| Common Name: | PARA BOWL BLOCK WITH ENZYMES |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 7/18/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 3EEF7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
DATE ISSUED: 7/18/2019
| SECTION 1: IDENTIFICATION OF THE PREPARATION AND THE COMPANY |  |
PRODUCT NAME: PARA BOWL BLOCK WITH ENZYMES
RECOMMENDED USE: DEODORIZER
RESTRICTIONS ON USE: FOR INTENDED USE ONLY
MANUFACTURED FOR:
W.W. GRAINGER, INC.
100 GRAINDER PARKWAY
LAKE FOREST, IL 60045
USA
TELEPHONE: 1+800-472-4643
FAX: 1+847-588-9055
EMERGENCY CONTACT (SPILL/RELEASE): 800-424-9300
ITEM NUMBER: 3EEF7
| SECTION 2: HAZARDS IDENTIFICATION | |
GENERAL:
CONTAINS SMALL AMOUNTS OF CHEMICALS THAT ARE HAZARDOUS TO HEALTH AND THE
ENVIRONMENT BUT IN QUANTITIES TOO SMALL TO CONSTITUTE ANY PRACTICAL RISKS
TO HEALTH OR THE ENVIRONMENT.
CLASSIFICATION:
ACUTE TOXICITY ORAL 4
ACUTE TOXICITY DERMAL 4
EYE DAMAGE/IRRITATION 2A
CARCINOGENICITY 2
EXCLAMATION MARK
HEALTH HAZARD
WARNING
HAZARD PHRASES:
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H319: CAUSES SERIOUS EYE IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY PHRASES:
P102: KEEP OUT OF REACH OF CHILDREN
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+ P352: IF ON SKIN, WASH WITH PLENTY OF WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
P308+P313: IF EXPOSED OR CONCERNED GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P330: RINSE MOUTH
P332+P313: IF RASH OCCURS, SEEK MEDICAL ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P405: STORE LOCKED UP
P501: DISPOSE OF CONTENTS TO AN APPROVED WASTE DISPOSAL PLANT.
| SECTION 3: INGREDIENT INFORMATION | |
CHEMICAL IDENTIFICATION: CRYSTALLINE SOLID
FORM/SHAPE: PARA BLOCKS COME IN VARIOUS SHAPES AND SIZES.
CAS NUMBER: NOT APPLICABLE SINCE THE PRODUCT IS A PREPARATION.
EINECS/ELINCS #: NOT APPLICABLE SINCE THE PRODUCT IS A PREPARATION.
THE PRODUCT IS A COMPLEX MIXTURE OF SUBSTANCES OF WHICH THE FOLLOWING HAVE
BEEN CLASSIFIED AS PRESENTING A HEALTH OR ENVIRONMENTAL HAZARD OR AS HAVING
AN OCCUPATIONAL EXPOSURE LIMIT WITHIN THE MEANING OF THE DIRECTIVE
67/548/EEC OR 1999/45/EC
LEVEL CAS NR EC NR SUBSTANCE HAZARD CLASSIFICATION
(%) (DIR. (REG. CE
67/548/CE) 1272/2008)
99% 106-46-7 203-400-5 P-DICHLOROBENZENE H302
H312
H319
H351
*EXACT PERCENTAGE AND CHEMICAL IDENTITIY HAS BEEN WITHHELD AS A TRADE
SECRET.
| SECTION 4: FIRST AID MEASURES | |
GENERAL: NO SPECIFIC ACUTE EFFECTS OR SYMPTOMS ARE KNOWN.
INHALATION:
NO ACUTE EFFECTS EXPECTED. IF PERSON IS FEELING UNWELL, REMOVE TO FRESH
AIR.
INGESTION:
POSSIBILITY OF INGESTION LIMITED DUE TO PRODUCT FORM AND DIFFICULTY TO
CHEW AND INGEST. IN THE EVENT OF INGESTION, RINSE MOUTH THOROUGHLY WITH
WATER.
SKIN: WASH OFF WITH SOAP AND WATER.
EYES:
POSSIBILITY OF EYE CONTACT LIMITED. IN THE EVENT, WASH THOROUGHLY WITH
WATER OR APPROVED EYEWASH.
| SECTION 5: FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR THE SURROUNDING FIRE. WATER SPRAY,
FOG OR MIST. DRY CHEMICALS, SAND ETC.
EXPOSURE HAZARDS:
THERMAL DECOMPOSITION OR BURNING MAY RELEASE A VARIETY OF PRODUCTS RANGING
FROM SIMPLE HYDROCARBONS TO TOXIC/IRRITATING GASES INCLUDING CARBON
MONOXIDE AND CARBON DIOXIDE. FULL PROTECTIVE CLOTHING SHOULD BE WORN
BEFORE A CONFINED FIRE SPACE IS ENTERED. SELF-CONTAINED BREATHING APPARATUS
SHOULD BE WORN.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
NO SPECIAL REQUIREMENTS FOR ACCIDENTAL RELEASE REQUIRED. APPLY GOOD
HOUSEKEEPING PRACTICES.
| SECTION 7: HANDLING AND STORAGE | |
USAGE PRECAUTIONS:
FOLLOW NORMAL GOOD-HOUSEKEEPING PRACTICES. KEEP AWAY FROM DIRECT FLAMES.
STORAGE PRECAUTIONS:
KEEP IN COOL, DRY CONDITIONS IN ORIGINAL CONTAINERS AT NO MORE THAN
30 DEG. C
| SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMIT: NOT ESTABLISHED
RESPIRATORY PROTECTION: NONE REQUIRED UNDER NORMAL USAGE
PROTECTION:
ALTHOUGH UNEXPECTED, AVOID PROLONGED SKIN CONTACT. USE CHEMICALLY
RESISTANT GLOVES AS NEEDED.
EYE PROTECTION: NONE REQUIRED
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CRYSTALLINE SOLID IN VARIOUS SHAPES AND SIZES
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT DETERMINED
COLOR: VARIOUS COLOR
PH VALUE: NOT DETERMINED/APPLICABLE
MELTING PT: ESTIMATED 60 DEG. C
BOILING PT: NOT APPLICABLE.
FLASH PT: NOT APPLICABLE.
EVAPORATION RATE: NOT APPLICABLE.
FLAMMABILITY: NOT DETERMINED/APPLICABLE
UEL: NOT DETERMINED
LEL: NOT DETERMINED
VAPOR PRESSURE: NOT DETERMINED/APPLICABLE
VAPOR DENSITY: NOT DETERMINED/APPLICABLE
RELATIVE DENSITY: NOT DETERMINED
SOLUBILITY IN WATER: INSOLUBLE.
PARTITION COEFFICIENT: NOT DETERMINED
AUTIIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NOT DETERMINED/APPLICABLE
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: NORMALLY STABLE.
CONDITIONS TO AVOID: AVOID EXTREME HEAT AND NAKED FLAMES.
MATERIALS TO AVOID: STRONG OXIDIZING AGENTS.
DECOMPOSITION PRODUCTS: NONE UNDER NORMAL STORAGE CONDITIONS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
ACUTE EFFECTS:
INGREDIENTS INCLUDE A SMALL QUANTITY OF VOLATILE CHEMICALS WHICH MAY
CONTAIN SMALL AMOUNTS OF SUBSTANCES THAT ARE HARMFUL IF SWALLOWED AND/OR
IRRITATING TO THE EYES AND SKIN.
CHRONIC EFFECTS: NONE ARE KNOWN.
HEALTH RISKS:
INHALATION:
PROLONGED EXPOSURE TO VOLATILE INGREDIENTS IS UNLIKELY TO CAUSE IRRITATION
OR OTHER ADVERSE HEALTH EFFECTS.
INGESTION: NO PRACTICAL RISK OF ADVERSE HEALTH EFFECTS.
SKIN CONTACT: NO PRACTICAL RISK OF ADVERSE HEALTH EFFECTS.
EYE CONTACT: NO PRACTICAL RISK OF ADVERSE HEALTH EFFECTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
NO SPECIFIC INFORMATION HAS BEEN ESTABLISHED REGARDING THE PRODUCT. HOWEVER
ACCORDING TO THE CONVENTIONAL METHOD OF DIRECTIVE 99/45/EC THE PRODUCT IS
CLASSIFIED AS HARMFUL TO AQUATIC ORGANISMS, OR CAUSING LONG-TERM EFFECTS
IN THE AQUATIC ENVIRONMENT.
ECOTOXICITY: N/A
PERSISTENCE AND DEGRADABILITY: N/A
BIOACCUMULATIVE POTENTIAL: N/A
MOBILITY IN SOIL: N/A
OTHER ADVERSE EFFECTS: N/A
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH LOCAL AUTHORITY REQUIREMENTS E.G., FOR USED
PRODUCT, AS HOUSEHOLD WASTE
| SECTION 14: TRANSPORT INFORMATION | |
PRODUCT IS NOT REGULATED AS HAZARDOUS
DOT CLASSIFICATIONS: HAZARDOUS
UN-NUMBER: UN3077
UN PROPER SHIPPING NAME: 1,4 DICHLOROBENZENE, DICHLORO-1,4 BENZENE
TRANSPORT HAZARD CLASS: 9
PACKING GROUP: III
MARINE POLLUTANT: P
SPECIAL PRECAUTIONS WITH TRANSPORT: LIMITED QUANTITY EXCEPTION OF 5 KG
| SECTION 15: REGULATORY INFORMATION | |
CLASSIFICATION, PACKAGING AND LABELING ACCORDING TO DIRECTIVE 99/45/EC
SIGNAL WORD: WARNING
PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
HAZARD PHRASES:
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H319: CAUSES SERIOUS EYE IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY PHRASES:
P102: KEEP OUT OF REACH OF CHILDREN
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+ P352: IF ON SKIN, WASH WITH PLENTY OF WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
P308+P313: IF EXPOSED OR CONCERNED GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P330: RINSE MOUTH
P332+P313: IF RASH OCCURS, SEEK MEDICAL ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P405: STORE LOCKED UP
P501: DISPOSE OF CONTENTS TO AN APPROVED WASTE DISPOSAL PLANT.
| SECTION 16: OTHER INFORMATION | |
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELING OF CHEMICALS (GHS)