| Common Name: | DURA-INK 80 |
| Manufacturer: | LA-CO INDUSTRIES |
| SDS Revision Date: | 5/18/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3LKJ9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LA-CO INDUSTRIES, INC.
DURA-INK 80
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS, CANADA HPR
DATE OF ISSUE: 12/21/2015
REVISION DATE: 05/18/2017
VERSION: 2.0
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURE
TRADE NAME: DURA-INK 80
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: INK.
RESTRICTIONS ON USE: NO ADDITIONAL INFORMATION AVAILABLE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LA-CO INDUSTRIES, INC.
1201 PRATT BOULEVARD ELK GROVE VILLAGE, IL.
60007-5746
PHONE: (847) 956-7600
FAX: (847) 956-9885
E-MAIL: CUSTOMER_SERVICE@LACO.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
24-HOUR EMERGENCY:
CHEMTREC- U.S.: 1-800-424-9300
INTERNATIONAL: +1-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS, CATEGORY 2: H225
SKIN SENSITIZATION, CATEGORY 1: H317
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3,
NARCOSIS: H336
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 3:
H412
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. LABEL ELEMENTS
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P261: AVOID BREATHING MIST, SPRAY, VAPORS
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P272: CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE
P273: AVOID RELEASE TO THE ENVIRONMENT
P280: WEAR PROTECTIVE CLOTHING, PROTECTIVE GLOVES
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P312: CALL A DOCTOR IF YOU FEEL UNWELL
P321: SPECIFIC TREATMENT (SEE FIRST AID MEASURES ON THIS LABEL)
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE
P370+P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), DRY EXTINGUISHING POWDER, FOAM, WATER SPRAY TO
EXTINGUISH
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER %
1-METHOXY-2-PROPANOL (CAS-NO.) 107-98-2 58.18
ETHANOL (CAS-NO.) 64-17-5 9.87
ISOPROPANOL (CAS-NO.) 67-63-0 1.74
ETHYL ACETATE (CAS-NO.) 141-78-6 1.16
PROPYL ACETATE (CAS-NO.) 109-60-4 0.58
BIS(1,2,2,6,6-PENTAMETHYL-4- (CAS-NO.) 41556-26-7 0.21 - 0.25
PIPERIDYL) SEBACATE
POLYETHYLENE GLYCOL DI(3-(3- (CAS-NO.) 104810-47-1 0.09 - 0.18
(2H-BENZOTRIAZOL-2-YL)-5-
TERT-BUTYL-4-HYDROXYPHENYL)-
1-OXOPROPYL) ETHER
POLY(OXY-1,2-ETHANEDIYL), A- (CAS-NO.) 104810-48-2 0.09 - 0.18
(3-(3-(2H-BENZOTRIAZOL-2-
YL)-5-(1,1-DIMETHYLETHYL)-
4-HYDROXYPHENYL)-1-
OXOPROPYL)-W-HYDROXY-
NAME GHS-US CLASSIFICATION
1-METHOXY-2-PROPANOL FLAM. LIQ. 3, H226
STOT SE 3, H336
ETHANOL FLAM. LIQ. 2, H225
ISOPROPANOL FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
ETHYL ACETATE FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
PROPYL ACETATE FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
BIS(1,2,2,6,6-PENTAMETHYL-4- FLAM. LIQ. 4, H227
PIPERIDYL) SEBACATE SKIN SENS. 1, H317
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
POLYETHYLENE GLYCOL DI(3-(3- SKIN SENS. 1, H317
(2H-BENZOTRIAZOL-2-YL)-5- AQUATIC CHRONIC 2, H411
TERT-BUTYL-4-HYDROXYPHENYL)-
1-OXOPROPYL) ETHER
POLY(OXY-1,2-ETHANEDIYL), A- SKIN SENS. 1, H317
(3-(3-(2H-BENZOTRIAZOL-2- AQUATIC CHRONIC 2, H411
YL)-5-(1,1-DIMETHYLETHYL)-
4-HYDROXYPHENYL)-1-
OXOPROPYL)-W-HYDROXY-
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING. WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
FIRST-AID MEASURES AFTER INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. CALL
A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
DIRECT CONTACT WITH THE EYES IS LIKELY TO BE IRRITATING.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: CARBON DIOXIDE. DRY POWDER. WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO
ENTER DRAINS OR WATER COURSES.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION. WEAR A SELF CONTAINED BREATHING APPARATUS. WEAR
FIRE/FLAME RESISTANT/RETARDANT CLOTHING.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
AVOID ALL EYE AND SKIN CONTACT AND DO NOT BREATHE VAPOR AND MIST.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
WEAR SUITABLE GLOVES. IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY
PROTECTION.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
WEAR SUITABLE GLOVES. WHERE EXCESSIVE VAPOR, MIST, OR DUST MAY RESULT, USE
APPROVED RESPIRATORY PROTECTION EQUIPMENT.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. DO NOT DISCHARGE INTO DRAINS OR THE
ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP FOR CONTAINMENT:
ABSORB AND/OR CONTAIN SPILL WITH INERT MATERIAL, THEN PLACE IN SUITABLE
CONTAINER.
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. TAKE UP IN NON-COMBUSTIBLE ABSORBENT MATERIAL AND SHOVE
INTO CONTAINER FOR DISPOSAL. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE WAY, AND AS PER LOCAL LEGISLATION.
6.4. REFERENCE TO OTHER SECTIONS:
SECTION 13: DISPOSAL INFORMATION.
SECTION 7: SAFE HANDLING.
SECTION 8: PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
HYGIENE MEASURES:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP IN FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A DRY,
COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: HEAT SOURCES. SOURCES OF IGNITION.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
DURA-INK 80:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
ETHYL ACETATE (141-78-6):
ACGIH:
ACGIH TWA (MG/M3): 1440 MG/M3
ACGIH:
ACGIH TWA (PPM): 400 PPM
ACGIH:
REMARK (ACGIH): URT & EYE IRR
ETHYL ACETATE (141-78-6):
OSHA:
OSHA PEL (TWA) (MG/M3): 1400 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 1440 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 400 PPM
ISOPROPANOL (67-63-0):
ACGIH:
ACGIH TWA (MG/M3): 490 MG/M3
ACGIH:
ACGIH TWA (PPM): 200 PPM
ACGIH:
ACGIH STEL (MG/M3): 960 MG/M3
ACGIH:
ACGIH STEL (PPM): 400 PPM
ACGIH:
REMARK (ACGIH): EYE & URT IRR; CNS IMPAIR
OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
CANADA (QUEBEC):
VECD (MG/M3): 1230 MG/M3
CANADA (QUEBEC):
VECD (PPM): 500 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 983 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 400 PPM
PROPYL ACETATE (109-60-4):
ACGIH:
ACGIH TWA (MG/M3): 835 MG/M3
ACGIH:
ACGIH TWA (PPM): 200 PPM
ACGIH:
ACGIH STEL (MG/M3): 1040 MG/M3
ACGIH:
ACGIH STEL (PPM): 250 PPM
ACGIH:
REMARK (ACGIH): EYE & URT IRR; CNS IMPAIR
OSHA:
OSHA PEL (TWA) (MG/M3): 840 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
CANADA (QUEBEC):
VECD (MG/M3): 1040 MG/M3
CANADA (QUEBEC):
VECD (PPM): 250 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 835 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 200 PPM
1-METHOXY-2-PROPANOL (107-98-2):
ACGIH:
ACGIH TWA (MG/M3): 369 MG/M3
ACGIH:
ACGIH TWA (PPM): 50 PPM
ACGIH:
ACGIH STEL (MG/M3): 553 MG/M3
ACGIH:
ACGIH STEL (PPM): 100 PPM
ACGIH:
REMARK (ACGIH):
EYE IRR; CNS IMPAIR; A4 (NOT CLASSIFIABLE AS A HUMAN CARCINOGEN: AGENTS
WHICH CAUSE CONCERN THAT THEY COULD BE CARCINOGENIC FOR HUMANS BUT WHICH
CANNOT BE ASSESSED CONCLUSIVELY BECAUSE OF A LACK OF DATA. IN VITRO OR
ANIMAL STUDIES DO NOT PROVIDE INDICATIONS OF CARCINOGENICITY WHICH ARE
SUFFICIENT TO CLASSIFY THE AGENT INTO ONE OF THE OTHER CATEGORIES)
OSHA: NOT APPLICABLE
CANADA (QUEBEC):
VECD (MG/M3): 553 MG/M3
CANADA (QUEBEC):
VECD (PPM): 150 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 369 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 100 PPM
BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL) SEBACATE (41556-26-7):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
POLYETHYLENE GLYCOL DI(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-TERT-BUTYL-4-
HYDROXYPHENYL)-1-OXOPROPYL) ETHER (104810-47-1):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
POLY(OXY-1,2-ETHANEDIYL), A-(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-(1,1-
DIMETHYLETHYL)-4-HYDROXYPHENYL)-1-OXOPROPYL)-W-HYDROXY-(104810-48-2):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
ETHANOL (64-17-5):
ACGIH:
ACGIH TWA (MG/M3): 1884 MG/M3
ACGIH:
ACGIH TWA (PPM): 1000 PPM
ACGIH:
ACGIH STEL (PPM): 1000 PPM
ACGIH:
REMARK (ACGIH): URT IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 1900 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 1000 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 1880 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 1000 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
AVOID CREATING MIST OR SPRAY. AVOID SPLASHING. EITHER LOCAL EXHAUST OR
GENERAL ROOM VENTILATION IS USUALLY REQUIRED.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION:
IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE SKIN CONTACT. WEAR
SUITABLE GLOVES. NITRILE RUBBER GLOVES.
EYE PROTECTION:
IN CASE OF SPLASHING OR AEROSOL PRODUCTION: PROTECTIVE GOGGLES.
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION. USE AN
APPROVED RESPIRATOR EQUIPPED WITH OIL/MIST CARTRIDGES.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: OPAQUE LIQUID.
COLOUR: BLACK
ODOUR: SOLVENT
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 79 DEG. C (ESTIMATED FROM ETHANOL CONTENT)
FLASH POINT: 16 DEG. C (ESTIMATED FROM ETHANOL CONTENT)
RELATIVE EVAPORATION RATE (BUTYLACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: 1.05 G/ML
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 72% / 6.3 LBS/GAL / 756 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR
MIXTURE. FLAMMABLE LIQUID AND VAPOR.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
AVOID EXCESSIVE HEAT OR COLD. DIRECT SUNLIGHT. HEAT. KEEP AWAY FROM SOURCES
OF IGNITION. OPEN FLAME. OVERHEATING. SPARKS.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
MAY RELEASE FLAMMABLE GASES. CARBON OXIDES (CO, CO2).
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
ETHYL ACETATE (141-78-6):
LD50 ORAL RAT: 5620 MG/KG
LD50 DERMAL RABBIT: >20000 MG/KG
LC50 INHALATION RAT (MG/L): >18 MG/L/4H
ATE US (ORAL): 5620 MG/KG BODYWEIGHT
ISOPROPANOL (67-63-0):
LD50 ORAL RAT: 5840 MG/KG
LD50 DERMAL RABBIT: 16.4 ML/KG
LC50 INHALATION RAT (PPM): >10000 PPM/4H
ATE US (ORAL): 5840 MG/KG BODYWEIGHT
PROPYL ACETATE (109-60-4):
LD50 ORAL RAT: 8700 MG/KG
LD50 DERMAL RABBIT: >17800 MG/KG
LC50 INHALATION RAT (MG/L): 32 MG/L/4H
ATE US (ORAL): 8700 MG/KG BODYWEIGHT
ATE US (VAPORS): 32 MG/L/4H
ATE US (DUST, MIST): 32 MG/L/4H
1-METHOXY-2-PROPANOL (107-98-2):
LD50 ORAL RAT: 4016 MG/KG BODYWEIGHT
LD50 DERMAL RAT: >2000 MG/KG BODYWEIGHT
LC50 INHALATION RAT (PPM): >7000 PPM 6 HR
ATE US (ORAL): 4016 MG/KG BODYWEIGHT
BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL) SEBACATE (41556-26-7):
LD50 ORAL RAT: 2369 (2369 - 3920) MG/KG
ATE US (ORAL): 2369 MG/KG BODYWEIGHT
POLYETHYLENE GLYCOL DI(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-TERT-BUTYL-4-
HYDROXYPHENYL)-1-OXOPROPYL) ETHER (104810-47-1)
LD50 ORAL RAT: >5000 MG/KG BODYWEIGHT
LD50 DERMAL RAT: >2000 MG/KG BODYWEIGHT
POLY(OXY-1,2-ETHANEDIYL), A-(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-(1,1-
DIMETHYLETHYL)-4-HYDROXYPHENYL)-1-OXOPROPYL)-W-HYDROXY-(104810-48-2):
LD50 ORAL RAT: >5000 MG/KG BODYWEIGHT
LD50 DERMAL RAT: >2000 MG/KG BODYWEIGHT
ETHANOL (64-17-5):
LD50 ORAL RAT: 10470 MG/KG
LD50 DERMAL RABBIT: >20000 MG/KG
LC50 INHALATION RAT (MG/L): 133.8 MG/L/4H
ATE US (ORAL): 10470 MG/KG BODYWEIGHT
ATE US (VAPORS): 133.8 MG/L/4H
ATE US (DUST, MIST): 133.8 MG/L/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
ISOPROPANOL (67-63-0):
IARC GROUP 3 - NOT CLASSIFIABLE
ETHANOL (64-17-5):
IARC GROUP 1 - CARCINOGENIC TO HUMANS
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/EFFECTS AFTER INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
DIRECT CONTACT WITH THE EYES IS LIKELY TO BE IRRITATING.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: MAY CAUSE LONG LASTING HARMFUL EFFECTS TO AQUATIC LIFE.
ETHYL ACETATE (141-78-6):
LC50 FISH 1: 220 MG/L
EC50 DAPHNIA 1: 1200 MG/L
NOEC CHRONIC FISH: <9.35 MG/L
ISOPROPANOL (67-63-0):
LC50 FISH 1: 10000 MG/L
PROPYL ACETATE (109-60-4):
LC50 FISH 1: 60 MG/L 96 H
EC50 DAPHNIA 1: 91.5 MG/L 48 H
1-METHOXY-2-PROPANOL (107-98-2):
LC50 FISH 1: 20800 MG/L
EC50 DAPHNIA 1: 23300 MG/L
ERC50 (ALGAE): >1000 MG/L
BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL) SEBACATE (41556-26-7):
LC50 FISH 1: 0.97 MG/L 96 H
EC50 DAPHNIA 1: 20 MG/L 24 H
POLYETHYLENE GLYCOL DI(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-TERT-BUTYL-4-
HYDROXYPHENYL)-1-OXOPROPYL) ETHER (104810-47-1):
LC50 FISH 1: 2.8 MG/L ONCORHYNCHUS MYKISS
EC50 DAPHNIA 1: 4 MG/L
ERC50 (ALGAE): >9 MG/L
NOEC (CHRONIC): 1 MG/L
POLY(OXY-1,2-ETHANEDIYL), A-(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-(1,1-
DIMETHYLETHYL)-4-HYDROXYPHENYL)-1-OXOPROPYL)-W-HYDROXY- (104810-48-2):
LC50 FISH 1: 2.8 MG/L ONCORHYNCHUS MYKISS
EC50 DAPHNIA 1: 4 MG/L
ERC50 (ALGAE): >9 MG/L
NOEC (CHRONIC): 1 MG/L
ETHANOL (64-17-5):
LC50 FISH 1: 14200 MG/L
EC50 DAPHNIA 1: 5012 MG/L
12.2. PERSISTENCE AND DEGRADABILITY:
ETHYL ACETATE (141-78-6):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
ISOPROPANOL (67-63-0):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
PROPYL ACETATE (109-60-4):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIODEGRADATION: 62% 5 D
1-METHOXY-2-PROPANOL (107-98-2):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIODEGRADATION: 96% 28 D
BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL) SEBACATE (41556-26-7):
BIODEGRADATION: 38% 28 D
POLYETHYLENE GLYCOL DI(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-TERT-BUTYL-4-
HYDROXYPHENYL)-1-OXOPROPYL) ETHER (104810-47-1):
PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 24%
POLY(OXY-1,2-ETHANEDIYL), A-(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-(1,1-
DIMETHYLETHYL)-4-HYDROXYPHENYL)-1-OXOPROPYL)-W-HYDROXY- (104810-48-2):
PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 24%
ETHANOL (64-17-5):
BIODEGRADATION: >96% 28 D
12.3. BIOACCUMULATIVE POTENTIAL:
ETHYL ACETATE (141-78-6):
BIOACCUMULATIVE POTENTIAL: NOT EXPECTED TO BIOACCUMULATE.
ISOPROPANOL (67-63-0):
BIOACCUMULATIVE POTENTIAL: NOT EXPECTED TO BIOACCUMULATE.
PROPYL ACETATE (109-60-4):
LOG POW: 1.23
1-METHOXY-2-PROPANOL (107-98-2):
BIOACCUMULATIVE POTENTIAL: NOT EXPECTED TO BIOACCUMULATE.
BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDYL) SEBACATE (41556-26-7):
LOG POW: 0.37
POLYETHYLENE GLYCOL DI(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-TERT-BUTYL-4-
HYDROXYPHENYL)-1-OXOPROPYL) ETHER (104810-47-1):
BIOCONCENTRATION FACTOR (BCF REACH): 34
POLY(OXY-1,2-ETHANEDIYL), A-(3-(3-(2H-BENZOTRIAZOL-2-YL)-5-(1,1-
DIMETHYLETHYL)-4-HYDROXYPHENYL)-1-OXOPROPYL)-W-HYDROXY- (104810-48-2):
BIOCONCENTRATION FACTOR (BCF REACH): 34
ETHANOL (64-17-5):
BIOACCUMULATIVE POTENTIAL: NOT EXPECTED TO BIOACCUMULATE.
12.4. MOBILITY IN SOIL:
DURA-INK 80:
ECOLOGY - SOIL: NOT ESTABLISHED.
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH US-DOT 49-CFR AND THE HMR / TDG / ADR / IMDG / ICAO /
IATA:
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1210 PRINTING INK, FLAMMABLE, 3, II
UN-NO.(DOT): UN1210
PROPER SHIPPING NAME (DOT): PRINTING INK, FLAMMABLE ()
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
TRANSPORTATION OF DANGEROUS GOODS:
TRANSPORT DOCUMENT DESCRIPTION: UN1210 PRINTING INK, 3, II
UN-NO. (TDG): UN1210
PROPER SHIPPING NAME (TRANSPORTATION OF DANGEROUS GOODS): PRINTING INK
TDG PRIMARY HAZARD CLASSES: 3 - CLASS 3 - FLAMMABLE LIQUIDS
PACKING GROUP: II - MEDIUM DANGER
TRANSPORT BY SEA:
UN-NO. (IMDG): 1210
PROPER SHIPPING NAME (IMDG): PRINTING INK
CLASS (IMDG): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IMDG): II - SUBSTANCES PRESENTING MEDIUM DANGER
LIMITED QUANTITIES (IMDG): 5 L
AIR TRANSPORT:
UN-NO. (IATA): 1210
PROPER SHIPPING NAME (IATA): PRINTING INK
CLASS (IATA): 3 - FLAMMABLE LIQUIDS
PACKING GROUP (IATA): II - MEDIUM DANGER
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.:
ISOPROPANOL CAS-NO. 67-63-0 1.741335 - 1.741335%
ETHYL ACETATE (141-78-6):
CERCLA RQ 5000 LB
ISOPROPANOL (67-63-0):
SARA SECTION 311/312 HAZARD CLASSES FIRE HAZARD
15.2. INTERNATIONAL REGULATIONS:
NATIONAL REGULATIONS:
DURA-INK 80:
ALL INGREDIENTS ARE LISTED IN THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
ALL INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST (DSL)
OR NON-DOMESTIC SUBSTANCES LIST (NDSL).
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
ETHYL ACETATE (141-78-6):
U.S. - DELAWARE:
POLLUTANT DISCHARGE REQUIREMENTS - REPORTABLE QUANTITIES
U.S. - IDAHO:
NON-CARCINOGENIC TOXIC AIR POLLUTANTS - ACCEPTABLE AMBIENT CONCENTRATIONS
U.S. - NEW JERSEY: RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK:
REPORTING OF RELEASES PART 597 - LIST OF HAZARDOUS SUBSTANCES
U.S. - PENNSYLVANIA: RTK (RIGHT TO KNOW) LIST
ISOPROPANOL (67-63-0):
U.S. - IDAHO:
NON-CARCINOGENIC TOXIC AIR POLLUTANTS - ACCEPTABLE AMBIENT CONCENTRATIONS
U.S. - NEW JERSEY: RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK:
REPORTING OF RELEASES PART 597 - LIST OF HAZARDOUS SUBSTANCES
PROPYL ACETATE (109-60-4):
U.S. - IDAHO:
NON-CARCINOGENIC TOXIC AIR POLLUTANTS - ACCEPTABLE AMBIENT CONCENTRATIONS
U.S. - NEW JERSEY: RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK:
REPORTING OF RELEASES PART 597 - LIST OF HAZARDOUS SUBSTANCES
1-METHOXY-2-PROPANOL (107-98-2):
U.S. - IDAHO: OCCUPATIONAL EXPOSURE LIMITS - CEILINGS
U.S. - IDAHO: NON-CARCINOGENIC TOXIC AIR POLLUTANTS - EMISSION LEVELS (ELS)
U.S. - IDAHO:
NON-CARCINOGENIC TOXIC AIR POLLUTANTS - ACCEPTABLE AMBIENT CONCENTRATIONS
U.S. - MINNESOTA: HAZARDOUS SUBSTANCE LIST
U.S. - NEW JERSEY: RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK: RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - WASHINGTON: PERMISSIBLE EXPOSURE LIMITS - STELS
U.S. - WASHINGTON: PERMISSIBLE EXPOSURE LIMITS - TWAS
ETHANOL (64-17-5):
U.S. - IDAHO:
NON-CARCINOGENIC TOXIC AIR POLLUTANTS - ACCEPTABLE AMBIENT CONCENTRATIONS
U.S. - NEW JERSEY: RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK:
REPORTING OF RELEASES PART 597 - LIST OF HAZARDOUS SUBSTANCES
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 05/18/2017
DATA SOURCES:
ESIS (EUROPEAN CHEMINCAL SUBSTANCES INFORMATION SYSTEM; ACCESSED AT:
HTTP://ESIS.JRC.EC.EUROPA.EU/INDEX.PHP?PGM=CLA.
EUROPEAN CHEMICALS AGENCY (ECHA) REGISTERED SUBSTANCES LIST. ACCESSED AT
HTTP://ECHA.EUROPA.EU/.
KRISTER FORSBERG AND S.Z. MANSDORF, "QUICK SELECTION GUIDE TO CHEMICAL
PROTECTIVE CLOTHING", FIFTH EDITION.
NATIONAL FIRE PROTECTION ASSOCIATION; FIRE PROTECTION GUIDE TO HAZARDOUS
MATERIALS; 10TH EDITION.
OSHA 29CFR 1910.1200 HAZARD COMMUNICATION STANDARD.
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006.
TSCA CHEMICAL SUBSTANCE INVENTORY. ACCESSED AT
HTTP://WWW.EPA.GOV/OPPT/EXISTINGCHEMICALS/PUBS/TSCAINVENTORY/HOWTO.HTML.
OTHER INFORMATION: NONE.
FULL TEXT OF H-STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H226: FLAMMABLE LIQUID AND VAPOR
H227: COMBUSTIBLE LIQUID
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H319: CAUSES SERIOUS EYE IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H400: VERY TOXIC TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
ABBREVIATIONS AND ACRONYMS:
ACGIH: (AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS)
ATE: ACUTE TOXICITY ESTIMATE
CAS: (CHEMICAL ABSTRACTS SERVICE) NUMBER
CLP: CLASSIFICATION, LABELING, PACKAGING.
DNEL: DERIVED NO EFFECT LEVEL
EC50:
ENVIRONMENTAL CONCENTRATION ASSOCIATED WITH A RESPONSE BY 50% OF THE TEST
POPULATION.
GHS:
GLOBALLY HARMONIZED SYSTEM (OF CLASSIFICATION AND LABELING OF CHEMICALS).
LD50: LETHAL DOSE FOR 50% OF THE TEST POPULATION
NOEC: NO OBSERVABLE EFFECT CONCENTRATION
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION
PBT: PERSISTENT, BIOACCUMULATIVE, TOXIC
PNEC: PREDICTED NO EFFECT LEVEL
STEL: SHORT TERM EXPOSURE LIMITS
TSCA: TOXIC SUBSTANCES CONTROL ACT
TWA: TIME WEIGHTED AVERAGE
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS (INCLUDING FINELY DIVIDED
SUSPENDED SOLIDS) THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT TEMPERATURE CONDITIONS.
NFPA REACTIVITY 1 - MATERIALS THAT IN THEMSELVES ARE NORMALLY STABLE BUT
CAN BECOME UNSTABLE AT ELEVATED TEMPERATURES AND
PRESSURES.
INDICATION OF CHANGES: COMPOSITION/INFORMATION ON INGREDIENTS.
SDS PREPARED BY:
THE REDSTONE GROUP, LLC
6077 FRANTZ RD.
SUITE 206
DUBLIN, OH 43016
USA
T: 614-923-7472
WWW.REDSTONEGRP.COM
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT
05/18/2017
EN (ENGLISH)