| Common Name: | DRY LAYUP ADHESIVE 09091,16.5 OZ, RED |
| Manufacturer: | 3M |
| SDS Revision Date: | 1/21/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 3RAL5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM)DRY LAYUP ADHESIVE 09091, 16.5 OZ, RED
01/21/19
3M
SAFETY DATA SHEET
COPYRIGHT, 2019, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 20-5777-6
VERSION NUMBER: 11.00
ISSUE DATE: 01/21/19
SUPERCEDES DATE: 05/21/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM)DRY LAYUP ADHESIVE 09091, 16.5 OZ, RED
PRODUCT IDENTIFICATION NUMBERS:
60-4300-5068-6
7100010064
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE
RESTRICTIONS ON USE:
NOT FOR SALE OR USE IN CA, CT, DE, IL, IN, MA, MD, ME, MI, NH, NJ, NY, OH,
PA, RI, UT, VA AND DISTRICT OF COLUMBIA.
CONSULT LOCAL AIR QUALITY RULES
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION:
ELECTRICAL MARKETS DIVISION
MARINE & SPECIALTY VEHICLE
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE AEROSOL: CATEGORY 1.
GAS UNDER PRESSURE: LIQUEFIED GAS.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SIMPLE ASPHYXIANT.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM |
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
SUPPLEMENTAL INFORMATION:
INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
15% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
NON-VOLATILE COMPONENTS - N.J. TRADE TRADE SECRET* 20 - 30
SECRET REGISTRY NO. 04499600-5776P
CYCLOHEXANE 110-82-7 10 - 20 TRADE SECRET *
2,3-DIMETHYLBUTANE 79-29-8 <15 TRADE SECRET *
2-METHYLPENTANE 107-83-5 <15 TRADE SECRET *
3-METHYLPENTANE 96-14-0 <15 TRADE SECRET *
DIMETHYL ETHER 115-10-6 5 - 15 TRADE SECRET *
ISOBUTANE 75-28-5 5 - 15 TRADE SECRET *
NEOHEXANE 75-83-2 <15 TRADE SECRET *
PROPANE 74-98-6 5 - 15 TRADE SECRET *
PENTANE 109-66-0 <2 TRADE SECRET *
HEXANE 110-54-3 <1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN BROMIDE DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE. WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED,
POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT AND
PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, AND PROTECTIVE
COVERING FOR EXPOSED AREAS OF THE HEAD.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
IF POSSIBLE, SEAL LEAKING CONTAINER. PLACE LEAKING CONTAINERS IN A
WELL-VENTILATED AREA, PREFERABLY AN OPERATING EXHAUST HOOD, OR IF NECESSARY
OUTDOORS ON AN IMPERMEABLE SURFACE UNTIL APPROPRIATE PACKAGING FOR THE
LEAKING CONTAINER OR ITS CONTENTS IS AVAILABLE. CLOSE CYLINDER. CONTAIN
SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN APPROPRIATE
AQUEOUS FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM AROUND THE
EDGES OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR
COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT
ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES
NOT REMOVE A TOXIC, CORROSIVITY OR FLAMMABILITY HAZARD. COLLECT AS MUCH OF
THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL/OCCUPATIONAL USE ONLY. NOT FOR CONSUMER SALE OR USE. DO NOT
USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM
HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN
FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO
NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN,
OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH OXIDIZING AGENTS (EG.
CHLORINE, CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES,
RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. PROTECT
FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM HEAT.
STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
2-METHYLPENTANE 107-83-5 ACGIH TWA: 500 PPM;
STEL: 1000 PPM
PENTANE 109-66-0 ACGIH TWA: 1000 PPM
PENTANE 109-66-0 OSHA TWA:
2950 MG/M3(1000
PPM)
HEXANE 110-54-3 ACGIH TWA: 50 PPM SKIN
HEXANE 110-54-3 OSHA TWA:
1800 MG/M3(500
PPM)
CYCLOHEXANE 110-82-7 ACGIH TWA: 100 PPM
CYCLOHEXANE 110-82-7 OSHA TWA:
1050 MG/M3(300
PPM)
DIMETHYL ETHER 115-10-6 AIHA TWA:
1880 MG/M3(1000
PPM)
PROPANE 74-98-6 ACGIH LIMIT VALUE NOT SIMPLE ASPHYXIANT
ESTABLISHED:
PROPANE 74-98-6 OSHA TWA:
1800 MG/M3(1000
PPM)
ISOBUTANE 75-28-5 ACGIH STEL: 1000 PPM
NATURAL GAS 75-28-5 ACGIH LIMIT VALUE NOT SIMPLE ASPHYXIANT
ESTABLISHED:
NEOHEXANE 75-83-2 ACGIH TWA: 500 PPM;
STEL: 1000 PPM
2,3-DIMETHYL- 79-29-8 ACGIH TWA: 500 PPM;
BUTANE STEL: 1000 PPM
3-METHYL- 96-14-0 ACGIH TWA: 500 PPM;
PENTANE STEL: 1000 PPM
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
DO NOT REMAIN IN AREA WHERE AVAILABLE OXYGEN MAY BE REDUCED. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
ORGANIC VAPOR RESPIRATORS MAY HAVE SHORT SERVICE LIFE.
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: GAS
ODOR, COLOR, GRADE: DARK RED, SWEET/FRUITY ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: APPROXIMATELY 6.7
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: -42.00 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP]
EVAPORATION RATE: 1.9 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): FLAMMABLE AEROSOL: CATEGORY 1.
FLAMMABLE LIMITS(LEL): APPROXIMATELY 1.5% VOLUME
FLAMMABLE LIMITS(UEL): APPROXIMATELY 8.6% VOLUME
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: 2.97 [REF STD: AIR=1]
DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY: 0.697 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
AVERAGE PARTICLE SIZE: NO DATA AVAILABLE
BULK DENSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: <=1% WEIGHT
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: 75%
PERCENT VOLATILE: 75% WEIGHT
SOFTENING POINT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
527 G/L [TEST METHOD: TESTED PER SCAQMD METHOD 305]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: COMBUSTIBLES
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
SIMPLE ASPHYXIATION:
SIGNS/SYMPTOMS MAY INCLUDE INCREASED HEART RATE, RAPID RESPIRATIONS,
DROWSINESS, HEADACHE, INCOORDINATION, ALTERED JUDGMENT, NAUSEA, VOMITING,
LETHARGY, SEIZURES, COMA, AND MAY BE FATAL.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
SINGLE EXPOSURE, ABOVE RECOMMENDED GUIDELINES, MAY CAUSE:
CARDIAC SENSITIZATION:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS,
CHEST PAIN, AND MAY BE FATAL.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
2-METHYLPENTANE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
2-METHYLPENTANE INHALATION- LC50 ESTIMATED TO BE: >50 MG/L
VAPOR
2-METHYLPENTANE INGESTION LD50 ESTIMATED TO BE:
>5,000 MG/KG
3-METHYLPENTANE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
3-METHYLPENTANE INHALATION- LC50 ESTIMATED TO BE: >50 MG/L
VAPOR
3-METHYLPENTANE INGESTION LD50 ESTIMATED TO BE:
>5,000 MG/KG
ISOBUTANE INHALATION- RAT LC50: 276,000 PPM
GAS (4
HOURS)
PROPANE INHALATION- RAT LC50: >200,000 PPM
GAS (4
HOURS)
CYCLOHEXANE DERMAL RAT LD50: >2,000 MG/KG
CYCLOHEXANE INHALATION- RAT LC50: >32.9 MG/L
VAPOR (4
HOURS)
CYCLOHEXANE INGESTION RAT LD50: 6,200 MG/KG
2,3-DIMETHYLBUTANE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
2,3-DIMETHYLBUTANE INHALATION- LC50 ESTIMATED TO BE: >50 MG/L
VAPOR
2,3-DIMETHYLBUTANE INGESTION LD50 ESTIMATED TO BE:
>5,000 MG/KG
NEOHEXANE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
NEOHEXANE INHALATION- LC50 ESTIMATED TO BE: >50 MG/L
VAPOR
NEOHEXANE INGESTION LD50 ESTIMATED TO BE:
>5,000 MG/KG
DIMETHYL ETHER INHALATION- RAT LC50: 164,000 PPM
GAS (4
HOURS)
NON-VOLATILE DERMAL LD50 ESTIMATED TO BE:
COMPONENTS - N.J. >5,000 MG/KG
TRADE SECRET
REGISTRY NO.
04499600-5776P
NON-VOLATILE INGESTION LD50 ESTIMATED TO BE:
COMPONENTS - N.J. 2,000 - 5,000 MG/KG
TRADE SECRET
REGISTRY NO.
04499600-5776P
PENTANE DERMAL RABBIT LD50: 3,000 MG/KG
PENTANE INHALATION- RAT LC50: >18 MG/L
VAPOR (4
HOURS)
PENTANE INGESTION RAT LD50: >2,000 MG/KG
HEXANE DERMAL RABBIT LD50: >2,000 MG/KG
HEXANE INHALATION- RAT LC50: 170 MG/L
VAPOR (4
HOURS)
HEXANE INGESTION RAT LD50: >28,700 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
2-METHYLPENTANE PROFESSIONAL JUDGMENT MILD IRRITANT
3-METHYLPENTANE PROFESSIONAL JUDGMENT MILD IRRITANT
ISOBUTANE PROFESSIONAL JUDGMENT NO SIGNIFICANT
IRRITATION
PROPANE RABBIT MINIMAL IRRITATION
CYCLOHEXANE RABBIT MILD IRRITANT
2,3-DIMETHYLBUTANE PROFESSIONAL JUDGMENT MILD IRRITANT
NEOHEXANE PROFESSIONAL JUDGMENT MILD IRRITANT
NON-VOLATILE COMPONENTS - PROFESSIONAL JUDGMENT MINIMAL IRRITATION,
N.J. TRADE SECRET REGISTRY
NO. 04499600-5776P
PENTANE RABBIT MINIMAL IRRITATION
HEXANE HUMAN AND ANIMAL MILD IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
2-METHYLPENTANE PROFESSIONAL JUDGMENT MODERATE IRRITANT
3-METHYLPENTANE PROFESSIONAL JUDGMENT MODERATE IRRITANT
ISOBUTANE PROFESSIONAL JUDGMENT NO SIGNIFICANT
IRRITATION
PROPANE RABBIT MILD IRRITANT
CYCLOHEXANE RABBIT MILD IRRITANT
2,3-DIMETHYLBUTANE PROFESSIONAL JUDGMENT MODERATE IRRITANT
NEOHEXANE PROFESSIONAL JUDGMENT MODERATE IRRITANT
PENTANE RABBIT MILD IRRITANT
HEXANE RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
PENTANE GUINEA PIG NOT CLASSIFIED
HEXANE HUMAN NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ISOBUTANE IN VITRO NOT MUTAGENIC
PROPANE IN VITRO NOT MUTAGENIC
CYCLOHEXANE IN VITRO NOT MUTAGENIC
CYCLOHEXANE IN VIVO SOME POSITIVE DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
DIMETHYL ETHER IN VITRO NOT MUTAGENIC
DIMETHYL ETHER IN VIVO NOT MUTAGENIC
PENTANE IN VIVO NOT MUTAGENIC
PENTANE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
HEXANE IN VITRO NOT MUTAGENIC
HEXANE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIMETHYL ETHER INHALATION RAT NOT CARCINOGENIC
HEXANE DERMAL MOUSE NOT CARCINOGENIC
HEXANE INHALATION MOUSE SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
CYCLOHEXANE INHALATION NOT RAT NOAEL: 2
CLASSIFIED 24 MG/L GENERATION
FOR FEMALE
REPRODUCTION
CYCLOHEXANE INHALATION NOT RAT NOAEL: 2
CLASSIFIED 24 MG/L GENERATION
FOR MALE
REPRODUCTION
CYCLOHEXANE INHALATION NOT RAT NOAEL: 2
CLASSIFIED 6.9 MG/L GENERATION
FOR
DEVELOPMENT
DIMETHYL INHALATION NOT RAT NOAEL: DURING
ETHER CLASSIFIED 40,000 PPM ORGANOGENESIS
FOR
DEVELOPMENT
PENTANE INGESTION NOT RAT NOAEL: DURING
CLASSIFIED 1,000 ORGANOGENESIS
FOR MG/KG/DAY
DEVELOPMENT
PENTANE INHALATION NOT RAT NOAEL: DURING
CLASSIFIED 30 MG/L ORGANOGENESIS
FOR
DEVELOPMENT
HEXANE INGESTION NOT MOUSE NOAEL: DURING
CLASSIFIED 2,200 ORGANOGENESIS
FOR MG/KG/DAY
DEVELOPMENT
HEXANE INHALATION NOT RAT NOAEL: DURING
CLASSIFIED 0.7 MG/L GESTATION
FOR
DEVELOPMENT
HEXANE INGESTION TOXIC TO RAT NOAEL: 90 DAYS
MALE 1,140
REPRODUCTION MG/KG/DAY
HEXANE INHALATION TOXIC TO RAT LOAEL: 28 DAYS
MALE 3.52 MG/L
REPRODUCTION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-METHYLPENTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
2-METHYLPENTANE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2-METHYLPENTANE INHALATION CARDIAC NOT CLASSIFIED
SENSITIZATION
2-METHYLPENTANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
3-METHYLPENTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
3-METHYLPENTANE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
3-METHYLPENTANE INHALATION CARDIAC NOT CLASSIFIED
SENSITIZATION
3-METHYLPENTANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ISOBUTANE INHALATION CARDIAC CAUSES DAMAGE TO ORGANS
SENSITIZATION
ISOBUTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ISOBUTANE INHALATION RESPIRATORY NOT CLASSIFIED
IRRITATION
PROPANE INHALATION CARDIAC CAUSES DAMAGE TO ORGANS
SENSITIZATION
PROPANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
PROPANE INHALATION RESPIRATORY NOT CLASSIFIED
IRRITATION
CYCLOHEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
CYCLOHEXANE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CYCLOHEXANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
2,3-DIMETHYL- INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
BUTANE SYSTEM DEPRESSION DIZZINESS
2,3-DIMETHYL- INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
BUTANE IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
2,3-DIMETHYL- INHALATION CARDIAC NOT CLASSIFIED
BUTANE SENSITIZATION
2,3-DIMETHYL- INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
BUTANE SYSTEM DEPRESSION DIZZINESS
NEOHEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
NEOHEXANE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NEOHEXANE INHALATION CARDIAC NOT CLASSIFIED
SENSITIZATION
NEOHEXANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
DIMETHYL ETHER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
DIMETHYL ETHER INHALATION CARDIAC SOME POSITIVE DATA EXIST,
SENSITIZATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PENTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
PENTANE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
PENTANE INHALATION CARDIAC NOT CLASSIFIED
SENSITIZATION
PENTANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
HEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
HEXANE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HEXANE INHALATION RESPIRATORY NOT CLASSIFIED
SYSTEM
NAME SPECIES TEST RESULT EXPOSURE
DURATION
2-METHYLPENTANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
2-METHYLPENTANE NOAEL: NOT AVAILABLE
2-METHYLPENTANE DOG NOAEL: NOT AVAILABLE
2-METHYLPENTANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
3-METHYLPENTANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
3-METHYLPENTANE NOAEL: NOT AVAILABLE
3-METHYLPENTANE DOG NOAEL: NOT AVAILABLE
3-METHYLPENTANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
ISOBUTANE MULTIPLE ANIMAL NOAEL: NOT AVAILABLE
SPECIES
ISOBUTANE HUMAN AND ANIMAL NOAEL: NOT AVAILABLE
ISOBUTANE MOUSE NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
CYCLOHEXANE HUMAN AND ANIMAL NOAEL: NOT AVAILABLE
CYCLOHEXANE HUMAN AND ANIMAL NOAEL: NOT AVAILABLE
CYCLOHEXANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
2,3-DIMETHYL- PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
BUTANE
2,3-DIMETHYL- NOAEL: NOT AVAILABLE
BUTANE
2,3-DIMETHYL- DOG NOAEL: NOT AVAILABLE
BUTANE
2,3-DIMETHYL- PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
BUTANE
NEOHEXANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
NEOHEXANE NOAEL: NOT AVAILABLE
NEOHEXANE DOG NOAEL: NOT AVAILABLE
NEOHEXANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE
DIMETHYL ETHER RAT LOAEL: 10,000 PPM 30 MINUTES
DIMETHYL ETHER DOG NOAEL: 100,000 PPM 5 MINUTES
PENTANE MULTIPLE ANIMAL NOAEL: NOT AVAILABLE NOT AVAILABLE
SPECIES
PENTANE NOT AVAILABLE NOAEL: NOT AVAILABLE NOT AVAILABLE
PENTANE DOG NOAEL: NOT AVAILABLE NOT AVAILABLE
PENTANE PROFESSIONAL JUDGMENT NOAEL: NOT AVAILABLE NOT AVAILABLE
HEXANE HUMAN NOAEL: NOT AVAILABLE NOT AVAILABLE
HEXANE RABBIT NOAEL: NOT AVAILABLE 8 HOURS
HEXANE RAT NOAEL: 24.6 MG/L 8 HOURS
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2-METHYLPENTANE INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
2-METHYLPENTANE INGESTION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
2-METHYLPENTANE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
3-METHYLPENTANE INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
3-METHYLPENTANE INGESTION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
3-METHYLPENTANE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
ISOBUTANE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
CYCLOHEXANE INHALATION LIVER NOT CLASSIFIED
CYCLOHEXANE INHALATION AUDITORY SYSTEM NOT CLASSIFIED
CYCLOHEXANE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
CYCLOHEXANE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
CYCLOHEXANE INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
2,3-DIMETHYL- INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
BUTANE SYSTEM
2,3-DIMETHYL- INGESTION PERIPHERAL NERVOUS NOT CLASSIFIED
BUTANE SYSTEM
2,3-DIMETHYL- INGESTION KIDNEY AND/OR NOT CLASSIFIED
BUTANE BLADDER
NEOHEXANE INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
NEOHEXANE INGESTION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
NEOHEXANE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
DIMETHYL ETHER INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
DIMETHYL ETHER INHALATION LIVER NOT CLASSIFIED
PENTANE INHALATION PERIPHERAL NERVOUS NOT CLASSIFIED
SYSTEM
PENTANE INHALATION HEART | SKIN | NOT CLASSIFIED
ENDOCRINE SYSTEM |
GASTROINTESTINAL
TRACT | BONE,
TEETH, NAILS,
AND/OR HAIR |
HEMATOPOIETIC
SYSTEM | LIVER |
IMMUNE SYSTEM |
MUSCLES | NERVOUS
SYSTEM | EYES |
KIDNEY AND/OR
BLADDER |
RESPIRATORY
SYSTEM
PENTANE INGESTION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
HEXANE INHALATION PERIPHERAL NERVOUS CAUSES DAMAGE TO
SYSTEM ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
HEXANE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HEXANE INHALATION LIVER NOT CLASSIFIED
HEXANE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
HEXANE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
HEXANE INHALATION AUDITORY SYSTEM | NOT CLASSIFIED
IMMUNE SYSTEM |
EYES
HEXANE INHALATION HEART | SKIN | NOT CLASSIFIED
ENDOCRINE SYSTEM
HEXANE INGESTION PERIPHERAL NERVOUS SOME POSITIVE DATA
SYSTEM EXIST, BUT THE
DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HEXANE INGESTION ENDOCRINE SYSTEM | NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM | LIVER |
IMMUNE SYSTEM |
KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
2-METHYLPENTANE RAT NOAEL: 5.3 MG/L 14 WEEKS
2-METHYLPENTANE RAT NOAEL: NOT AVAILABLE 8 WEEKS
2-METHYLPENTANE RAT LOAEL: 2,000 MG/KG 28 DAYS
3-METHYLPENTANE RAT NOAEL: 5.3 MG/L 14 WEEKS
3-METHYLPENTANE RAT NOAEL: NOT AVAILABLE 8 WEEKS
3-METHYLPENTANE RAT LOAEL: 2,000 MG/KG 28 DAYS
ISOBUTANE RAT NOAEL: 4,500 PPM 13 WEEKS
CYCLOHEXANE RAT NOAEL: 24 MG/L 90 DAYS
CYCLOHEXANE RAT NOAEL: 1.7 MG/L 90 DAYS
CYCLOHEXANE RABBIT NOAEL: 2.7 MG/L 10 WEEKS
CYCLOHEXANE MOUSE NOAEL: 24 MG/L 14 WEEKS
CYCLOHEXANE RAT NOAEL: 8.6 MG/L 30 WEEKS
2,3-DIMETHYL- RAT NOAEL: 5.3 MG/L 14 WEEKS
BUTANE
2,3-DIMETHYL- RAT NOAEL: NOT AVAILABLE 8 WEEKS
BUTANE
2,3-DIMETHYL- RAT LOAEL: 2,000 MG/KG 28 DAYS
BUTANE
NEOHEXANE RAT NOAEL: 5.3 MG/L 14 WEEKS
NEOHEXANE RAT NOAEL: NOT AVAILABLE 8 WEEKS
NEOHEXANE RAT LOAEL: 2,000 MG/KG 28 DAYS
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 20,000 PPM 30 WEEKS
PENTANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
PENTANE RAT NOAEL: 20 MG/L 13 WEEKS
PENTANE RAT NOAEL: 28 DAYS
2,000 MG/KG/DAY
HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
HEXANE MOUSE LOAEL: 1.76 MG/L 13 WEEKS
HEXANE RAT NOAEL: NOT AVAILABLE 6 MONTHS
HEXANE RAT LOAEL: 1.76 MG/L 6 MONTHS
HEXANE MOUSE NOAEL: 35.2 MG/L 13 WEEKS
HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
HEXANE RAT NOAEL: 1.76 MG/L 6 MONTHS
HEXANE RAT NOAEL: 90 DAYS
1,140 MG/KG/DAY
HEXANE RAT NOAEL: NOT AVAILABLE 13 WEEKS
ASPIRATION HAZARD:
NAME VALUE
2-METHYLPENTANE ASPIRATION HAZARD
3-METHYLPENTANE ASPIRATION HAZARD
CYCLOHEXANE ASPIRATION HAZARD
2,3-DIMETHYLBUTANE ASPIRATION HAZARD
NEOHEXANE ASPIRATION HAZARD
PENTANE ASPIRATION HAZARD
HEXANE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. FACILITY MUST BE
CAPABLE OF HANDLING AEROSOL CANS. COMBUSTION PRODUCTS WILL INCLUDE HALOGEN
ACID (HCL/HF/HBR). FACILITY MUST BE CAPABLE OF HANDLING HALOGENATED
MATERIALS. AS A DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE
DISPOSAL FACILITY. THE FACILITY SHOULD BE EQUIPPED TO HANDLE GASEOUS WASTE.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D001 (IGNITABLE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
GAS UNDER PRESSURE
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
SERIOUS EYE DAMAGE OR EYE IRRITATION
SIMPLE ASPHYXIANT
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
CYCLOHEXANE 110-82-7 TRADE SECRET 10 - 20
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
N-HEXANE 110-54-3 MALE REPRODUCTIVE TOXIN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
SPECIAL HAZARDS NONE
AEROSOL STORAGE CODE: 3
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 20-5777-6
VERSION NUMBER: 11.00
ISSUE DATE: 01/21/19
SUPERCEDES DATE: 05/21/18
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