| Common Name: | HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL) |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/28/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3MA16, 400G24, 51ME83 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL)
04/28/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 16-4935-9
VERSION NUMBER: 11.00
ISSUE DATE: 04/28/17
SUPERCEDES DATE: 09/23/16
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) HI-STRENGTH SPRAY ADHESIVE 90 (AEROSOL)
PRODUCT IDENTIFICATION NUMBERS:
62-4942-4730-7, 62-4942-4920-4, 62-4942-4921-2, 62-4942-4922-0,
62-4942-4925-3, 62-4942-4927-9, 62-4942-4930-3, 624942-4935-2,
62-4942-4950-1, 62-4942-4955-0, 62-4942-4970-9, 62-4942-4975-8,
CS-0406-7111-0
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
AEROSOL ADHESIVE. RECOMMENDED FOR INDUSTRIAL AND PROFESSIONAL USE.,
HI-STRENGTH AEROSOL ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE AEROSOL: CATEGORY 1.
GAS UNDER PRESSURE: LIQUEFIED GAS.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SIMPLE ASPHYXIANT.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
SUPPLEMENTAL INFORMATION:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING CONTENTS CAN
BE HARMFUL OR FATAL.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
DIMETHYL ETHER 115-10-6 35 - 45 TRADE SECRET *
METHYL ACETATE 79-20-9 25 - 35 TRADE SECRET *
NONVOLATILE COMPONENTS TRADE SECRET* 10 - 20 TRADE SECRET *
(N.J.T.S. REG. NO. 0449960-6448P)
CYCLOHEXANE 110-82-7 7 - 13 TRADE SECRET *
1,1-DIFLUOROETHANE 75-37-6 1 - 5 TRADE SECRET *
PENTANE 109-66-0 1 - 5 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND
EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
IRRITANT VAPORS OR GASES DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH
AIR.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
IF POSSIBLE, SEAL LEAKING CONTAINER. PLACE LEAKING CONTAINERS IN A
WELL-VENTILATED AREA, PREFERABLY AN OPERATING EXHAUST HOOD, OR IF
NECESSARY OUTDOORS ON AN IMPERMEABLE SURFACE UNTIL APPROPRIATE PACKAGING
FOR THE LEAKING CONTAINER OR ITS CONTENTS IS AVAILABLE. CLOSE CYLINDER.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING
TOOLS. PLACE IN A METAL CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT
SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION
SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID CONTACT
WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. STORE
AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
PENTANE 109-66-0 OSHA TWA:
2950 MG/M3
(1000 PPM)
PENTANE 109-66-0 ACGIH TWA: 1000 PPM
CYCLOHEXANE 110-82-7 OSHA TWA:
1050 MG/M3
(300 PPM)
CYCLOHEXANE 110-82-7 ACGIH TWA: 100 PPM
DIMETHYL ETHER 115-10-6 AIHA TWA:
1880 MG/M3
(1000 PPM)
1,1-DIFLUOROETHANE 75-37-6 AIHA TWA:
2700 MG/M3
(1000 PPM)
METHYL ACETATE 79-20-9 ACGIH TWA: 200 PPM
STEL: 250 PPM
METHYL ACETATE 79-20-9 OSHA TWA:
610 MG/M3
(200 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
DO NOT REMAIN IN AREA WHERE AVAILABLE OXYGEN MAY BE REDUCED. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IF VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND
DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE
CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER
FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
ORGANIC VAPOR RESPIRATORS MAY HAVE SHORT SERVICE LIFE.
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: GAS
SPECIFIC PHYSICAL FORM: AEROSOL
ODOR, COLOR, GRADE: CLEAR, SWEET FRUITY ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: -42.00 DEG. F [TEST METHOD.TAGLIABUE CLOSED CUP]
EVAPORATION RATE: 1.9 [RE/STD:ETHER=1]
FLAMMABILITY (SOLID, GAS):
FLAMMABLE AEROSOL: CATEGORY 1.
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR DENSITY: 2.97 [RE/STD: AIR=1]
DENSITY: 0.726 G/ML
SPECIFIC GRAVITY: 0.726 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
HAZARDOUS AIR POLLUTANTS: <=0% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
<=55% [TEST METHOD: CALCULATED PER CARB TITLE 2]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
SIMPLE ASPHYXIATION:
SIGNS/SYMPTOMS MAY INCLUDE INCREASED HEART RATE, RAPID RESPIRATIONS,
DROWSINESS, HEADACHE, INCOORDINATION, ALTERED JUDGEMENT, NAUSEA, VOMITING,
LETHARGY, SEIZURES, COMA, AND MAY BE FATAL.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED
OR HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
SINGLE EXPOSURE, ABOVE RECOMMENDED GUIDELINES, MAY CAUSE:
CARDIAC SENSITIZATION:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS,
CHEST PAIN, AND MAY BE FATAL.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR CALCULATED ATE:
(4 HR) >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
DIMETHYL ETHER INHALATION- RAT LC50: 164,000 PPM
GAS
(4 HOURS)
METHYL ACETATE DERMAL RAT LD50: >2,000 MG/KG
METHYL ACETATE INHALATION- RAT LC50: >49 MG/L
VAPOR
(4 HOURS)
METHYL ACETATE INGESTION RAT LD50: >5,000 MG/KG
CYCLOHEXANE DERMAL RAT LD50: >2,000 MG/KG
CYCLOHEXANE INHALATION- RAT LC50: >32.9 MG/L
VAPOR
(4 HOURS)
CYCLOHEXANE INGESTION RAT LD50: 6,200 MG/KG
NONVOLATILE COMPONENTS DERMAL LD50 ESTIMATED
(N.J.T.S. REG. NO. TO BE >5,000 MG/KG
0449960-6448P)
NONVOLATILE COMPONENTS INGESTION RAT LD50: >34,000 MG/KG
(N.J.T.S. REG. NO.
0449960-6448P)
PENTANE DERMAL RABBIT LD50: 3,000 MG/KG
PENTANE INHALATION- RAT LC50: >18 MG/L
VAPOR
(4 HOURS)
PENTANE INGESTION RAT LD50: >2,000 MG/KG
1,1-DIFLUOROETHANE INHALATION- RAT LC50: >437,000 PPM
GAS
(4 HOURS)
1,1-DIFLUOROETHANE INGESTION RAT LD50: >1,500 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT NO SIGNIFICANT IRRITATION
CYCLOHEXANE RABBIT MILD IRRITANT
PENTANE RABBIT MINIMAL IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT MODERATE IRRITANT
CYCLOHEXANE RABBIT MILD IRRITANT
PENTANE RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
METHYL ACETATE HUMAN NOT CLASSIFIED
PENTANE GUINEA PIG NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
DIMETHYL ETHER IN VITRO NOT MUTAGENIC
DIMETHYL ETHER IN VIVO NOT MUTAGENIC
METHYL ACETATE IN VITRO NOT MUTAGENIC
METHYL ACETATE IN VIVO NOT MUTAGENIC
CYCLOHEXANE IN VITRO NOT MUTAGENIC
CYCLOHEXANE IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
PENTANE IN VIVO NOT MUTAGENIC
PENTANE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
1,1-DIFLUOROETHANE IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
1,1-DIFLUOROETHANE IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIMETHYL ETHER INHALATION RAT NOT CARCINOGENIC
1,1-DIFLUOROETHANE INHALATION RAT SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
DIMETHYL ETHER INHALATION NOT CLASSIFIED FOR DEVELOPMENT
CYCLOHEXANE INHALATION NOT CLASSIFIED FOR FEMALE REPRODUCTION
CYCLOHEXANE INHALATION NOT CLASSIFIED FOR MALE REPRODUCTION
CYCLOHEXANE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
PENTANE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
PENTANE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
1,1-DIFLUOROETHANE INHALATION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL ETHER RAT NOAEL: DURING ORGANOGENESIS
40,000 PPM
CYCLOHEXANE RAT NOAEL: 24 MG/L 2 GENERATION
CYCLOHEXANE RAT NOAEL: 24 MG/L 2 GENERATION
CYCLOHEXANE RAT NOAEL: 6.9 MG/L 2 GENERATION
PENTANE RAT NOAEL: DURING ORGANOGENESIS
1,000 MG/KG/DAY
PENTANE RAT NOAEL: 30 MG/L DURING ORGANOGENESIS
1,1-DIFLUOROETHANE RAT NOAEL: DURING ORGANOGENESIS
50,000 PPM
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIMETHYL ETHER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
DIMETHYL ETHER INHALATION CARDIAC SOME POSITIVE DATA
SENSITIZATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ACETATE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
METHYL ACETATE INHALATION BLINDNESS NOT CLASSIFIED
METHYL ACETATE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
CYCLOHEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
CYCLOHEXANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CYCLOHEXANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
PENTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
PENTANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PENTANE INHALATION CARDIAC NOT CLASSIFIED
SENSITIZATION
PENTANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
1,1-DIFLUOROETHANE INHALATION CARDIAC CAUSES DAMAGE TO
SENSITIZATION ORGANS
1,1-DIFLUOROETHANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
1,1-DIFLUOROETHANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL ETHER RAT LOAEL: 30 MINUTES
10,000 PPM
DIMETHYL ETHER DOG NOAEL: 5 MINUTES
100,000 PPM
METHYL ACETATE HUMAN AND NOAEL:
ANIMAL NOT AVAILABLE
METHYL ACETATE HUMAN AND NOAEL:
ANIMAL NOT AVAILABLE
METHYL ACETATE NOAEL:
NOT AVAILABLE
METHYL ACETATE NOAEL:
NOT AVAILABLE
CYCLOHEXANE HUMAN AND NOAEL
ANIMAL NOT AVAILABLE
CYCLOHEXANE HUMAN AND NOAEL:
ANIMAL NOT AVAILABLE
CYCLOHEXANE PROFESSIONAL NOAEL:
JUDGEMENT NOT AVAILABLE
PENTANE MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL NOT AVAILABLE
SPECIES
PENTANE NOT NOAEL: NOT AVAILABLE
AVAILABLE NOT AVAILABLE
PENTANE DOG NOAEL: NOT AVAILABLE
NOT AVAILABLE
PENTANE PROFESSIONAL NOAEL: NOT AVAILABLE
JUDGEMENT NOT AVAILABLE
1,1-DIFLUOROETHANE HUMAN AND NOAEL: POISONING
ANIMAL NOT AVAILABLE AND/OR ABUSE
1,1-DIFLUOROETHANE HUMAN AND NOAE:
ANIMAL 100,000 PPM
1,1-DIFLUOROETHANE NOT NOAEL: NOT AVAILABLE
AVAILABLE NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIMETHYL ETHER INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
DIMETHYL ETHER INHALATION LIVER NOT CLASSIFIED
METHYL ACETATE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM
LIVER
IMMUNE SYSTEM
KIDNEY AND/OR
BLADDER
CYCLOHEXANE INHALATION LIVER NOT CLASSIFIED
CYCLOHEXANE INHALATION AUDITORY SYSTEM NOT CLASSIFIED
CYCLOHEXANE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
CYCLOHEXANE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
CYCLOHEXANE INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
PENTANE INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
PENTANE INHALATION HEART NOT CLASSIFIED
SKIN
ENDOCRINE SYSTEM
BONE, TEETH,
NAILS, AND/OR HAIR
HEMATOPOIETIC
SYSTEM
LIVER
IMMUNE SYSTEM
MUSCLES
NERVOUS SYSTEM
EYES
KIDNEY AND/OR
BLADDER
RESPIRATORY SYSTEM
PENTANE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
1,1-DIFLUOROETHANE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
KIDNEY AND/OR
BLADDER
RESPIRATORY SYSTEM
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 20,000 PPM 30 WEEKS
METHYL ACETATE RAT NOAEL: 1.1 MG/L 28 DAYS
METHYL ACETATE RAT NOAEL: 6.1 MG/L 28 DAYS
CYCLOHEXANE RAT NOAEL: 24 MG/L 90 DAYS
CYCLOHEXANE RAT NOAEL: 1.7 MG/L 90 DAYS
CYCLOHEXANE RABBIT NOAEL: 2.7 MG/L 10 WEEKS
CYCLOHEXANE MOUSE NOAEL: 24 MG/L 14 WEEKS
CYCLOHEXANE RAT NOAEL: 8.6 MG/L 30 WEEKS
PENTANE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
PENTANE RAT NOAEL: 20 MG/L 13 WEEKS
PENTANE RAT NOAEL: 28 DAYS
2,000 MG/KG/DAY
1,1-DIFLUOROETHANE RAT NOAEL: 25,000 PPM 2 YEARS
ASPIRATION HAZARD:
NAME VALUE
CYCLOHEXANE ASPIRATION HAZARD
PENTANE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF
THIS SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL
AND/OR ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS
A DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. FACILITY MUST BE CAPABLE OF HANDLING AEROSOL CANS. THE FACILITY
SHOULD BE EQUIPPED TO HANDLE GASEOUS WASTE. EMPTY DRUMS/BARRELS/CONTAINERS
USED FOR TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D001 (IGNITABLE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
EPCRA 311/312 HAZARD CLASSIFICATIONS (EFFECTIVE JANUARY 1, 2018):
PHYSICAL HAZARDS:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
GAS UNDER PRESSURE
HEALTH HAZARDS:
SERIOUS EYE DAMAGE OR EYE IRRITATION
SIMPLE ASPHYXIANT
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
CYCLOHEXANE 110-82-7 TRADE SECRET 7 - 13
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
SPECIAL HAZARDS NONE
AEROSOL STORAGE CODE 3
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 16-4935-9
VERSION NUMBER: 11.00
ISSUE DATE: 04/28/17
SUPERCEDES DATE: 09/23/16
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THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
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REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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