| Common Name: | ENERGIZER BATTERY, LITHIUM MANGANESE DIOXIDE, 12004-A |
| Manufacturer: | ENERGIZER BATTERY |
| SDS Revision Date: | 1/1/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 2LBJ6, 3KKJ1, 65TG93, 65TG94, 65TG96, 9LG53 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ENERGIZER(R*)
PRODUCT SAFETY DATA SHEET
CYLINDRICAL LITHIUM MANGANESE DIOXIDE BATTERIES
JANUARY 2017
PRODUCT SAFETY DATA SHEET
PRODUCT NAME: ENERGIZER BATTERY
TYPE NO: 123, 1CR2, 223, 2CR5, 2L76, CRV3, LA522, L522
VOLTS: 3.0, 9.0
TRADE NAMES: CYLINDRICAL LITHIUM MANGANESE DIOXIDE BATTERIES
APPROXIMATE WEIGHT: 11 - 40 G.
CHEMICAL SYSTEM: LITHIUM MANGANESE DIOXIDE
DESIGNED FOR RECHARGE: NO
DOCUMENT NUMBER: 12004-A
ENERGIZER HAS PREPARED COPYRIGHTED PRODUCT SAFETY DATASHEETS TO PROVIDE
INFORMATION ON THE DIFFERENT EVEREADY/ENERGIZER BATTERY SYSTEMS. BATTERIES
ARE ARTICLES AS DEFINED UNDER THE GHS AND EXEMPT FROM GHS CLASSIFICATION
CRITERIA (SECTION 1.3.2.1.1 OF THE GHS). THE INFORMATION AND
RECOMMENDATIONS SET FORTH HEREIN ARE MADE IN GOOD FAITH, FOR INFORMATION
ONLY, AND ARE BELIEVED TO BE ACCURATE AS OF THE DATE OF PREPARATION.
HOWEVER, ENERGIZER BATTERY MANUFACTURING, INC. MAKES NO WARRANTY, EITHER
EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL
LIABILITY FROM REFERENCE ON IT.
| SECTION 1 - MANUFACTURER INFORMATION |  |
MANUFACTURED FOR:
ENERGIZER BATTERY MANUFACTURING, INC.
25225 DETROIT RD.
WESTLAKE, OH 44145
TELEPHONE NUMBER FOR INFORMATION: 800-383-7323 (USA / CANADA)
DATE PREPARED: JANUARY 2017
| SECTION 2 - HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION: N/A
SIGNAL WORD: N/A
HAZARD CLASSIFICATION: N/A
UNDER NORMAL CONDITIONS OF USE, THE BATTERY IS HERMETICALLY SEALED.
INGESTION: SWALLOWING A BATTERY CAN BE HARMFUL.
INHALATION: CONTENTS OF AN OPEN BATTERY CAN CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CONTENTS OF AN OPEN BATTERY CAN CAUSE SKIN IRRITATION.
EYE CONTACT: CONTENTS OF AN OPEN BATTERY CAN CAUSE SEVERE IRRITATION.
| SECTION 3 - INGREDIENTS | |
IMPORTANT NOTE:
THE BATTERY SHOULD NOT BE OPENED OR BURNED. EXPOSURE TO THE INGREDIENTS
CONTAINED WITHIN OR THEIR COMBUSTION PRODUCTS COULD BE HARMFUL.
MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/WT.
CARBON BLACK 3.5 MG/M3 TWA 3.5 MG/M3 TWA 0-1
(CAS# 1333-86-4)
1,2-DIMETHOXYETHANE NONE ESTABLISHED NONE ESTABLISHED 0-6
(CAS# 110-71-4)
1,3-DIOXOLANE NONE ESTABLISHED NONE ESTABLISHED 0-8
(CAS# 646-06-0)
GRAPHITE 15 MG/M3 TWA (TOTAL 2 MG/M3 TWA 0-3
(CAS# 7782-42-5) DUST) (RESPIRABLE
5 MG/M3 TWA FRACTION)
(RESPIRABLE FRACTION)
LITHIUM OR LITHIUM NONE ESTABLISHED NONE ESTABLISHED 1-6
ALLOY
(CAS# 7439-93-2)
LITHIUM TRIFLUORO- NONE ESTABLISHED NONE ESTABLISHED 0-3
METHANESULFONATE
(CAS# 33454-82-9)
LITHIUM TRIFLUORO- NONE ESTABLISHED NONE ESTABLISHED 0-3
METHANESULFONIMIDE
(CAS# 90076-65-6)
MANGANESE DIOXIDE 5 MG/M3 CEILING 0.2 MG/M3 TWA 12-42
(CAS# 1313-13-9) (AS Mn) (AS Mn)
PROPYLENE CARBONATE NONE ESTABLISHED NONE ESTABLISHED 0-8
(CAS# 108-32-7)
NON-HAZARDOUS COMPONENTS:
STEEL NONE ESTABLISHED NONE ESTABLISHED 20
(IRON CAS# 65997-19-5)
PLASTIC AND OTHER NONE ESTABLISHED NONE ESTABLISHED BALANCE
| SECTION 4 - FIRST AID MEASURES | |
INGESTION: DO NOT INDUCE VOMITING OR GIVE FOOD OR DRINK.
INHALATION: PROVIDE FRESH AIR AND SEEK MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH SOAP AND WATER.
EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES,
LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF THE CHEMICAL REMAINS.
SEEK MEDICAL ATTENTION.
NOTE:
CARBON BLACK IS LISTED AS A POSSIBLE CARCINOGEN BY INTERNATIONAL AGENCY
FOR RESEARCH ON CANCER (IARC).
| SECTION 5 - FIRE FIGHTING MEASURES | |
IN CASE OF FIRE WHERE LITHIUM BATTERIES ARE PRESENT, FLOOD AREA WITH WATER
OR SMOTHER WITH A CLASS D FIRE EXTINGUISHANT APPROPRIATE FOR LITHIUM METAL,
SUCH AS LITH-X. WATER MAY NOT EXTINGUISH BURNING BATTERIES BUT WILL COOL
THE ADJACENT BATTERIES AND CONTROL THE SPREAD OF FIRE. BURNING BATTERIES
WILL BURN THEMSELVES OUT. VIRTUALLY ALL FIRES INVOLVING LITHIUM BATTERIES
CAN BE CONTROLLED BY FLOODING WITH WATER. HOWEVER, THE CONTENTS OF THE
BATTERY WILL REACT WITH WATER AND FORM HYDROGEN GAS. IN A CONFINED SPACE,
HYDROGEN GAS CAN FORM AN EXPLOSIVE MIXTURE. IN THIS SITUATION, SMOTHERING
AGENTS ARE RECOMMENDED. A SMOTHERING AGENT WILL EXTINGUISH BURNING LITHIUM
BATTERIES.
EMERGENCY RESPONDERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS.
BURNING LITHIUM MANGANESE DIOXIDE BATTERIES PRODUCE TOXIC AND CORROSIVE
LITHIUM HYDROXIDE FUMES.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
TO CLEANUP LEAKING BATTERIES:
VENTILATION REQUIREMENTS:
ROOM VENTILATION MAY BE REQUIRED IN AREAS WHERE THERE ARE OPEN OR LEAKING
BATTERIES.
RESPIRATORY PROTECTION:
AVOID EXPOSURE TO ELECTROLYTE FUMES FROM OPEN OR LEAKING BATTERIES.
EYE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS IF HANDLING AN OPEN OR LEAKING
BATTERY.
GLOVES:
USE NEOPRENE OR NATURAL RUBBER GLOVES IF HANDLING AN OPEN OR LEAKING
BATTERY.
BATTERY MATERIALS SHOULD BE COLLECTED IN A LEAK-PROOF CONTAINER.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE:
STORE IN A COOL, WELL VENTILATED AREA. ELEVATED TEMPERATURES CAN RESULT IN
SHORTENED BATTERY LIFE. IN LOCATIONS THAT HANDLE LARGE QUANTITIES OF
LITHIUM BATTERIES, SUCH AS WAREHOUSES, LITHIUM BATTERIES SHOULD BE ISOLATED
FROM UNNECESSARY COMBUSTIBLES.
MECHANICAL CONTAINMENT:
IF POTTING OR SEALING THE BATTERY IN AN AIRTIGHT OR WATERTIGHT CONTAINER IS
REQUIRED, CONSULT YOUR ENERGIZER BATTERY MANUFACTURING, INC. REPRESENTATIVE
FOR PRECAUTIONARY SUGGESTIONS. DO NOT OBSTRUCT SAFETY RELEASE VENTS ON
BATTERIES. ENCAPSULATION OF BATTERIES WILL NOT ALLOW CELL VENTING AND CAN
CAUSE HIGH PRESSURE RUPTURE.
HANDLING:
ACCIDENTAL SHORT CIRCUIT FOR A FEW SECONDS WILL NOT SERIOUSLY AFFECT THE
BATTERY. PROLONGED SHORT CIRCUIT WILL CAUSE THE BATTERY TO LOSE ENERGY,
GENERATE SIGNIFICANT HEAT AND CAN CAUSE THE SAFETY RELEASE VENT TO OPEN.
SOURCES OF SHORT CIRCUITS INCLUDE JUMBLED BATTERIES IN BULK CONTAINERS,
METAL JEWELRY, METAL COVERED TABLES OR METAL BELTS USED FOR ASSEMBLY OF
BATTERIES INTO DEVICES. DAMAGING A LITHIUM BATTERY MAY RESULT IN AN
INTERNAL SHORT CIRCUIT.
THE CONTENTS OF AN OPEN BATTERY, INCLUDING A VENTED BATTERY, WHEN EXPOSED
TO WATER, MAY RESULT IN A FIRE AND/OR EXPLOSION. CRUSHED OR DAMAGED
BATTERIES MAY RESULT IN A FIRE.
IF SOLDERING OR WELDING TO THE BATTERY IS REQUIRED, CONSULT YOUR ENERGIZER
REPRESENTATIVE FOR PROPER PRECAUTIONS TO PREVENT SEAL DAMAGE OR SHORT
CIRCUIT.
CHARGING:
THIS BATTERY IS MANUFACTURED IN A CHARGED STATE. IT IS NOT DESIGNED FOR
RECHARGING. RECHARGING CAN CAUSE BATTERY LEAKAGE OR, IN SOME CASES, HIGH
PRESSURE RUPTURE. INADVERTENT CHARGING CAN OCCUR IF A BATTERY IS INSTALLED
BACKWARDS.
LABELING:
IF THE ENERGIZER LABEL OR PACKAGE WARNINGS ARE NOT VISIBLE, IT IS IMPORTANT
TO PROVIDE A PACKAGE AND/OR DEVICE LABEL STATING:
WARNING:
BATTERY CAN EXPLODE OR LEAK AND CAUSE BURNS IF INSTALLED BACKWARDS,
DISASSEMBLED, CHARGED, OR EXPOSED TO WATER, FIRE OR HIGH TEMPERATURE.
WHERE ACCIDENTAL INGESTION OF SMALL BATTERIES IS POSSIBLE, THE LABEL SHOULD
INCLUDE:
WARNING
(1) KEEP OUT OF REACH OF CHILDREN. SWALLOWING MAY LEAD TO SERIOUS INJURY OR
DEATH IN AS LITTLE AS 2 HOURS DUE TO CHEMICAL BURNS AND POTENTIAL
PERFORATION OF THE ESOPHAGUS. IMMEDIATELY SEE DOCTOR; HAVE DOCTOR PHONE
(202) 625-3333. KEEP IN ORIGINAL PACKAGE UNTIL READY TO USE. DISPOSE OF
USED BATTERIES IMMEDIATELY.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
VENTILATION REQUIREMENTS: NOT NECESSARY UNDER NORMAL CONDITIONS.
RESPIRATORY PROTECTION: NOT NECESSARY UNDER NORMAL CONDITIONS.
EYE PROTECTION: NOT NECESSARY UNDER NORMAL CONDITIONS.
GLOVES: NOT NECESSARY UNDER NORMAL CONDITIONS.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE (PHYSICAL STATE, COLOR, ETC.): SOLID OBJECT
UPPER EXPLOSIVE LIMITS: NOT APPLICABLE FOR AN ARTICLE
LOWER EXPLOSIVE LIMITS NOT APPLICABLE FOR AN ARTICLE
ODOR: NO ODOR
VAPOR PRESSURE (MM Hg @ 25 DEG. C): NOT APPLICABLE FOR AN ARTICLE
ODOR THRESHOLD: NO ODOR
VAPOR DENSITY (AIR = 1): NOT APPLICABLE FOR AN ARTICLE
PH: NOT APPLICABLE FOR AN ARTICLE
DENSITY (G/CM3): 2.0-3.0
MELTING POINT/FREEZING POINT: NOT APPLICABLE FOR AN ARTICLE
SOLUBILITY IN WATER (% BY WEIGHT): NOT APPLICABLE FOR AN ARTICLE
BOILING POINT @ 760 MM Hg (DEG. C): NOT APPLICABLE FOR AN ARTICLE
FLASH POINT: NOT APPLICABLE FOR AN ARTICLE
EVAPORATION RATE (BUTYL ACETATE = 1): NOT APPLICABLE FOR AN ARTICLE
FLAMMABILITY: NOT APPLICABLE FOR AN ARTICLE
PARTITION COEFFICIENT: NOT APPLICABLE FOR AN ARTICLE
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE FOR AN ARTICLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE FOR AN ARTICLE
VISCOSITY: NOT APPLICABLE FOR AN ARTICLE
| SECTION 10 - STABILITY AND REACTIVITY | |
LITHIUM MANGANESE DIOXIDE BATTERIES CONTAIN NO SULFIDES OR CYANIDES AND
THEY DO NOT MEET ANY OTHER REACTIVITY CRITERIA INCLUDING "REACTS VIOLENTLY
WITH WATER" AND THEREFORE DO NOT MEET ANY OF THE CRITERIA ESTABLISHED IN 40
CFR 261.2 FOR REACTIVITY.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
UNDER NORMAL CONDITIONS OF USE, LITHIUM MANGANESE DIOXIDE BATTERIES ARE
NON-TOXIC.
| SECTION 12 - ECOLOGICAL INFORMATION | |
ISSUES SUCH AS ECOTOXICITY, PERSISTENCE AND BIOACCUMULATION ARE NOT
APPLICABLE FOR ARTICLES.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
LiMnO2 BATTERIES ARE NOT HAZARDOUS WASTE PER THE UNITED STATES RESOURCE
CONSERVATION AND RECOVERY ACT(RCRA) - 40 CFR PART 261 SUBPART C.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
IN GENERAL, ALL BATTERIES IN ALL FORMS OF TRANSPORTATION (GROUND, AIR, OR
OCEAN) MUST BE PACKAGED IN A SAFE AND RESPONSIBLE MANNER. REGULATORY
CONCERNS FROM ALL AGENCIES FOR SAFE PACKAGING REQUIRE THAT BATTERIES BE
PACKAGED IN A MANNER THAT PREVENTS SHORT CIRCUITS AND BE CONTAINED IN
"STRONG OUTER PACKAGING" THAT PREVENTS SPILLAGE OF CONTENTS. ALL ORIGINAL
PACKAGING FOR ENERGIZER LITHIUM BATTERIES ARE COMPLIANT WITH THESE
REGULATORY CONCERNS.
ENERGIZER LITHIUM MANGANESE DIOXIDE BATTERIES ARE EXEMPT FROM THE
CLASSIFICATION AS DANGEROUS GOODS AS THEY MEET THE REQUIREMENTS OF THE
SPECIAL PROVISIONS LISTED BELOW. (ESSENTIALLY, THEY ARE PROPERLY PACKAGED
AND LABELED, CONTAIN LESS THAN 1 GRAM OF LITHIUM AND PASS THE TESTS DEFINED
IN UN MODEL REGULATION SECTION 38.3).
REGULATORY BODY SPECIAL PROVISIONS
ADR 188, 230, 310, 636, 656
IMDG 188, 230, 310, 957
UN UN 3090, UN 3091
US DOT 29, A54, A100, A101
IATA 58TH EDITION, ICAO PACKAGING INSTRUCTIONS 968 - 970
TRANSPORT CANADA TDG 34
ENERGIZER IS REGISTERED WITH CHEMTREC. IN THE EVENT OF AN INCIDENT DURING
TRANSPORT CALL 1-800-424-9300 (NORTH AMERICA) OR 1-703-527-3887
(INTERNATIONAL).
A GLOBAL LITHIUM LABEL CHART IS PROVIDED BELOW TO SUMMARIZE THE CURRENT
GLOBAL LABELING REQUIREMENTS.
LABEL SUMMARY CHART:
SHIPPING Li CONTENT NET QUANTITY BATTERY TYPE CLASS 9 - <??> CARGO
MODE WT. OF MISCELLA- AIRCRAFT
BATTERIES NEOUS ONLY
PER PACKAGE
AIR 0.3G TO </=2.5 KG 123, 1CR2, YES YES YES
</=1G/CELL 223, 2CR5,
0.3G TO 2L76, CRV3,
</=2G/ LA522
BATTERY
</=0.3G/ </=2.5KG ALL Li COIN NO YES YES
CELL AND 2L76
</=0.3G/ >2.5KG ALL Li COIN YES YES YES
CELL AND 2L76
LAND/ ALL ALL ALL NO YES YES
SEA ONLY
| SECTION 15 - REGULATORY INFORMATION | |
OUTSIDE OF THE TRANSPORTATION REQUIREMENTS NOTED IN SECTION 14, LITHIUM
MANGANESE DIOXIDE BATTERIES MARKETED BY ENERGIZER BATTERY MANUFACTURING,
INC. ARE NOT REGULATED.
SARA/TITLE III - AS AN ARTICLE, THIS BATTERY AND ITS CONTENTS ARE NOT
SUBJECT TO THE REQUIREMENTS OF THE EMERGENCY PLANNING AND COMMUNITY
RIGHT-TO-KNOW ACT.
| SECTION 16 - OTHER INFORMATION | |
NONE.
(C)2017 ENERGIZER