIATE MANAGERIAL OR SUPERVISORY PERSONNEL OF ALL
ENVIRONMENTAL RELEASES.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
MINIMIZE FIRE RISKS FROM FLAMMABLE AND COMBUSTIBLE MATERIALS (INCLUDING
COMBUSTIBLE DUST AND STATIC ACCUMULATING LIQUIDS) OR DANGEROUS REACTIONS
WITH INCOMPATIBLE MATERIALS.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE
IS THOROUGHLY DRY. USE CAUTION AROUND ENERGIZED EQUIPMENT. THE METAL
CONTAINER WILL CONDUCT ELECTRICITY IF IT CONTACTS A LIVE SOURCE. THIS MAY
RESULT IN INJURY TO THE USER FROM ELECTRICAL SHOCK AND/OR FLASH FIRE. AVOID
BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID
PROLONGED EXPOSURE. USE ONLY IN WELL-VENTILATED AREAS. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING.
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. AVOID RELEASE TO THE
ENVIRONMENT. FOR PRODUCT USAGE INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 3 AEROSOL.
PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE, INCINERATE
OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES
OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH MAY CAUSE
SPARK AND BECOME AN IGNITION SOURCE. AVOID SPARK PROMOTERS. THESE ALONE MAY
BE INSUFFICIENT TO REMOVE STATIC ELECTRICITY. STORE IN A WELL-VENTILATED
PLACE. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
CARBON DIOXIDE PEL 9000 MG/M3
(CAS 124-38-9) 5000 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
CARBON DIOXIDE STEL 30000 PPM
(CAS 124-38-9)
TWA 5000 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS:
COMPONENTS TYPE VALUE
CARBON DIOXIDE STEL 54000 MG/M3
(CAS 124-38-9) 30000 PPM
TWA 9000 MG/M3
5000 PPM
US. AIHA WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
D-LIMONENE TWA 165.5 MG/M3
(CAS 5989-27-5) 30 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS:
NITRILE. VITON(R*). POLYVINYL CHLORIDE (PVC).
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: WATER-WHITE.
ODOR: CITRUS.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -139.9 DEG. F (-95.5 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
304 DEG. F (151.1 DEG. C) ESTIMATED
FLASH POINT: 150 DEG. F (65.6 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: SLOW.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 0.7 % ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 5.4 % ESTIMATED
VAPOR PRESSURE: 2076.9 HPA ESTIMATED
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: 0.95 ESTIMATED
SOLUBILITY (WATER): NEGLIGIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 401 DEG. F (205 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 96.4 % ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
HEAT, FLAMES AND SPARKS. AVOID TEMPERATURES EXCEEDING THE FLASH POINT.
CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG BASES. STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
ALDEHYDES. KETONES. ORGANIC ACIDS. CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE IRRITATION TO THE RESPIRATORY SYSTEM. PROLONGED INHALATION MAY
BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
SWALLOWING SMALL AMOUNTS DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE
HARMFUL EFFECTS. SWALLOWING LARGE AMOUNTS MAY BE HARMFUL. MAY CAUSE
GASTROINTESTINAL IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. MAY CAUSE RESPIRATORY IRRITATION. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY IRRITATION.
PRODUCT SPECIES TEST RESULTS
NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER:
ACUTE:
DERMAL:
LD50 RABBIT 2305 MG/KG ESTIMATED
INHALATION:
LC50 RAT 24 MG/L, 4 HOURS ESTIMATED
ORAL:
LD50 RAT 2147 MG/KG ESTIMATED
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
D-LIMONENE (CAS 5989-27-5):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRODUCT SPECIES TEST RESULTS
NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER:
AQUATIC:
FISH LC50 FISH 8.5631 MG/L,
96 HOURS ESTIMATED
ACUTE:
CRUSTACEA EC50 DAPHNIA 159.6211 MG/L,
48 HOURS ESTIMATED
COMPONENTS SPECIES TEST RESULTS
DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE (CAS 88917-22-0):
AQUATIC:
ACUTE:
CRUSTACEA LC50 WATER FLEA (DAPHNIA MAGNA) 2701 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW 151 MG/L, 96 HOURS
(PIMEPHALES PROMELAS)
RAINBOW TROUT, DONALDSON 111 MG/L, 96 HOURS
TROUT (ONCORHYNCHUS MYKISS)
DIPROPYLENE GLYCOL MONOPROPYL ETHER (DPMP) (CAS 29911-27-1):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >100 MG/L, 48 HOURS
FISH LC50 RAINBOW TROUT, DONALDSON >100 MG/L, 96 HOURS
TROUT (ONCORHYNCHUS MYKISS)
D-LIMONENE (CAS 5989-27-5):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA PULEX) 69.6 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW 0.619 - 0.796 MG/L,
(PIMEPHALES PROMELAS) 96 HOURS
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE: 0.61 OECD 107
DIPROPYLENE GLYCOL MONOPROPYL ETHER (DPMP): 0.87 OECD 107
D-LIMONENE: 4.232
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
IF DISCARDED, THIS PRODUCT IS CONSIDERED A RCRA IGNITABLE WASTE, D001.
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER
SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR
USED CONTAINER. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS: YES
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED.
CARGO AIRCRAFT ONLY: ALLOWED.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT
TRANSPORT HAZARD CLASS(ES):
CLASS: 2
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
NOT LISTED.
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312 HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. CALIFORNIA CONTROLLED SUBSTANCES. CA DEPARTMENT OF JUSTICE (CALIFORNIA
HEALTH AND SAFETY CODE SECTION 11100): NOT LISTED.
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
CARBON DIOXIDE (CAS 124-38-9)
US. MASSACHUSETTS RTK - SUBSTANCE LIST: CARBON DIOXIDE (CAS 124-38-9)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
CARBON DIOXIDE (CAS 124-38-9)
US. RHODE ISLAND RTK: NONE.
US. CALIFORNIA PROPOSITION 65:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS
CARCINOGENS OR REPRODUCTIVE TOXINS.
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 97 %
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A GENERAL PURPOSE DEGREASER (AEROSOL). THIS
PRODUCT IS COMPLIANT FOR USE IN ALL 50 STATES.
VOC CONTENT (CA): 9.7 %
VOC CONTENT (OTC): 9.7 %
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL YES
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 04-28-2015
PREPARED BY: ALLISON CHO
VERSION #: 01
FURTHER INFORMATION: CRC # 598E
HMIS(R*) RATINGS:
HEALTH 1
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 3
INSTABILITY 0
NFPA RATINGS:
1
3
0
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY
CRC TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND
DIRECTIONS ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION
CONTAINED ON THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY
PROFESSIONAL, OR CRC INDUSTRIES.
MATERIAL NAME: NATURAL DEGREASER(TM) CITRUS-BASED DEGREASER
SDS: US