| Common Name: | LOCTITE EA 9011 KNOWN AS FIXMASTER ANC BLT GRT HP 11OZ A, 1108394_210476, LOCTIT |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 10/27/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 3NVK5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 005.0
ISSUE DATE: 10/27/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE EA 9011 KNOWN AS FIXMASTER ANC BLT GRT HP 11OZ A
PRODUCT TYPE: EPOXY
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1108394
ITEM NUMBER: 1108394_210476
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. CONTAMINATED
WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION IF YOU
FEEL UNWELL.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
BISPHENOL A - EPICHLOROHYDRIN POLYMER 25085-99-8 50 - 60
1,3-PROPANEDIOL, 2-(HYDROXYMETHYL)- 68460-21-9 10 - 20
2-METHYL-, POLYMER WITH
2-(CHLOROMETHYL)OXIRANE
QUARTZ (SiO2) 14808-60-7 10 - 20
ETHYLENE GLYCOL 107-21-1 1 - 5
TITANIUM DIOXIDE 13463-67-7 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING,
SUCH AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. CLOSED CONTAINERS
MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING VAPORS. TOXIC FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL
PROTECTION" PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL
(E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE
UP SPILLED MATERIAL AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP CONTAINER TIGHTLY
CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE
MATERIALS. STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF
IGNITION. KEEP FROM FREEZING.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
BISPHENOL A - NONE NONE NONE NONE
EPICHLOROHYDRIN POLYMER
1,3-PROPANEDIOL, NONE NONE NONE NONE
2-(HYDROXYMETHYL)-
2-METHYL-, POLYMER WITH
2-(CHLOROMETHYL)OXIRANE
QUARTZ (SiO2) 0.025 MG/M3 2.4 MPPCF TWA NONE NONE
TWA RESPIRABLE.
RESPIRABLE
FRACTION. 0.1 MG/M3 TWA
RESPIRABLE.
0.05 MG/M3
TWA
(RESPIRABLE
DUST.)
0.025 MG/M3
OSHA_ACT
(RESPIRABLE
DUST.)
0.05 MG/M3
PEL
RESPIRABLE
DUST.
ETHYLENE GLYCOL 25 PPM TWA NONE NONE NONE
VAPOR
FRACTION
50 PPM STEL
VAPOR
FRACTION
10 MG/M3 STEL
AEROSOL,
INHALABLE.
TITANIUM DIOXIDE 10 MG/M3 TWA 15 MG/M3 PEL NONE NONE
TOTAL DUST.
15 MPPCF TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST.
50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED SUPPLIED AIR RESPIRATOR WITH AN ORGANIC CARTRIDGE IF
THE POTENTIAL TO EXCEED ESTABLISHED EXPOSURE LIMITS EXISTS.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: WHITE
ODOR: SLIGHT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT DETERMINED
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.4
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 7.84 G/L (VALUE AS MIXED FOR USE)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS: ACIDS. OXIDIZING AGENTS. PEROXIDES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. PROTECT
FROM DIRECT SUNLIGHT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED. NOT EXPECTED
UNDER NORMAL CONDITIONS OF USE.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
BISPHENOL A - NONE ALLERGEN, IRRITANT
EPICHLOROHYDRIN POLYMER
1,3-PROPANEDIOL, NONE NO RECORDS
2-(HYDROXYMETHYL)-
2-METHYL-, POLYMER WITH
2-(CHLOROMETHYL)OXIRANE
QUARTZ (SiO2) NONE IMMUNE SYSTEM, LUNG,
SOME EVIDENCE OF
CARCINOGENICITY
ETHYLENE GLYCOL ORAL LD50 (RAT): BLOOD, BONE MARROW,
5.89 G/KG CENTRAL NERVOUS
SYSTEM, DEVELOPMENTAL,
ORAL LD50 (MOUSE): EYES, IRRITANT,
14.6 G/KG KIDNEY, LIVER,
METABOLIC
DERMAL LD50 (RABBIT):
9,530 MG/KG
TITANIUM DIOXIDE NONE IRRITANT, RESPIRATORY,
SOME EVIDENCE OF
CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
BISPHENOL A - NO NO NO
EPICHLOROHYDRIN POLYMER
1,3-PROPANEDIOL, NO NO NO
2-(HYDROXYMETHYL)-
2-METHYL-, POLYMER WITH
2-(CHLOROMETHYL)OXIRANE
QUARTZ (SiO2) KNOWN TO BE GROUP 1 YES
HUMAN
CARCINOGEN.
ETHYLENE GLYCOL NO NO NO
TITANIUM DIOXIDE NO GROUP 2B NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(BISPHENOL A DIGLYCIDYL ETHER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(BISPHENOL A DIGLYCIDYL ETHER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: BISPHENOL A DIGLYCIDYL ETHER
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
ETHYLENE GLYCOL (CAS# 107-21-1).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2, 3
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 10/27/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 11/06/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE EA 9011 KNOWN AS FIXMASTER ANC BLT GRT HP 11OZ B
PRODUCT TYPE: EPOXY
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1108395
ITEM NUMBER: 1108395_210477
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
HARMFUL IF SWALLOWED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY ORAL 4
SKIN CORROSION 1B
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. CONTAMINATED
WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION IF YOU
FEEL UNWELL.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
QUARTZ (SiO2) 14808-60-7 40 - 50
C18 FATTY ACID DIMER, TALL OIL FATTY 68082-29-1 10 - 20
ACID, TRIETHYLENETETRAMINE POLYMER
BENZYL ALCOHOL 100-51-6 5 - 10
N-AMINOETHYLPIPERAZINE 140-31-8 5 - 10
4-NONYLPHENOL, BRANCHED 84852-15-3 30 - 40
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 90-72-2 5 - 10
ETHYLENE GLYCOL 107-21-1 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE
MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING,
SUCH AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. CLOSED CONTAINERS
MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING VAPORS. TOXIC FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL
AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO
CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP CONTAINER TIGHTLY
CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE
MATERIALS. STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF
IGNITION. AVOID MOISTURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
QUARTZ (SiO2) 0.025 MG/M3 2.4 MPPCF NONE NONE
TWA TWA
RESPIRABLE RESPIRABLE.
FRACTION.
0.1 MG/M3
TWA
RESPIRABLE.
0.05 MG/M3
TWA
(RESPIRABLE
DUST.)
0.025 MG/M3
OSHA_ACT
(RESPIRABLE
DUST.)
0.05 MG/M3
PEL
RESPIRABLE
DUST.
C18 FATTY ACID DIMER, NONE NONE NONE NONE
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
BENZYL ALCOHOL NONE NONE 10 PPM NONE
(44.20 MG/M3)
TWA
N-AMINOETHYLPIPERAZINE NONE NONE NONE NONE
4-NONYLPHENOL, BRANCHED NONE NONE NONE NONE
2,4,6-TRIS NONE NONE NONE NONE
(DIMETHYLAMINOMETHYL)
PHENOL
ETHYLENE GLYCOL 25 PPM TWA NONE NONE NONE
VAPOR
FRACTION
50 PPM STEL
VAPOR
FRACTION
10 MG/M3
STEL
AEROSOL,
INHALABLE.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED SUPPLIED AIR RESPIRATOR WITH AN ORGANIC CARTRIDGE IF
THE POTENTIAL TO EXCEED ESTABLISHED EXPOSURE LIMITS EXISTS.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: BLACK
ODOR: SLIGHT, AMINE-LIKE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT DETERMINED
BOILING POINT/RANGE: NOT DETERMINED
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.0
VAPOR DENSITY: NOT DETERMINED
FLASH POINT: >93 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 7.84 G/L (VALUE AS MIXED FOR USE)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING VAPORS. TOXIC FUMES.
INCOMPATIBLE MATERIALS: ACIDS. OXIDIZING AGENTS. PEROXIDES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
EXPOSURE TO MOISTURE. ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND
OTHER SOURCES OF IGNITION. STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MISTS, VAPORS OR LIQUID MAY CAUSE SEVERE IRRITATION OR BURNS.
SKIN CONTACT: CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
HARMFUL IF SWALLOWED. IRRITATION AND CORROSIVE ACTION CAN OCCUR IN THE
MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
QUARTZ (SiO2) NONE IMMUNE SYSTEM, LUNG,
SOME EVIDENCE OF
CARCINOGENICITY
C18 FATTY ACID DIMER, NONE NO RECORDS
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
BENZYL ALCOHOL ORAL LD50 (RABBIT): ALLERGEN, CENTRAL
1,940 MG/KG NERVOUS SYSTEM,
CORROSIVE, IRRITANT
ORAL LD50 (RAT):
1,230 - 3,100 MG/KG
ORAL LD50 (MOUSE):
1,580 MG/KG
ORAL LD50 (RAT):
3,100 MG/KG
DERMAL LD50 (RABBIT):
2,000 MG/KG
N-AMINOETHYLPIPERAZINE NONE IRRITANT, CORROSIVE,
ALLERGEN
4-NONYLPHENOL, BRANCHED NONE IRRITANT, CORROSIVE
2,4,6-TRIS NONE IRRITANT, ALLERGEN
(DIMETHYLAMINOMETHYL)
PHENOL
ETHYLENE GLYCOL ORAL LD50 (RAT): BLOOD, BONE MARROW,
5.89 G/KG CENTRAL NERVOUS
SYSTEM, DEVELOPMENTAL,
ORAL LD50 (MOUSE): EYES, IRRITANT,
14.6 G/KG KIDNEY, LIVER,
METABOLIC
DERMAL LD50 (RABBIT):
9,530 MG/KG
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
QUARTZ (SiO2) KNOWN TO BE GROUP 1 YES
HUMAN
CARCINOGEN.
C18 FATTY ACID DIMER, NO NO NO
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
BENZYL ALCOHOL NO NO NO
N-AMINOETHYLPIPERAZINE NO NO NO
4-NONYLPHENOL, BRANCHED NO NO NO
2,4,6-TRIS NO NO NO
(DIMETHYLAMINOMETHYL)PHENOL
ETHYLENE GLYCOL NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE
TIME OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES,
ETC., MAY RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO
THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
CORROSIVE LIQUIDS, N.O.S. (AMINOETHYLPIPERAZINE, NONYLPHENOL)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 1760
PACKING GROUP: III
MARINE POLLUTANT: NONYLPHENOL
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
CORROSIVE LIQUID, N.O.S. (AMINOETHYLPIPERAZINE, NONYLPHENOL)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 1760
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
CORROSIVE LIQUID, N.O.S. (AMINOETHYLPIPERAZINE, NONYLPHENOL)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 1760
PACKING GROUP: III
MARINE POLLUTANT: NONYLPHENOL
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: ALKYL PHENOL (CAS# 84852-15-3).
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
4-NONYLPHENOL, BRANCHED (CAS# 84852-15-3).
ETHYLENE GLYCOL (CAS# 107-21-1).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2, 3
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 11/06/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.