| Common Name: | LOCTITE SI 595 LOCTITE SUPERFLEX CLEAR RTV, 59575 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 3/11/2020 |
| SDS Format: | No Format Specified |
| Item Number(s): | 3KMY8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 009.0
ISSUE DATE: 03/11/2020
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE SI 595 LOCTITE(R*) SUPERFLEX(R*) CLEAR RTV
PRODUCT TYPE/USE: SILICONE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 193999
ITEM NUMBER: 59575
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL: NOT PRESCRIBED
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
SILICON DIOXIDE 7631-86-9 5 - 10
TRIACETOXYETHYLSILANE 17689-77-9 0.1 - 1
METHYLSILANETRIYL TRIACETATE 4253-34-3 0.1 - 1
*EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER. IF
SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS. IF EYE
IRRITATION PERSISTS, CONSULT A SPECIALIST.
INGESTION:
DO NOT INDUCE VOMITING. IF A PERSON FEELS UNWELL OR SYMPTOMS OF SKIN
IRRITATION APPEAR, CONSULT A PHYSICIAN.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES: WEAR SELF CONTAINED BREATHING APPARATUS.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. SPILLED MATERIAL WILL SOLIDIFY.
STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. MAINTAIN GOOD
VENTILATION FOR LARGE SPILLS.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT HANDLE CONTACT LENSES
UNTIL ALL SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY
TRANSFER TO LENSES AND CAUSE EYE IRRITATION.
STORAGE: STORE IN A DRY AREA BELOW 90 DEG. F. KEEP CONTAINER CLOSED.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
SILICON DIOXIDE 6 MG/M3 TWA 20 MPPCF TWA NONE 3 MG/M3 TWA
0.8 MG/M3 TWA RESPIRABLE
FRACTION.
TRIACETOXYETHYLSILANE NONE NONE NONE NONE
METHYLSILANETRIYL NONE NONE NONE NONE
TRIACETATE
ENGINEERING CONTROLS:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. USE LOCAL
VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN VAPOR
CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION: CHEMICAL RESISTANT, IMPERMEABLE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: TRANSLUCENT
ODOR: ACETIC ACID
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: <10 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.01 AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 4%
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 19.9%
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT DETERMINED
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 3.0%; 30 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
PROLONGED HEATING AT TEMPERATURES ABOVE 150 DEG. C. EXPOSURE TO MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
WHEN HEATED TO TEMPERATURES EXCEEDING 300 DEG. F (150 DEG. C) IN THE
PRESENCE OF AIR, SILICONES MAY FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS A
POTENTIAL CANCER HAZARD AND A KNOWN SKIN AND RESPIRATORY SENSITIZER. VAPORS
IRRITATE THE EYES, NOSE AND THROAT. SAFE HANDLING CONDITIONS MAY BE
MAINTAINED BY KEEPING FORMALDEHYDE VAPOR CONCENTRATIONS BELOW THE OSHA
PERMISSIBLE LIMIT. MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
SILICON DIOXIDE ORAL LD50 (RAT): NUISANCE DUST
>22,500 MG/KG
ORAL LD50 (MOUSE):
>15,000 MG/KG
TRIACETOXYETHYLSILANE NONE NO TARGET ORGANS
METHYLSILANETRIYL NONE IRRITANT, ALLERGEN
TRIACETATE
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC OSHA CARCINOGEN
CARCINOGEN (SPECIFICALLY
REGULATED)
SILICON DIOXIDE NO NO NO
TRIACETOXYETHYLSILANE NO NO NO
METHYLSILANETRIYL TRIACETATE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2, 3, 8, 11, 15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 03/11/2020
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF ANY
KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY OTHER
JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.