| Common Name: | AEROSIL 200, SILICON DIOXIDE, CHEMICALLY PREPARED |
| Manufacturer: | EVONIK |
| SDS Revision Date: | 2/20/2014 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3EGD2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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E
EVONIK INDUSTRIES
MATERIAL SAFETY DATA SHEET
AEROSIL(R*) 200
MATERIAL NO.:
SPECIFICATION: 132138
ORDER NUMBER:
VERSION: 3.29 / US
REVISION DATE: 02/20/2014
PRINT DATE: 03/03/2015
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT INFORMATION:
TRADE NAME: AEROSIL(R*) 200 SILICON DIOXIDE, CHEMICALLY PREPARED
USE OF THE SUBSTANCE / PREPARATION:
SEALANTS
COLOURED PRINTING INKS
PAINTS AND VARNISHES.
ADHESIVE
SILICONE RUBBER
COSMETIC INGREDIENT
COSMETICS
AGROCHEMICALS
FUNCTION:
ANTICAKING AGENT
ANTIBLOCKING AGENTS
COATING AGENT
DISPERSING AGENT
FLOW-PROMOTING AGENT.
REINFORCING AGENT.
CARRIER
COMPANY:
EVONIK CORPORATION USA
299 JEFFERSON ROAD
PARSIPPANY,NJ 07054-0677
USA
TELEPHONE: 973-929-8000
TELEFAX: 973-929-8040
US:
CHEMTREC EMERGENCY NUMBER: 800-424-9300
CANADA:
CANUTEC EMERGENCY NUMBER: 613-996-6666
PRODUCT REGULATORY SERVICES: 973-929-8060
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
FORM: POWDER
COLOR: WHITE
ODOR: ODORLESS
DUST MAY BE IRRITATING TO RESPIRATORY TRACT.
POTENTIAL HEALTH EFFECTS:
EYE CONTACT: POSSIBLY IRRITATING.
SKIN CONTACT: MAY CAUSE SKIN IRRITATION.
INHALATION: MAY CAUSE IRRITATIONS OF THE RESPIRATORY TRACT.
INGESTION: NO HAZARD EXPECTED IN NORMAL USE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CAS-NO.: 112945-52-5, 7631-86-9
INFORMATION ON INGREDIENTS / HAZARDOUS COMPONENTS:
SILICON DIOXIDE, CHEMICALLY PREPARED:
CAS-NO.: 112945-52-5
PERCENT (WT./ WT.): 100 %
OTHER INFORMATION:
THIS MATERIAL IS CLASSIFIED AS HAZARDOUS UNDER OSHA REGULATIONS.
A NEW CAS, 112945-52-5, HAS BEEN ASSIGNED TO AMORPHOUS, FUMED SILICA
TO DISTINGUISH IT FROM CRYSTALLINE SILICA. ACCORDING TO THE EPA, THIS
PRODUCT MEETS TSCA REQUIREMENTS AND IS LISTED ON THE TSCA INVENTORY AS
SILICA WITH CAS 7631-86-9.
| 4. FIRST AID MEASURES | |
INHALATION:
IN CASE PRODUCT DUST IS RELEASED:
POSSIBLE DISCOMFORT: COUGH, SNEEZING MOVE VICTIMS INTO FRESH AIR.
SKIN CONTACT: WASH OFF WITH SOAP AND PLENTY OF WATER.
EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES OR UNTIL ALL MATERIAL HAS BEEN REMOVED. OBTAIN MEDICAL
ATTENTION.
INGESTION:
IF ACCIDENTALLY SWALLOWED, RINSE MOUTH THOROUGHLY WITH WATER AND
AFTERWARDS, DRINK PLENTY OF WATER. IN CASE OF DISCOMFORT, OBTAIN
MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: NOT APPLICABLE
LOWER EXPLOSION LIMIT: NOT APPLICABLE
UPPER EXPLOSION LIMIT: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY, FOAM, CO2, DRY POWDER., ADAPT FIRE-EXTINGUISHING MEASURES
TO SURROUNDINGS
EXTINGUISHING MEDIA WHICH MUST NOT BE USED FOR SAFETY REASONS:
DO NOT USE FULL-FORCE WATER JET IN ORDER TO AVOID DISPERSAL AND SPREAD OF
THE FIRE.
SPECIFIC HAZARDS DURING FIRE FIGHTING: NONE KNOWN.
FURTHER INFORMATION:
AS IN ANY FIRE, WEAR SELF-CONTAINED POSITIVE-PRESSURE BREATHING APPARATUS,
(MSHA/NIOSH APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
OBEY RELEVANT LOCAL, STATE, PROVINCIAL AND FEDERAL LAWS AND REGULATIONS.
DO NOT CONTAMINATE ANY LAKES, STREAMS, PONDS, GROUNDWATER OR SOIL.
DO NOT ALLOW ENTRANCE IN SEWAGE WATER, SOIL STRETCHES OF WATER,
GROUNDWATER, DRAINAGE SYSTEMS.
METHODS FOR CLEANING UP:
SWEEP UP OR VACUUM UP SPILLAGE AND COLLECT IN SUITABLE CONTAINER FOR
DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
SAFE HANDLING ADVICE: USE WITH ADEQUATE VENTILATION.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
STORAGE:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL PLACE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
COMPONENT OCCUPATIONAL EXPOSURE GUIDELINES:
SILICON DIOXIDE, CHEMICALLY PREPARED:
CAS-NO.: 112945-52-5
CONTROL PARAMETERS:
20MILLIONS OF PARTICLES PER CUBIC FOOT OF AIR:
TIME WEIGHTED AVERAGE (TWA): (Z3)
0.8 MG/M3:
TIME WEIGHTED AVERAGE (TWA): (Z3)
THE EXPOSURE LIMIT IS CALCULATED FROM THE EQUATION, 80/(%SIO2), USING
A VALUE OF 100% SIO2. LOWER VALUES OF % SIO2 WILL GIVE HIGHER EXPOSURE
LIMITS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
OR APPLICABLE FEDERAL/PROVINCIAL REQUIREMENTS MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT RESPIRATOR USE. NIOSH'S "RESPIRATOR DECISION
LOGIC" MAY BE USEFUL IN DETERMINING THE SUITABILITY OF VARIOUS TYPES OF
RESPIRATORS.
HAND PROTECTION: USE IMPERMEABLE GLOVES.
EYE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS. IN CASE DUSTS ARE FORMED, WEAR
CLOSE FITTING PROTECTIVE GOGGLES.
SKIN AND BODY PROTECTION:
A SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE READILY AVAILABLE.
TO IDENTIFY ADDITIONAL PERSONAL PROTECTIVE EQUIPMENT (PPE) REQUIREMENTS,
IT IS RECOMMENDED THAT A HAZARD ASSESSMENT IN ACCORDANCE WITH THE OSHA PPE
STANDARD (29CFR1910.132) BE CONDUCTED BEFORE USING THIS PRODUCT.
HYGIENE MEASURES:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. WASH FACE AND/OR HANDS BEFORE
BREAK AND END OF WORK.
TO ENSURE IDEAL SKIN PROTECTION:
USE SUPER FATTED SOAPS AND SKIN CREAM FOR SKIN CARE.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
PROTECTIVE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES.
IF THERE IS THE POSSIBILITY OF SKIN/EYE CONTACT, THE INDICATED HAND/EYE/
BODY PROTECTION SHOULD BE USED.
IF THE WORKPLACE THRESHOLD LIMIT VALUE IS EXCEEDED AND/OR THE SUBSTANCE
IS RELEASED, USE APPROPRIATE RESPIRATORY PROTECTION.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
FORM: POWDER
COLOR: WHITE
ODOR: ODORLESS
PHYSICAL STATE: SOLID
SAFETY DATA:
PH: 3.7 - 4.5 (40 G / L) (20 DEG. C) (SUSPENSION)
MELTING POINT/RANGE: CA. 1700 DEG. C
BOILING POINT/RANGE: NOT DETERMINED
FLASH POINT: NOT APPLICABLE
FLAMMABILITY: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
AUTOINFLAMMABILITY: NOT APPLICABLE
EXPLOSIVENESS: NOT TO BE EXPECTED IN VIEW OF THE STRUCTURE
LOWER EXPLOSION LIMIT: NOT APPLICABLE
UPPER EXPLOSION LIMIT: NOT APPLICABLE
MINIMUM IGNITION ENERGY: NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
DENSITY: CA. 2.2 G/CM3 (20 DEG. C)
TAPPED DENSITY: CA. 50 G / L
METHOD: DIN / ISO 787/11
WATER SOLUBILITY: >1 MG/L
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT APPLICABLE
VISCOSITY, DYNAMIC: NOT APPLICABLE
VAPOUR DENSITY: NOT APPLICABLE
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
OPERATIONS THAT CREATE DUST.
MATERIALS TO AVOID: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
THERMAL DECOMPOSITION: >2000 DEG. C
HAZARDOUS REACTIONS: SEE SECT. 10.1 REACTIVITY.
FURTHER INFORMATION:
STABLE UNDER NORMAL CONDITIONS.
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT ACUTE ORAL TOXICITY:
LD50 RAT: >3300 MG/KG
NO DEATHS OCCURRED.
LD50 RAT: >5000 MG/KG
METHOD:
OECD TEST GUIDELINE 401
COMPARABLE PRODUCT
PRODUCT ACUTE INHALATION TOXICITY:
LC0 RAT: 0.139 MG/L / 4H
METHOD:
ANALOGY OECD-METHOD
(MAXIMUM CONCENTRATION ATTAINABLE IN EXPERIMENTS)
NO DEATHS OCCURRED.
PRODUCT ACUTE DERMAL TOXICITY:
LD50 RABBIT:
>5000 MG/KG
COMPARABLE PRODUCT
PRODUCT SKIN IRRITATION:
RABBIT: NOT IRRITATING
METHOD: ANALOGY OECD-METHOD
PRODUCT EYE IRRITATION:
RABBIT: NOT IRRITATING
METHOD: ANALOGY OECD-METHOD
PRODUCT SENSITIZATION: NOT KNOWN
PRODUCT REPEATED DOSE TOXICITY:
ORAL: NO NEGATIVE EFFECTS.
INHALATION: NO IRREVERSIBLE CHANGES AND NO INDICATION OF SILICOSIS.
COMPONENT GENTOXICITY IN VITRO:
SILICON DIOXIDE, CHEMICALLY PREPARED: 112945-52-5
NO EVIDENCE OF MUTAGENIC EFFECTS LITERATURE
COMPONENT GENTOXICITY IN VIVO:
SILICON DIOXIDE, CHEMICALLY PREPARED: 112945-52-5
NO EVIDENCE OF MUTAGENIC EFFECTS LITERATURE
PRODUCT MUTAGENICITY ASSESSMENT:
NO EVIDENCE OF MUTAGENIC EFFECTS
NO EVIDENCE OF MUTAGENIC EFFECTS REPORTED IN LITERATURE.
PRODUCT CARCINOGENICITY: NO NEGATIVE EFFECTS.
PRODUCT TOXICITY TO REPRODUCTION: NO NEGATIVE EFFECTS.
PRODUCT GENERAL TOXICITY INFORMATION:
THE CLASSIFICATION CRITERIA ARE NOT MET BASED ON THE AVAILABLE DATA.
PRODUCT HUMAN EXPERIENCE:
SILICOSIS OR OTHER PRODUCT SPECIFIC ILLNESSES OF THE RESPIRATORY TRACT
HAVE NOT BEEN REPORTED.
| 12. ECOLOGICAL INFORMATION | |
ELIMINATION INFORMATION (PERSISTENCE AND DEGRADABILITY):
BIODEGRADABILITY:
INORGANIC PRODUCT, TEST OF THE BIODEGRADABILITY CANNOT BE CARRIED OUT.
BEHAVIOUR IN ENVIRONMENTAL COMPARTMENTS:
BIOACCUMULATION: NOT TO BE EXPECTED.
MOBILITY: NO REMARKABLE MOBILITY IN SOIL IS TO BE EXPECTED.
ECOTOXICITY EFFECTS:
TOXICITY TO FISH:
LC50 (BRACHYDANIO RERIO): >10000 MG/L / 96 H
METHOD: OECD 203
TOXICITY TO DAPHNIA:
EC50 DAPHNIA MAGNA: >10000 MG/L / 24 H
METHOD: OECD 202
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
ADVICE ON DISPOSAL:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, PROVINCIAL
AND LOCAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
TRANSPORT/FURTHER INFORMATION:
NOT DANGEROUS ACCORDING TO TRANSPORT REGULATIONS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
OSHA:
IF LISTED BELOW, CHEMICAL SPECIFIC STANDARDS APPLY TO THE PRODUCT OR
COMPONENTS:
NONE LISTED
CLEAN AIR ACT SECTION (112):
IF LISTED BELOW, COMPONENTS PRESENT AT OR ABOVE THE DE MINIMUS LEVEL ARE
HAZARDOUS AIR POLLUTANTS:
NONE LISTED
CERCLA REPORTABLE QUANTITIES:
IF LISTED BELOW, A REPORTABLE QUANTITY (RQ) APPLIES TO THE PRODUCT BASED
ON THE PERCENT OF THE NAMED COMPONENT:
NONE LISTED
SARA TITLE III SECTION 311/312 HAZARD CATEGORIES:
THE PRODUCT MEETS THE CRITERIA ONLY FOR THE LISTED HAZARD CLASSES:
ACUTE HEALTH HAZARD
SARA TITLE III SECTION 313 REPORTABLE SUBSTANCES:
IF LISTED BELOW, COMPONENTS ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 AND 40 CFR PART 372:
NONE LISTED
TOXIC SUBSTANCES CONTROL ACT (TSCA):
IF LISTED BELOW, NON-PROPRIETARY SUBSTANCES ARE SUBJECT TO EXPORT
NOTIFICATION UNDER SECTION 12 (B) OF TSCA:
NONE LISTED
STATE REGULATIONS:
THE LISTING REQUIREMENTS OF THE RIGHT TO KNOW (RTK) LEGISLATION VARIES BY
STATE. ALL INFORMATION FOR NJ, PA, MA AND OTHER STATES CAN BE DERIVED FROM
THE LISTING OF HAZARDOUS AND NON-HAZARDOUS COMPONENTS IN SECTION 2 AND 15
OF THIS MSDS.
CALIFORNIA PROPOSITION 65:
A WARNING UNDER THE CALIFORNIA DRINKING WATER ACT IS REQUIRED ONLY IF
LISTED BELOW:
NONE LISTED
INTERNATIONAL CHEMICAL INVENTORY STATUS
UNLESS OTHERWISE NOTED, THIS PRODUCT IS IN COMPLIANCE WITH THE INVENTORY
LISTING OF THE COUNTRIES SHOWN BELOW. FOR INFORMATION ON LISTING FOR
COUNTRIES NOT SHOWN, CONTACT THE PRODUCT REGULATORY SERVICES DEPARTMENT.
USA (TSCA): LISTED/REGISTERED
AUSTRALIA (AICS): LISTED/REGISTERED
JAPAN (MITI): LISTED/REGISTERED
KOREA (TCCL): LISTED/REGISTERED
PHILIPPINES (PICCS): LISTED/REGISTERED
CHINA: LISTED/REGISTERED
EUROPE (EINECS/ELINCS): LISTED/REGISTERED
CANADA (DSL): LISTED/REGISTERED
NEW ZEALAND: LISTED/REGISTERED
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
FURTHER INFORMATION:
CHANGES SINCE THE LAST VERSION ARE HIGHLIGHTED IN THE MARGIN. THIS VERSION
REPLACES ALL PREVIOUS VERSIONS.
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS
NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
MSDS-US (R11/011) / 3/3/2015 3:03