| Common Name: | DOUBLE BUBBLE SILICONE (04030) |
| Manufacturer: | ROYAL ADHESIVES & SEALANTS |
| SDS Revision Date: | 9/14/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3KZC3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ROYAL
ADHESIVES & SEALANTS
SAFETY DATA SHEET
ACC. TO OSHA HCS
PRINTING DATE: 09/14/2017
REVISION NUMBER: 2
REVISION DATE: 09/14/2017
| 1 IDENTIFICATION |  |
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PRODUCT IDENTIFIER:
TRADE NAME: DOUBLE BUBBLE SILICONE (04030)
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE.: SEALANT
APPLICATION OF THE SUBSTANCE / THE MIXTURE: SEALANT
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
ROYAL ADHESIVES & SEALANTS
800 E. ANAHEIM STREET
WILMINGTON. CA 90744
(310) 830-9904
INFORMATION DEPARTMENT: ENVIRONMENT PROTECTION DEPARTMENT.
EMERGENCY TELEPHONE NUMBER:
CHEMTREC:
DAY OR NIGHT WITHIN USA AND CANADA: 1-800-424-9300.
OUTSIDE USA AND CANADA: +1 703-527-3887 (COLLECT CALLS ACCEPTED)
| 2 HAZARDS(S) IDENTIFICATION | |
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CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS07: EXCLAMATION MARK
SKIN IRRIT. 2
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2B
H320: CAUSES EYE IRRITATION.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS07: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS: CAUSES SKIN AND EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
WEAR PROTECTIVE GLOVES.
WASH THOROUGHLY AFTER HANDLING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
SPECIFIC TREATMENT (SEE ON THIS LABEL).
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
CLASSIFICATION SYSTEM:
NFPA RATINGS (SCALE 0 - 4):
HEALTH 2
FIRE 1
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH FIRE 2
FIRE 1
PHYSICAL HAZARD 0
OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
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CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION: SILICONE ADHESIVE/SEALANT (BROWN AND WHITE PACKAGE)
HAZARDOUS COMPONENTS:
4253-34-3 METHYLSILANETRIYL TRIACETATE 2.5-10%
| 4 FIRST-AID MEASURES | |
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DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION:
SUPPLY FRESH AIR OR OXYGEN; CALL FOR DOCTOR.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
WIPE EXCESS FROM SKIN.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
INFORMATION FOR DOCTOR:
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
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EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY.
USE FIRE FIGHTING MEASURES THAT SUIT THE ENVIRONMENT.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
PROTECTIVE CLOTHING AND RESPIRATORY PROTECTIVE DEVICE.
ADDITIONAL INFORMATION:
DURING A FIRE PRODUCT MAY RELEASE CARBON OXIDES AND TRACES OF INCOMPLETELY
BURNED CARBON COMPOUNDS. SILICON DIOXIDE AND FORMALDEHYDE.
| 6 ACCIDENTAL RELEASE MEASURES | |
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PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ENSURE ADEQUATE VENTILATION
WEAR PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS / SURFACE OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID BINDERS,
UNIVERSAL BINDERS, SAWDUST).
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
PROTECTIVE ACTION CRITERIA FOR CHEMICALS:
PAC-1:
SILICONE 190 MG/M3
4253-34-3 METHYLSILANETRIYL TRIACETATE 5 MG/M3
PAC-2:
SILICONE 2,100 MG/M3
4253-34-3 METHYLSILANETRIYL TRIACETATE 35 MG/M3
PAC-3:
SILICONE 13,000 MG/M3
4253-34-3 METHYLSILANETRIYL TRIACETATE 250 MG/M3
| 7 HANDLING AND STORAGE | |
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HANDLING:
PRECAUTIONS FOR SAFE HANDLING: USE ONLY IN WELL VENTILATED AREAS.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
NO SPECIAL MEASURES REQUIRED.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION AWAY FROM DIRECT HEAT.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES.
STORE AWAY FROM WATER.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
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ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL SYSTEMS: NO FURTHER DATA.
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
ACETIC ACID IS FORMED UPON CONTACT WITH WATER OR HUMID AIR. PROVIDE
ADEQUATE VENTILATION TO CONTROL EXPOSURES WITHIN ESTABLISHED GUIDELINES.
OSHA PEL: TWA 10 PPM AND ACGIH TLV: TWA 10 PPM, STEL I5 PPM.
ADDITIONAL INFORMATION:
THE LISTS THAT -WERE VALID DURING THE CREATION WERE USED AS BASIS.
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT (SEE LISTINGS BELOW):
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE FOLLOWED.
BREATHING EQUIPMENT: NOT NECESSARY IF ROOM IS WELL-VENTILATED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT /THE
SUBSTANCE / THE PREPARATION.
MATERIAL OF GLOVES:
NITRILE RUBBER, NBR
CHLOROPRENE RUBBER, CR
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE
PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS.
BODY PROTECTION: PROTECTIVE WORK CLOTHING
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
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INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: PASTE
COLOR: WHITISH
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT: UNDETERMINED.
BOILING POINT: UNDETERMINED
FLASH POINT: >727 DEG. C (>250 DEG. F)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
IGNITION TEMPERATURE:
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO IGNITING: PRODUCT IS NOT SELFIGNITING.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
FLAMMABLE LIMITS:
LOWER: NOT AVAILABLE
UPPER: NOT AVAILABLE
VAPOR PRESSURE: NOT DETERMINED.
SPECIFIC GRAVITY AT 20 DEG. C (68 DEG. F): 1.05 G/CM3 (8.762 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
ORGANIC SOLVENTS: 0.0%
VOC (PER EPA 24): 82.68 GMS/L
SOLIDS CONTENT: NOT AVAILABLE.
OTHER INFORMATION: NO FARTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
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REACTIVITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NO FURTHER INFORMATION IS AVAILABLE.
CONDITIONS TO AVOID: EXPOSURE TO HIGH TEMPERATURES.
INCOMPATIBLE MATERIALS: REACTS WITH OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
ACETIC ACID ON EXPOSURE TO MOISTURE OR AIR, SILICON DIOXIDE, CARBON OXIDES.
FORMALDEHYDE WILL FORM FROM THERMAL DEGRADATION.
| 11 TOXICOLOGICAL INFORMATION | |
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INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRIMARY IRRITANT EFFECT:
ON THE SKIN: SKIN IRRITANT.
ON THE EYE: IRRITATING EFFECT.
VAPORS MAY BE IRRITATING TO THE EYES.
SENSITIZATION: NO SENSITIZING EFFECTS KNOWN.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO INTERNALLY APPROVED
CALCULATION METHODS FOR PREPARATIONS: IRRITANT
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS IS LISTED.
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
| 12 ECOLOGICAL INFORMATION | |
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TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
BEHAVIOR IN ENVIRONMENTAL SYSTEMS:
BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES: AT PRESENT THERE ARE NO ECOTOXICOLOGICAL ASSESSMENTS.
RESULTS OF PET AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
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WASTE TREATMENT METHODS:
RECOMMENDATION: MUST BE SPECIALLY TREATED ADHERING TO OFFICIAL REGULATIONS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
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UN-NUMBER:
DOT, ADN, IMDG, IATA: NOT REGULATED
UN PROPER SHIPPING NAME:
DOT, ADN, IMDG, IATA: NOT REGULATED
TRANSPORT HAZARD CLASS(ES):
DOT, ADN, IMDG, IATA:
CLASS: NOT REGULATED
PACKING GROUP:
DOT, IMDG, IATA: NOT REGULATED
ENVIRONMENTAL HAZARDS: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
DOT, ADR, IMDG, IATA - NOT REGULATED IN TRANSPORT.
NOT DANGEROUS ACCORDING TO THE ABOVE SPECIFICATIONS.
UN "MODEL REGULATION ": NOT REGULATED
| 15 REGULATORY INFORMATION | |
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SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS IS LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT):
AH COMPONENTS OF THIS PRODUCT ARE ON THE TSCA INVENTORY OR ARE EXEMPT FROM
TSCA INVENTORY REQUIREMENTS.
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
(DSL) CANADA DOMESTIC SUBSTANCE LIST:
ALL COMPONENTS OF THIS PRODUCT ARE ON THE DSL(CANADA DOMESTIC SUBSTANCE
LIST) OR ARE EXEMPT FROM DSL REQUIREMENTS.
NEW JERSEY RIGHT-TO-KNOW LIST: NONE OF THE INGREDIENTS IS LISTED.
NEW JERSEY SPECIAL HAZARDOUS SUBSTANCE LIST:
NONE OF THE INGREDIENTS IS LISTED.
PENNSYLVANIA RIGHT-TO-KNOW LIST: NONE OF THE INGREDIENTS IS LISTED.
PENNSYLVANIA SPECIAL HAZARDOUS SUBSTANCE LIST:
NONE OF THE INGREDIENTS IS LISTED.
CANCEROGENITY CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY): NONE OF THE INGREDIENTS IS LISTED.
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
NONE OF THE INGREDIENTS LISTED.
MAK (GERMAN MAXIMUM WORKPLACE CONCENTRATION):
NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
NATIONAL REGULATIONS:
WATER HAZARD CLASS:
WATER HAZARD CLASS 1 (SELF-ASSESSMENT): SLIGHTLY HAZARDOUS FOR WATER.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
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ALTHOUGH THE INFORMATION AND RECOMMENDATIONS SET FORTH IN THIS SDS ARE
PRESENTED IN GOOD FAITH AND ARE BELIEVED TO BE CORRECT AS OF THE DATE OF
THIS SDS, ROYAL ADHESIVES & SEALANTS MAKES NO REPRESENTATIONS AS TO THE
COMPLETENESS OR ACCURACY THEREOF. INFORMATION IS SUPPLIED ON THE CONDITION
THAT THE PERSONS RECEIVING AND USING IT WILL MAKE THEIR OWN DETERMINATION
AS TO THE SUITABILITY FOR THEIR PURPOSE PRIOR TO USE. IN NO EVENT WILL
ROYAL ADHESIVES & SEALANTS OR ANY AFFILIATE THEREOF BE RESPONSIBLE FOR
DAMAGES OF ANY NATURE WHATSOEVER RESULTING FROM THE USE OR RELIANCE ON THE
INFORMATION SET FORTH IN THE SDS.
DEPARTMENT ISSUING SDS: ENVIRONMENT PROTECTION DEPARTMENT.
CREATION DATE: 09/14/2017
DATE OF PREPARATION / LAST REVISION: 09/14/2017 / 1
ABBREVIATIONS AND ACRONYMS:
RID:
REGLEMENT INTERNATIONAL CONCERNANT LE TRANSPORT DES MARCHANDISES
DANGEREUSES PAR CHEMIN DEFER (REGULATIONS CONCERNING THE INTERNATIONAL
TRANSPORT OF DANGEROUS GOODS BY RAIL)
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
TLV: THRESHOLD LIMIT VALUE
PEL: PERMISSIBLE EXPOSURE LIMIT
REL: RECOMMENDED EXPOSURE LIMIT
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2B: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2B
USA