| Common Name: | LOCTITE 380 INSTANT ADHESIVE KNOWN AS BLACK MAX BLACK TOUGHENED INS, 38004 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 4/12/2022 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3KE57 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 006.1
ISSUE DATE: 04/12/2022
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE 380 INSTANT ADHESIVE KNOWN AS BLACK MAX(R*) BLACK TOUGHENED INS
IDH NUMBER: 232834
PRODUCT TYPE/USE: CYANOACRYLATE
ITEM NUMBER: 38004
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
BONDS SKIN IN SECONDS.
COMBUSTIBLE LIQUID.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF CAUSING CANCER.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 4
EYE IRRITATION 2B
CARCINOGENICITY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT, SPARKS,
OPEN FLAMES, HOT SURFACES - NO SMOKING. AVOID BREATHING VAPORS, MIST, OR
SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR
IN A WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE
PROTECTION.
RESPONSE:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
ETHYL 2-CYANOACRYLATE 7085-85-0 80 - 90
CARBON BLACK 1333-86-4 1 - 5
HYDROQUINONE 123-31-9 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
DO NOT PULL BONDED SKIN APART. SOAK IN WARM SOAPY WATER. GENTLY PEEL APART
USING A BLUNT INSTRUMENT. IF SKIN IS BURNED DUE TO THE RAPID GENERATION OF
HEAT BY A LARGE DROP, SEEK MEDICAL ATTENTION. IF LIPS ARE BONDED, APPLY
WARM WATER TO THE LIPS AND ENCOURAGE WETTING AND PRESSURE FROM SALIVA IN
MOUTH. PEEL OR ROLL LIPS APART. DO NOT PULL LIPS APART WITH DIRECT OPPOSING
FORCE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. IF EYELIDS ARE BONDED CLOSED, RELEASE EYELASHES WITH WARM WATER
BY COVERING WITH A WET PAD. DO NOT FORCE EYE OPEN. CYANOACRYLATE WILL BOND
TO EYE PROTEIN AND WILL CAUSE A LACHRYMATORY EFFECT WHICH WILL HELP TO
DEBOND THE ADHESIVE. KEEP EYE COVERED UNTIL DEBONDING IS COMPLETE, USUALLY
WITHIN 1-3 DAYS. MEDICAL ATTENTION SHOULD BE SOUGHT IN CASE SOLID PARTICLES
OF POLYMERIZED CYANOACRYLATE TRAPPED BEHIND THE EYELID CAUSED ABRASIVE
DAMAGE.
INGESTION:
ENSURE BREATHING PASSAGES ARE NOT OBSTRUCTED. THE PRODUCT WILL POLYMERIZE
RAPIDLY AND BOND TO THE MOUTH MAKING IT ALMOST IMPOSSIBLE TO SWALLOW.
SALIVA WILL SEPARATE ANY SOLIDIFIED PRODUCT IN SEVERAL HOURS. PREVENT THE
PATIENT FROM SWALLOWING ANY SEPARATED MASS.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN:
SURGERY IS NOT NECESSARY TO SEPARATE ACCIDENTALLY BONDED TISSUES.
EXPERIENCE HAS SHOWN THAT BONDED TISSUES ARE BEST TREATED BY PASSIVE,
NON-SURGICAL FIRST AID. IF RAPID CURING HAS CAUSED THERMAL BURNS THEY
SHOULD BE TREATED SYMPTOMATICALLY AFTER ADHESIVE IS REMOVED.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR A SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED
IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
TRACE AMOUNTS OF TOXIC AND/OR IRRITATING FUMES MAY BE RELEASED AND THE USE
OF BREATHING APPARATUS IS RECOMMENDED.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
VENTILATE AREA. DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
DO NOT USE CLOTHS FOR MOPPING UP. FLOOD WITH WATER TO COMPLETE
POLYMERIZATION AND SCRAPE OFF THE FLOOR. CURED MATERIAL CAN BE DISPOSED OF
AS NON-HAZARDOUS WASTE. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL
PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH FABRIC OR PAPER
GOODS. CONTACT WITH THESE MATERIALS MAY CAUSE RAPID POLYMERIZATION WHICH
CAN GENERATE SMOKE AND STRONG IRRITATING VAPORS, AND CAUSE THERMAL BURNS.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
ETHYL 2-CYANOACRYLATE 1 PPM STEL NONE
0.2 PPM TWA
(RESPIRATORY
SENSITIZATION)
(DERMAL SENSITIZATION)
CARBON BLACK 3 MG/M3 TWA 3.5 MG/M3 PEL
INHALABLE FRACTION.
5 MG/M3 TWA
RESPIRABLE FRACTION.
50 MPPCF TWA
TOTAL DUST.
15 MPPCF TWA
RESPIRABLE FRACTION.
15 MG/M3 TWA
TOTAL DUST.
HYDROQUINONE 1 MG/M3 TWA 2 MG/M3 PEL
(DERMAL SENSITIZATION)
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
ETHYL 2-CYANOACRYLATE NONE NONE
CARBON BLACK NONE NONE
HYDROQUINONE NONE NONE
ENGINEERING CONTROLS:
USE POSITIVE DOWN-DRAFT EXHAUST VENTILATION IF GENERAL VENTILATION IS
INSUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE
LIMITS.
RESPIRATORY PROTECTION:
IN CIRCUMSTANCES WHERE EXPOSURE TO CYANOACRYLATE VAPORS CANNOT BE
CONTROLLED BY VENTILATION A NIOSH APPROVED RESPIRATOR WITH AN ORGANIC VAPOR
CARTRIDGE CAN BE USED. WHEN SUCH A RESPIRATOR IS USED CARTRIDGE FUNCTION
MUST BE MONITORED FREQUENTLY AS THE CYANOACRYLATE VAPOR WILL POLYMERIZE AND
THE FILTER WILL BECOME BLOCKED. FOR THAT REASON WE STRONGLY RECOMMEND THAT
ADEQUATE VENTILATION IS IN PLACE SO A RESPIRATOR WILL NOT BE NEEDED.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE NITRILE GLOVES AND APRONS AS NECESSARY TO PREVENT CONTACT. DO NOT USE
PVC, NYLON OR COTTON.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BLACK
ODOR: IRRITATING
ODOR THRESHOLD: 1 - 2 PPM
PH: NOT APPLICABLE
VAPOR PRESSURE: <0.2 MMHg (77 DEG. F (25 DEG. C))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT DETERMINED
SPECIFIC GRAVITY: 1.1
VAPOR DENSITY: 3 APPROXIMATELY
FLASH POINT: 86.95 DEG. C (188.51 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: 485 DEG. C (905 DEG. F)
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: POLYMERISES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT APPLICABLE
VOC CONTENT: <2%; <20 G/L (CALIFORNIA SCAQMD METHOD 316B) (ESTIMATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
HAZARDOUS REACTIONS:
RAPID EXOTHERMIC POLYMERIZATION WILL OCCUR IN THE PRESENCE OF WATER,
AMINES, ALKALIS AND ALCOHOLS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE
INCOMPATIBLE MATERIALS: WATER, AMINES, ALKALIS AND ALCOHOLS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: SPONTANEOUS POLYMERIZATION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. EXPOSURE TO VAPORS ABOVE THE
ESTABLISHED EXPOSURE LIMIT RESULTS IN RESPIRATORY IRRITATION, WHICH MAY
LEAD TO DIFFICULTY IN BREATHING AND TIGHTNESS IN THE CHEST.
SKIN CONTACT:
BONDS SKIN IN SECONDS. MAY CAUSE SKIN IRRITATION. CYANOACRYLATES HAVE BEEN
REPORTED TO CAUSE ALLERGIC REACTION BUT DUE TO RAPID POLYMERIZATION AT THE
SKIN SURFACE, AN ALLERGIC RESPONSE IS RARE. CYANOACRYLATES GENERATE HEAT
ON SOLIDIFICATION. IN RARE CIRCUMSTANCES A LARGE DROP WILL BURN THE SKIN.
CURED ADHESIVE DOES NOT PRESENT A HEALTH HAZARD EVEN IF BONDED TO THE SKIN.
EYE CONTACT:
IRRITATING TO EYES. CAUSES EXCESSIVE TEARING. EYELIDS MAY BOND.
INGESTION:
NOT EXPECTED TO BE HARMFUL BY INGESTION. RAPIDLY POLYMERIZES (SOLIDIFIES)
AND BONDS IN MOUTH. IT IS ALMOST IMPOSSIBLE TO SWALLOW.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
ETHYL 2-CYANOACRYLATE NONE IRRITANT, ALLERGEN,
RESPIRATORY
CARBON BLACK ORAL LD50 (RAT): RESPIRATORY, SOME
>8,000 MG/KG EVIDENCE OF
CARCINOGENICITY
HYDROQUINONE ORAL LD50 (RAT): BLOOD, BONE MARROW,
320 MG/KG CENTRAL NERVOUS
SYSTEM, DEVELOPMENTAL,
ORAL LD50 (MOUSE): EYES, IMMUNE SYSTEM,
245 MG/KG IRRITANT, LIVER,
MUTAGEN, SKIN,
ORAL LD50 (RABBIT): THYROID
540 MG/KG
DERMAL LD50 (RAT):
>900 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
ETHYL 2-CYANOACRYLATE NO NO NO
CARBON BLACK NO GROUP 2B NO
HYDROQUINONE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS OR DIVISION: COMBUSTIBLE LIQUID
IDENTIFICATION NUMBER: NA 1993
PACKING GROUP: III
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AVIATION REGULATED LIQUID, N.O.S. (CYANOACRYLATE ESTER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3334
PACKING GROUP: III
EXCEPTIONS:
PRIMARY PACKS CONTAINING LESS THAN 500ML ARE UNREGULATED BY THIS MODE OF
TRANSPORT AND MAY BE SHIPPED UNRESTRICTED.
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: HYDROQUINONE (CAS# 123-31-9).
CERCLA/SARA SECTION 311/312:
IMMEDIATE HEALTH, DELAYED HEALTH, FIRE, REACTIVE
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
HYDROQUINONE (CAS# 123-31-9): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 8
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 04/12/2022
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF ANY
KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY OTHER
JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.