| Common Name: | LOCTITE LB 8023, 34395 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 3/11/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 3KE63 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 003.0
ISSUE DATE: 03/11/2019
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE LB 8023
PRODUCT TYPE/USE: LUBRICANT
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 299175
ITEM NUMBER: 34395
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
REPRODUCTIVE TOXICITY 2
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING VAPORS, MIST,
OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
2% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
RESIDUAL OILS (PETROLEUM), 64742-01-4 10 - 20
SOLVENT-REFINED, <3% DMSO
CALCIUM OXIDE 1305-78-8 10 - 20
GRAPHITE 7782-42-5 10 - 20
DISTILLATES (PETROLEUM), 64741-88-4 10 - 20
SOLVENT-REFINED HEAVY
PARAFFINIC
PETROLEUM DISTILLATES, 64742-53-6 5 - 10
HYDROTREATED, LIGHT
NAPHTHENIC
DISTILLATES (PETROLEUM), 64742-52-5 5 - 10
HYDROTREATED HEAVY
NAPHTHENIC
CALCIUM DISTEARATE 1592-23-0 5 - 10
CALCIUM DODECYLBENZENE 26264-06-2 1 - 5
SULFONATE
CALCIUM DIHYDROXIDE 1305-62-0 1 - 5
SULFONIC ACIDS, PETROLEUM, 61789-86-4 1 - 5
CALCIUM SALTS
BORON OXIDE (B2O3) 1303-86-2 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR.
IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION. WASH CLOTHING
BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
KEEP INDIVIDUAL CALM. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, POWDER
SPECIAL FIREFIGHTING PROCEDURES:
WEAR A SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED
IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF NITROGEN. OXIDES OF CARBON. OXIDES OF SULFUR. CALCIUM OXIDE.
TOXIC FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. CLEAN RESIDUE WITH SOAP AND WATER.
STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. REFER TO
SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED.
STORAGE: KEEP CONTAINER CLOSED. KEEP IN A COOL, WELL VENTILATED AREA.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
RESIDUAL OILS (PETROLEUM), INCLUDED IN THE NONE
SOLVENT-REFINED, <3% DMSO REGULATION BUT
WITH NO DATA
VALUES. SEE
REGULATION FOR
FURTHER DETAILS
5 MG/M3 TWA
INHALABLE
FRACTION.
EXPOSURE BY ALL
ROUTES SHOULD
BE CAREFULLY
CONTROLLED TO
LEVELS AS LOW
AS POSSIBLE.
CALCIUM OXIDE 2 MG/M3 TWA 5 MG/M3 PEL
GRAPHITE 2 MG/M3 TWA 5 MG/M3 PEL
RESPIRABLE RESPIRABLE FRACTION.
FRACTION. 15 MG/M3 PEL TOTAL
DUST. 15 MPPCF TWA
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 500 PPM (2,000
SOLVENT-REFINED HEAVY INHALABLE MG/M3) PEL
PARAFFINIC FRACTION. 5 MG/M3 PEL MIST.
5 MG/M3 TWA MIST 5 MG/M3 TWA MIST
10 MG/M3 STEL MIST
PETROLEUM DISTILLATES, 5 MG/M3 TWA 500 PPM (2,000
HYDROTREATED, LIGHT INHALABLE MG/M3) PEL
NAPHTHENIC FRACTION. 5 MG/M3 PEL MIST.
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 500 PPM (2,000
HYDROTREATED HEAVY INHALABLE MG/M3) PEL
NAPHTHENIC FRACTION. 5 MG/M3 PEL MIST.
CALCIUM DISTEARATE 3 MG/M3 TWA NONE
RESPIRABLE
FRACTION.
3 MG/M3 TWA
RESPIRABLE
FRACTION.
10 MG/M3 TWA
INHALABLE
FRACTION.
CALCIUM DODECYLBENZENE NONE NONE
SULFONATE
CALCIUM DIHYDROXIDE 5 MG/M3 TWA 5 MG/M3 PEL
RESPIRABLE FRACTION.
15 MG/M3 PEL TOTAL
DUST.
SULFONIC ACIDS, PETROLEUM, NONE NONE
CALCIUM SALTS
BORON OXIDE (B2O3) 10 MG/M3 TWA 15 MG/M3 PEL TOTAL
DUST.
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
RESIDUAL OILS (PETROLEUM), NONE NONE
SOLVENT-REFINED, <3% DMSO
CALCIUM OXIDE NONE NONE
GRAPHITE NONE NONE
DISTILLATES (PETROLEUM), NONE NONE
SOLVENT-REFINED HEAVY
PARAFFINIC
PETROLEUM DISTILLATES, NONE NONE
HYDROTREATED, LIGHT
NAPHTHENIC
DISTILLATES (PETROLEUM), NONE NONE
HYDROTREATED HEAVY
NAPHTHENIC
CALCIUM DISTEARATE NONE NONE
CALCIUM DODECYLBENZENE NONE NONE
SULFONATE
CALCIUM DIHYDROXIDE NONE NONE
SULFONIC ACIDS, PETROLEUM, NONE NONE
CALCIUM SALTS
BORON OXIDE (B2O3) NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR 1910.134). USE NIOSH
APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. SAFETY SHOWERS AND EYE
WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: BLACK
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.2648
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: NOT APPLICABLE
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <3 %; 38.4 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SULFUR. CALCIUM OXIDE.
TOXIC FUMES.
INCOMPATIBLE MATERIALS:
STRONG ACIDS AND STRONG BASES. STRONG OXIDIZING AGENTS. STRONG REDUCING
AGENTS. WATER. ALKALIS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. AVOID
DUST FORMATION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
PRINCIPAL HAZARD OF INGESTION IS ASPIRATION INTO THE LUNGS AND SUBSEQUENT
PNEUMONITIS.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
RESIDUAL OILS (PETROLEUM), NONE IRRITANT
SOLVENT-REFINED, <3% DMSO
CALCIUM OXIDE NONE IRRITANT, CORROSIVE, EYES
GRAPHITE NONE LUNG
DISTILLATES (PETROLEUM), NONE IRRITANT
SOLVENT-REFINED HEAVY
PARAFFINIC
PETROLEUM DISTILLATES, NONE IRRITANT
HYDROTREATED, LIGHT
NAPHTHENIC
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED HEAVY
NAPHTHENIC
CALCIUM DISTEARATE NONE NO TARGET ORGANS
CALCIUM DODECYLBENZENE NONE EYES, IRRITANT
SULFONATE
CALCIUM DIHYDROXIDE ORAL LD50 (RAT): IRRITANT, CORROSIVE
7,340 MG/KG
SULFONIC ACIDS, PETROLEUM, NONE NO DATA
CALCIUM SALTS
BORON OXIDE (B2O3) ORAL LD50 (MOUSE): BLOOD, CENTRAL NERVOUS
3,163 MG/KG SYSTEM, GASTROINTESTINAL,
IRRITANT, KIDNEY, LIVER,
LUNG, METABOLIC, NUISANCE
DUST, SKIN, VASCULAR
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
RESIDUAL OILS (PETROLEUM), KNOWN TO GROUP 1 NO
SOLVENT-REFINED, <3% DMSO BE HUMAN
CARCINOGEN.
CALCIUM OXIDE NO NO NO
GRAPHITE NO NO NO
DISTILLATES (PETROLEUM), NO NO NO
SOLVENT-REFINED HEAVY
PARAFFINIC
PETROLEUM DISTILLATES, NO NO NO
HYDROTREATED, LIGHT
NAPHTHENIC
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED HEAVY
NAPHTHENIC
CALCIUM DISTEARATE NO NO NO
CALCIUM DODECYLBENZENE NO NO NO
SULFONATE
CALCIUM DIHYDROXIDE NO NO NO
SULFONIC ACIDS, PETROLEUM, NO NO NO
CALCIUM SALTS
BORON OXIDE (B2O3) NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY:
CALCIUM DODECYLBENZENE SULFONATE (CAS# 26264-06-2): 1,000 LBS. (454 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 03/11/2019
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION
OF ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS
OF ANY OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.