| Common Name: | TEROSON SI 9160 BK KNOWN AS SILATECH SILICONE SEALANT IND, 32390 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 10/27/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3HFL5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 008.1
ISSUE DATE: 10/27/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TEROSON SI 9160 BK KNOWN AS SILATECH(R*) SILICONE SEALANT IND
PRODUCT TYPE: SEALANT
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 475373
ITEM NUMBER: 32390
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE DAMAGE.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
PICTOGRAM(S): CORROSION
PRECAUTIONARY STATEMENTS:
PREVENTION:
WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL: NOT PRESCRIBED
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), 64742-46-7 5 - 10
HYDROTREATED MIDDLE
SILICON DIOXIDE 7631-86-9 5 - 10
METHYLSILANETRIYL TRIACETATE 4253-34-3 1 - 5
TRIACETOXYETHYLSILANE 17689-77-9 1 - 5
CARBON BLACK 1333-86-4 1 - 5
ACETIC ACID 64-19-7 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER.
IF SKIN IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF ADVERSE HEALTH EFFECTS DEVELOP SEEK MEDICAL
ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. IN CASE OF ADVERSE HEALTH EFFECTS SEEK MEDICAL
ADVICE.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING,
SUCH AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED
TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE. ACRID SMOKE AND FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. SPILLED MATERIAL
WILL SOLIDIFY. SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. MAINTAIN GOOD
VENTILATION FOR LARGE SPILLS.
| 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT GET IN EYES. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT GET
ON SKIN OR CLOTHING. DO NOT HANDLE CONTACT LENSES UNTIL ALL SEALANT HAS
BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY TRANSFER TO LENSES AND CAUSE
EYE IRRITATION.
STORAGE: KEEP CONTAINER CLOSED. STORE IN A DRY AREA BELOW 90 DEG. F.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 5 MG/M3 PEL MIST.
HYDROTREATED MIDDLE INHALABLE 100 PPM (400 MG/M3)
FRACTION. PEL
SILICON DIOXIDE 6 MG/M3 TWA 20 MPPCF TWA
0.8 MG/M3 TWA
METHYLSILANETRIYL NONE NONE
TRIACETATE
TRIACETOXYETHYLSILANE NONE NONE
CARBON BLACK 3 MG/M3 TWA 3.5 MG/M3 PEL
INHALABLE
FRACTION.
ACETIC ACID 15 PPM STEL 10 PPM (25 MG/M3)
10 PPM TWA PEL
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
DISTILLATES (PETROLEUM), NONE NONE
HYDROTREATED MIDDLE
SILICON DIOXIDE NONE 3 MG/M3 TWA
RESPIRABLE FRACTION.
METHYLSILANETRIYL NONE NONE
TRIACETATE
TRIACETOXYETHYLSILANE NONE NONE
CARBON BLACK NONE NONE
ACETIC ACID NONE NONE
ENGINEERING CONTROLS:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS.
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. USE NIOSH
APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: BLACK
ODOR: ACETIC ACID
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT DETERMINED
VAPOR PRESSURE: <10 MMHg (68 DEG. F (20 DEG. C))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.01 AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 4 % (ACETIC ACID)
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 19.9 % (ACETIC ACID)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT SOLUBLE. POLYMERIZES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT:
<3%
30 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
ACETIC ACID IS LIBERATED SLOWLY UPON CONTACT WITH MOISTURE. OXIDES OF
CARBON. OXIDES OF SILICON. FORMALDEHYDE. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS: BASES. ACIDS. OXIDIZING AGENTS. WATER
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
EXPOSURE TO MOISTURE. PROLONGED HEATING AT TEMPERATURES ABOVE 150 DEG. C.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
WHEN HEATED TO TEMPERATURES EXCEEDING 300 DEG. F (150 DEG. C) IN THE
PRESENCE OF AIR, SILICONES MAY FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS
A POTENTIAL CANCER HAZARD AND A KNOWN SKIN AND RESPIRATORY SENSITIZER.
VAPORS IRRITATE THE EYES, NOSE AND THROAT. SAFE HANDLING CONDITIONS MAY BE
MAINTAINED BY KEEPING FORMALDEHYDE VAPOR CONCENTRATIONS BELOW THE OSHA
PERMISSIBLE LIMIT. ACETIC ACID PRODUCED DURING CURE MAY IRRITATE EYES,
NOSE AND THROAT.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. MAY CAUSE GASTROINTESTINAL
TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED MIDDLE
SILICON DIOXIDE ORAL LD50 (RAT): NUISANCE DUST
>22,500 MG/KG
ORAL LD50 (MOUSE):
>15,000 MG/KG
METHYLSILANETRIYL NONE IRRITANT, ALLERGEN
TRIACETATE
TRIACETOXYETHYLSILANE NONE NO TARGET ORGANS
CARBON BLACK ORAL LD50 (RAT): RESPIRATORY, SOME
>8,000 MG/KG EVIDENCE OF
CARCINOGENICITY
ACETIC ACID ORAL LD50 (RABBIT): ALLERGEN, CORROSIVE,
1,200 MG/KG EYES, GASTROINTESTINAL,
IMMUNE SYSTEM, IRRITANT,
ORAL LD50 (MOUSE): KIDNEY
4,960 MG/KG
ORAL LD50 (RAT):
3.53 G/KG
ORAL LD50 (RAT):
3.31 G/KG
DERMAL LD50 (RABBIT):
1,060 MG/KG
INHALATION LC50
(RAT, 4 H): 11.4 MG/L
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED MIDDLE
SILICON DIOXIDE NO NO NO
METHYLSILANETRIYL NO NO NO
TRIACETATE
TRIACETOXYETHYLSILANE NO NO NO
CARBON BLACK NO GROUP 2B NO
ACETIC ACID NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 3, 5, 10
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 10/27/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.