| Common Name: | LOCTITE SI 594 WH AE KNOWN AS 594 RTV WHITE 190ML AE, 40466 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 3/22/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3KNK4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 03/22/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE SI 594 WH AE KNOWN AS 594 RTV WHITE 190ML AE
PRODUCT TYPE: SILICONE SEALANT
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 743541
ITEM NUMBER: 40466
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE DAMAGE.
HAZARD CLASS HAZARD CATEGORY
GASES UNDER PRESSURE COMPR. GAS
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
PICTOGRAM(S):
GAS CYLINDER
CORROSION
PRECAUTIONARY STATEMENTS:
PREVENTION:
WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL: NOT PRESCRIBED
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED 64742-46-7 5 - 10
MIDDLE
SILICON DIOXIDE 7631-86-9 5 - 10
NORFLURANE 811-97-2 5 - 10
METHYLSILANETRIYL TRIACETATE 4253-34-3 1 - 5
TRIACETOXYETHYLSILANE 17689-77-9 1 - 5
TITANIUM DIOXIDE 13463-67-7 1 - 5
ACETIC ACID 64-19-7 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR IN CASE OF ACCIDENTAL INHALATION OF VAPOURS OR
DECOMPOSITION PRODUCTS. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER. IF SKIN
IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF ADVERSE HEALTH EFFECTS DEVELOP SEEK MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. IN CASE OF ADVERSE HEALTH EFFECTS SEEK MEDICAL
ADVICE.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
COOL AEROSOL CONTAINERS WITH JET OF WATER. CONTAINERS MAY EXPLODE.
HAZARDOUS COMBUSTION PRODUCTS:
ACRID SMOKE AND FUMES. FORMALDEHYDE. IRRITATING ORGANIC VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEM.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. SPILLED MATERIAL WILL SOLIDIFY.
STORE IN A CLOSED CONTAINER UNTIL READY FOR DISPOSAL. MAINTAIN GOOD
VENTILATION FOR LARGE SPILLS.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. DO NOT HANDLE CONTACT LENSES UNTIL ALL
SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY TRANSFER TO
LENSES AND CAUSE EYE IRRITATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE, PLEASE REVIEW LABELS ON CONTAINER OR
CHECK THE TECHNICAL DATA SHEET.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
DISTILLATES 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
(PETROLEUM), INHALABLE MIST.
HYDROTREATED FRACTION.
MIDDLE 100 PPM (400
MG/M3) PEL
SILICON DIOXIDE 6 MG/M3 TWA 20 MPPCF TWA NONE 3 MG/M3
0.8 MG/M3 TWA TWA
RESPIRABLE
FRACTION.
NORFLURANE NONE NONE 1,000 PPM NONE
(4240
MG/M3) TWA
METHYLSILANETRIYL NONE NONE NONE NONE
TRIACETATE
TRIACETOXYETHYLSILANE NONE NONE NONE NONE
TITANIUM DIOXIDE 10 MG/M3 15 MG/M3 PEL NONE NONE
TWA TOTAL DUST.
15 MPPCF TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST
50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
ACETIC ACID 15 PPM STEL 10 PPM NONE NONE
10 PPM TWA (25 MG/M3)
PEL
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. SAFETY SHOWERS AND EYE
WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE, /, SOLID
COLOR: WHITE
ODOR: ACETIC ACID
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT:
>93 DEG. C (>199.4 DEG. F) TAGLIABUE CLOSED CUP; THIS PRODUCT EXHIBITS NO
FLASHBACK WHEN TESTED FOR FLAME EXTENSION.
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <4%; <40 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NOT AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
ACETIC ACID IS LIBERATED SLOWLY UPON CONTACT WITH MOISTURE. FORMALDEHYDE.
OXIDES OF CARBON. OXIDES OF SILICON.
INCOMPATIBLE MATERIALS: ACIDS. BASES. OXIDIZING AGENTS. WATER.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
PROLONGED HEATING AT TEMPERATURES ABOVE 150 DEG. C. EXPOSURE TO MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
ACETOXY CURING SILICONES RELEASE ACETIC ACID VAPOURS IN CONTACT WITH
MOISTURE. ACETIC ACID IS CORROSIVE AND IRRITATING TO THE EYES AND
RESPIRATORY SYSTEM. WHEN HEATED TO TEMPERATURES EXCEEDING 300 DEG. F
(150 DEG. C) IN THE PRESENCE OF AIR, SILICONES MAY FORM FORMALDEHYDE
VAPORS. FORMALDEHYDE IS A POTENTIAL CANCER HAZARD AND A KNOWN SKIN AND
RESPIRATORY SENSITIZER. VAPORS IRRITATE THE EYES, NOSE AND THROAT. SAFE
HANDLING CONDITIONS MAY BE MAINTAINED BY KEEPING FORMALDEHYDE VAPOR
CONCENTRATIONS BELOW THE OSHA PERMISSIBLE LIMIT. MAY CAUSE RESPIRATORY
TRACT IRRITATION.
SKIN CONTACT:
CAUSES SKIN IRRITATION. PROLONGED AND/OR REPEATED SKIN CONTACT WITH THIS
PRODUCT MAY CAUSE IRRITATION/DERMATITIS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
NOT A LIKELY ROUTE OF ENTRY. NOT EXPECTED TO BE HARMFUL BY INGESTION.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED MIDDLE
SILICON DIOXIDE ORAL LD50 (RAT): NUISANCE DUST
>22,500 MG/KG
ORAL LD50 (MOUSE):
>15,000 MG/KG
NORFLURANE NONE CARDIAC, CENTRAL NERVOUS
SYSTEM, IRRITANT,
RESPIRATORY, SKIN
METHYLSILANETRIYL NONE IRRITANT ALLERGEN
TRIACETATE
TRIACETOXYETHYLSILANE NONE NO TARGET ORGANS
TITANIUM DIOXIDE NONE IRRITANT, RESPIRATORY,
SOME EVIDENCE OF
CARCINOGENICITY
ACEDIC ACID ORAL LD50 (RABBIT): ALLERGEN, CORROSIVE,
1,200 MG/KG EYES, GASTROINTESTINAL,
IMMUNE SYSTEM, IRRITANT,
ORAL LD50 (MOUSE): KIDNEY
4,960 MG/KG
ORAL LD50 (RAT):
3.53 G/KG
ORAL LD50 (RAT):
3.31 G/KG
DERMAL LD50 (RABBIT):
1,060 MG/KG
INHALATION LC50
(RAT, 4 H):
11.4 MG/L
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED MIDDLE
SILICON DIOXIDE NO NO NO
NORFLURANE NO NO NO
METHYLSILANETRIYL NO NO NO
TRIACETATE
TRIACETOXYETHYLSILANE NO NO NO
TITANIUM DIOXIDE NO GROUP 2B NO
ACETIC ACID NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS. OTHERWISE DISPOSE OF IN ACCORDANCE WITH LOCAL AND NATIONAL
REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO
THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/
CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: REGULATORY AFFAIRS
ISSUE DATE: 03/22/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.