| Common Name: | SPECSEAL FIRESTOP PILLOWS |
| Manufacturer: | SPECIFIED TECHNOLOGIES |
| SDS Revision Date: | 1/29/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 3PA71, 3PA72, 3PA73, 3PA74 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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STI(R*)
SAFETY DATA SHEET
PREPARED TO U.S. OSHA, CM A, ANSI, CANADIAN WHMIS, THE KOREAN ISHA
(NOTICE 2009-68), THE JAPANESE INDUSTRIAL STANDARD JIS Z 7250:
2000, MEXICAN NOM018-STPS 2000, SPRING SINGAPORE, AND THE GLOBAL
HARMONIZATION STANDARD
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY UNDERTAKING
IDENTIFICATION OF THE MIXTURE:
TRADE/MATERIAL NAME: SPECSEAL(R*) FIRESTOP PILLOWS
CHEMICAL NAMES:
FIRE-RESISTANT COATED MINERAL WOOL BATTS PACKAGED IN PLASTIC
SYNONYMS: NONE
RELEVANT USE OF THE SUBSTANCE: FIRE BARRIER
USES ADVISED AGAINST: OTHER THAN RELEVANT USE
SUPPLIER/MANUFACTURER'S NAME (USA/CANADA): SPECIFIED TECHNOLOGIES, INC.
ADDRESS:
210 EVANS WAY
SOMERVILLE, NEW JERSEY 08876
BUSINESS PHONE: (908) 526-8000 (8:00AM TO 5:00PM EASTERN STANDARD TIME)
EMERGENCY PHONE:
U.S., CANADA: 1-800-255-3924 (24 HRS)
INTERNATIONAL: +1-813-248-0585 (COLLECT-24 HRS)
SUPPLIER/IMPORTER'S NAME (ASIA):
ADDRESS:
BUSINESS PHONE:
EMAIL OF COMPETENT PERSON FOR INFORMATION ON SDS: TECHSERV@STIFIRESTOP.COM
NOTE:
ALL UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION STANDARD
(29 CFR 1910.1200), U.S. STATE EQUIVALENT STANDARDS, CANADIAN WHMIS
[CONTROLLED PRODUCTS REGULATIONS], MEXICAN NOM018-STPS 2000, SPRING
SINGAPORE, AND JAPANESE JIS Z7250 REQUIRED INFORMATION IS INCLUDED IN
APPROPRIATE SECTIONS BASED ON THE U.S. ANSI Z400.1-2010 FORMAT. THIS
PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE COUNTRIES LISTED ABOVE.
| 2. HAZARD IDENTIFICATION | |
GLOBAL HARMONIZATION AND JAPANESE JIS Z7253 LABELING AND CLASSIFICATION:
THIS PRODUCT HAS BEEN CLASSIFIED PER UN GHS STANDARDS UNDER U.S., JAPANESE
AND OTHER APPLICABLE REGULATIONS THAT REQUIRE GLOBAL HARMONIZATION
COMPLIANCE.
CLASSIFICATION:
CARCINOGENIC CAT. 2, EYE IRRITATION CAT. 2A, STOT (INHALATION-RESPIRATORY
IRRITATION) SE CAT. 3
SIGNAL WORD: WARNING
HAZARD STATEMENT CODES: H351, H319, H335
PRECAUTIONARY STATEMENT CODES:
P201, P202, P261, P271, P264, P280, P308 + P313, P305 + P351 + P338,
P337 + P313, P304 + P340, P312, P321, P403 + P233 + P405, P501
HAZARD SYMBOLS:
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
KOREAN ISHA (NOTICE 2009-68) LABELING AND CLASSIFICATION:
CLASSIFIED IN ACCORDANCE WITH ISHA NOTICE 2009-68. UNDER ISHA,
NO DIFFERENCES IN CLASSIFICATION ARE APPLICABLE.
EMERGENCY OVERVIEW:
PRODUCT DESCRIPTION:
THIS PRODUCT CONSISTS OF A MINERAL WOOL CORE WITH ENCAPSULATED FIRE
RESISTANT COATING PACKAGED IN A SEALED POLY BAG. THE COATING IS A LAYER
ACRYLIC ADHESIVE, A LAYER OF GRAPHITE AND A SECOND LAYER OF ADHESIVE.
HEALTH HAZARDS:
THIS PRODUCT DOES NOT NORMALLY PRESENT AN EXPOSURE HAZARD. IF THE
ENCAPSULATION BAG IS BROKEN, EXPOSURE TO PARTICLES OF THE MINERAL WOOL MAY
RESULT IN MECHANICAL EYE IRRITATION AND RESPIRATORY IRRITATION. LONG-TERM
INHALATION OF GLASS WOOL FIBERS CAN CAUSE DAMAGE TO THE LUNGS. THE MINERAL
WOOL COMPONENT IS A SUSPECT CARCINOGEN BY INHALATION (AS SYNTHETIC VITREOUS
GLASS WOOL FIBERS).
FLAMMABILITY HAZARDS:
THIS PRODUCT IS FORMULATED TO BE NON-FLAMMABLE AND NON-COMBUSTIBLE. IF
INVOLVED IN A FIRE, THIS PRODUCT WILL RELEASE SMOKE, ACRID VAPORS AND TOXIC
GASES (E.G., AMMONIA, CARBON, SILICON, NITROGEN OXIDES, FORMALDEHYDE,
PHENOL AND ACRYLIC MONOMERS).
REACTIVITY HAZARDS: THIS PRODUCT IS NOT REACTIVE.
ENVIRONMENTAL HAZARDS:
THIS PRODUCT HAS NOT BEEN TESTED FOR POTENTIAL HAZARDS IF RELEASED TO THE
ENVIRONMENT; HOWEVER THE PROPRIETARY BENZOATE ESTERS COMPONENT MAY CAUSE
ACUTE AND CHRONIC HARM TO AQUATIC ORGANISMS. ALL RELEASE SHOULD BE AVOIDED.
EMERGENCY CONSIDERATIONS:
EMERGENCY RESPONDERS SHOULD WEAR APPROPRIATE PROTECTION FOR THE SITUATION
TO WHICH THEY RESPOND.
| 3. COMPOSITION AND INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS # WT%
EXPANDABLE GRAPHITE FLAKES 7782-42-5 PROPRIETARY
MINERAL WOOL 65997-17-3 PROPRIETARY
POLY BAG MIXTURE PROPRIETARY
PROPRIETARY ACRYLIC ADHESIVE MIXTURE PROPRIETARY
CHEMICAL NAME CHINESE JAPANESE KOREAN TAIWAN
IECSC INVENTORY ENCS # ECL # NESCI ECS
EXPANDABLE LISTED EXCEPTED KE-18101
GRAPHITE FLAKES AS A MINERAL
MINERAL WOOL LISTED NOT LISTED KE-17630
POLY BAG MIXTURE MIXTURE MIXTURE MIXTURE
PROPRIETARY ACRYLIC MIXTURE MIXTURE MIXTURE MIXTURE
ADHESIVE
CHEMICAL NAME LABEL ELEMENTS
GHS & JAPANESE JIS Z7253 CLASSIFICATION
KOREAN ISHA CLASSIFICATION
GHS HAZARD CODES
EXPANDABLE GRAPHITE FLAKES SELF CLASSIFICATION
GHS & JAPANESE JIS Z7253, KOREAN ISHA:
CLASSIFICATION:
EYE IRRITATION CAT. 2B, STOT
(INHALATION-RESPIRATORY IRRITATION)
SE CAT. 3
HAZARD CODES: H320, H335
MINERAL WOOL SELF CLASSIFICATION
GHS & JAPANESE JIS Z7253, KOREAN ISHA:
CLASSIFICATION:
EYE IRRITATION CAT. 2A, STOT
(INHALATION-RESPIRATORY IRRITATION)
SE CAT. 3
HAZARD CODES: H319, H335
POLY BAG CLASSIFICATION: NOT APPLICABLE
PROPRIETARY ACRYLIC ADHESIVE CLASSIFICATION: NOT APPLICABLE
SEE SECTION 16 FOR FULL TEXT OF CLASSIFICATION
| 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
CONTAMINATED INDIVIDUALS MUST BE TAKEN FOR MEDICAL ATTENTION IF ANY ADVERSE
EFFECTS OCCUR. REMOVE CONTAMINATED CLOTHING AND SHOES. TAKE A COPY OF THIS
SDS TO HEALTH PROFESSIONAL WITH VICTIM. WASH CLOTHING AND THOROUGHLY CLEAN
SHOES BEFORE REUSE. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. TAKE A COPY OF LABEL AND SDS TO
PHYSICIAN OR HEALTH PROFESSIONAL WITH THE CONTAMINATED INDIVIDUAL.
SKIN EXPOSURE:
IF ADVERSE SKIN EFFECTS OCCUR, DISCONTINUE USE AND FLUSH CONTAMINATED AREA.
SEEK MEDICAL ATTENTION IF ADVERSE EFFECT OCCURS AFTER FLUSHING.
INHALATION:
IF FUMES OR VAPORS ARE INHALED, REMOVE VICTIM TO FRESH AIR. IF NECESSARY,
USE ARTIFICIAL RESPIRATION TO SUPPORT VITAL FUNCTIONS. SEEK MEDICAL
ATTENTION IF ADVERSE EFFECT CONTINUES AFTER REMOVAL TO FRESH AIR.
EYE EXPOSURE:
IF THIS PRODUCT CONTAMINATES THE EYES, RINSE EYES UNDER GENTLY RUNNING
WATER. USE SUFFICIENT FORCE TO OPEN EYELIDS AND THEN "ROLL" EYES WHILE
FLUSHING. MINIMUM FLUSHING IS FOR 20 MINUTES. THE CONTAMINATED INDIVIDUAL
MUST SEEK MEDICAL ATTENTION IF ANY ADVERSE EFFECT CONTINUES AFTER RINSING.
INGESTION:
IF THIS PRODUCT IS SWALLOWED, CALL PHYSICIAN OR POISON CONTROL CENTER FOR
MOST CURRENT INFORMATION. IF PROFESSIONAL ADVICE IS NOT AVAILABLE, DO NOT
INDUCE VOMITING. NEVER INDUCE VOMITING OR GIVE DILUENTS (MILK OR WATER) TO
SOMEONE WHO IS UNCONSCIOUS, HAVING CONVULSIONS, OR UNABLE TO SWALLOW. IF
VICTIM IS CONVULSING, MAINTAIN AN OPEN AIRWAY AND OBTAIN IMMEDIATE MEDICAL
ATTENTION.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PRE-EXISTING RESPIRATORY DISORDERS MAY BE AGGRAVATED BY OVEREXPOSURES TO
THIS PRODUCT.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT IF NEEDED:
TREAT SYMPTOMS AND ELIMINATE EXPOSURE.
| 5. FIRE-FIGHTING MEASURES | |
FLASH POINT: NOT DETERMINED.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABLE LIMITS (IN AIR BY VOLUME, %): NOT APPLICABLE.
FIRE EXTINGUISHING MEDIA:
USE EXTINGUISHING MATERIALS SUITABLE FOR THE SURROUNDING AREA.
UNSUITABLE FIRE EXTINGUISHING MEDIA: NONE KNOWN.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
THIS PRODUCT IS FORMULATED TO BE NON-FLAMMABLE AND NON-COMBUSTIBLE. WHEN
INVOLVED IN A FIRE, THIS MATERIAL MAY DECOMPOSE AND PRODUCE IRRITATING
VAPORS AND TOXIC GASES (E.G., AMMONIA, CARBON, SILICON, NITROGEN OXIDES,
FORMALDEHYDE, PHENOL AND ACRYLIC MONOMERS).
EXPLOSION SENSITIVITY TO MECHANICAL IMPACT: NOT SENSITIVE.
EXPLOSION SENSITIVITY TO STATIC DISCHARGE: NOT SENSITIVE.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
INCIPIENT FIRE RESPONDERS SHOULD WEAR EYE PROTECTION. STRUCTURAL
FIREFIGHTERS MUST WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL
PROTECTIVE EQUIPMENT.
CHEMICAL RESISTANT CLOTHING MAY BE NECESSARY. MOVE CONTAINERS FROM FIRE
AREA IF IT CAN BE DONE WITHOUT RISK TO PERSONNEL. WATER SPRAY CAN BE USED
TO COOL FIRE-EXPOSED CONTAINERS. WATER FOG OR SPRAY CAN ALSO BE USED BY
TRAINED FIREFIGHTERS TO DISPERSE THIS PRODUCT'S VAPORS AND TO PROTECT
PERSONNEL. IF POSSIBLE, PREVENT RUNOFF WATER FROM ENTERING STORM DRAINS,
BODIES OF WATER, OR OTHER ENVIRONMENTALLY SENSITIVE AREAS.
NFPA RATING:
HEALTH 2
FLAMMABILITY 0
INSTABILITY 0
OTHER
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS AND EMERGENCY PROCEDURES:
UNCONTROLLED RELEASES SHOULD BE RESPONDED TO BY TRAINED PERSONNEL USING
PRE-PLANNED PROCEDURES. PROPER PROTECTIVE EQUIPMENT SHOULD BE USED. CALL
CHEMTREC (1-800-424-9300) FOR EMERGENCY ASSISTANCE. OR IF IN CANADA, CALL
CANUTEC (613-996-6666). THE ATMOSPHERE MUST AT LEAST 19.5 PERCENT OXYGEN
BEFORE NON-EMERGENCY PERSONNEL CAN BE ALLOWED IN THE AREA WITHOUT
SELF-CONTAINED BREATHING APPARATUS AND FIRE PROTECTION.
PERSONAL PROTECTIVE EQUIPMENT:
PROPER PROTECTIVE EQUIPMENT SHOULD BE USED. USE ONLY NON-SPARKING TOOLS AND
EQUIPMENT.
SMALL SPILLS:
WEAR RUBBER GLOVES, SPLASH GOGGLES, AND APPROPRIATE BODY PROTECTION.
LARGE SPILLS:
MINIMUM PERSONAL PROTECTIVE EQUIPMENT SHOULD BE RUBBER GLOVES, RUBBER
BOOTS, FACE SHIELD, AND TYVEK SUIT. MINIMUM LEVEL OF PERSONAL PROTECTIVE
EQUIPMENT FOR RELEASES IN WHICH THE LEVEL OF OXYGEN IS LESS THAN 19.5% OR
IS UNKNOWN MUST BE LEVEL B:
TRIPLE-GLOVES (RUBBER GLOVES AND NITRILE GLOVES OVER LATEX GLOVES), BOOTS,
TYVEK OR SIMILAR PROTECTIVE CLOTHING, HARD HAT, AND SELF-CONTAINED
BREATHING APPARATUS.
METHODS FOR CLEAN-UP AND CONTAINMENT:
SPILLS OF THIS PRODUCT PRESENT MINIMAL HAZARD.
SMALL SPILLS:
SMALL RELEASES OF THE MINERAL WOOL CAN BE CAREFULLY SWEPT UP OR CLEANED UP
USING A DAMP SPONGE OR POLYPADS.
LARGE SPILLS:
ACCESS TO THE SPILL AREA SHOULD BE RESTRICTED. FOR LARGE SPILLS, DIKE OR
OTHERWISE CONTAIN SPILL AND SWEEP-UP OR VACUUM WITH NON-SPARKING VACUUM,
AVOIDING GENERATION OF DUSTS AND PARTICULATES.
ALL SPILLS:
PLACE ALL SPILL RESIDUE IN A DOUBLE PLASTIC BAG OR OTHER CONTAINMENT AND
SEAL. CLOSE OFF SEWERS AND TAKE OTHER MEASURES TO PROTECT HUMAN HEALTH AND
THE ENVIRONMENT AS NECESSARY. RINSE AREA WITH SOAP AND WATER SOLUTION AND
FOLLOW WITH A WATER RINSE. DECONTAMINATE THE AREA THOROUGHLY. DO NOT MIX
WITH WASTES FROM OTHER MATERIALS. DISPOSE OF IN ACCORDANCE WITH APPLICABLE
FEDERAL, STATE, AND LOCAL PROCEDURES (SEE SECTION 13, DISPOSAL
CONSIDERATIONS). FOR SPILLS ON WATER, CONTAIN, MINIMIZE DISPERSION AND
COLLECT. DISPOSE OF RECOVERED MATERIAL AND REPORT SPILL PER REGULATORY
REQUIREMENTS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. RUN-OFF WATER MAY BE CONTAMINATED BY
OTHER MATERIALS AND SHOULD BE CONTAINED TO PREVENT POSSIBLE ENVIRONMENTAL
DAMAGE.
REFERENCE TO OTHER SECTIONS:
SEE INFORMATION IN SECTION 8 (EXPOSURE CONTROLS - PERSONAL PROTECTION) AND
SECTION 13 (DISPOSAL CONSIDERATIONS) FOR ADDITIONAL INFORMATION.
| 7. HANDLING AND USE | |
PRECAUTIONS FOR SAFE HANDLING:
AS WITH ALL CHEMICALS, AVOID GETTING THIS MATERIAL ON YOU OR IN YOU. DO NOT
EAT, DRINK, SMOKE, OR APPLY COSMETICS WHILE HANDLING THIS PRODUCT. WASH
HANDS THOROUGHLY AFTER HANDLING THIS PRODUCT OR CONTAINERS OF THIS PRODUCT.
AVOID BREATHING FUMES OR VAPORS GENERATED BY THIS PRODUCT. USE IN A
WELL-VENTILATED LOCATION.
CONDITIONS FOR SAFE STORAGE:
STORE CONTAINERS IN A COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT,
SOURCES OF INTENSE HEAT.
SPECIFIC END USE(S):
THIS PRODUCT IS FOR USE AS A SEALANT. FOLLOW ALL INDUSTRY STANDARDS FOR USE
OF THIS PRODUCT.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT:
FOLLOW PRACTICES INDICATED IN SECTION 6 (ACCIDENTAL RELEASE MEASURES).
MAKE CERTAIN THAT APPLICATION EQUIPMENT IS LOCKED AND TAGGED-OUT SAFELY,
IF NECESSARY. COLLECT ALL RINSATES AND DISPOSE OF ACCORDING TO APPLICABLE
FEDERAL, STATE, AND LOCAL PROCEDURES.
| 8. EXPOSURE CONTROLS - PERSONAL PROTECTION | |
EXPOSURE LIMITS/CONTROL PARAMETERS:
VENTILATION AND ENGINEERING CONTROLS:
USE WITH ADEQUATE VENTILATION TO ENSURE EXPOSURE LEVELS ARE MAINTAINED
BELOW THE LIMITS PROVIDED BELOW (IF APPLICABLE). EXHAUST DIRECTLY TO THE
OUTSIDE, TAKING NECESSARY PRECAUTIONS FOR ENVIRONMENTAL PROTECTION.
WORKPLACE EXPOSURE LIMITS/CONTROL PARAMETERS:
CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR
ACGIH-TLVS OSHA-PELS
TWA STEL TWA STEL
MG/M3 MG/M3 MG/M3 MG/M3
EXPANDABLE 7782-42-5 2 (RESP. NE 15 MPPCF
GRAPHITE FLAKES FRACT.)
MINERAL WOOL 65997-17-3 10 NE 15 (TOTAL NE
FIBER DUST)
10
(VACATED
1989 PEL)
NE
SYNTHETIC 1 F/CC(F) NE NE NE
VITREOUS FIBERS
PROPRIETARY ACRYLIC NE NE NE NE
POLYMER
CHEMICAL NAME EXPOSURE LIMITS IN AIR
NIOSH-RELS NIOSH OTHER
TWA STEL IDLH MG/M3
MG/M3 MG/M3 MG/M3
EXPANDABLE 2.5 (RESP. NE NE DFG MAKS:
GRAPHITE FLAKES DUST) TWA:
1.5 (RESPIRATION
FRACTION)
4 (INHALABLE
FRACTION)
DFG MAK PREGNANCY
RISK CLASSIFICATION:
C
MINERAL WOOL 5 (TOTAL NE 5000 NE
FIBER MINERAL WOOL (CA)
DUST, OR
3 F/CC TWA
(FIBERS
</=3.5 UM
DIAMETER;
>/=10 UM
LENGTH)
SYNTHETIC VITREOUS NE NE NE CARCINOGEN:
FIBERS IARC-3, MAK-
3B, TLV-A3
PROPRIETARY NE NE NE NE
ACRYLIC POLYMER
NE = NOT ESTABLISHED.
SEE SECTION 16 FOR DEFINITIONS OF OTHER TERMS USED
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS:
CURRENTLY, THE FOLLOWING ADDITIONAL EXPOSURE LIMIT VALUES HAVE BEEN
ESTABLISHED BY VARIOUS COUNTRIES FOR THE COMPONENTS OF THIS MIXTURE. MORE
CURRENT LIMITS MAY BE AVAILABLE; INDIVIDUAL COUNTRIES SHOULD BE CONSULTED
TO DETERMINE IF NEWER LIMITS ARE AVAILABLE.
GRAPHITE:
BELGIUM:
TWA: 2 MG/M3 (RESP. DUST), MAR 2002
DENMARK:
TWA: 2.5 MG/M3 (RESPIRABLE), MAY 2011
FINLAND:
TWA: 2 MG/M3, NOV 2011
FRANCE:
VME: 2 MG/M3, FEB 2006
GERMANY:
MAK: 1.5 MG/M3, RESP, 2011
GERMANY:
MAK: 4 MG/M3, INHAL, 2011
ICELAND:
TWA: 2.5 MG/M3 (RESP. DUST), NOV 2011
JAPAN:
OEL: 0.5 MG/M3 (RESPIRABLE), 2 MG/M3 (TOTAL), MAY 2012
KOREA:
TWA: 10 MG/M3, 2006
KOREA:
TWA: 2.5 MG/M3, 2006
MEXICO:
TWA: 2 MG/M3, 2004
THE NETHERLANDS:
MAC-TGG: 2 MG/M3, 2003
NEW ZEALAND:
TWA: 3 MG/M3 (RESPIRABLE DUST), JAN 2002
PERU:
TWA: 2 MG/M3, JUL 2005
SWEDEN:
TWA: 0.2 F/CC, JUN 2005
SWEDEN:
TWA: 5 MG/M3, JUN 2005
SWITZERLAND:
MAK-W: 5 MG/M3, INHAL, JAN 2011
SWITZERLAND:
MAK-W: 2.5 MG/M3, RESP, JAN 2011
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
MINERAL WOOL FIBERS:
MEXICO:
TWA: 10 MG/M3 (DUST), 2004
PROTECTIVE EQUIPMENT:
THE FOLLOWING INFORMATION ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT IS
PROVIDED TO ASSIST EMPLOYERS IN COMPLYING WITH OSHA REGULATIONS FOUND IN
29 CFR SUBPART I (BEGINNING AT 1910.132, INCLUDING U.S. FEDERAL OSHA
RESPIRATORY PROTECTION (29 CFR 1910.134), OSHA EYE PROTECTION 29 CFR
1910.133, OSHA HARD PROTECTION 29 CFR 1910.138, OSHA FOOT PROTECTION 29 CFR
1910.136 AND OSHA BODY PROTECTION 29 CFR1910.132), EQUIVALENT STANDARDS OF
CANADA (INCLUDING CSA RESPIRATORY STANDARD Z94.4-02, Z94.3-M1982,
INDUSTRIAL EYE AND FACE PROTECTORS AND CSA STANDARD Z195-02, PROTECTIVE
FOOTWEAR), OR STANDARDS OF JAPAN (INCLUDING JIS T 8116:2005 FOR GLOVE
SELECTION, JIS T 8150:2006 FOR RESPIRATORY PPE, JIS T 8147:2003 FOR EYE
PROTECTORS, AND JIS T 8030:2005 FOR PROTECTIVE CLOTHING). PLEASE REFERENCE
APPLICABLE REGULATIONS AND STANDARDS FOR RELEVANT DETAILS.
RESPIRATORY PROTECTION:
MAINTAIN AIRBORNE CONTAMINANT CONCENTRATIONS BELOW EXPOSURE LIMITS LISTED
ABOVE. FOR MATERIALS WITHOUT LISTED EXPOSURE LIMITS, MINIMIZE RESPIRATORY
EXPOSURE. IF NECESSARY, USE ONLY RESPIRATORY PROTECTION AUTHORIZED UNDER
APPROPRIATE REGULATIONS. OXYGEN LEVELS BELOW 19.5% ARE CONSIDERED IDLH BY
U.S. OSHA. IN SUCH ATMOSPHERES, USE OF A FULL-FACEPIECE PRESSURE/DEMAND
SCBA OR A FULL FACEPIECE, SUPPLIED AIR RESPIRATOR WITH AUXILIARY
SELF-CONTAINED AIR SUPPLY IS REQUIRED UNDER U.S. OSHA'S RESPIRATORY
PROTECTION STANDARD (1910.134-1998). THE FOLLOWING ARE NIOSH RESPIRATORY
PROTECTIVE EQUIPMENT GUIDELINES FOR THE MINERAL WOOL FIBER COMPONENT TO
AID IN SELECTION OF RESPIRATORY EQUIPMENT IN EVENT OF RELEASE OF FIBERS.
MINERAL WOOL FIBERS:
CONCENTRATION RESPIRATORY PROTECTION
5X REL: QM ANY SUPPLIED-AIR RESPIRATOR (SAR).
10X REL: 95XQ
25X REL: ANY POWERED AIR-PURIFYING RESPIRATOR (PAPR) WITH A
SA:CF HIGH-EFFICIENCY PARTICULATE FILTER.
50X REL: 100F PAPR WITH A TIGHT-FITTING FACEPIECE AND A
HIGH-EFFICIENCY PARTICULATE FILTER, OR ANY
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A
FULL FACEPIECE, OR ANY SAR WITH A FULL FACEPIECE.
EMERGENCY OR PLANNED ANY SCBA THAT HAS A FULL FACEPIECE AND IS OPERATED
ENTRY INTO UNKNOWN IN A PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE
CONCENTRATIONS OR MODE, OR ANY SAR THAT HAS A FULL-FACEPIECE AND
IDLH CONDITIONS IS OPERATED IN A PRESSURE-DEMAND OR OTHER
POSITIVE-PRESSURE MODE IN COMBINATION WITH AN
AUXILIARY SCBA OPERATED IN PRESSURE-DEMAND OR OTHER
POSITIVE-PRESSURE MODE.
ESCAPE ANY AIR-PURIFYING, FULL-FACEPIECE RESPIRATOR WITH
AN N100, R100, OR P100 FILTER.
EYE PROTECTION:
WEAR SPLASH GOGGLES OR SAFETY GLASSES AS APPROPRIATE FOR THE TASK.
HAND PROTECTION:
WASH HANDS AND WRISTS BEFORE PUTTING ON AND AFTER REMOVING GLOVES. DURING
MANUFACTURE OR OTHER SIMILAR OPERATIONS, WEAR THE APPROPRIATE HAND
PROTECTION FOR THE PROCESS. USE DOUBLE GLOVES FOR SPILL RESPONSE, AS STATED
IN SECTION 6 (ACCIDENTAL RELEASE MEASURES) OF THIS SDS. BECAUSE ALL GLOVES
ARE TO SOME EXTENT PERMEABLE AND THEIR PERMEABILITY INCREASES WITH TIME,
THEY SHOULD BE CHANGED REGULARLY (HOURLY IS PREFERABLE) OR IMMEDIATELY IF
TORN OR PUNCTURED. IF NECESSARY REFER TO APPROPRIATE REGULATIONS.
SKIN PROTECTION:
USE APPROPRIATE PROTECTIVE CLOTHING FOR THE TASK (E.G., LAB COAT, ETC.).
IF NECESSARY, REFER TO THE U.S. OSHA TECHNICAL MANUAL (SECTION VII:
PERSONAL PROTECTIVE EQUIPMENT) OR OTHER APPROPRIATE REGULATIONS. FULL-BODY
CHEMICAL PROTECTIVE CLOTHING IS RECOMMENDED FOR EMERGENCY RESPONSE
PROCEDURES. IF A HAZARD OF INJURY TO THE FEET EXISTS DUE TO FALLING
OBJECTS, ROLLING OBJECTS, WHERE OBJECTS MAY PIERCE THE SOLES OF THE FEET
OR WHERE EMPLOYEE'S FEET MAY BE EXPOSED TO ELECTRICAL HAZARDS, USE FOOT
PROTECTION, AS DESCRIBED IN U.S. OSHA AND CANADIAN STANDARDS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM: AS DESCRIBED IN SECTION 2.
COLOR: AS DESCRIBED IN SECTION 2.
MOLECULAR FORMULA: MIXTURE.
MOLECULAR WEIGHT: MIXTURE.
ODOR: MILD ACRYLIC.
ODOR THRESHOLD: NOT AVAILABLE.
FLAMMABLE LIMITS (IN AIR BY VOLUME, %): NOT APPLICABLE.
OXIDIZING PROPERTIES: NOT APPLICABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
PERCENT VOLATILE: 24
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
FREEZING/MELTING POINT: NOT APPLICABLE.
BOILING POINT: NOT APPLICABLE.
VAPOR PRESSURE: NOT APPLICABLE.
SPECIFIC GRAVITY (WATER = 1): 0.1
VAPOR DENSITY (AIR = 1): NOT APPLICABLE.
CARB VOC: NOT APPLICABLE.
EVAPORATION RATE (N-BUAC = 1): NOT APPLICABLE.
SCAQMD (U.S. EPA METHOD 24): NOT APPLICABLE.
SOLUBILITY IN WATER: DISSOLVES WHEN WET; INSOLUBLE WHEN CURED.
SOLUBILITY IN SOLVENTS: NOT AVAILABLE.
COEFFICIENT WATER/OIL DISTRIBUTION: NOT ESTABLISHED.
PH: NOT APPLICABLE.
HOW TO DETECT THIS SUBSTANCE (WARNING PROPERTIES IN EVENT OF ACCIDENTAL
RELEASE):
THE APPEARANCE MAY BE CHARACTERISTICS TO DISTINGUISH A RELEASE OF THIS
PRODUCT.
| 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
THIS PRODUCT IS STABLE WHEN PROPERLY STORED AT NORMAL TEMPERATURE AND
PRESSURES (SEE SECTION 7, HANDLING AND STORAGE).
DECOMPOSITION PRODUCTS:
COMBUSTION:
IF EXPOSED TO EXTREMELY HIGH TEMPERATURES, THERMAL DECOMPOSITION MAY
GENERATE IRRITATING FUMES AND TOXIC GASES (E.G., AMMONIA, CARBON, SILICON,
NITROGEN OXIDES, FORMALDEHYDE, PHENOL AND ACRYLIC MONOMERS).
HYDROLYSIS: NONE KNOWN.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE:
THIS PRODUCT IS INCOMPATIBLE WITH STRONG OXIDIZERS.
POSSIBILITY OF HAZARDOUS POLYMERIZATION OR REACTION: WILL NOT OCCUR.
CONDITIONS TO AVOID:
AVOID EXPOSURE TO OR CONTACT WITH EXTREME TEMPERATURES AND INCOMPATIBLE
CHEMICALS.
| 11. TOXICOLOGICAL INFORMATION | |
SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE:
THE HEALTH HAZARD INFORMATION PROVIDED BELOW IS PERTINENT TO EMPLOYEES
USING THIS PRODUCT IN AN OCCUPATIONAL SETTING. THE FOLLOWING PARAGRAPHS
DESCRIBE THE SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE.
INHALATION:
ALTHOUGH UNLIKELY DUE TO THE FORM OF THE PRODUCT, INHALATION IS NOT LIKELY
UNLESS THE POLYPAD IS TORN AND PARTICULATES ARE BREATHED. IN THIS EVENT,
INHALATION OF PARTICLES CAN CAUSE IRRITATION TO THE RESPIRATORY SYSTEM.
CHRONIC INHALATION OF MINERAL WOOL FIBERS CAN CAUSE DAMAGE TO THE LUNGS.
THE MINERAL WOOL COMPONENT IS A SUSPECT CARCINOGEN BY INHALATION. DUE TO
THE FORM OF THIS PRODUCT, THIS HAZARD IS LESSENED; HOWEVER, ALL INHALATION
EXPOSURE MUST BE AVOIDED IN ORDER TO MITIGATE CARCINOGENIC POTENTIAL.
CONTACT WITH SKIN OR EYES:
DIRECT EYE CONTACT WITH PARTICULATES MAY CAUSE IRRITATION, REDNESS, AND
TEARING FROM MECHANICAL IRRITATION. SKIN CONTACT WITH THE MINERAL WOOL MAY
CAUSE MECHANICAL IRRITATION OF THE SKIN.
SKIN ABSORPTION:
COMPONENTS ARE NOT KNOWN TO BE ABSORBED THROUGH INTACT SKIN.
INGESTION:
INGESTION IS NOT A SIGNIFICANT ROUTE OF OCCUPATIONAL EXPOSURE AND IS
UNLIKELY TO OCCUR. IF THIS PRODUCT IS SWALLOWED, IRRITATION OF THE MOUTH,
THROAT, ESOPHAGUS AND OTHER TISSUES OF THE DIGESTIVE SYSTEM MAY OCCUR.
BLOCKAGE OF THE DIGESTIVE SYSTEM MAY OCCUR.
INJECTION:
ACCIDENTAL INJECTION OF THIS PRODUCT, VIA LACERATION OR PUNCTURE BY A
CONTAMINATED OBJECT CAN CAUSE REDNESS AT THE SITE OF INJECTION. ANIMAL
DATA FOR THE CRYSTALLINE SILICA COMPONENT INDICATE THAT IT MAY CAUSE
CARCINOGENIC EFFECTS BY THIS ROUTE OF EXPOSURE.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: AN EXPLANATION IN LAY TERMS.
EXPOSURE TO THIS PRODUCT MAY CAUSE THE FOLLOWING HEALTH EFFECTS:
ACUTE:
INHALATION OF PARTICULATES MAY CAUSE IRRITATION OF RESPIRATORY SYSTEM. EYE
CONTACT MAY CAUSE MECHANICAL IRRITATION.
CHRONIC:
PROLONGED OR REPEATED SKIN EXPOSURE MAY CAUSE DERMATITIS (DRY RED SKIN).
THE MINERAL WOOL COMPONENT IS A SUSPECT HUMAN CARCINOGEN BY INHALATION.
TARGET ORGANS:
ACUTE: EYES, RESPIRATORY SYSTEM.
CHRONIC: RESPIRATORY SYSTEM.
TOXICITY DATA:
CURRENTLY, THE FOLLOWING TOXICOLOGICAL DATA ARE AVAILABLE FOR COMPONENTS OF
1% OR MORE CONCENTRATION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM:
HEALTH HAZARD (BLUE) 2*
FLAMMABILITY HAZARD (RED) 0
PHYSICAL HAZARD (YELLOW) 0
PROTECTIVE EQUIPMENT:
EYES: CHEMICAL GOGGLES
RESPIRATORY: SEE SECTION 8
HANDS: GLOVES
BODY: SEE SECTION 8
FOR ROUTINE INDUSTRIAL USE AND HANDLING APPLICATIONS
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
* = CHRONIC HAZARD
MINERAL WOOL FIBER:
LD (INTRATRACHEAL-MOUSE) >20 MG/KG:
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
BIOCHEMICAL:
ENZYME INHIBITION, INDUCTION, OR CHANGE IN BLOOD OR TISSUE LEVELS:
PHOSPHATASES
TCLO (INHALATION-RAT) 16 MG/M3/6 HOURS/13 WEEKS-INTERMITTENT:
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
TCLO (INHALATION-RAT) 5 MG/M3/7 HOURS/90 WEEKS-INTERMITTENT:
TUMORIGENIC: CARCINOGENIC BY RTECS CRITERIA
BLOOD: LEUKEMIA
TCLO (INHALATION-HAMSTER) 30 MG/M3/6 HOURS/13 WEEKS-INTERMITTENT:
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
BIOCHEMICAL:
ENZYME INHIBITION, INDUCTION, OR CHANGE IN BLOOD OR TISSUE LEVELS:
DEHYDROGENASES
TCLO (INHALATION-HAMSTER) 30 MG/M3/6HOURS/78 WEEKS-INTERMITTENT:
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
TDLO (INTRAPERITONEAL-RAT) 50 MG/KG:
TUMORIGENIC: EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA
GASTROINTESTINAL: TUMORS
TDLO (INTRAPERITONEAL-HAMSTER) 400 MG/KG:
TUMORIGENIC: EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA
GASTROINTESTINAL: TUMORS
TDLO (INTRAPERITONEAL-RABBIT) 25 MG/KG:
TUMORIGENIC: EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA
GASTROINTESTINAL: TUMORS
TDLO (INTRATRACHEAL-HAMSTER) 125 MG/KG/5 WEEKS-INTERMITTENT:
TUMORIGENIC: EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA
LUNGS, THORAX, OR RESPIRATION: TUMORS
TDLO (INTRAPLEURAL-RAT) 100 MG/KG:
TUMORIGENIC: EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA
LUNGS, THORAX, OR RESPIRATION: TUMORS
TDLO (IMPLANT-RAT) 200 MG/KG:
TUMORIGENIC: NEOPLASTIC BY RTECS CRITERIA, TUMORS AT SITE OF APPLICATION
TDLO (IMPLANT-RAT) 200 MG/KG:
TUMORIGENIC:
EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA, TUMORS AT SITE OF
APPLICATION
TDLO (IMPLANT-MOUSE) 1600 MG/KG:
TUMORIGENIC: EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA
LUNGS, THORAX, OR RESPIRATION: TUMORS
KIDNEY/URETER/BLADDER: TUMORS
MUTATION TEST SYSTEMS-NOT OTHERWISE SPECIFIED (HUMAN-FIBROBLAST): 10 MG/L
MUTATION TEST SYSTEMS-NOT OTHERWISE SPECIFIED (HAMSTER OVARY): 10 MG/L
MICRONUCLEUS TEST (HAMSTER OVARY): 2 (MICRO)G/CM2
IRRITANCY OF PRODUCT:
IF PARTICULATES FROM THE MINERAL WOOL COMPONENT ESCAPE THE POLY BAG,
INHALATION OR EYE CONTACT MAY CAUSE IRRITATION.
SENSITIZATION OF PRODUCT:
THIS PRODUCT IS NOT CURRENTLY KNOWN TO CAUSE ALLERGIC SKIN OR RESPIRATORY
REACTION.
CARCINOGENIC POTENTIAL OF COMPONENTS:
COMPONENTS OF THIS PRODUCT ARE LISTED BY AGENCIES TRACKING THE CARCINOGENIC
POTENTIAL OF CHEMICAL COMPOUNDS, AS FOLLOWS:
CRYSTALLINE SILICA:
ACGIH-TLV-A2 (SUSPECTED HUMAN CARCINOGEN); IARC-1 (CARCINOGENIC TO HUMANS);
MAK-1 (SUBSTANCES THAT CAUSE CANCER IN MAN AND CAN BE ASSUMED TO MAKE A
SIGNIFICANT CONTRIBUTION TO CANCER RISK); NIOSH-CA (POTENTIAL OCCUPATIONAL
CARCINOGEN WITH NO FURTHER CATEGORIZATION); NTP-K (KNOWN TO BE A HUMAN
CARCINOGEN)
MINERAL WOOL FIBER (AS SYNTHETIC VITREOUS FIBERS):
ACGIH TLV-A3 (CONFIRMED ANIMAL CARCINOGEN); IARC-3 (UNCLASSIFIABLE AS TO
CARCINOGENICITY IN HUMANS); NIOSH-CA (POTENTIAL OCCUPATIONAL CARCINOGEN,
WITH NO FURTHER CATEGORIZATION); MAK-3B (SUBSTANCES FOR WHICH IN VITRO
TESTS OR ANIMAL STUDIES HAVE YIELDED EVIDENCE OF CARCINOGENIC EFFECTS THAT
IS NOT SUFFICIENT FOR CLASSIFICATION IN ONE OF THE OTHER CATEGORIES.
FURTHER STUDIES ARE REQUIRED BEFORE A FINAL CLASSIFICATION CAN BE MADE.)
THE REMAINING COMPONENTS ARE NOT FOUND ON THE FOLLOWING LISTS:
U.S. EPA, U.S. NTP, U.S. OSHA, U.S. NIOSH, GERMAN MAK, IARC, OR ACGIH AND
THEREFORE IS NEITHER CONSIDERED TO BE NOR SUSPECTED TO BE A CANCER-CAUSING
AGENT BY THESE AGENCIES.
REPRODUCTIVE TOXICITY INFORMATION:
COMPONENTS OF THIS PRODUCT HAVE NO REPORTED MUTAGENIC, EMBRYOTOXIC,
TERATOGENIC OR REPRODUCTIVE TOXICITY.
ACGIH BIOLOGICAL EXPOSURE INDICES (BEIS):
CURRENTLY, THERE ARE NO ACGIH BIOLOGICAL EXPOSURE INDICES (BEIS) DETERMINED
FOR THIS MATERIAL.
DEGREE OF EFFECT TO THE HEALTH OF THE POLLUTING AGENT OF ENVIRONMENT OF
WORK (PER MEXICAN NOM-010 STPS-1999): 0
| 12. ECOLOGICAL INFORMATION | |
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL
CONTAMINATION.
MOBILITY: THIS PRODUCT HAS NOT BEEN TESTED FOR MOBILITY IN SOIL.
PERSISTENCE AND BIODEGRADABILITY:
THIS PRODUCT HAS NOT BEEN TESTED FOR PERSISTENCE OR BIODEGRADABILITY.
THE MINERAL COMPONENTS ARE NOT EXPECTED TO BIODEGRADE TO GREAT EXTENT.
BIO-ACCUMULATION POTENTIAL:
THIS PRODUCT HAS NOT BEEN TESTED FOR BIO-ACCUMULATION POTENTIAL.
ECOTOXICITY:
THIS PRODUCT HAS NOT BEEN TESTED FOR AQUATIC OR ANIMAL TOXICITY. ALL
RELEASES TO TERRESTRIAL, ATMOSPHERIC AND AQUATIC ENVIRONMENTS SHOULD BE
AVOIDED. NO AQUATIC TOXICITY DATA ARE AVAILABLE FOR COMPONENTS.
OTHER ADVERSE EFFECTS:
THIS MATERIAL IS NOT LISTED AS HAVING OZONE DEPLETION POTENTIAL.
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO
WATERWAYS.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
IT IS THE RESPONSIBILITY OF THE GENERATOR TO DETERMINE AT THE TIME OF
DISPOSAL WHETHER THE PRODUCT MEETS THE CRITERIA OF A HAZARDOUS WASTE PER
REGULATIONS OF THE AREA IN WHICH THE WASTE IS GENERATED AND/OR DISPOSED OF.
WASTE DISPOSAL MUST BE IN ACCORDANCE WITH APPROPRIATE FEDERAL, STATE, AND
LOCAL REGULATIONS. THIS PRODUCT, IF UNALTERED BY USE, MAY BE DISPOSED OF BY
TREATMENT AT A PERMITTED FACILITY OR AS ADVISED BY YOUR LOCAL HAZARDOUS
WASTE REGULATORY AUTHORITY. SHIPMENT OF WASTES MUST BE DONE WITH
APPROPRIATELY PERMITTED AND REGISTERED TRANSPORTERS.
DISPOSAL CONTAINERS:
WASTE MATERIALS MUST BE PLACED IN AND SHIPPED IN APPROPRIATE 5-GALLON OR
55-GALLON POLY OR METAL WASTE PAILS OR DRUMS. PERMEABLE CARDBOARD
CONTAINERS ARE NOT APPROPRIATE AND SHOULD NOT BE USED. ENSURE THAT ANY
REQUIRED MARKING OR LABELING OF THE CONTAINERS BE DONE TO ALL APPLICABLE
REGULATIONS.
PRECAUTIONS TO BE FOLLOWED DURING WASTE HANDLING:
WEAR PROPER PROTECTIVE EQUIPMENT WHEN HANDLING WASTE MATERIALS.
U.S. EPA WASTE NUMBER: NOT APPLICABLE.
| 14. TRANSPORTATION INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER U.S. DOT
REGULATIONS, UNDER 49 CFR 172.101.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER REGULATIONS OF
TRANSPORT CANADA.
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS UNDER RULES OF IATA.
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS BY THE INTERNATIONAL
MARITIME ORGANIZATION.
OFFICIAL MEXICAN STANDARD; REGULATION FOR THE TRANSPORT OF DANGEROUS GOODS
AND RESIDUES:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER TRANSPORT
REGULATIONS OF MEXICO.
SINGAPORE STANDARD 286:
PART A:
THIS PRODUCT HAS NO REQUIREMENTS UNDER THE SPECIFICATION FOR CAUTION
LABELING FOR HAZARDOUS SUBSTANCES, PART 4:
MARKING OF PACKAGES, CONTAINERS AND VEHICLES, AS IT DOES NOT MEET THE
CRITERIA FOR ANY HAZARD CLASS UNDER THIS REGULATION.
TRANSPORT IN BULK ACCORDING TO THE IBC CODE:
SEE THE INFORMATION UNDER THE INDIVIDUAL JURISDICTION LISTINGS FOR IBC
INFORMATION.
ENVIRONMENTAL HAZARDS:
THIS MATERIAL DOES NOT MEET THE CRITERIA OF ENVIRONMENTALLY HAZARDOUS
ACCORDING TO THE CRITERIA OF THE UN MODEL REGULATIONS (AS REFLECTED IN THE
IMDG CODE, ADR, RID, AND ADN) AND IS NOT LISTED IN ANNEX III UNDER MARPOL
73/78.
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS OF SECTIONS 302,
304, AND 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT.
U.S. SARA HAZARD CATEGORIES (SECTION 311/312, 40 CFR 370-21):
ACUTE: NO
CHRONIC: YES
FIRE: NO
REACTIVE: NO
SUDDEN RELEASE: NO
U.S. SARA THRESHOLD PLANNING QUANTITY (TPQ):
THERE ARE NO SPECIFIC THRESHOLD PLANNING QUANTITIES FOR COMPONENTS. THE
DEFAULT FEDERAL SDS SUBMISSION AND INVENTORY REQUIREMENT FILING THRESHOLD
OF 10,000 LB (4,540 KG) MAY APPLY, PER 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): NOT APPLICABLE.
U.S. TSCA INVENTORY STATUS:
COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
THE MINERAL WOOL COMPONENT (LISTED AS GLASS WOOL FIBER) IS ON THE
CALIFORNIA PROPOSITION 65 LISTS.
WARNING!
THIS PRODUCT CONTAINS A COMPOUND KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS:
COMPONENTS ARE ON THE DSL OR NDSL INVENTORIES.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS:
COMPONENTS ARE NOT ON THE CEPA PRIORITIES SUBSTANCES LISTS.
CANADIAN WHMIS CLASSIFICATION AND SYMBOLS:
THIS PRODUCT WOULD BE CATEGORIZED AS A CONTROLLED PRODUCT, D2B (OTHER
TOXIC EFFECTS-POTENTIAL CARCINOGENIC EFFECT, IRRITATION) AS PER THE
CONTROLLED PRODUCT REGULATIONS.
CHINESE REGULATIONS:
CHINESE INVENTORY OF EXISTING CHEMICAL SUBSTANCES STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE CHINESE INVENTORY OF
EXISTING CHEMICAL SUBSTANCES (IECSC).
JAPANESE REGULATIONS:
JAPANESE ENCS:
COMPONENTS LISTED BY CAS# ARE ON THE ENCS INVENTORY OR ARE EXCEPTED.
JAPANESE MINISTRY OF ECONOMY, TRADE, AND INDUSTRY (METI) STATUS:
COMPONENTS ARE NOT LISTED AS CLASS I SPECIFIED CHEMICAL SUBSTANCES,
CLASS II SPECIFIED CHEMICAL SUBSTANCES, OR DESIGNATED CHEMICAL SUBSTANCES
BY THE JAPANESE METI.
POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW:
COMPONENTS ARE NOT LISTED AS A SPECIFIED POISONOUS SUBSTANCE UNDER THE
POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW.
KOREAN REGULATIONS:
KOREAN EXISTING CHEMICALS LIST (ECL) STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE KOREAN ECL INVENTORY.
MEXICAN REGULATIONS:
MEXICAN WORKPLACE REGULATIONS (NOM-018-STPS-2000):
THIS PRODUCT IS CLASSIFIED AS HAZARDOUS.
SINGAPORE REGULATIONS:
LIST OF CONTROLLED HAZARDOUS SUBSTANCES:
COMPONENTS LISTED BY CAS# ARE NOT LISTED ON THE SINGAPORE LIST OF
CONTROLLED SUBSTANCES.
CODE OF PRACTICE ON POLLUTION CONTROL REQUIREMENTS:
THE COMPONENTS IDENTIFIED BY CAS# IN SECTION 2 (COMPOSITION AND
INFORMATION ON INGREDIENTS) NOT ARE SUBJECT TO THE REQUIREMENTS UNDER
THE SINGAPORE CODE OF PRACTICE ON POLLUTION CONTROL.
TAIWANESE REGULATIONS:
TAIWAN EXISTING CHEMICAL SUBSTANCES INVENTORY STATUS:
CURRENTLY, IT CANNOT BE DETERMINED IF COMPONENTS ARE LISTED ON THE TAIWAN
EXISTING CHEMICALS LIST.
| 16. OTHER INFORMATION | |
LABELING (PRECAUTIONARY STATEMENTS) ANSI LABELING (Z129.1):
CAUTION!
IF RELEASED TO THE AIR, PARTICULATES FROM MINERAL WOOL MAY CAUSE IRRITATION
BY INHALATION AND EYE CONTACT. CONTAINS SUSPECT CARCINOGEN BY INHALATION
AVOID BREATHING PARTICULATES. DO NOT TASTE OR SWALLOW. KEEP CONTAINER
CLOSED. USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
WEAR APPROPRIATE EYE, HAND, AND BODY PROTECTION. AVOID EXPOSURE TO ELEVATED
TEMPERATURES.
FIRST-AID:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN OR EYES WITH PLENTY OF WATER FOR
AT LEAST 20 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET
MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. IF INHALED, REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.
IN CASE OF FIRE: USE WATER FOG, FOAM, DRY CHEMICAL, OR CO2.
IN CASE OF SPILL:
SWEEP OR VACUUM SPILLED MATERIAL, AVOIDING GENERATION OF DUSTS AND
PLACE IN SUITABLE CONTAINER. PLACE RESIDUAL IN APPROPRIATE CONTAINER AND
SEAL. DISPOSE OF IN ACCORDANCE WITH U.S. FEDERAL, STATE, AND LOCAL
HAZARDOUS WASTE DISPOSAL REGULATIONS. CONSULT SAFETY DATA SHEET FOR
ADDITIONAL INFORMATION.
GLOBAL HARMONIZATION AND JAPANESE JIS Z7253 LABELING AND CLASSIFICATION:
THIS PRODUCT HAS BEEN CLASSIFIED PER UN GHS STANDARDS UNDER U.S., JAPANESE
AND OTHER APPLICABLE REGULATIONS THAT REQUIRE GLOBAL HARMONIZATION
COMPLIANCE.
CLASSIFICATION:
CARCINOGENIC CATEGORY 2, EYE IRRITATION CATEGORY 2A, SPECIFIC TARGET ORGAN
TOXICITY (INHALATION-RESPIRATORY IRRITATION) SINGLE EXPOSURE CATEGORY 3
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H350I: MAY CAUSE CANCER BY INHALATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P261: AVOID BREATHING VAPORS, FUME.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES, CLOTHING, EYE PROTECTION AND FACE PROTECTION.
P284: WEAR RESPIRATORY PROTECTION.
RESPONSE:
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P304 + P340:
IF INHALED, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION
COMFORTABLE FOR BREATHING.
P312: CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
P321: SPECIFIC TREATMENT (REMOVE FROM EXPOSURE AND TREAT SYMPTOMS).
STORAGE:
P403 + P233 + P405:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINERS IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARD SYMBOLS: GHS07, GHS08
KOREAN ISHA (NOTICE 2009-68) LABELING AND CLASSIFICATION:
CLASSIFIED IN ACCORDANCE WITH ISHA NOTICE 2009-68. UNDER ISHA, NO
DIFFERENCES IN CLASSIFICATION ARE APPLICABLE.
COMPONENT CLASSIFICATION:
LABELING AND CLASSIFICATION FULL TEXT UNDER GHS:
GRAPHITE: THIS IS A SELF-CLASSIFICATION.
CLASSIFICATION:
EYE IRRITATION CATEGORY 2B, SPECIFIC TARGET ORGAN TOXICITY
(INHALATION-RESPIRATORY IRRITATION) SINGLE EXPOSURE CATEGORY 3
HAZARD STATEMENTS:
H320: CAUSES EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
MINERAL WOOL: THIS IS A SELF-CLASSIFICATION.
CLASSIFICATION:
CARCINOGENIC CATEGORY 2, EYE IRRITATION CATEGORY 2A, SPECIFIC TARGET ORGAN
TOXICITY (INHALATION-RESPIRATORY IRRITATION) SINGLE EXPOSURE CATEGORY 3
HAZARD STATEMENTS:
H350I: MAY CAUSE CANCER BY INHALATION.
H319:
CAUSES SERIOUS EYE IRRITATION. SPECIFIC TARGET ORGAN TOXICITY
(INHALATION-RESPIRATORY IRRITATION) SINGLE EXPOSURE CATEGORY 3
REVISION DETAILS: NEW.
REFERENCES AND DATA SOURCES: CONTACT THE SUPPLIER FOR INFORMATION.
METHODS OF EVALUATING INFORMATION FOR THE PURPOSE OF CLASSIFICATION:
CRITERIA OF THE GHS WERE USED FOR CLASSIFICATION.
PREPARED BY:
CHEMICAL SAFETY ASSOCIATES, INC.
PO BOX 1961
HILO, HI 96721-1961
(800) 441-3365
DATE OF PRINTING: MAY 29, 2015
REVISION HISTORY: NEW.
EFFECTIVE DATE: JANUARY 29, 2015