| Common Name: | LOCTITE 2046 THRDLCK 12ML PT A, 1186840_1363470, LOCTITE 2046 THRDLCK 12ML PT B, |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 5/23/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3HPW1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 004.1
ISSUE DATE: 05/23/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE 2046 THRDLCK 12ML PT A
PRODUCT TYPE: ANAEROBIC ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1189205
ITEM NUMBER: 1186840_1363470
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HARMFUL IF INHALED.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY INHALATION 4
SKIN IRRITATION 2
EYE IRRITATION 2A
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION. IN CASE OF INADEQUATE VENTILATION WEAR
RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
METHYLENE BISPHENYL ISOCYANATE 26447-40-5 60 - 70
METHYLENEBIS(PHENYLISOCYANATE) 101-68-8 10 - 20
1,2-PROPANEDIOL, POLYMER WITH 1,3- 150449-03-9 10 - 20
BUTANEDIOL, TRIPROPYLENE GLYCOL AND
DIPHENYLMETHANE DIISOCYANATE
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. ASTHMATIC-TYPE SYMPTOMS MAY DEVELOP
AND MAY BE IMMEDIATE OR DELAYED UP TO SEVERAL HOURS. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE. FOR
SEVERE EXPOSURES, GET UNDER SAFETY SHOWER AFTER REMOVING CLOTHING, THEN GET
MEDICAL ATTENTION. FOR LESSER EXPOSURE, SEEK MEDICAL ATTENTION IF
IRRITATION DEVELOPS OR PERSISTS AFTER AREA IS WASHED.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE
MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN:
EYES:
STAIN FOR EVIDENCE OF CORNEAL INJURY. IF CORNEA IS BURNED, INSTILL
ANTIBIOTIC STEROID PREPARATION FREQUENTLY. WORKPLACE VAPORS HAVE
PRODUCED REVERSIBLE CORNEAL EPITHELIAL EDEMA IMPAIRING VISION.
SKIN:
TREAT SYMPTOMATICALLY AS FOR CONTACT DERMATITIS OR THERMAL BURNS. THIS
COMPOUND IS A KNOWN SKIN SENSITIZER.
INGESTION:
TREAT SYMPTOMATICALLY. THERE IS NO SPECIFIC ANTIDOTE. INDUCING VOMITING IS
CONTRAINDICATED BECAUSE OF THE IRRITATING NATURE OF THIS COMPOUND.
RESPIRATORY:
THIS COMPOUND IS A KNOWN PULMONARY SENSITIZER. TREAT SYMPTOMATICALLY AND
SUPPORTIVELY.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. DURING A FIRE, MDI VAPORS AND OTHER IRRITATING, HIGHLY
TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR COMBUSTION. AT
TEMPERATURES ABOVE 204.4 DEG. C (400 DEG. F), POLYMERIC MDI CAN POLYMERIZE
AND DECOMPOSE WHICH CAN CAUSE PRESSURE BUILD-UP IN CLOSED CONTAINERS.
EXPLOSIVE RUPTURE IS POSSIBLE.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS. SEALED CONTAINERS AT ELEVATED
TEMPERATURES OR CONTAMINATED WITH WATER MAY RUPTURE EXPLOSIVELY. WATER OR
FOG MAY CAUSE FROTHING WHICH CAN BE VIOLENT ESPECIALLY IF SPRAYED INTO
CONTAINERS OF HOT OR BURNING LIQUID. DO NOT ALLOW RUN-OFF FROM FIRE
FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. HYDROCARBONS. HYDROGEN CYANIDE.
TOXIC AND IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. IF TEMPORARY CONTROL OF ISOCYANATE VAPOR IS REQUIRED, A
BLANKET OF PROTEIN FOAM (AVAILABLE AT MOST FIRE DEPARTMENTS) MAY BE PLACED
OVER SPILL. LARGE QUANTITIES MAY BE PUMPED INTO CLOSED, BUT NOT SEALED
CONTAINERS FOR DISPOSAL. FOR MINOR SPILLS, ABSORB ISOCYANATES WITH SAWDUST
OR OTHER ABSORBENT, SHOVEL INTO SUITABLE UNSEALED CONTAINERS, TRANSPORT TO
WELL VENTILATED AREA (OUTSIDE) AND TREAT WITH NEUTRALIZING SOLUTION:
MIXTURE OF 80% WATER AND 20% NON-IONIC SURFACTANT TERGITOL TMN-10; OR
90% WATER, 3-8% CONCENTRATED AMMONIA AND 2% DETERGENT. ADD ABOUT TEN PARTS
OF NEUTRALIZER PER PART OF ISOCYANATE, WITH MIXING. ALLOW TO STAND
UNCOVERED FOR 48 HOURS TO LET CARBON DIOXIDE ESCAPE. DECONTAMINATE FLOOR
WITH DECONTAMINATION SOLUTION LETTING STAND FOR AT LEAST 15 MINUTES. REFER
TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
PROTECT FROM MOISTURE. EXPOSURE TO VAPORS OF HEATED MDI CAN BE EXTREMELY
DANGEROUS. KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 16 DEG. C (60.8 DEG. F) AND 38 DEG. C
(100.4 DEG. F) KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS
AND OPEN FLAME. KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE. DO NOT
LET MOISTURE CONTAMINATE THIS MATERIAL. PRODUCT REACTS WITH WATER TO
RELEASE CARBON DIOXIDE, WHICH COULD BUILD UP PRESSURE IN CLOSED CONTAINERS
AND LEAD TO BURSTING. DO NOT RESEAL IF MOISTURE CONTAMINATION IS SUSPECTED.
DO NOT RESEAL IF CONTAMINATION IS SUSPECTED. MDI REACTS SLOWLY WITH WATER
TO FORM CARBON DIOXIDE GAS. THIS GAS CAN CAUSE SEALED CONTAINERS TO EXPAND
AND POSSIBLY RUPTURE. DO NOT STORE IN REACTIVE METAL CONTAINERS. IF
CONTAINER IS EXPOSED TO HIGH HEAT (204.4 DEG. C (400 DEG. F)), IT CAN BE
PRESSURIZED AND POSSIBLY RUPTURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
METHYLENE BISPHENYL NONE NONE NONE NONE
ISOCYANATE
METHYLENEBIS 0.005 PPM TWA 0.02 PPM NONE NONE
(PHENYLISOCYANATE) (0.2 MG/M3)
CEILLING
1,2-PROPANEDIOL, POLYMER NONE NONE NONE NONE
WITH 1,3-BUTANEDIOL,
TRIPROPYLENE GLYCOL AND
DIPHENYLMETHANE
DIISOCYANATE
ENGINEERING CONTROLS:
LOCAL EXHAUST SHOULD BE USED TO MAINTAIN LEVELS BELOW THE TLV WHENEVER MDI
IS PROCESSED, HEATED OR SPRAY APPLIED. STANDARD REFERENCE SOURCES REGARDING
INDUSTRIAL VENTILATION (I.E., ACGIH INDUSTRIAL VENTILATION) SHOULD BE
CONSULTED FOR GUIDANCE ABOUT ADEQUATE VENTILATION.
AIR MONITORING:
MONITORING OF AIRBORNE ISOCYANATES IN THE BREATHING ZONE OF INDIVIDUALS
SHOULD BECOME PART OF THE OVERALL EMPLOYEE EXPOSURE CHARACTERIZATION
PROGRAM. ISOCYANATE EXPOSURE LEVELS MUST BE MONITORED. MONITORING
TECHNIQUES HAVE BEEN DEVELOPED BY NIOSH AND OSHA.
MEDICAL SURVEILLANCE:
MEDICAL SUPERVISION OF ALL EMPLOYEES WHO HANDLE OR COME IN CONTACT WITH
ISOCYANATES IS RECOMMENDED. THESE SHOULD INCLUDE PREEMPLOYMENT AND PERIODIC
MEDICAL EXAMINATIONS WITH PULMONARY FUNCTION TESTS (FEV, FVC AS A MINIMUM).
PERSONS WITH ASTHMATIC-TYPE CONDITIONS, CHRONIC BRONCHITIS, OTHER CHRONIC
RESPIRATORY DISEASES OR RECURRENT SKIN ECZEMA OR SENSITIZATION SHOULD BE
EXCLUDED FROM WORKING WITH ISOCYANATES. ONCE A PERSON IS DIAGNOSED AS
SENSITIZED TO AN ISOCYANATE, NO FURTHER EXPOSURE CAN BE PERMITTED.
RESPIRATORY PROTECTION:
CONCENTRATIONS GREATER THAN THE TLV CAN OCCUR WHEN MDI IS SPRAYED, HEATED
OR USED IN A POORLY VENTILATED AREA. IN SUCH CASES, OR WHENEVER
CONCENTRATIONS OF MDI EXCEED THE TLV, RESPIRATORY PROTECTION MUST BE WORN.
A POSITIVE PRESSURE, SUPPLIED-AIR RESPIRATOR OR A SELF-CONTAINED BREATHING
APPARATUS IS RECOMMENDED. IN SITUATIONS WHERE MDI IS NOT SPRAYED, HEATED,
OR USED IN A POORLY VENTILATED AREA, AND A SUPPLIED-AIR OR SELF-CONTAINED
BREATHING APPARATUS IS UNAVAILABLE OR ITS USE IMPRACTICAL, AT LEAST AN
AIR-PURIFYING CARTRIDGE AND PARTICULATE PRE-FILTERS MUST BE WORN.
HOWEVER, THIS SHOULD BE PERMITTED ONLY FOR SHORT PERIODS OF TIME (LESS
THAN ONE HOUR) AT RELATIVELY LOW CONCENTRATIONS (AT OR NEAR THE TLV).
HOWEVER, DUE TO THE POOR WARNING PROPERTIES OF MDI, PROPER FIT AND TIMELY
REPLACEMENT OF FILTER ELEMENTS MUST BE ENSURED. OBSERVE OSHA REGULATIONS
FOR RESPIRATOR USE (29 CFR 1910.134).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE. VAPOR
RESISTANT GOGGLES SHOULD BE WORN WHEN CONTACT LENSES ARE IN USE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. PERMEATION RESISTANT GLOVES
(BUTYL RUBBER, NITRILE RUBBER, POLYVINYL ALCOHOL). HOWEVER, PLEASE NOTE
THAT POLYVINYL ALCOHOL DEGRADES IN WATER. COVER AS MUCH OF THE EXPOSED SKIN
AREA AS POSSIBLE WITH APPROPRIATE CLOTHING. IF SKIN CREAMS ARE USED, KEEP
THE AREA COVERED BY THE CREAM TO A MINIMUM.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: LIGHT, YELLOW
ODOR: SLIGHTLY, MUSTY
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: >300 DEG. C (>572 DEG. F)DECOMPOSES.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.23
VAPOR DENSITY: 8.5
FLASH POINT: >110 DEG. C (>230 DEG. F) CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: >600 DEG. C (1,112 DEG. F)
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.37% (VALUE AS MIXED FOR USE)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS.
OXIDES OF NITROGEN. OXIDES OF CARBON. HYDROGEN CYANIDE. ISOCYANATES.
INCOMPATIBLE MATERIALS:
BASES. WATER, AMINES, ALKALIS, ALCOHOLS. WILL CAUSE SOME CORROSION TO
COPPER ALLOYS AND ALUMINUM.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS. CONTAMINATION WITH WATER.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
ACUTE:
HARMFUL IF INHALED. METHYLENE BISPHENYL ISOCYANATE (MDI) VAPORS OR MIST AT
CONCENTRATIONS ABOVE THE TLV CAN IRRITATE THE MUCOUS MEMBRANES IN THE
RESPIRATORY TRACT (NOSE, THROAT, LUNGS) CAUSING RUNNY NOSE, SORE THROAT,
COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION
(BREATHING OBSTRUCTION). PERSONS WITH PREEXISTING, NONSPECIFIC BRONCHIAL
HYPER-REACTIVITY CAN RESPOND TO CONCENTRATIONS BELOW THE TLV WITH SIMILAR
SYMPTOMS AS WELL AS LEAD TO BRONCHITIS, BRONCHIAL SPASM AND PULMONARY EDEMA
(FLUID IN LUNGS).
CHRONIC:
AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURES OR A SINGLE LARGE DOSE,
CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION (CHEMICAL ASTHMA)
WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE TO ISOCYANATE AT LEVELS
WELL BELOW THE TLV. CHRONIC OVEREXPOSURE TO ISOCYANATES HAS BEEN REPORTED
TO CAUSE LUNG DAMAGE. MAY CAUSE ALLERGIC RESPIRATORY REACTION. THESE
SYMPTOMS, WHICH CAN INCLUDE CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF
BREATH OR ASTHMA ATTACK, COULD BE IMMEDIATE OR DELAYED (UP TO SEVERAL HOURS
AFTER EXPOSURE). SIMILAR TO MANY NON-SPECIFIC ASTHMATIC RESPONSES, THERE
ARE REPORTS THAT ONCE SENSITIZED AN INDIVIDUAL CAN EXPERIENCE THESE
SYMPTOMS UPON EXPOSURE TO DUST, COLD AIR, OR OTHER IRRITANTS. THIS
INCREASED LUNG SENSITIVITY CAN PERSIST FOR WEEKS AND IN SEVERE CASES FOR
SEVERAL YEARS. OVER EXPOSURE TO ISOCYANATES HAS ALSO BEEN REPORTED TO CAUSE
LUNG DAMAGE (INCLUDING DECREASE IN LUNG FUNCTION) WHICH MAY BE PERMANENT.
SENSITIZATION CAN EITHER BE TEMPORARY OR PERMANENT.
SKIN CONTACT:
ACUTE:
CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. ISOCYANATES REACT
WITH SKIN PROTEIN AND MOISTURE AND CAN CAUSE IRRITATION WHICH MAY INCLUDE
THE FOLLOWING SYMPTOMS:
REDDENING, SWELLING, RASH, SCALING OR BLISTERING. CURED MATERIAL IS
DIFFICULT TO REMOVE.
CHRONIC:
PROLONGED CONTACT CAN CAUSE REDDENING, SWELLING, RASH, SCALING, BLISTERING
AND IN SOME CASES, SKIN SENSITIZATION. INDIVIDUALS WHO HAVE SKIN
SENSITIZATION CAN DEVELOP THESE SYMPTOMS FROM CONTACT WITH LIQUID OR VAPOR.
ONCE SENSITIZED, AN INDIVIDUAL MAY REACT EVEN TO AIRBORNE LEVELS BELOW THE
TLV WITH THE FOLLOWING SYMPTOMS:
ITCHING AND TINGLING OF THE EARLOBES AND NECK, RASH, HIVES, SWELLING OF THE
ARMS AND LEGS OR OTHER SYMPTOMS COMMON TO ALLERGIC DERMATITIS. ANIMAL TESTS
HAVE INDICATED THAT RESPIRATORY SENSITIZATION CAN RESULT FROM SKIN CONTACT
WITH MDI. THESE DATA REINFORCE THE NEED TO PREVENT DIRECT SKIN CONTACT WITH
MDI.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. LIQUID, AEROSOLS OR VAPOR ARE IRRITATING
AND CAN CAUSE TEARING, REDDENING AND SWELLING. IF LEFT UNTREATED, CORNEAL
DAMAGE CAN OCCUR AND INJURY IS SLOW TO HEAL. DAMAGE HOWEVER IS USUALLY
REVERSIBLE.
INGESTION:
MAY CAUSE IRRITATION OR BURNS OF MOUTH, THROAT, AND STOMACH, WITH NAUSEA,
ABDOMINAL PAIN, AND POSSIBLE COLLAPSE.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
METHYLENE BISPHENYL NONE ALLERGEN, IRRITANT,
ISOCYANATE MUTAGEN, RESPIRATORY
METHYLENEBIS INHALATION LC50 (RAT, 4 H): IRRITANT RESPIRATORY
(PHENYLISOCYANATE) 0.38 MG/L ALLERGEN
INHALATION LC50 (RAT, 4 H):
0.369 MG/L
1,2-PROPANEDIOL, NONE NO RECORDS
POLYMER WITH 1,3-
BUTANEDIOL,
TRIPROPYLENE GLYCOL
AND DIPHENYLMETHANE
DIISOCYANATE
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
METHYLENE BISPHENYL NO NO NO
ISOCYANATE
METHYLENEBIS NO NO NO
(PHENYLISOCYANATE)
1,2-PROPANEDIOL, POLYMER NO NO NO
WITH 1,3-BUTANEDIOL,
TRIPROPYLENE GLYCOL AND
DIPHENYLMETHANE
DIISOCYANATE
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO
THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
DOT HAZARDOUS SUBSTANCE(S): METHYLENE DIPHENYL DIISOCYANATE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
METHYLENEBIS(PHENYLISOCYANATE) (CAS# 101-68-8).
CERCLA REPORTABLE QUANTITY:
METHYLENEBIS(PHENYLISOCYANATE) (CAS# 101-68-8): 5,000 LBS. (2,270 KG)
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES LIST.
ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE
DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE TRACKED BY
ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT CANADA. THEY
MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE CONTACT
REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: REVIEWED SDS. REISSUED WITH NEW DATE.
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 05/23/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.2
ISSUE DATE: 04/24/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE 2046 THRDLCK 12ML PT B
PRODUCT TYPE: ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1189206
ITEM NUMBER: 1186840_1359494
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY
AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF
THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
POLYPROPYLENE GLYCOL 39420-45-6 20 - 30
MONOMETHACRYLATE
HYDROXYALKYL METHACRYLATE 27813-02-1 1 - 5
TERT-BUTYL PERBENZOATE 614-45-9 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. IRRITATING ORGANIC VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL
AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO
CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 23 DEG. C (73.4 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
POLYPROPYLENE GLYCOL NONE NONE NONE NONE
MONOMETHACRYLATE
HYDROXYALKYL METHACRYLATE NONE NONE NONE 1 PPM TWA
3 PPM STEL
TERT-BUTYL PERBENZOATE NONE NONE NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NATURAL RUBBER GLOVES.
NEOPRENE GLOVES. BUTYL RUBBER GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BLUE
ODOR: SLIGHTLY, AROMATIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.06
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F); ESTIMATED
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.37% (VALUE AS MIXED FOR USE)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. IRRITATING ORGANIC VAPOURS.
INCOMPATIBLE MATERIALS:
MOISTURE. OXYGEN SCAVENGERS. STRONG OXIDIZING AGENTS. STRONG REDUCING
AGENTS. ALKALIS. OTHER POLYMERIZATION INITIATORS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
POLYPROPYLENE GLYCOL NONE IRRITANT, ALLERGEN
MONOMETHACRYLATE
HYDROXYALKYL METHACRYLATE NONE IRRITANT, ALLERGEN
TERT-BUTYL PERBENZOATE NONE CENTRAL NERVOUS SYSTEM,
IRRITANT, MUTAGEN
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
POLYPROPYLENE GLYCOL NO NO NO
MONOMETHACRYLATE
HYDROXYALKYL NO NO NO
METHACRYLATE
TERT-BUTYL PERBENZOATE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO
THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
DOT HAZARDOUS SUBSTANCE(S): P-BENZOQUINONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
TERT-BUTYL PERBENZOATE (CAS# 614-45-9): 100 LBS. (45.4 KG)
P-BENZOQUINONE (CAS# 106-51-4): 10 LBS. (4.54 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 3, 15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 04/24/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.