| Common Name: | LOCTITE PL PREMIUM POLYURETHANE CONSTRUCTION ADHESIVE |
| Manufacturer: | ULTRATECH INTERNATIONAL |
| SDS Revision Date: | 10/23/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3EXA7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ULTRATECH INTERNATIONAL, INC.
DATE UPDATED: 10/23/2015
SAFETY DATA SHEET
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY INFORMATION |  |
PRODUCT NAME: LOCTITE PL PREMIUM POLYURETHANE CONSTRUCTION ADHESIVE
PRODUCT TYPE: 1-COMPONENT-POLYURETHANE ADHESIVE
EMERGENCY 24-HOUR PHONE (ENGLISH):
CHEMTREC NUMBER: +(800) 424-9300
COMPANY INFORMATION:
ULTRATECH INTERNATIONAL, INC.
11542 DAVIS CREEK COURT
JACKSONVILLE, FLORIDA 32256
USA
E-MAIL: INFO@SPILLCONTAINMENT.COM
WEB: WWW.SPILLCONTAINMENT.COM
TELEPHONE:
800-353-1611
904-292-1611
(M-F 8:00 A.M. - 5:00 P.M. EST)
FAX: 904.292.1325
| SECTION 2 - HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
FATAL IF INHALED.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY INHALATION 2
SKIN IRRITATION 2
EYE IRRITATION 2A
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST OR FUMES. WASH THOROUGHLY AFTER HANDLING. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR EYE AND FACE PROTECTION. WEAR
PROTECTIVE GLOVES. [IN CASE OF INADEQUATE VENTILATION] WEAR RESPIRATORY
PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CONTROL CENTER OR PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERN MENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT CAS NUMBER % BY WT
TALC 14807-96-6 30 - 60
METHYLENEBIS (PHENYLISOCYANATE) 101-68-8 10 - 30
HYDROCARBON C11-25 DEAROMATIZED 64742-46-7 5 - 10
METHYLENE BISPHENYL ISOCYANATE 26447-40-5 1 - 5
ISOCYANIC ACID, POLYMETHYLENEPOLYPHENYLENE 9016-87-9 1 - 5
ESTER
| SECTION 4 - FIRST AID MEASURES | |
INHALATION:
IF INHALED, IMMEDIATELY REMOVE THE AFFECTED PERSON TO FRESH AIR. IMMEDIATE
MEDICAL TREATMENT NECESSARY.
SKIN CONTACT:
WASH AFFECTED AREA IMMEDIATELY WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND
PERSIST, GET MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHES.
EYE CONTACT:
IN CASE OF CONTACT WITH THE EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER
FOR 15 MINUTES, AND SEEK IMMEDIATE MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. RINSE THE MOUTH. DRINK PLENTY OF WATER. IMMEDIATE
MEDICAL ADVICE NECESSARY.
NOTES TO PHYSICIAN:
AN INDIVIDUAL HAVING A DERMAL OR PULMONARY SENSITIZATION REACTION TO THIS
MATERIAL SHOULD BE REMOVED FROM FURTHER EXPOSURE TO ANY DIISOCYANATE.
TREATMENT BASED ON JUDGEMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF
THE PATIENT.
| SECTION 5 - FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: WATER FOG. FOAM CARBON DIOXIDE.
SPECIAL INFORMATION:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
NITROUS GASES IRRITATING FUMES. ISOCYANATE VAPORS.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT EMPTY INTO DRAINS / SURFACE WATER / GROUND WATER.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. SCRAPE UP SPILLED MATERIAL AND PLACE IN A
CLOSED CONTAINER FOR DISPOSAL. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES
AND EYE/ FACE PROTECTION.
| SECTION 7 - HANDLING & STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID EXTREME TEMPERATURES.
EXPOSURE TO VAPORS OF HEATED MDI CAN BE EXTREMELY DANGEROUS. WASH
THOROUGHLY AFTER HANDLING. PROTECT FROM MOISTURE. USE ONLY WITH ADEQUATE
VENTILATION.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 18.3 DEG. C (64.9 DEG. F) AND
40 DEG. C (104 DEG. F)
AVOID MOISTURE. KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS
AND OPEN FLAME. KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE, PLEASE REVIEW LABELS ON CONTAINER OR
CHECK THE TECHNICAL DATA SHEET.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENT ACGIH TLV OSHA PEL AIHA WEEL OTHER
TALC 2 MG/M3 TWA 20 MPPCF TWA NONE 50 PPM
RESPIRABLE
FRACTION. 2.4 MPPCF TWA
RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
0.3 MG/M3 TWA
TOTAL DUST.
METHYLENEBIS 0.005 PPM TWA 0.02 PPM (0.2 NONE NONE
(PHENYLISOCYANATE) MG/M3) CEILING
HYDROCARBON C11-25 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
DEAROMATIZED INHALABLE MIST.
FRACTION.
METHYLENE NONE NONE NONE NONE
BISPHENYL
ISOCYANATE
ISOCYANIC ACID, 0.005 PPM TWA 0.02 PPM NONE NONE
POLYMETHYLENE- (0.2 MG/M3)
POLYPHENYLENE CEILING
ESTER
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION BELOW OCCUPATIONAL EXPOSURE
LIMITS.
RESPIRATORY PROTECTION:
OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR 1910.134). USE A NIOSH
APPROVED AIR-PURIFYING RESPIRATOR IF THE POTENTIAL TO EXCEED ESTABLISHED
EXPOSURE LIMITS EXISTS. RESPIRATOR WITH COMBINATION FILTER FOR
VAPOR/PARTICULATE. HOWEVER, DUE TO THE POOR WARNING PROPERTIES OF MDI,
PROPER FIT AND TIMELY REPLACEMENT OF FILTER ELEMENTS MUST BE ENSURED.
EYE/FACE PROTECTION:
SAFETY GLASSES WITH SIDE-SHIELDS. FULL FACE PROTECTION SHOULD BE USED IF
THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS.
SKIN PROTECTION: SUITABLE PROTECTIVE CLOTHING.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
PHYSICAL STATE: HIGHLY VISCOUS, SOLID
COLOR: TAN
ODOR: OILY, MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NEUTRAL
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: 172 - 341 DEG. C (341.6 - 645.8 DEG. F) NO METHOD
MELTING POINT/ RANGE: NOT APPLICABLE
SPECIFIC GRAVITY: 1.26
VAPOR DENSITY: HEAVIER THAN AIR
FLASH POINT: >93.34 DEG. C (>200.01 DEG. F) NO METHOD
AUTOIGNITION TEMPERATURE: NO INFORMATION AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHTLY SOLUBLE
VOC CONTENT:
3.5%; 45 G/L (BY WEIGHT, CALCULATED USING CARB METHOD; G/L LESS WATER,
LESS EXEMPTS CALCULATED USING SCAQMD METHOD)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 1.6%
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 10.2%
| SECTION 10 - STABILITY & REACTIVITY | |
STABILITY: STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE.
HAZARDOUS REACTIONS:
CONTACT WITH MOISTURE, OTHER MATERIALS THAT REACT WITH ISOCYANATES, OR
TEMPERATURES ABOVE 350 DEG. F (177 DEG. C), MAY CAUSE POLYMERIZATION.
HAZARDOUS DECOMPOSITION PRODUCTS:
IRRITATING AND/OR TOXIC FUMES AND GASES MAY BE EMITTED UPON THE PRODUCT'S
DECOMPOSITION. NITROGEN OXIDES AROMATIC ISOCYANATES. CARBON OXIDES.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ALCOHOLS. WATER.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
AVOID MOISTURE. KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF
IGNITION. PROLONGED EXPOSURE TO HEAT.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURES OR A SINGLE LARGE DOSE,
CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION (CHEMICAL ASTHMA)
WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE TO ISOCYANATE AT LEVELS
WELL BELOW THE TLV. CHRONIC OVEREXPOSURE TO ISOCYA NATES HAS BEEN REPORTED
TO CAUSE LUNG DAMAGE. DRYNESS OF NASAL PASSAGES, SORE THROAT, COUGH,
TIGHTNESS OF CHEST, SHORTNESS OF BREATH. PERSONS SUFFERING FROM ALLERGIC
REACTIONS TO ISOCYANATES SHOULD AVOID CONTACT WITH THE PRODUCT. THIS
PRODUCT MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT. MAY CAUSE
RESPIRATORY TRACT IRRITATION.
SKIN CONTACT:
CONTACT WITH SKIN CAN CAUSE IRRITATION AND ALLERGIC REACTION
(SENSITIZATION) IN SOME INDIVIDUALS. THIS PRODUCT MAY DISCOLOR THE SKIN.
EYE CONTACT: CONTACT WITH EYES WILL CAUSE IRRITATION.
INGESTION:
INGESTION OF THIS PRODUCT MAY CAUSE NAUSEA, VOMITING AND DIARRHEA.
INGREDIENT LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
TALC NONE IRRITANT, LUNG, SOME
EVIDENCE OF
CARCINOGENICITY
METHYLENEBIS INHALATION LC50 IRRITANT, RESPIRATORY,
(PHENYLISOCYANATE) (RAT, 4 H): 0.38 MG/L ALLERGEN
INHALATION LC50
(RAT, 4 H): 0.369 MG/L
HYDROCARBON C11-25 NONE IRRITANT
DEAROMATIZED
METHYLENE BISPHENYL NONE ALLERGEN, IRRITANT,
ISOCYANATE MUTAGEN, RESPIRATORY
ISOCYANIC ACID, NONE ALLERGEN, IRRITANT,
POLYMETHYLENEPOLY- KIDNEY, LIVER,
PHENYLENE ESTER RESPIRATORY
INGREDIENT NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
TALC NO GROUP 2B NO
METHYLENEBIS NO NO NO
(PHENYLISOCYANATE)
HYDROCARBON C11-25 NO NO NO
DEAROMATIZED
METHYLENE BISPHENYL NO NO NO
ISOCYANATE
ISOCYANIC ACID, NO NO NO
POLYMETHYLENEPOLY-
PHENYLENE ESTER
| SECTION 12 - ECOLOGICAL INFORMATION | |
NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE TIME
OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES, ETC., MAY
RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| SECTION 14 - TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| SECTION 15 - REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
AH COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC SUBSTANCES
CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
METHYLENEBIS (PHENYLISOCYANATE) (CAS# 101-68-8).
ISOCYANIC ACID, POLYMETH-YLENEPOLYPHENYLENE ESTER (CAS# 9016-87-9).
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES LIST.
ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE
DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE TRACKED BY
ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT CANADA. THEY
MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE CONTACT
REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| SECTION 16 - OTHER INFORMATION | |
FURTHER INFORMATION: THIS VERSION REPLACES ALL PREVIOUS VERSIONS.
THE INFORMATION THIS SAFETY DATA SHEET IS BELIEVED TO BE ACCURATE AND IS
THE BEST INFORMATION AVAILABLE TO ULTRATECH INTERNATIONAL, INC. THIS
DOCUMENT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONS TO
HANDLING A CHEMICAL BY A PERSON TRAINED IN CHEMICAL HANDLING. ULTRATECH
INTERNATIONAL MAKES NO WARRANTY OF MECHANTABILITY AND ANY OTHER WARRANTY,
EXPRESS OR IMPLIED WITH RESPECT TO SUCH INFORMATION OR THE PRODUCT TO WHICH
IT RELATES, AND WE ASSUME NO LIABILITY RESULTING FROM THE USE, MISUSE OR
HANDLING OF THE PRODUCT TO WHICH THE SAFETY DATA SHEET RELATES. USERS AND
HANDLERS OF THIS PRODUCT SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE
THE SUITABILITY OF THE INFORMATION PROVIDED HEREIN FOR THEIR OWN PURPOSES.