| Common Name: | INDUSTRIAL DEGREASER CONCENTRATE (PRODUCT NO. 26, CHEMICAL MANAGEMENT SYSTEMS) |
| Manufacturer: | 3M |
| SDS Revision Date: | 5/22/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 39CZ63, 3HB91, 3HB92 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (PRODUCT NO. 26, 3M(TM) CHEMICAL
MANAGEMENT SYSTEMS)
05/22/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 31-4059-7
VERSION NUMBER: 4.00
ISSUE DATE: 05/22/18
SUPERCEDES DATE: 01/10/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (PRODUCT NO. 26, 3M(TM) CHEMICAL
MANAGEMENT SYSTEMS)
PRODUCT IDENTIFICATION NUMBERS:
61-0000-6352-1, 61-0000-6353-9, 61-0000-6388-5, 61-0000-6389-3,
61-0000-6415-6, 70-0715-9446-2, 70-0715-9447-0, 700715-9448-8,
70-0715-9449-6, 70-0716-5884-6, 70-0716-8360-4, 70-0716-8361-2,
70-0716-8362-0, 70-0716-8363-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE RECOMMENDED USE:
REMOVES PETROLEUM-BASED GREASE AND OIL, ANIMAL FATS, FOOD SOILS AND HEAVY
DIRT BUILDUP. CAN BE USED IN INDUSTRIAL PLANTS, TRANSPORTATION AND AUTO
FACILITIES, SCHOOLS, HOSPITALS AND OTHER FACILITIES TO CLEAN A VARIETY OF
SURFACES., HARD SURFACE CLEANER
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 4.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
COMBUSTIBLE LIQUID.
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
37% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
37% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
2-AMINOISOBUTANOL 124-68-5 15 - 40 TRADE SECRET*
ALCOHOLS, C8-10, ETHERS 68154-99-4 15 - 40 TRADE SECRET*
WITH POLYETHYLENE-
POLYPROPYLENE GLYCOL
MONOBENZYL ETHER
WATER 7732-18-5 10 - 30 TRADE SECRET*
2-(2-ETHYLHEXYLOXY)ETHANOL 1559-35-9 5 - 10 TRADE SECRET*
QUATERNARY AMMONIUM CHLORIDE 68610-19-5 5 - 10 TRADE SECRET*
ISOPROPYL ALCOHOL 67-63-0 1 - 5 TRADE SECRET*
DIETHYLENE GLYCOL MONO(2- 1559-36-0 1 - 5 TRADE SECRET*
ETHYLHEXYL) ETHER
CITRUS FRAGRANCE ADDED MIXTURE 1 - 5 TRADE SECRET*
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND
EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE. WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED,
POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND
PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE
COVERING FOR EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE
USING NON-SPARKING TOOLS. PLACE IN A CLOSED CONTAINER APPROVED FOR
TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE WITH WATER.
SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN
ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
THIS PRODUCT IS NOT INTENDED TO BE USED WITHOUT PRIOR DILUTION AS SPECIFIED
ON THE PRODUCT LABEL. GROUNDING OR SAFETY SHOES WITH ELECTROSTATIC
DISSIPATING SOLES (ESD) ARE NOT REQUIRED WITH A CHEMICAL DISPENSING SYSTEM.
KEEP OUT OF REACH OF CHILDREN.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR
ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE,
CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS,
ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE AWAY FROM ACIDS.
STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
ISOPROPYL 67-63-0 ACGIH TWA: 200 PPM A4:
ALCOHOL STEL: 400 PPM NOT CLASS. AS
HUMAN CARCIN
ISOPROPYL 67-63-0 OSHA TWA:
ALCOHOL 980 MG/M3
(400 PPM)
CYCLOHEXENE, MIXTURE AIHA TWA:
1-METHYL-4-(1- 165.5 MG/M3
METHYLETHENYL)- (30 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SPECIAL
VENTILATION IS NOT REQUIRED. USE GENERAL DILUTION VENTILATION AND/OR LOCAL
EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IF VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, EYE CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR.
IF THE PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE
IS AN ACCIDENTAL RELEASE, WEAR PROTECTIVE EYE/FACE PROTECTION. SELECT AND
USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SKIN CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
FLUOROELASTOMER
NITRILE RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
SELECT AND USE BODY PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF
AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
BOOTS - NITRILE
APRON - NITRILE
RESPIRATORY PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, RESPIRATORY
PROTECTION IS NOT REQUIRED.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS
AN ACCIDENTAL RELEASE:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ORGANIC VAPORS
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE:
BRIGHT RED LIQUID WITH MILD CLEAN AND FRESH SCENT
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 10.5 - 11.5
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >147 DEG. F
FLASH POINT: 147 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR PRESSURE: 27 MMHg [@ 20 DEG. C] [REF STD: AIR=1]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 0.97 - 1.01 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 23.4 - 25.7 SAYBOLT UNIVERSAL SECOND [@ 72 DEG. F]
MOLECULAR WEIGHT: NOT APPLICABLE
VOLATILE ORGANIC COMPOUNDS: 25 - 35% WEIGHT [TEST METHOD: ESTIMATED]
VOC LESS H2O & EXEMPT SOLVENTS: 350 - 450 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NOT DETERMINED
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS STRONG OXIDIZING AGENTS REDUCING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
2-AMINOISOBUTANOL DERMAL RABBIT LD50: >2,000 MG/KG
2-AMINOISOBUTANOL INGESTION RAT LD50: 2,900 MG/KG
2-(2-ETHYLHEXYLOXY) DERMAL RABBIT LD50: 2,120 MG/KG
ETHANOL
2-(2-ETHYLHEXYLOXY) INGESTION RAT LD50: 3,080 MG/KG
ETHANOL
ISOPROPYL ALCOHOL DERMAL RABBIT LD50: 12,870 MG/KG
ISOPROPYL ALCOHOL INHALATION- RAT LC50: 72.6 MG/L
VAPOR
(4 HOURS)
ISOPROPYL ALCOHOL INGESTION RAT LD50: 4,710 MG/KG
DIETHYLENE GLYCOL DERMAL RABBIT LD50: 2,310 MG/KG
MONO(2-ETHYLHEXYL)
ETHER
DIETHYLENE GLYCOL INGESTION RAT LD50: 5,110 MG/KG
MONO(2-ETHYLHEXYL)
ETHER
CITRUS FRAGRANCE INHALATION- MOUSE LC50: >3.14 MG/L
ADDED VAPOR
(4 HOURS)
CITRUS FRAGRANCE DERMAL RABBIT LD50: >5,000 MG/KG
ADDED
CITRUS FRAGRANCE INGESTION RAT LD50: 4,400 MG/KG
ADDED
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
2-AMINOISOBUTANOL RABBIT IRRITANT
ISOPROPYL ALCOHOL MULTIPLE NO SIGNIFICANT IRRITATION
ANIMAL
SPECIES
CITRUS FRAGRANCE ADDED RABBIT MILD IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
2-AMINOISOBUTANOL RABBIT CORROSIVE
ISOPROPYL ALCOHOL RABBIT SEVERE IRRITANT
CITRUS FRAGRANCE ADDED RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
2-AMINOISOBUTANOL GUINEA NOT CLASSIFIED
PIG
ISOPROPYL ALCOHOL GUINEA NOT CLASSIFIED
PIG
CITRUS FRAGRANCE ADDED MOUSE SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
2-AMINOISOBUTANOL IN VITRO NOT MUTAGENIC
2-AMINOISOBUTANOL IN VIVO NOT MUTAGENIC
ISOPROPYL ALCOHOL IN VITRO NOT MUTAGENIC
ISOPROPYL ALCOHOL IN VIVO NOT MUTAGENIC
CITRUS FRAGRANCE ADDED IN VITRO NOT MUTAGENIC
CITRUS FRAGRANCE ADDED IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
ISOPROPYL ALCOHOL INHALATION RAT SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CITRUS FRAGRANCE INGESTION RAT SOME POSITIVE DATA EXIST,
ADDED BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
2-AMINOISOBUTANOL INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
2-AMINOISOBUTANOL INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
2-AMINOISOBUTANOL DERMAL NOT CLASSIFIED FOR DEVELOPMENT
2-AMINOISOBUTANOL INGESTION TOXIC TO DEVELOPMENT
ISOPROPYL ALCOHOL INGESTION NOT CLASSIFIED FOR DEVELOPMENT
ISOPROPYL ALCOHOL INHALATION NOT CLASSIFIED FOR DEVELOPMENT
CITRUS FRAGRANCE INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
ADDED
CITRUS FRAGRANCE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
ADDED
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-AMINOISOBUTANOL RAT NOAEL: PREMATING
1,000 MG/KG/DAY INTO LACTATION
2-AMINOISOBUTANOL RAT NOAEL:
1,000 MG/KG/DAY 37 DAYS
2-AMINOISOBUTANOL RAT NOAEL: DURING
300 MG/KG/DAY GESTATION
2-AMINOISOBUTANOL RAT NOAEL: PREMATING
100 MG/KG/DAY INTO LACTATION
ISOPROPYL ALCOHOL RAT NOAEL: DURING
400 MG/KG/DAY ORGANOGENESIS
ISOPROPYL ALCOHOL RAT LOAEL: DURING
9 MG/L GESTATION
CITRUS FRAGRANCE RAT NOAEL: PREMATING &
ADDED 750 MG/KG/DAY DURING GESTATION
CITRUS FRAGRANCE MULTIPLE NOAEL: DURING
ADDED ANIMAL 591 MG/KG/DAY ORGANOGENESIS
SPECIES
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-AMINOISOBUTANOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ISOPROPYL ALCOHOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
ISOPROPYL ALCOHOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ISOPROPYL ALCOHOL INHALATION AUDITORY SYSTEM NOT CLASSIFIED
ISOPROPYL ALCOHOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
CITRUS FRAGRANCE INGESTION NERVOUS SYSTEM NOT CLASSIFIED
ADDED
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-AMINOISOBUTANOL MOUSE NOAEL:
NOT AVAILABLE
ISOPROPYL ALCOHOL HUMAN NOAEL:
NOT AVAILABLE
ISOPROPYL ALCOHOL HUMAN NOAEL:
NOT AVAILABLE
ISOPROPYL ALCOHOL GUINEA NOAEL: 24 HOURS
PIG 13.4 MG/L
ISOPROPYL ALCOHOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
CITRUS FRAGRANCE NOAEL:
ADDED NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-AMINOISOBUTANOL INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
2-AMINOISOBUTANOL INGESTION BLOOD NOT CLASSIFIED
EYES
KIDNEY
AND/OR BLADDER
ISOPROPYL ALCOHOL INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ISOPROPYL ALCOHOL INHALATION NERVOUS SYSTEM NOT CLASSIFIED
ISOPROPYL ALCOHOL INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
CITRUS FRAGRANCE INGESTION KIDNEY AND/OR NOT CLASSIFIED
ADDED BLADDER
CITRUS FRAGRANCE INGESTION LIVER NOT CLASSIFIED
ADDED
CITRUS FRAGRANCE INGESTION HEART NOT CLASSIFIED
ADDED ENDOCRINE
SYSTEM
BONE, TEETH,
NAILS, AND/OR
HAIR
HEMATOPOIETIC
SYSTEM
IMMUNE SYSTEM
MUSCLES
NERVOUS SYSTEM
RESPIRATORY
SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-AMINOISOBUTANOL RAT NOAEL: 90 DAYS
23 MG/KG/DAY
2-AMINOISOBUTANOL DOG NOAEL: 1 YEARS
2.8 MG/KG/DAY
ISOPROPYL ALCOHOL RAT NOAEL: 24 MONTHS
12.3 MG/L
ISOPROPYL ALCOHOL RAT NOAEL: 13 WEEKS
12 MG/L
ISOPROPYL ALCOHOL RAT NOAEL: 12 WEEKS
400 MG/KG/DAY
CITRUS FRAGRANCE RAT LOAEL: 103 WEEKS
ADDED 75 MG/KG/DAY
CITRUS FRAGRANCE MOUSE NOAEL: 103 WEEKS
ADDED 1,000 MG/KG/DAY
CITRUS FRAGRANCE RAT NOAEL: 103 WEEKS
ADDED 600 MG/KG/DAY
ASPIRATION HAZARD:
NAME VALUE
CITRUS FRAGRANCE ADDED ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/
MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
RESPIRATORY OR SKIN SENSITIZATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 2
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 31-4059-7
VERSION NUMBER: 4.00
ISSUE DATE: 05/22/18
SUPERCEDES DATE: 01/10/18
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INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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